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By Nicolle Krusberski

Potential errors in XRF analysis are discussed and investigated with specific reference to the analysis of ilmenite samples. A selection of ilmenite samples was chosen and prepared using two XRF preparation techniques: pressed powder pellet and unroasted fusion bead. The merits of the two methods have been discussed in this paper for ilmenite analysis by XRF. Recommendations have been made regarding the use of pressed powder pellets especially with regard to the mineralogical effects that were evidenced during this investigation. The fusion bead technique was found to be far more accurate and able to meet short turnaround requirements provided the calibration methodology used is specific to the grade of samples analyzed.

Jan 1, 2014

By D. G. Krige

The problem addressed is that of estimating grade differences between sub- divisions of a new gold mining prospect when only borehole results are available. Such differential grade estimates are required in choosing the best area for initial production, and in defining the grade profile over the mine's life for purposes of feasibility studies. It is also often necessary to differentiate between the grades and hence the values of subareas, owned by separate companies, for the purpose of fixing relative share participation percentages in the new mining company. It is shown that exaggerated grade differentials will be obtained from grade estimates of the subareas based only on boreholes within each such subarea, respectively, and that it would be more realistic to apply some 'smoothing', preferably by kriging. This is feasible because the lognormal-de Wijsian model can be used to give an indication of the spatial structure for the boreholes, even where they are spaced far apart; also the degree of 'smoothing' indicated is shown to be relatively insensitive to inaccurate estimates of the relevant semivariogram parameters.

Jan 1, 1987

By V. G. Pienaar, B. M. Mbiya, P. T. Slatter

[a constant b constant cc onstant c' constant D pipe diameter (m) Dshear shear diameter (m) E error function fth theoretical friction factor F function F' function K fluid consistency index (Pa sn) kv valve loss coefficient L pipe length (m) n flow behaviour index N number of data points ?P valve pressure drop (Pa) Q flow rate (m3/s) Re Reynolds number Re3 Reynolds number (Slatter) V average velocity (m/s) Vann annulus velocity (m/s) x variable X number of independent variables y variable Y number of fundamental dimensions z variable µeff effective viscosity (Pa s) ? valve degree of opening d partial derivative ? fluid density (kg/m3) [ ] function]

Jan 1, 2007

By A. L. Hinde, P. J. D. Lloyd, A. R. Atkins, J. G. MacKay

The control of milling circuits by A. R. ATKINS, M.Se. (Elee. Eng.) (Visitor), A. L. HINDE, S.Se., Ph.D. (London) (Visitor), P. J. D. LLOYD, S.Se. (Chem. Eng.), Ph.D. (Cape) (Fellow) and J. G. MACKA Y, S.Se. (Chem. Eng.) (Visitor). The general behaviour of mills is described in an attempt to find a control philosophy that will permit milling circuits to produce a constant particle size. Although the experimental work has been confined to a single section of the milling circuit of one mine, it is felt that the findings are applicable to other milling circuits.

Jan 6, 1974

By L. S. Bicalho, W. J. Rodrigues, P. M. A. Rollo, P. R. G. Brandão, W. C. da Silva

Quadrilátero Ferrífero is an important mineral province located in Minas Gerais state, responsible for a substantial amount of iron production in Brazil. Among the concentration methods for iron ore practised by the mining companies in this region, the most important is the reverse cationic flotation. Dolomite iron formations, with the presence of hematite, quartz and dolomite, occur in several areas of mining and, with the deepening of the deposits, this type of ore, with low iron content and more complex mineralogy occurs frequently. Carbonaceous minerals, mainly dolomite, present a technological challenge for the concentration of iron ore by flotation. In the present study, the concentration of iron ore with 6% of dolomite content was evaluated. Bench flotation trials indicated that conventional iron ore flotation is not selective to float dolomite, thus compromising the iron content in the final concentrate. Alternative flotation routes were evaluated, and a selective condition was reached to float both quartz and dolomite using the combination of the cationic collector Flotigam 16424 with an anionic collector Flotinor 16551. It was demonstrated that the flotation of dolomite was improved with the combined use of both collectors in the cleaner stage, and by a previous quartz flotation in the rougher stage. Zeta potential analysis indicated specific adsorption as the adsorption mechanism between Flotinor 16551 and dolomite, confirming the high selectivity observed in the bench flotation tests. Keywords: Flotation, iron ore, dolomite

Jan 1, 2020

By S. Shi, X. Xia, F. Xuesai, Z. Shen, D. Han

The hydrodynamic characteristics of a mechanical flotation cell’s transportation zone have significant impact on its metallurgical performance, especially on coarse particles recovery efficiency. However, how to define and adjust the transportation zone was seldom investigated by researchers. In this paper a method will be introduced to define the boundary of the transportation zone by PIV measurement. It is found that the transportation zone can be extended upwards by enlarging the entire rotor-stator assembly from the bottom of tank and increasing the jet angle of the impeller. Two control methods have been validated in industry tests on KYF-160m3 and KYF-320m3 air-forced mechanical flotation cells. The result shows coarse particles recovery are both improved distinctly. It is suggested that enlarging the top transport boundary is able to helpful to reduce the floating distance of bubbleparticle aggregates, which contribute to improve coarse particle recovery in large flotation cells. Key Words: Flotation cell; Transportation zone; Coarse particles flotation

Jan 1, 2020

By A. G. W. Knock

Logistic curves are used in the prediction of the primary production of tin metal from estimated worldwide resources. Such curves are asymptotic to the total cumulative reserves, which are a function of prevailing metal prices and total resources. The figures for tin resources are based on the findings of Robertson and of Brobst and Pratt, the latter authors including estimates of undiscovered deposits. It is suggested that tin production will slump from the present level to 100000 long tons per annum by the end of the century, but will reach a new peak of 200 000 long tons some thirty years later. It appears that production will never exceed 300000 long tons per annum unless substantial new resources, excluding those predicted, are discovered.

Jan 1, 1979

By More-O&apos, R. C. Ferrall, J. W. Wilson

SYNOPSIS The theory of elasticity has been shown to provide a means of determining the stresses and displacements induced by mining in deep level hard rock mines. This theory has been incorporated into an electrical resistance analogue on which the plane of a reef or ore-body can be modelled to enable the rapid determination of stresses and displacements at points in the plane of the reef. This electrical analogue has been used to determine energy release rates caused by scattered mining, which, to some extent, is a measure of the degree of hangingwall fracture. A correlation between predicted energy release rates and actual underground conditions in stopes in the O.F.S. goldfields has been encouraging enough to define parameters on which future stoping layouts can be based. The use of the elastic theory through the analogue has been extended to the assessment of the influence of stoping operations on off-reef excavations. Underground conditions at damaged and undamaged areas have been compared with predicted elastic stresses at the positions under review, resulting in the derivation of design parameters for use in siting off-reef excavations in the prevailing geological conditions in the O.F.S. and Klerksdorp goldfields. The analogue has also been used to assess the vulnerability of certain un mined dykes to bursting. Correlations between stresses induced on dykes by stoping and dyke behaviour underground has enabled critical stress levels to be determined for several persistent dykes occurring in the O.F.S. and Klerksdorp goldfields. A number of long and short term planning projects at mines operating in the Anglo American Corporation and General Mining and Finance Groups are described, where the data derived from the electrical resistance analogue is processed by computer programmes and assessed on the strength of the design factors derived from the correlation of field work and the elastic theory.

Jan 1, 1970

By A. Santana, J. Jankolovits, G. S. Reyes

The flotation of sulfide ores that contain carbonaceous gangue requires significant operational and chemical intervention to achieve suitable metallurgical outcomes. Carbonaceous gangue dilutes concentrate grades, alters the froth behaviour, reduces operational stability, adsorbs reagents, and reduces value recovery. Carbon management processing strategies like preflotation and depression are often presented as point solutions. Moreover, oversimplified mechanisms of carbon depressants belie their complex and nuanced impact on flotation behaviour. Optimising the flotation of carbonaceous sulfide ores requires a holistic consideration of interactions between the carbon management reagents and the processing strategy, ore mineralogy, flotation behaviour, flowsheet, and all other aspects of the flotation system. Examples are shown where conventional, simplistic mechanisms of carbon depressants fail to explain the observed flotation behaviour. The multifaceted impacts of carbon depressants on froth behaviour, collector performance, and value recovery highlight the need for a holistic approach to carbon management. Keywords: Carbon management, carbonaceous ores, sulfide flotation, carbon depressant

Jan 1, 2020

By Mr P. W. J. van Rensburg

SOUTH AFRICAN NATIONAL COMMITTEE ON TUNNELLING In 1970, the South African Institution of Civil Engineers, the South African Institute of Mining and Metallurgy, the South African Institute of Mechanical Engineers, and the Geological Society of South Africa held an international conference on tunnelling, known as Tuncon 1970. SUID-AFRIKAANSE NASIONALE TONNELBOUKOMITEE In 1970 het die Suid-Afrikaanse Instituut van Siviele Ingenieurs, die Suid-Afrikaanse Instituut vir Mynbou en Metallurgie, die Suid-Afrikaanse Instituut van Meganiese Ingenieurs en Die Geologiese Vereniging van Suid-Afrika 'n internasionale konferensie in verband met tonnelbou gehou, wat bekend gestaan het as Tonkon 1970.

Jan 5, 1974

By Y. Wang

Arsenic-bearing acidic effluent from hydrometallurgical processes contains many harmful metal ions and must be appropriately treated before discharge. In the present study, arsenic, copper, zinc, aluminum, and magnesium were co-precipitated by means of the Fenton reaction. The precipitates obtained under different conditions were investigated to determine their stability. The results indicate that pH value and hydrogen peroxide (H2O2) dosage have significant effects on the removal of various elements. Arsenic, copper, zinc, and aluminum (but not magnesium) can be removed at pH 5–6 and anH2O2/As mole ratio of 2 at ambient temperature. The precipitates were mainly amorphous and granular with particle size in the micrometre range. The arsenic concentration in leachate from the toxicity characteristic leaching test was 3.6 mg/L, which proves that the precipitates are effective in fixing arsenic.

Aug 3, 2023

By D. Sethuram, P. G. Koppad, S. Iyengar, R. Shobha

TiB2 and CeO2 particle-reinforced Al6061 hybrid composites were manufactured using stir casting and hot rolling techniques. The base alloy and composites were hot-rolled at 500ºC and a 50% reduction was achieved through 12 passes. The effect of varying TiB2 and CeO2 particle additions on the microstructure and mechanical properties of the Al6061 matrix was studied. Scanning electron microscopy showed uniform dispersion of both the reinforcements, with good interfacial bonding. Microhardness and tensile properties like yield and tensile strength were found to be higher for hybrid composite with 2.5% TiB2 and 2.5% CeO2 compared to Al6061 alloy and other hybrid composites. The increased tensile strength is attributed to good dispersion and interfacial bonding between the particles and Al6061 matrix. Fracture analysis using a scanning electron microscope revealed ductile fracture for the Al6061 alloy and mixed characteristics of ductile-brittle fracture for hybrid composites

Oct 1, 2021

By G. R. Sawyer

Although backfilling has been in operation for many years, the methods for selecting appropriate slurry dewatering aids have, in some cases, been rather unsophisticated. This has led to many misconceptions regarding the role of the dewatering aid and its various means of application. Testing procedures employed in the correct selection of any practically applied dewatering aid must mirror the actual working processes in which they are to be used. This constraint necessitates the development of complex testing methods when applied to backfilling. The current testing procedures were scrutinized and their various merits noted. From this study a series of testing methods was evolved which incorporate the best aspects of these testing procedures with novel ideas which would eventually result in the correct selection of the dewatering aid. A major consideration in the application of any of these methods is the modus operandi of the backfilling process, and the relevance of the tests to the process. This work attempts to consolidate the testwork performed in the past and suggest new approaches in the correct selection of acceptable dewatering aids for backfilling.

Jan 1, 1988

By P. Wiesner, H. –M. Stonner

A brief account is given of the influence of sulphuric acid and chloride ions during the recovery of uranium by solvent extraction, followed by a discussion of the settling behaviour of dispersions and models to represent that behaviour. The paper ends with a description of various methods for the recovery of solvent, which is lost in the solvent-extraction process by entrainment and adsorption on solids and by dissolution.

Jan 1, 1982

Anglo Platinum is in the process of introducing a number of initiatives, varied in nature, on a scale that will impact operations in the short, medium and long-term. The advent of mechanization on a large scale and the introduction of new mining technologies therefore require a different approach to the design of ventilation and cooling systems. In addition, the ventilation and cooling systems serving increasingly deeper operations will place a greater demand on electrical power consumption?this in an environment where power generation is limited and increasingly expensive. Ventilation and cooling systems currently being employed in platinum operations have evolved from practices first pioneered in deep level gold mines. However, in modern and future platinum mines, deepening of operations will take place in a somewhat different environment?particularly in terms of geothermal settings and electrical power utilization. This provides the opportunities to devise novel and energy-efficient ventilation and cooling strategies tailor-made to meet these challenges. The need for refrigeration and cooling at depth will increase the capital and operational cost component of ventilation systems and the medium-term limitations on the availability of electrical power will require the provision of innovative systems. The increased use of diesel-powered vehicles underground, the viability of energy recovery and feasibility of thermal storage opportunities are discussed in this paper. Some of the challenges and the solutions currently proposed in terms of ventilation system design, refrigeration plant selection and chilled water distribution methodologies are described. Changes in strategies core to this discipline that affect the health and safety of employees and the profitability of modern operations are deemed necessary to support the transformations that are envisaged.

Jan 1, 2008

By F. Yang, S. S. Long

Mixed fatty acids, such as oxidised paraffin soap, are frequently used as a substitute for oleic acid in flotation of scheelite in China. Not only because it is cheaper than oleic acid, but also because it is superior in flotation performance to oleic acid. This superiority is generally attributed to the mixed fatty acids' synergistic effect. In this paper, the synergistic effect of oxidised paraffin soap was investigated. We found it mainly consists of a series of saturated fatty acid salts, with six to nineteen carbon atoms. All the contained fatty acids were classified into four groups based on their chain length to make the research work practical. Also, the groups were labelled as 1, 2, 3, and 4 in order. The research was simplified into studying the synergistic effect of four equivalent collectors, instead of fourteen fatty acids. It is justified by the fact that neighbouring fatty acids are expected to have a similar flotation performance. The synergistic effect of the four groups of fatty acids was studied by single-mineral flotation with single groups, binary mixtures, ternary mixtures, and the full component, as collector respectively. The flotation performance index and synergy value were introduced to evaluate flotation performance and synergistic effect of groups, respectively. The results show that the mixture 1+2+3 has the strongest synergy of all followed by the mixtures 1+3 and 2+3. The mixture 3+4 and 1+2, on the other hand, have negative synergy. The synergistic effect of mixtures of groups indicate that being consecutive in length and a broad range of lengths are vital for fatty acids to enhance synergy. Group 3 is fundamental for the collecting action of 733 oxidised paraffin soap in the flotation of scheelite. The fatty acid soap in group 4 is not suitable for flotation due to its low solubility. Keywords: Mixed collectors, synergistic effect, scheelite

Jan 1, 2020

By A. S. Nhleko, P. R. Lobe, H. Mtegha

"Government’s equity role in the minerals sector is one of the nationalist measures implemented in order to ensure greater control and management of a country’s mineral resources. This paper evaluates the Tanzanian government’s equity participation in the minerals sector from 1996 to 2015. The research methodology included determination of the number of mineral rights, minimum allowable exploration expenditures in prospecting licences (PLs), and forms of equity role of the government. Data was collected and analysed for PLs, mining licences (MLs), and special mining licences (SMLs).The study revealed a number of challenges faced by the Tanzanian government as regards its equity strategy in the mineral sector. One of the major challenges was the secrecy surrounding agreements and contracts entered into between the government and private sector investors, which were concluded via various business ownership and mineral development projects. This secrecy resulted in non-transparency and lack ofaccountability in the mining industry.The financial benefits accruing to the government were inadequately realized, evident through inconsistent payments of corporate income tax and mining royalties by the mining companies. Furthermore, the government does not have solid mechanisms and frameworks for assessing non-financial benefits, thus it is difficult to measure the impact of these factors.It is recommended that the Tanzanian government review the Mining Act and Regulations of 2010 to include the provision of solid mechanisms and frameworks for all forms of government equity role.This paper is based on an MSc research study undertaken at the University of the Witwatersrand.IntroductionGovernments can grant private companies mining rights to extract mineral resources, or take a stake in the companies as well as establish state companies to oversee their interests in the minerals sector. The establishment of a state company to oversee government interests in the mining sector implies the direct participation of government by way of equity participation. Equity participation or role is defined as the holding of shares in an enterprise, company, or asset by individuals or a body corporate (Otto, n.d.; Brown, 2013; Natural Resource Governance Institute, 2015)."

Mar 1, 2019

By M. A. Belokrys, F. O. Milovich, D. D. Aksenova, V. A. Ignatkina, V. A. Bocharov, A. A. Kayumov

Copper remains one of the most sought-after metals in the industry. Tennantite (Cu12As4S13) and tetrahedrite (Cu12Sb4S13) that occur in pyrite copper, copper-zinc and polymetallic ores are an additional reserve for increasing technological parameters of flotation. Pyrite mass (85% and more) has similar flotation properties to other sulfide minerals, and imperfection of reagent regime is a common problem that occurs during quality copper concentrate processing. Due to tennantite's and chalcopyrite's differences in flotation properties with butyl xanthate at pH > 10, tennantite often reports to the flotation tails. Hight alkalinity of the medium increases the oxidation level of sulfide minerals, thus increasing the concentration of S2O3 2-, SO3 2- SO4 2-. At processing facilities in the Russian Federation, the concentration of thiosulfate ions in pulp is in the range of 0.5 to 1.5 g/l and higher, which leads to a decrease in flotation activity of the tennantite. The effect of butyl xanthate (as standard), thionocarbamate, dithiophosphate and M-TF (a mixture of dithiophosphate and thionocarbamate) on monomineral (tennantite and pyrite) flotation in the presence of sodium thiosulfate was studied. The variable parameters of the "thiosulfate-collector" flotation complex were thiosulfate concentration (100-900); pH (8-12,5). The scientific methods included contact angle for hydration assessment; TEM for surface studies; UV spectroscopy and iodometric titration for solubility control. Comprehensive studies have established a connection between the concentration of thiosulfate ions and tennantite flotation selectivity. Flotation activity of tennantite is higher at pH 8 with a thiosulfate concentration under 300 mg/l. Pyrite remains active with butyl xanthate under the same conditions. TEM images of the surface films of the collectors on pyrite were acquired at pH 8. The MTF provides the biggest difference in adsorption, wettability and flotation activity between tennantite and pyrite at pH 8 and thiosulfate concentration under 300 mg/l, in comparison with butyl xanthate. The results of the research will be applied to improve selective reagent regimes of tennantite minerals flotation. Keywords: Tennantite, pyrite, chalcopyrite, sphalerite, flotation, sulfhydryl collectors, thiosulfate, adsorption, mechanism, reagent regime

Jan 1, 2020

By Y. Ren, B. Yang

The magnetic field characteristics due to electromagnetic stirring in the secondary cooling zone of an extra-thick slab during continuous casting are numerically determined using Maxwell's equations, with particular emphasis on the distribution of magnetic induction intensity and electromagnetic force, as well as the influence of process parameters on the magnetic field. The orientation of the electromagnetic force is the same when the electromagnetic stirrers at the 30° and 60° posistions of the arc-shaped slab are powered in the same direction; otherwise, the orientation is opposite. The magnetic induction at the centre of the section of the stirrer's central axis at the 30° positio, as well as the current, frequency, and fitting formulae, are as follows: B = {0.075I.(1/A)-0.3} mT and B = {-1.75f.(1/Hz)+22} mT. The electromagnetic force and current fitting formula at the central point of the B-B section is F = {0.03168I2.(1/A2)-03.762I.(1/A)+326.7} N/m3, and the fitting formula of electromagnetic force and frequency at the centre point is divided into two segments. The first takes the form of a parabola: = {-21((f-4.3).(1/Hz)2)+970} N/m3, and the second segment is negative linear: F = {-1.65f.(1/Hz)+51.5} N/m3.

Apr 16, 2024

By Y. Makola, M. Kilumba, S. Mwaba, P. Ilunga, F. Banze, B. Nel, P. Kyoni, N. Mautsa, R. Nkomba, G. Ilu

Kamoto Copper Company is a copper cobalt mining company established in Lualaba Province of Democratic Republic of Congo under a Joint Venture between Glencore PLC and Gecamines (the state-owned mining company). Operations consist of underground and open pit mines, a concentrator producing sulfide concentrate and oxide ores milled slurry, and a hydrometallurgy plant producing copper cathode and cobalt hydroxides from concentrate and ores. The production capacity is 300 k/a of copper cathode and 35 kt/a of cobalt hydroxide. Since Q4 2020, the Luilu hydrometallurgy plant has experienced operational instabilities due to increase in proportion of dolomite in the ore mined and fed to the plant. This was diagnosed by the significant increase in calcium grade in ore and acid consumption, continuous foaming, and overflow of tanks with subsequent adverse impact on equipment availability due to corrosion caused by acidic spills, structure integrity, and safety concerns around the acidic slurry spills. Production was adversely impact due above equipment availability and often throughput restriction to mitigate the foaming and overflows. A high gangue-acid-consuming ore management programme was developed with the aim of mitigating these impacts. The programme included: (i) use of defoamer agent in leach to stop foaming and overflow, (ii) design of a mechanical solution to leach foaming and overflow, and (iii) froth flotation for copper and cobalt minerals separation from dolomite. Only option (i) is presented in this paper. Through laboratory testwork, pilot-plant testing, plant trial, and full plant implementation, Kamoto Copper successfully implemented a defoamer agent (Kemfoam X9980) dosing at leach, resulting in significant reduction in foaming and overflow of leach reactors and countercurrent decantation thickeners. The optimum defoamer dose rate obtained was 20 mg/L. Since then, the Luilu recovered its operational stability, the corrosion of critical equipment ceased, and availability improved as the acidic leach slurry spills ceased. The constraint on throughput due to leach foaming was addressed and the frequency of sliming events in the thickeners was significantly reduced as the foaming on the supernatant surface ceased, with subsequent significant reduction in interfacial crud in solvent extraction.

Jan 1, 2023