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By N. V. Nemchinova, A. A. Kozlov, A. V. Epiforov

The gold dissolution in sulfuric acid media during industrial oxidative leaching test of sulfide gold-copper flotation concentrates has been achieved. The reason for this was using technological water containing thiocyanates and cyanides, which can dissolve gold under these conditions. The carbon in column (CIC) process for gold recovery from these solutions was proposed. However, significant amounts of copper and iron were adsorbed onto the carbon during CIC technology industrial tests. This resulted in a decrease of the gold content in the loaded carbon up to 0.5 kg/t. Further development of the technology was conducted by optimisation of gold and impurities stripping and implementation of carbon reactivation. It was shown, that the copper extraction from the loaded carbon during cyanide treatment was about 95%. The copper content in the stripped carbon after cyanide treatment was 1.76 kg/t. The gold recovery during high-pressure elution by caustic solution was 98%. The hydrochloric acidic treatment with thermal pre-treatment (reactivation) for removing iron and calcium from gold-free carbon was proposed. In this case, the iron and calcium extractions from carbon were 40-45 and 50-55% respectively. These tests showed that for carbon recycling the sequence operations of ‘cyanide treatment, gold elution, thermal pre-treatment, hydrochloric acidic treatment’ can be used. Keywords: Thiocyanate leaching, recovery of gold, carbon adsorption, gold elution, copper stripping, thermal reactivation of carbon, activated carbon, carbon-in-column

Jan 1, 2020

By S. T. L. Harrison, A. Kotsiopoulos, M. D. Maluleke, E. Govender-Opitz

In the extraction of base metals from printed circuit boards (PCBs) using bioleaching, the accumulation of metal ion stress in solution has been shown to inhibit the microbial regeneration of ferric iron. This poses a challenge for the development of this technology for e-waste treatment. The paper explores the application of a microbial immobilisation system in a two-stage bioleaching system consisting of a chemical leaching reactor in series with a microbial ferric iron regenerating reactor to mitigate microbial inhibition and to enhance base metal extraction. A mixed microbial culture dominated by L. ferriphilum, L. ferrooxidans and At. Caldus was maintained over a period of two months in the presence of polyurethane foam which acted as the biomass support particle. Microbial metabolic activity of immobilised cells and their tolerance to inhibitory Cu ions was investigated. Results showed that immobilised microbial cells maintained higher ferrous iron oxidation activity compared to planktonic cells in the presence of increasing Cu2+ concentrations up to 6 g/L. This presents an opportunity for microbial immobilised systems to be adopted in two-stage bioleaching system. Keywords: Bioleaching, microbial immobilisation systems, microbial inhibition and ferrous iron oxidation

Jan 1, 2020

By N. Naude, R. Foisy, F. Bornman

Spiral separators have been widely accepted as one of the most flexible gravity separation devices for several decades. The International Journal of Mineral Processing, 84, pp. 118 – 132 mentioned that spirals are for treating material too coarse for flotation and too fine for dense-media separation. Powder Technology V 102, pp 244 – 252, 1999 stated that there exists a genuine need for extending the performance envelope of spirals – whether to treat finer or coarser material than the traditional size ranges. In recent times there has been an upsurge in interest, particularly in the development of newer fine gravity separators. Spiral separators for the recovery of ultra-fine particles have a unique profile, pitch and features to ensure efficient performance. The flow on the spiral trough must be controlled to minimise turbulence that will entrain fine particles in the outer section of the trough. The experimental test work showed a movement of mass from the outer region towards the centre column of the spiral, i.e., from the fine tailings band towards the concentrate. As recovery on the spiral trough is a function of mass yield and grade, the ultra-fine 7 spiral had a better recovery than the HX5. This makes the UF7 an ideal rougher spiral. Keywords: Ultra-fine particles, spiral, design, recovery

Jan 1, 2020

By K. Muchima, C. Siame, L. Little, B. Kaputula, Q. Mclennan

"The variability of copper mineralization at Kansanshi mine significantly affects the efficiencies of the processes used to recover copper. Quantifying this variability is therefore essential for monitoring and optimizing the performance of the concentrator, which comprises three different flotation circuits (sulphide, mixed, and oxide) and an atmospheric leach circuit. Onsite automated scanning electron microscopy with energy-dispersive X-ray spectrometry (Auto-SEM-EDS) is used to analyse routine weekly composite samples for each circuit, providing detailed analyses of bulk mineralogy, copper deportment to different minerals, mineral liberation, and associations. Weekly mineralogical trends are used to assess changes in process performance, and characterization of the copper losses has inspired a number of projects to target the specific particle types responsible for the main losses. In this paper we describe the relationship between mineralogy and plant performance at Kansanshi, and discus IntroductionKansanshi is a copper and gold mine located in the Northwestern Province of Zambia, with an annual production in the region of 250 000 t of copper and 160 000 ounces of gold. Ore mined from the epigenetic vein-hosted deposit is classified into three ore types based on the extent of oxidation and supergene enrichment. Sulphide, oxide, and mixed ore are fed to separate mineral processing circuits tailored for recovery of the dominant copper minerals in each. After comminution to a target grind size of 80% passing 150 µm, each ore type is subjected to flotation to recover the copper sulphide minerals (chalcopyrite, bornite, chalcocite, covellite). The oxide float tails and a large proportion of the mixed float tails are then treated by atmospheric leaching to extract copper from the remaining copper-hosting minerals, which include cuprite, malachite, chrysocolla, and delafossite. Some native copper is recovered by flotation and some of it is recovered by leaching. A small portion of the combined concentrate from all circuits is subjected to high-pressure leaching and the rest is sent to the smelter. Sulphuric acid produced during smelting is used for the atmospheric leach."

Nov 1, 2018

By B. Mbuya, A. F. Mulaba-Bafubianda, J. M. Mvita

The paper explains the main effects of input leaching parameters, such as addition of a reducing agent, acidity, agitation, temperature, and leaching system potential, in relation to observed and predicted yields of sought-after cobalt. An artificial neural network coupled with graphical probability networks was developed wherein the abovementioned input parameters were used to predict the percentage of dissolved cobalt. Furthermore, similarities and differences between the Bayesian and neural network approaches in terms of their key outcomes are compared with respect to study of the dissolution of cobalt in sulfuric acid. Key results indicate that there is a need to use neural network results to predict conditions for dissolution of cobalt, while using Bayesian network to explain inferences about conditions of the input parameters, thereby achieving realistic predictions.

Jan 1, 2023

By P. Hand

Most coal plants must run under conditions of varying feed conditions or are asked to produce qualities different from that used in the design. This can cause overloaded conditions as the ?bottlenecks? within the plant, depending on plant operation or as the feed changes. During plant design, geological information can be used to determine washability envelopes and blends that may be expected. Historical data can also be used to develop a size distribution envelope as well as to assign reasonable models for each of the unit processes. In operation, a plant can be sampled to determine changes and to refine process models. The information obtained can then be used in an accurate simulation to define how the plant can deal with the changing environment. This paper uses Limn: The Flowsheet Processor to simulate the coal plant in detail and will produce an accurate model, in terms of equipment sizing as well as water, medium, and solids balance, for each change in feed condition. It will show examples of running the simulation through complete density and size ranges and will determine the equipment required to address each part of the performance envelope.

Jan 1, 2010

By L. H. Lindstad

The paper reviews the tapping process and the major wear mechanisms on the tap-hole, including wear from tapping tools. Measured temperatures in different tap-holes are related to choice of binder and material for repair pastes. The strength and disadvantage of carbon and silicon carbide materials are compared. Normal daily and weekly maintenance of tapholes is described, together with the major repairs that are done during longer furnace shutdowns. The objective is to show that the type of repair and repair material needs to be adapted to each individual furnace.

Jan 1, 2014

By I. Kaabachi, F. Meunier, N. Morales

In open pit mining, ore and waste are hauled outside of the excavation area by trucks that move along a system of ramps. The design of these ramps must be carefully addressed because they have to comply with geomechanical constraints to ensure the stability of the pit walls, provide access to the different levels and phases, but also maximise the value of the extracted ore and reduce the extraction of waste. Because an optimisation approach able to deal with the design of the full ramp system seems to be out of reach at the moment, this paper addresses the problem of designing one ramp providing access to a single pushback, which has been determined beforehand. The optimisation objective is therefore to find a ramp that gives access to one given potential volume, while minimising its impact on the economic value of the volume. Two versions of the problem are formalised. One version allows the extraction of ore and waste only if this extraction is necessary for the ramp system. This version somehow minimises the intrinsic value of the ramp system. In the second version, it is possible to extract more than is needed by the ramp system. For instance, this takes into account the possibility of attaining ore on the wall opposite to the ramp as soon as the ramp reaches its level. In the setting mentioned above, the contribution of this work is three-fold. First, the computational complexity of the two different versions of the problem is presented and discussed; in particular, they are shown to be NP-hard. Second, compact integer programs modelling these two versions are proposed. Third, an efficient GRASP algorithm able to cope with the large instances of the problem is proposed. To assess the proposed approaches, the models and algorithms are applied to real instances with an off-the-shelf solver, illustrating and discussing their potential and relevance for the two versions of the problem. They are also compared with other approaches from the literature in terms of value and resulting designs.

Sep 1, 2021

By L. Gutierrez, R. Yepsena

Enargite in porphyry copper deposits is an important mineral as it displays good floatability under the presence of the collectors usually used in the flotation of copper sulfides. As a result, copper concentrates grades are reduced. As scarcity of water resources is a problem relevant to Chilean mining, the use of seawater is a feasible solution. The behaviour of copper sulfides and molybdenite in the process of flotation in seawater was previously studied but not for enargite. The objective of this research is to study the behaviour of the enargite in different conditions of electrochemical potential during the process of flotation using seawater. The study was carried through micro-flotation tests using pure samples of enargite, at Eh values ranging from -300 to 500 mV(SHE), both in seawater and aqueous solutions containing calcium and magnesium. The results show that at pH 10.5 in seawater, the enargite and chalcopyrite recoveries are reduced throughout the whole range of Eh studied. At pH 9 in seawater, enargite and chalcopyrite are depressed under reducing and slightly oxidising conditions. The recovery of both minerals drastically decreases at Eh values lower than -100 mV and greater than 400 mV. The behaviour of enargite in seawater flotation differs from that observed in conventional water, since in the latter case the recovery of enargite decreases at higher potentials close to 500 mV. Keywords: Enargite, flotation, seawater, redox potential

Jan 1, 2020

By D. Kok

A challenge in mine planning is the optimal allocation of resources to the appropriate workplaces within the shift cycle (labour, equipment type, and other resources) in order to carry out the shift cycle activities, achieve planned production targets, and ultimately maximize production within all infrastructure constraints. Generally, detailed mine planning is done on a monthly basis at a workplace level in order to determine the production targets. The production supervisor, mine overseer, or equivalent production manager must then make the appropriate resource allocation trade-off decisions on a daily basis per shift to try and deliver to the plan and required production target. Due to the complexity and number of permutations of possible resource allocation decisions, it is impossible for a human brain to make the appropriate and optimal allocation decisions that will result in achieving the maximum or target production. These allocation decision permutations must deal with the current status of workplaces (availability, position in the cycle etc.), the status of equipment availability (available, planned maintenance, or breakdown etc.), distance between the workplaces (traveling time of equipment between workplaces, etc.) and equipment type required for that shift cycle activity. All these factors need to be taken into account in resource allocation to plan for the shift, and even during the shift if a major piece of equipment becomes unavailable or a workplace activity is not progressing as planned. This paper is a case study on how an optimization algorithm can be used to create a production planning system for optimization of resource allocation in a mechanized underground platinum operation. A business case for optimal allocation of resources is demonstrated and compared to the current manual planned allocation.

Jan 1, 2012

A General Meeting and Colloquium was held in Kelvin House, Johannesburg on Wednesday 29th September, 1971. The theme of the Colloquium was "The Ferro-alloy Industry". Prof D. D. Howat (President) was in the Chair. The meeting was attended by 106 delegates and was opened by the President at 10.05 a.m. OBITUARY The President: "It is my sad duty to announce the death of G. C. Needham, Fellow, who joined the Institute in 1966 and passed away on 27th September, 1971. As a mark of respect to the memory of the deceased and in sympathy with the bereaved I would ask you all to rise and observe a few moments silence." MEMBERSHIP The President: "I have much pleasure in announcing that the names of the following candidates, having been published in accordance with By-Law 5.2.2, Council has elected them to membership of the Institute. Fellows: Richard Lloyd Blandy, Brian Roger Borton, Brian Teversham, Peter Donald Dickson. Members: Frederick Brian Peacock, Peter John Stacey, Kenneth Niles Thanstrom, Byron J. Hayley, Ian Flemming Buchan, Abraham Hercules le Roux. Graduate: Ian William Coy. Students: Peter Boesley J ames, Kenneth Brian Perel. TRANSFERS From Member to Fellow: Cecil Eugene Fivaz, Peter Edwards. From Student to Graduate: Roy Stavely Traviss. From Student to associate: William Mitchell. I welcome the new members to the Institute and congratulate those members who have been transferred to a higher grade. COLLOQUIUM The first paper, presented by Mr S. Selmer-Olsen, Consulting Metallurgist, Amcor Limited, on 'Trends in Ferro Alloy Production' was published in the May issue of the Journal and comprised information and data relating to new developments in ferro alloy production in various parts of the world. This was followed by a paper-'Conductivity and Viscosity Properties of Slags produced in ferro-alloy manufacture' by D. 1. Ossin et al. This was a record of laboratory test work on slags containing both lime and magnesia, corresponding with the composition of slags encountered in the production of ferro chrome alloys when a dolomite flux is employed. The third paper-'Review of the work of the Pyrometallurgical Research Group of N.I.M. and Metallurgy Department, Wits.' presented by Dr P. R. Jochens, leader of the Research Group, outlined the progress made on ten different research projects presently under way in the Department of Metallurgy. These projects range from studies of the kinetics and mechanism of the reduction of chromite ores through the determination of the activities of MnO in slags to phase studies and melting point determinations in the alloy systems Cr-Fe-Si-C and Cr-Fe-Si. A new feature of this Colloquium was the introduction of the discussion panel composed of four or five individuals known to have special knowledge or interest in the subject under duscussion. Mr J. J. Coetzee was chairman of the first panel, Professor D. D. Howat of the second and Dr R. E. Robinson of the third. During the discussion of Mr Selmer-Olsen's paper an interesting contribution was made by Mr Jack Hayley of Transalloys (Pty.) Limited who pointed out that the lowest power cost in the U.S.A. was that from the TV A at 6 mils per unit (0,43 cents S.A.) while costs from other sources were 7 to 8 mils per unit (0,50 to 0,57 cents S.A.) He also referred to the use of 'pile sintering' of ore fines plus coke at certain ferro alloy plants in the V.S. and to the recent practice of 'graphitising' the paste used for Soderberg electrodes. The last session in the afternoon was devoted to a group discussion on 'Practical problems in Arc Furnace Operation', Mr H. R. Reid of Middelburg Steel Alloys (Pty) Limited occupying the chair, members of the panel being Mr J. Meintjies (Rand Carbide Limited), Mr J. Benn (Amcor) and Mr E. J. Jackson (Transalloys (Pty.) Limited). Mr Reid initiated the discussion by talking of the design and composition of electrode shoes, mentioning the use of the 85/15 Cu/Zn alloy and the comparison of hollow shoes and shoes cooled by tubes. Mr Meintjies discussed electrode management with particular reference to breakages, and dealt with casing and fin design and the welding of fins. Mr Benn dealt with aspects of closed top furnace operation with particular reference to the control of eruptions in the furnace and indicated that preheating of the raw materials might be well worth considering together with the development of a system for the detection of the water vapour present. Mr J ackson was concerned with shells, linings, refractories and tap holes. He deprecated the use of oxygen for opening the tap hole emphasising how uncontrolled use of oxygen led to loss of shape of the tap hole and quite severe burning out of the front hole resulting in time and labour in repairs. A notable feature of the Colloquium was the free discussion 'from the floor' of the hall. Many valuable and highly pertinent contributions were made spontaneously and usually in reply to some controversial topic raised by the discussion group.

A powerful, interactive metallurgical process simulator for use on micro- computers has been developed in the Department of Metallurgy and Materials Engineering at the University of the Witwatersrand. MICROSIM presently allows simulation of all ore-dressing flowsheets and a selection of hydrometallurgical unit operations, and is extendable to all such processes. MICROSIM is written in Pascal. This modern language provides very versatile data structures which can be effectively used to solve the major problem in generalised simulation programs, namely storage and transmission of data relating to liquid and solid phases. Dynamic memory allocation allows optimal utilisation of computer storage space. The simulator utilises very efficient precalculation algorithms that determine the tear streams for optimal sequential modulator calculation convergence. Microcomputer graphics simplifies flowsheet specification, and form-filling data capture with supplied default values eliminate most common input errors.

Jan 1, 1987

By L. von Ketelhodt

During the period October 2003 to June 2004, a containerized optical sorting pilot plant was operated at Kloof Gold Mine on a waste rock dump. In this paper, we describe the test work and its results leading to the decision to operate this pilot plant. This paper presents the operational data and financial figures achieved during this project, in particular, for the month of June 2004 when the plant was run at full capacity on three shifts, 24 hour operation. These results are also extrapolated and presented to show the profitability of such an operation at today?s gold price levels and cost structure.

Jan 1, 2009

By L. Makua, K. Langa, Ndlovu. S., C. Saguru

"Global demand for the three platinum group metals (PGMs) Pt, Pd, and Rh has been steadily growing due to their widespread use in emission control, industrial catalysis, and numerous other applications. The primary supply of PGMs is currently the mining industry. However, legislative, operational, and environmental challenges faced by many mining operations result in erratic supply patterns and deficits for these three metals. Naturally, recycling scrap material to recover Pt, Pd, and Rh has therefore aroused research interest in the scientific and engineering communities. Given that the majority of the global demand for these three metals is driven by emission control devices, autocatalytic converters are therefore a significant source of already processed and beneficiated PGMs for recycling.Although pyrometallurgical processes dominate the recycling industry, hydrometallurgical processes may offer certain advantages, chief among these being lower emissions and reduced energy consumption. In this investigation, scrap converter material was leached in acidic chloride media and the leach liquor subjected to solvent extraction and cloud point extraction (CPE) to recover the PGMs. The recoveries for Pt and Pd using Alamine 308® dissolved in kerosene with decanol as a modifier were 95% and 81%, respectively. The maximum recoveries using CPE after complexation with 2-mercaptobenzothiazole (2-MBT) in the presence of Triton X-100 and tin (II) chloride dihydrate as a reductant were 97% for Pd, 96% for Pt, and 91% for Rh. This demonstrates that CPE, although relatively new, may have some potential as a breakthrough PGM recovery technology. IntroductionPlatinum group metals (PGMs) have found a wide variety of applications in different industries due to their chemical, catalytic, and physical properties. PGMs are essential in automobile emission abatement, petroleum refining, and the pharmaceutical and electrical industries (Carabias-Martinez et al., 2000). However, the abundance of PGMs in the Earth’s crust is low and their primary sources are fast depleting (Crundwell et al., 2011).The high demand for PGMs, together with social, economic, environmental, and political aspects related to their production, has led to concerns about their future supply. This has resulted in renewed interest in recycling end-of-life material. PGM supply from recycling has doubled over the last decade, and currently contributes 22% to global supply (Johnson Matthey, 2016). This is in part due to the environmental, social, and operational challenges associated with mining of PGMs. For example, labour unrest, energy cuts, declining commodity prices, and declining ore grades have collectively made the mining landscape economically challenging (KPMG, 2015). On the other hand, the high content of PGMs in secondary sources makes their recovery from the increasing quantities of waste products important from a resource conservation viewpoint. Moreover, PGMs obtained through recycling have been demonstrated to have a 1% environmental cost from a life-cycle perspective, whereas PGMs obtained from mining contribute the remaining 99% of environmental cost (Bossi and Gediga, 2017). Sustainable resource recovery and the economic incentive of recycling have therefore been major drivers to justify investment in PGM recycling. The autocatalytic converter industry accounts for about 70% of the global consumption of these metals (Johnson Matthey, 2016) and therefore recycling spent converters has become a major source of Pt, Pd, and Rh (Figure 1)."

May 1, 2019

By T. Nghipulile, M. Moys, M. Bwalya, H. Simonsen

The quest for efficiency in comminution is an ongoing concern as comminution usually constitutes a major cost component in the metal production industry. Such improvements can be made by circuit optimization or development of more efficient equipment. A novel crusher, known as the rotary offset crusher (ROC), promises to deliver in this space. The ROC was invented in 2002 by Michael Hunt, Henry Simonsen, and Ian Sinclair, but failed to garner enough support to progress to production. The original design concept was recently rekindled, and a laboratory version of the crusher has been built and commissioned at the University of the Witwatersrand. The crusher is simple in design, with two cylindrical discs that are parallel to each other, and, as the name implies, there is an offset between the vertical axes of the discs. The top disc has a conical section on its lower face, and this creates a crushing zone between the opposite faces of the two spinning discs. Centrifugal motion transports particles through the crushing zone. Batch experiments have been conducted with quartz at various crusher settings (discs offset, rotational speed, and vertical exit gap) for various feed size distributions. The indications so far suggest that the disc speed is a key factor affecting the performance. Size reduction ratios as high as 11 were recorded from experiments with quartz at a speed of 830 r/min.

Jan 1, 2021

By W. R. Matizamhuka

"The consolidation of nano-sized composite materials presents a challenge using conventional hot pressing methods. Spark plasma sintering (SPS) technology has shown great promise in the successful sintering of nanoreinforced composite materials. This qualitative review seeks to impart knowledge gathered, and progress made over the years on the consolidation of nanocomposite materials using SPS technology. The review is aimed at introducing this technology to the South African science and engineering community. Emphasis is on improving the mechanical properties of structural ceramic nanocomposite materials, which over the years have shown great promise in a wide range of applications, including transport, energy, mining, and the environment. Although success has been achieved within the laboratory for research purposes, there are still great opportunities to commercialize the technology for the production of larger components with more complex shapes.IntroductionSince the pioneering work of Niihara and Nakahira (1991) over a decade ago there have been extensive attempts to harness the potential of nanostructural metals, ceramics, and composites in a number of applications (Niihara and Nakahira, 1991; Selaho et al., 1997; Sekino and Niihara, 1995; Khalil, 2012; Aalund, 2008). It is generally realized that reducing the grain size of materials to nanoscale offers a significant improvement in properties. Attempts to synthesize nanostructured compacts by conventional sintering methods have not succeeded owing to the uncontrollable high rates of grain growth driven by long dwelling times at the sintering temperatures and large powder surface areas (Sergueeva et al., 2009; Gua, Khora, and Chieng, 2004; Tang et al., 2009). Following the development of spark plasma sintering (SPS) technology, it is now possible to process nanocrystalline materials with controlled grain growth. SPS, also referred to as the field-assisted sintering technique (FAST) or pulsed electric current sintering (PECS), was developed with the aim of improving on the well-established hot pressing (HP) technology (Kessel and Hennicke, 2007;"

Jan 1, 2016

By J. P. Garnier, T. Bhambhani, J. A. Garcia, N. Renaud

Most flotation plants use a static reagent scheme, i.e., a set combination of collectors, frothers, and modifiers. This scheme is usually developed and refined over time to deliver optimal (not necessarily the highest) performance when the major ore types are fed to the plant. However, when ore types or mineralogy coming to the plant change substantially (and this often happens as different areas of the pit(s) are mined and crushed at the same time), there are upsets in the process, typically leading to lower recoveries. Adapting to this variability is usually done only when performance drastically suffers, and the changes made may be too late and bring additional variability in performance. The premise for SmartFloat™ is that the reagent suite needs to be dynamic, adapting continuously to changes in the ore and operating conditions. Solvay has combined advanced analytics and data science techniques with its expertise in flotation reagent chemistry to systematically and automatically achieve the above, and in real time. Thus, SmartFloat™ is optimizing the reagent suite continuously, removing the additional variability created by belated human interactions resulting in a better and more stable process. In addition, this advanced approach allows for continuous improvement by identifying poor performing ore domains and improving the reagent suite using Solvay’s FM-100 approach to design appropriate solutions.

Jan 1, 2023

By F. S. Beretta

Mineral processing efficiency depends on various factors and among them includes head grade fluctuations feeding the processing plant. Head grades can fluctuate beyond an admissible range, implying in recovery decrease for the mineral of interest. Grades feeding the processing plant depend on the geological domain which is being mined and on the mining schedule. Therefore, it is necessary to keep grade variability controlled. Blending piles are an efficient alternative to reduce grade fluctuations. The main factors influencing blending efficiency are the pile size or its mass and the number of layers used to pile up. Large piles are more efficient to reduce variability, however, there are economical and operational limits associated with them. This study investigates a methodology to analyse the ideal pile size to reach an acceptable variability given the in situ grade fluctuations. Geostatistical simulations provide the means to assess grade variability using an optimized mining schedule. These block grades are used to simulate any given pile throughout the mine`s life. The methodology was illustrated using a case study to control coal ash content at a mine supplying ROM coal to a power plant. Keywords: homogenization, piles, geostatistical simulation.

Jan 1, 2009

By L. Thomas, A. Argyn, B. Mbao, G. Longo Banza

Since the first application of solvent extraction as part of the hydrometallurgical processing of copper, several studies have been carried out to optimize extractant formulations. In 2006, Solvay developed the ACORGA® OPT series of solvent-extraction reagents to optimize copper transfer by use of a blended formulation containing both aldoxime and ketoxime as well as selected modifiers. The incorporation of selected modifiers in these blended reagents resulted in increased copper transfer, due to the interaction between the modifier and oximes within the blend. By changing the ketoxime concentration and ratio of modifier to aldoxime, the strength of the formulation was optimized to enhance copper transfer and improve Cu:Fe selectivity. This formulation is well known in the African region under the ACORGA® OPT5540 name and provides the best performance at the conditions of agitated leach plants with pregnant leach solutions that fluctuate in Cu grade and pH. This paper discusses advantages of using ACORGA® OPT5540 in the Copperbelt

Jan 1, 2023

By M. Rudolph, A. van Hall, G. Öktem, S. G. Özkan, A. Hassanzadeh

Despite the four-decade study on ultrasound’s (US) impact on mineral’s floatabilities, there is still not clarity regarding its role in mineral surface wettability. For this purpose, the present investigation endeavours ……the hydrophobicity and floatability characteristics of a chalcopyrite-pyrite-quartz (Cp- Py-Qtz) system in the presence and absence of an ultrasonic pre-treatment. The ultrasonic process was carried out by a sonopuls at a constant frequency of 20 kHz with an adjustable power level from 30 to 200 W. Initially, the impact of sonication time (15, 30, 45, 60 and 90 s as well as 10, 20 and 30 min) and power magnitude (30, 60, 90, 120 and 180 W) were evaluated while the dissolved oxygen, temperature, conductivity and pH were also monitored. Collector-less micro-flotation tests were carried out on the non-pre-treated and the US pre-treated samples at 60 W and 15 s. The samples’ hydrophobicities were determined by the drop shape analysis approach. The dissolved-oxygen level was varied using a mini bench pressurised water reactor to study the effect of O2(aq) concentration on the chalcopyrite and pyrite wettability characteristics. The results showed that the minerals’ hydrophilicities were relatively more sensitive to the sonication’s time than its power that resulted in reducing all three minerals’ hydrophobicities. In addition, it was found that the dissolved-oxygen content and creation of sub-micron sized bubbles led to an improvement on chalcopyrite and pyrite hydrophobicities. Finally, we proved that the Cp’s floatability increased and Qtz’s recovery reduced while being subjected to the ultrasonic irradiation (15 s at 60 W); however, Py’s recovery remained constant. This conclusion confirmed the possibility of a selective separation in ultrasound-assisted copper ore flotation. We recommend that further advanced investigations be conducted, using an X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) to thoroughly understand the surface modifications induced by the ultrasonication

Jan 1, 2020