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By XUEWEN WANG, Changda Zhang, Huaguang Wang, Mingyu Wang, Bin Hu

The copper smelting process produces plenty of copper slag every year, which is a hazardous solid waste, but a secondary resource. In the present study, the extraction of copper, nickel, and cobalt from copper slag was investigated through the process of sulfation roasting–water leaching and the process of sulfation roasting–sulfate decomposition roasting–water leaching respectively. Compared with the process of sulfation roasting–water leaching, the process of sulfation roasting–sulfate decomposition roasting–water leaching is a better choice, which could not only get almost the same leaching of copper, nickel, and cobalt as the former process, but has a lower leaching of iron and aluminum. For the process of sulfation roasting–sulfate decomposition roasting–water leaching, the leaching of Cu, Ni, and Co reached up to 74.2%, 71.1%, and 69.6% respectively, under the optimal conditions including sulfation roasted with 80 wt% sulfuric acid addition at 200 °C for 60 min and sulfate decomposition roasted at 650 °C for 60 min, followed by water leached at 90 °C for 30min with a liquid–solid ratio of 2 ml/g. The leaching of Fe and Al was only 4.9% and 17.6%.

May 4, 2020

By Jr. Moulton

Extractions of minerals from Searles Lake brines have taken place since 1873. Early operations were for borax and raw trona found on the surface, expanded after 1914 to include potash, salt cake, and soda ash. A new soda ash plant now in operation will double area production. The evaporite beds were formed by desiccation of Eastern Sierra runoff. The resulting series of brine-bearing salt beds supply the fluids necessary to feed the area chemical plants. Production methods include evaporation and crystallization for potash, borax, and salt cake; carbonation of brine to recover soda ash; and organic extraction of borax.

Jan 1, 1980

By R. L. Zick

The High Density Sludge Process was originally developed by Bethlehem Steel Corporation for use on acid mine drainage and diluted waste pickle liquor discharges requiring continuous chemical treatment systems. This work began in the early 1970s and was first put into practical use around 1973. To date there are approximately 15 operating systems which have been installed on mine drainage in the United States, and another 10 systems worldwide. Dense Sludge is an innovative and improved method for treating acidic metal bearing streams in a manner which minimizes the volumetric generation of sludge for disposal. The technology utilizes a sludge recycle process which forms particles that have a low affinity for water, unlike conventional metal hydroxide solids which contain tightly bound interstitial waters. Typical acid mine drainage streams contain high sulfate concentrations which combine with calcium ions in lime based treatment systems to form gypsum crystals. The physical form of this gypsum is radically altered when the Dense Sludge process is utilized compared to the form generated in conventional lime treatment systems. The characteristics of the metals particles are also changed in this process, as the metal hydroxides are converted to metal oxides. Slides No. 1 and No.2 show scanning electron micrographs of conventional and densified sludges illustrating these differences. The magnification used was 300X. The dense sludge particles settle faster, dewater more readily, are more easily pumped, and hold much less water than conventional precipitates. In some cases, because the metal content of the sludge is more concentrated, it can be economically recovered.

Jan 1, 1998

By Ellen Amoako Afful, Michael Moats, Guang Xu, Ashish Kakoria

Electrowinning and solvent extraction are crucial steps in the production of high-purity copper. However, safety concerns have been raised regarding the acid mist generated from the electrowinning process. The mist generated results in health risks to workers and damage to machinery and infrastructure. Currently, chemicals and pellets are used to control acid mist. However, the effectiveness of these controls may vary depending on the type of organic solvent used in the solvent extraction process, which can influence the generation of acid mist. This study aims to evaluate the impacts of organic solvents and surfactants on acid mist suppression. In this study, an electrolyte is contacted with organic solvents to simulate the solvent extraction. The electrolyte is dosed with 20 mg/L of surfactant at each contact. Acid mist testing is performed on the electrolyte separated from the organic phase at the end of the solvent extraction step. The mist collected is analyzed to determine the level of acid mist generated. The results of this study indicate that organic solvents and surfactants showed significant acid mist suppression, but with somewhat different suppression efficiencies. After first contact, Licorice and the organic, for instance, showed a suppression efficiency of up to 69.7% but its efficiency gradually decreased as the number of contacts increased.

Feb 1, 2025

There are bound to be changes with age, so I should not have been surprised or disappointed when what I had considered as high ad- ventures were much fewer and more widely scattered in the last 20 years of my long and active business life. But such adventures came until I was past 80 years of age and no one could expect more than this. Frequent visits to mines in this country and Canada and directorships in Bralorne and its subsidiaries, Homestake Mining Co., Bradley Mining Co., and the Bunker Hill Co.; and Copper Range Co. and its great new White Pine mine in Michigan, lasted far beyond the usual retirement age. The least happy part of my last two decades of active life was the death or sickness of many of my old friends. Hubert d'Autremont, whose friendship no one could replace, died suddenly in 1946. Henry Carlisle and Temple Bridgeman, for many years office associates, had heart attacks that cut down their activities far too soon. Many other less intimate friends died or became ill, but I knew that with advancing years such losses were inevitable. These memoirs would be endless if they covered all of the unusual work and associations I found in the last 20 years. So I must confine the rest of my recollections to expeditions that would have thrilled any engineer at any time. Masaro Mine, Mindanao, Philippines The first of the four "high adventures" came late in 1949, when I was 65 years old. For over a month I had been discussing reported rich lead-silver-copper properties in the Philippines with Thayer Lindsley and other officers of Panaminas. A competent and agreeable "Elderly" (not as old as I was) engineer named Ward Williams had talked with Thayer about high grade mines in a remote part of the

Jan 1, 1976

By C. J. Webb

Abandoned uranium mines in the southern Black Hills of South Dakota were sampled for uranium, radium, and rare earth elements during 1992 and 1993. Analyses of water samples from several shallow ponds in the mine pits showed pH values between 3 and 4 with uranium concentrations between 1600 and 2600 ppb. Rare earth elements and their respective isotopes were analyzed with an inductively coupled plasma mass spectrometer and were referenced to a shale normalization pattern. All samples showed an enrichment in the middle rare earth elements. Rare earth levels often were greater than 0.2 ppm. At one site, the concentrations of lanthanides were 150,000 times above background levels. While the southern Black Hills have long been known for rich uranium ore deposits, these analyses show that significant levels of rare earth elements also are present, indicating that the potential exist for future development.

Jan 1, 1995

By Werner Bilfinger, Claudio Nahas, Marcelo Waimberg

"INTRODUCTION The so called Porto Maravilha Project consists of the re-urbanization of a 500 ha area in the Rio de Janeiro port region. Several changes in local infrastructure are being implemented, including a significant change in the road system, with the demolition of the former “Via Perimetral” viaduct and construction of 4 new tunnels: • Saúde tunnel - 35 m long (Waimberg et al, 2014); • “Binária tunnel” - 1012 m long; • “Via Expressa” twin tunnels - 1850 m long each way. The tunnels were excavated almost completely in rock using conventional drill and blast methodology and only some short stretches in weathered rock, associated to faults zones, residual soils and marine sediments close to the tunnel portals. During excavation of access shaft and “Via Expressa” and “Binária” tunnels significant ground settlements as well as settlements of buildings founded both on shallow and deep foundations were measured. These values could not be associated to conventional tunneling induced settlement troughs. This paper focuses on the “Via Expressa” tunnels, presenting a brief description of the project as a whole, its geological and geotechnical background, monitoring results, and a discussion of possible causes of the measured settlements. PROJECT DESCRIPTION The Porto Maravilha Project is an integrated multidisciplinary action on behalf of the Rio de Janeiro city council with support from the State and Federal Governments. In addition to creating new conditions for working, housing, transport, culture and leisure for the resident population, it also promotes expressive economic development in the region (Portonovo, 2015). Porto Maravilha Project is carrying out actions for the recovery of the region’s historical heritage, as well as promoting the population´s social and economic development. One of the main benefits of the Porto Maravilha Project is the construction of the new traffic system in the port area, consisting of the Express and Binário roadways. The new project, which will replace the current Perimetral Rodrigues Alves viaduct system, will increase traffic flow capacity by 27%."

Jan 1, 2016

By I. H. Warren

The high temperature lubricant molybdenite, MoS2, is usually produced by a complex sequence of processes involving mineral dressing of molybdenite concentrates followed by leaching with hydrofluoric acid to remove abrasive impurities such as silica (1). Many attempts have been made, mostly by techniques involving, direct fusion of molybdenum compounds with sulphur, to produce synthetic molybdenite. However, apart from some experiments of geochemical interest (2) in which aqueous solutions of sodium sulphomolybdate, Nat MoS4, were decomposed under pressure at temperatures between 300°C and 700°C, no attempts to produce the mineral by hydrometallurgical procedures have been reported. Since molybdenite is nominally a compound of tetravalent molybdenum with sulphur, and the most common state of molybdenum is +6, production of molybdenite is likely to involve reduction and sulphidization. The present study, therefore, describes the reduction, with hydrogen and carbon monoxide, of molybdenum in the hexavalent state in alkaline aqueous solutions containing sulphide ion. In these

Jan 1, 1972

By J. G. Pippenger

The Coteau Properties Company's Freedom Mine is a surface lignite mining operation located near Beulah, North Dakota. As part of the mining process, Coteau removes and replaces thin layers of suitable plant growth material (SPGM) generally ranging in thickness between one and five feet. Historically, tractor-scrapers completed this work; however, rising tractor-scraper costs and increasing haulage distances sent Coteau in search of a lower cost method resulting in the acquisition of a backhoe/truck fleet in 1995.

Jan 1, 1997

By William C. Peters

The Alpine-Himalayan system, the only major active tectonic belt mainly exposed in a continental mass, is of increasing interest to exploration geologists as well as to theoreticians. Answers to the broader problems of plate tectonics are being sought in this intricate system where the geosynclinal concept was born and where the geotectonic cycle was first applied to metallogeny. The search is all the more intense because it involves scientists from more than a dozen countries with a stimulating variety in perspective. The international Geodynamics Project has allocated the Alpine-Himalayan system to two separate study groups with one directing its attention to the Alpine-Mediterranean region and the other giving consideration to the Himalayan region. This geographic division is accepted in this paper, with remarks being confined to the former and to the west of boundary zone between the European-Asian and the Southeast Asian plates as envisioned by Dewey and Bird (1970). The region is well-mapped in some parts and it includes some of the most intensely-studied geology, most classic mines, and newest orebody discoveries. Within the region, an Alpine-age copper-molybdenum metallogenic belt extends from Rumania to Pakistan. The belt can be considered in terms of plate tectonics, and there is the possibility of using plate tectonics concepts in exploration.

Jan 1, 1973

By James R. Strong

Before getting into the subject of packaging and materials management, please permit me to introduce you to MICRO SWITCH. MICRO SWITCH, A Division of Honeywell Inc. is located in Freeport, Illinois. We manufacture and market thousands of types of precision snap-action electrical switches. Most of them are used as components by other manufacturers in industrial and commercial products. MICRO SWITCH also offers a broad line of industrial control devices including heavy- duty limit switches, relays, manual controls and proximity switches. Other product lines are solid state keyboards for the computer industry and high-performance d.c. motors used in computer related equipment. So you can see that we are a component manufacturer. With the exception of the keyboards, every one of our products would "fit comfortably into a breadbox." Some are so tiny that one could easily fit several thousand into a man's hat. In my position as supervisor-packaging. package design, and materials handling engineering, I am actively involved in package design projects, parts handling design projects, and numerous activities involving departmental layouts, storage facilities, and material handling equipment. Two package design technicians, a materials handling engineer, and a materials handling technician make up the technical staff.

Jan 1, 1973

By Yi Luo

A massive roof fall occurred in a small room-and-pillar coal mine. The roof falls occurred under a barrier pillar in a closed coal mine located a short distance above the active mine. The extensive fractures connected the active mine with the old mine, turning them into a “combined mine.” Since completely sealing off the roof fall area is prohibitively expensive for the mine, ventilating the connected old mine became the only option. A comprehensive investigation was conducted to understand the atmospheric condition in the old mine and to find an efficient way to ventilate the “combined mine.” A set of studies involving geology, gas content, pillar stability and mine subsidence were performed to explore whether the closed mine is filled with an explosive air-methane mixture. The air quantity measurement data were used to determine the resistance of the air path formed through the fractured zone. Observations and measurements made from a tour to the underground and mine surface enabled the formulation of simple but effective ways to ventilate the old mine. The ventilation network analysis also suggested methods of control, so that sufficient ventilation air can be directed to the two parts of the old mine.

Jan 1, 2010

By David Crouthamel, Raymond Henn

"The need to fill the void space or annulus created between an excavated tunnel or shaft and the final lining system has long been a requirement in underground construction. Most of those types of voids are created as a result of employing the two pass tunneling lining method. Filling of this void is called backfilling. For many years the materials used as backfill were primarily reinforced and non-reinforced concrete, sanded grout, neat cement grout, or blown-in sand/pea gravel. However, in the past 20 years the use of cellular grouts/cellular concrete as the backfill material has greatly increased. Most cellular grout is made of a mixture of water, Portland cement (with or without the addition of fly ash), a foaming agent and admixtures such as a water-reducer or superplasticizer.It is the authors’ preference to use the term cellular grout as opposed to cellular concrete since by ACI Concrete Terminology an ACI Standard (ACI CT 13), concrete contains aggregates. Normally cellular grout does not contain sand (finite aggregate), but almost never contain course aggregates.The authors believe there are several reasons for this increased use of cellular grout as backfill, such as:• The increase utilization of the various trenchless tunneling methods. Tunnels constructed using trenchless method tend to be smaller in size, excavated diameter or cross sectional area. Making man-entry for placing backfill from inside the secondary liner, utilizing pre-installed grout posts, more difficult if not impossible. It is these workspace restrictions that are the drivers as to when to utilize grout ports installed during the pipe/liner fabrication versus grout delivery pipes installed within the void/annulus space.• The ability of cellular backfills to be pumped and flow longer distances.• The unit weight of cellular grouts can be controlled by mix design and generally can range from 560 Kg/m3 (35 lbs/CF) to 1040 Kg/m3 (65 lbs/CF)."

Jan 12, 2017

By R. L. Loofbourow

Reasons for reexamining underground mining include: 1. The assurance that more deep deposits of useful minerals will be found. 2. The existence of deeply covered deposits of industrial minerals near large markets where quarries are becoming depleted or are lacking. 3. Surface property values, zoning and other limitations on open pit mining. 4. Expectation that underground space will be increasingly used for transportation, power plants, storage and similar purposes. 5. The improvements which have been made in underground mining. During the last three or four decades many changes and improvements have been made underground. All underground construction and mining has benefitted to some extent but the effect on the productivity of labor employed with some methods- has changed little and the use of these methods has declined. Productivity of labor in other methods has increased substantially. The relative usefulness of mining methods has changed and a vital industry, bituminous coal, has been returned to health. In this paper, consideration is limited to nine methods used with high productivity during the period under review. These methods are not necessarily better than others but they may be considered the prime methods in the sense that, in our economy, many, low grade ores, coal and the principal industrial minerals could hardly be produced by less productive means.2 Although most of the examples cited are from mining as such., the first four methods discussed can be used for the construction of stable excavations of various' shapes in sound rock.

Jan 1, 1967

By Gregory R. Wagner

As you know, NIOSH is the part of the United States Public Health Service with responsibility for conducting and supporting research leading to prevention and control of occupational diseases and injuries. Some years ago, NIOSH went through a process of identifying and leading occupational health and safety problems in the United States. Candidate problems were evaluated in terms of the number of people affected, the importance of the effects, and how amenable the conditions are to preventive interventions. Lung diseases were ranked first on the resulting list. Diseases from mining continue to contribute substantially to this unfortunate position of prominence. The work of the Generic Center is one of many answers to this critical problem. Although the research is often expressed in terms of dust characterization or dust control, the reality is that high dust levels are much like high blood pressure. No one cares about hypertension per se. We are concerned about the consequences of exposure to untreated high blood pressure--heart disease, kidney disease, and stroke. Similarly, if dusts were truly only a nuisance, there would be little justification for the diverse research program supported by the Bureau of Mines or by NIOSH. But mineral dusts do cause a range of significant health problems: pneumoconiosis, bronchitis, and emphysema. The research supported by the Center is aimed at doing something about them. Within a public health approach to occupational health, we have a hierarchy of interventions. Primary prevention of problems is prevention at the source: solving a problem before it affects a worker. What we call secondary prevention is an attempt to identify health problems at a sufficiently early stage that some intervention will interrupt the disease process or the development of significant impairment. Tertiary prevention refers to rehabilitation of the worker who has already suffered significant loss of function. At NIOSH, and in the Generic Center research programs, the focus is on primary prevention. Basic investigations into those things about specific dusts that promote or reduce toxicity is critical for our understanding of how to prevent disease. Also, the search for engineering solutions to reduce or control dust generation is essential to solving problems of dust over-exposure. But until the engineers create the foolproof safe environment, it will also be necessary to discover better ways to identify the earliest markers of disease. To do this, we must explore and explicate the basic mechanisms of disease through laboratory investigations as well as human observation and physiologic testing. The unique opportunity provided by the Generic Center program and highlighted in this diverse program over the next few days is that these efforts are being carried out in multiple disciplines concurrently. Also, there are periodic small and large gatherings such as this one where investigators have the chance to get together, formally present papers, and informally stimulate each other's progress towards disease prevention. To ignore the potential for this cross-cutting interaction would be a significant loss. To take full advantage of it is potentially revolutionary. I recently pulled out a book I hadn't read since I was an undergraduate. It specifically concerns the nature of intellectual ferment surrounding the development of the concept of a sun-centered rather than an earth-centered universe in the sixteenth century. The book is about more than developments in astronomy: it is a discussion of the nature of scientific revolutions. Scientific revolutions result from the brilliance, insight, and good fortune of the few superimposed on the evolutionary work of the many. They both cause and reflect significant itellectural and social ferment. For example, the revolutionary work of Copernicus in recognizing the limitations of the concept of an earth-centered universe reflected contemporaneous developments in optics, mathematics, physics, economics, and philosophy.

Jan 1, 1991

By Baron Miya, Keith Hanks, William Edgerton, Francis Fong

The City of Los Angeles capital improvement program includes the construction of a new 35-km interceptor sewer. This sewer will be built as a deep tunnel with finished diameters ranging from 2- to- 4 meters. The project will be constructed concurrently in two phases; an 18-km East-West and a 17-km North-South segment. The new sewer provides additional conveyance capacity for an existing deteriorating sewer that is scheduled for rehabilitation. Large sewage spills during the El Niño storms of 1998 resulted in a Cease and Desist Order that established an aggressive schedule for the completion of the project.

Jan 1, 1999

By Julián Ortiz C., Clayton V. Deutsch

Indicator simulation allows specification of different continuity of high and low values through the use of grade thresholds. The sequential implementation of indicator simulation has been widely used, but the problem of order relation deviations remains a significant drawback. A new procedure for "Hierarchical Indicator Simulation" is introduced that avoids order relations and offers greater flexibility than the conventional sequential approach. The new implementation simulates all locations at the largest threshold and then considers decreasing thresholds in turn. All nodes with grades that are above the previous threshold are excluded from the domain of the current threshold and therefore, they are not used as conditioning data. The probability of being above or below the threshold is calculated using simple indicator kriging using all conditioning data in the domain, thus the covariance structure is preserved. The theoretical framework of this new approach is fully developed. Practical implementation details are discussed. Application to a copper deposit shows the advantages and drawbacks of the method. Finally, the possibility of incorporating multiple-point statistics is discussed.

Jan 1, 2002

By Miguel Reyes, Bruce Whisner, Joseph Bickson, Lincan Yan, David Yantek, Justin Srednicki, Nicholas Damiano, Eric Bauer

Built-in-place (BIP) refuge alternatives (RAs) are designed to provide a secure space for miners who cannot escape during a mine emergency. Heat and humidity buildup within RAs may expose miners to physiological hazards such as heat stress. To minimize the risk of heat stress, Title 30 Code of Federal Regulations (CFR), or 30 CFR, mandates a maximum allowable apparent temperature (AT) for an occupied RA of 35 °C (95 °F). The National Institute for Occupational Safety and Health (NIOSH) has conducted extensive research on the thermal environment of occupied RAs intended for use in underground coal mines. NIOSH research has demonstrated that a fully occupied BIP RA can exceed the AT limit by more than 5.6 °C (10 °F) in mines with elevated mine strata and air temperatures. In this circumstance, an RA cooling system could provide a solution. This paper provides an overview of test methodology and findings as well as guidance on improving the performance of a cryogenic air system prototype by optimizing the flow rate, increasing the tank storage capacity, and improving the efficiency of the heat exchanger of the cryogenic system. This may enable BIP RAs to meet the 35 °C (95 °F) AT limit in mines with elevated temperatures. The information in this paper is useful for RA manufacturers and mines that may choose to implement a cryogenic air system as a heat mitigation strategy.

By Nasri Munfah

Long Island Rail Road’s (LIRR) service to New York City is limited to Penn Station on the West Side of Manhattan, which is operating at its practical capacity for the commuter railroad. This situation imposes serious considerations for future growth and limits the destination of many Long Island commuters. The East Side Access Project will provide a connection of the LIRR to the landmark Grand Central Terminal (GCT)on the East Side of Manhattan. The construction of the connection will require significant tunneling and underground work utilizing a variety of construction techniques. In Queens, the connection will require five soft ground tunnels using pressurized face tunnel boring machine. In Manhattan, the connection will require a series of rock tunnels and caverns connecting to two deep large station caverns under GCT to accommodate eight tracks with four platforms in a stacked configuration. The caverns housing train rooms are connected to the lower level of GCT where a large concourse will be provided. With a budget of $4.3 Billion, The East Side Access Project is the largest transportation project ever undertaken in New York City. This paper provides an overview of the project, discusses its environmental and the engineering challenges, and provides an insight into the design development to date.

Jan 1, 2001

By R. Fields

Nevada is primarily known today for its nation-leading production of gold and silver. However, industrial mineral production continues to play an important role in providing construction materials to help make the state the fastest growing in the United States. Aggregate production in Nevada was about 20 million tons in 1991. Most of that was used in construction in the fast-growing Las Vegas area. The state leads the nation in the production of barite and mined magnesite and has significant production of lithium carbonate, diatomite and gypsum. Other industrial minerals produced in the state include specialty clays, silica, lime and dolomite and relatively small production in salt, perlite and dimension stone. Industrial minerals operations are subject to state and federal permitting requirements, especially in the areas of air and water quality and mined land reclamation. As in all segments of the mineral producing industries throughout the nation, the amount and complexity of regulations affecting industrial minerals has increased significantly in recent years. Nevada is no exception.

Jan 1, 1993