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By Martin A. Elliott

"INTRODUCTION During the recent war the Bureau of Mines was requested to obtain in¬formation on the temperature at which ammonium nitrate mixed with certa: contaminants would react rapidly. This information was desired in connection with an investigation of an explosion that had occurred during the evaporation, by air agitation, of volutions containing ammonium nitrate in which compressor oil that might have passed the filters was suspected of being a contaminant.During the course of this work it was found that mixtures of ammonium nitrate and zinc reacted rapidly at comparatively low temperatures: and since zinc could not positively be eliminated as a contaminant in the explosion in question, a series of tests was carried out, not only with mixtures of ammonium nitrate and compressor oil but also ammonium nitrate and zinc with and without oil. A few experiments were made with metals other than zinc.The investigation was not as extensive as might have been desired, owing to limitations -in time. The results are presented at this time in view of their current interest in connection with the Texas City disaster, in which a large quantity of ammonium nitrate detonated in the holds of two ships."

Mar 1, 1948

By T. G. Carnahan

The Federal Bureau of Mines investigated, on a laboratory scale, a technique for recovery of silver from pregnant solutions generated in the hydro-metallurgical treatment of complex base-metal sulfide concentrates with oxidizing chloride media. This technique provides a means for recovery and simplified reduction of accessory silver to metal from chloride solutions. The method consists of adding NaI or KI to the solution to precipitate AgI, which is then contacted with Na2S to produce Ag2S and to regenerate the iodide salt solution. Silver recoveries range from 99 pct with 20 pct excess iodide precipitant, to 92 pct when the theoretical stoichiometric amount of precipitant is employed. The Ag2S product can be reduced to silver metal by contact with aluminum chips in NaOH solution followed by purification with conventional fire refining techniques.

Jan 1, 1980

By T. M. Barczak

This report describes Bureau of Mines research to develop methods to evaluate loading on longwall roof supports to permit better design and more efficient utilization of these structures in compliance with the geological conditions in which they are employed. The resultant vertical and horizontal force acting on the canopy of a shield can be determined, either from a statically determinate solution assuming rigid-body mechanics and elimination of certain unknowns, or from an elastic solu-tion by analysis of the load-displacement relationship of the shield structure. A two-dimensional rigid-body model is presented that determines resultant shield forces by measurement of leg, canopy capsule, and lemniscate link forces. An elastic solution is presented, in the form of an elastic stiffness model with two degrees of freedom, which describes the load-displacement relationship from the stiffness of the shield structure as determined in the Bureau's Mine Roof Simulator (MRS). The ability of both models to determine resultant forces acting on the shield canopy are evaluated from full-scale tests in the MRS. More advanced numerical models are also discussed as part of the Bureau's continuing effort in the evaluation of roof support structures.

Jan 1, 1987

By Tobias W. Goodman, Joseph Cervik

This Bureau of Mines report investigates the horizontal trajectory of boreholes drilled in coalbeds using the rotary drilling technique. Test holes drilled in coalbeds showed that the path of a borehole in the horizontal plane depends on drilling assembly configuration, drill bit rotation, and coalbed geologic features. An assembly that contained an 18-ft (5.53) long drill collar and two centralizers had the best horizontal stability evidenced by trajectories that deviated less than 16 ft (4.9 m) from a target at 1,000 ft (305 m). Removal of one of the centralizers resulted in a loss of control of hole trajectory in the horizontal plane. Generally, holes tended to turn to the right, presumably because of right-hand rotation of the bit. Deviations from the original bearing line were as much as 200 ft (61 m) or more at a depth of 1,000 ft (305 m).

Jan 1, 1988

By N. S. Dalal, X. Shi

It has been known for more than a decade that vanadium (V) stimulates the oxidation of NADH by plasma membranes (1) but the underlying mechanism is still not fully understood. This effect has been attributed to a membrane-associated NADH-dependent vanadium (V) oxidoreductase (1). Subsequent studies suggest that vanadium ( V) can accept an electron from fiavoprotein dehydrogenase that oxidizes NADH (2). The phenomenon ofNAD(P)H oxidation coupled to vanadium(V) reduction has also been demonstrated in other biological systems (3-6). A recent electron spin resonance (ESR) study from our laboratory reported on the accumulation of vanadium (IV) duringthe reduction ofvanadate (vanadium(V)) by the ftavoenzymes glutathione reductase (GSSG-R),4 lipoyl dehydrogenase, and ferredoxin-NADP+ oxidoreductase in the presence of NAD(P)H (7). It was concluded therein (7) that these ftavoenzymes function as NAD(P)H-dependent vanadium(V) reductases. More recently, however, Liochev and Fridovich (8) have argued that the ESR data (7) do not demonstrate that the investigated fiavoenzymes act as vanadate reductases. They suggest an alternative mechanism in which the fiavoenzyme simply serves as a generator ofsuperoxide (02) radical, which acts as a propagator of the radical chain reaction leading to NAD(P)H oxidation (9, 10), as summarized below:

Nov 1, 1995

By L. C. IlsLey

The last previous Bureau of Mines publication relative to details of permissible methane detectors (Bulletin 331, published in 1930) describes detectors of four different types, namely flame, combustion, catalytic, and a combination Weatstone-bridge and catalytic type in which catalytic action at the surface of a platinum filament when in methane causes a change in the temperature and resistance of the filament, thus unbalancing the bridge circuit and giving a reading proportional to the methane concentration. Three detractors of the latter type have been approved since 1930. A brief description of each follows: U. C. C. Detector Approval No. 902, covering the U. C. C. indicating detector, as described in Bulletin 331, was extended. January 27, 1930, to cover important changes in design that permit checking the calibration of the detector at any time whether in gas or fresh air. Essential features of the detector are shown in figure 1.

Jan 1, 1937

By Michael J. Sapko, Gregory M. Green, Harry C. Verakis, Kenneth L. Cashdollar

The National Institute for Occupational Safety and Health (NIOSH) and the Mine Safety and Health Administration (MSHA) conducted a joint survey to determine the range of coal particle sizes found in dust samples collected from intake airways of U.S. coal mines. The last comprehensive survey of this type was performed in the 1920’s. The size of the coal dust is relevant to the amount of rock dust required to inert the coal dust, with more rock dust needed to inert finer sizes of coal dust. Dust samples were collected by MSHA inspectors from several mines in each of MSHA’s ten bituminous Coal Mine Health and Safety Districts. Samples were normally collected in several intakes at each mine. The laboratory analysis procedures included acid leaching of the sample to remove the limestone rock dust, sonic sieving to determine the dust size, and low temperature ashing of the sieved fractions to correct for any remaining incombustible matter. The results indicate that particle sizes of mine coal dust in intake airways are finer than those measured in the 1920’s. The significance of these finer coal dust sizes is discussed relevant to the amount of rock dust required to prevent coal dust explosions.

By Richard J. Mainiero

The Bureau of Mines investigated coal-mine-type short-delay electric detonators marketed by three domestic manufacturers to determine the accuracy of delays and the probability of overlap between adjacent de- lay periods. The Winzer index was computed and compared with the probability of overlap. A close agreement between the Winzer criterion and overlap probability was demonstrated. A permissible blasting unit capable of delivering a maximum firing energy of 4.0 J and a digital oscilloscope were used to measure the delay time with an accuracy of 20.25 ms. Another oscilloscope and a pulse transformer were used to record firing current. Experimental data indicated negligible overlap probability in detonators of shorter delay periods: periods 1 to 4, which correspond to 25 to 250 ms. However, a significant probability of overlap was detected in some detonators of longer delay periods: periods 5 to 9, which cor- respond to 300 to 500 ms.

Jan 1, 1985

By Donald P. Blasko

The Bureau of Mines investigated two areas of the Alaska Peninsula (Iniskin Peninsula and Becharof Lake) where oil and gas seeps were known to occur in an attempt to determine (1) whether the seeps are still active and (2) the amount of bitumen contained in the drainage leaving the seeps. The oil, water, oil-water, and gas were sampled and analyzed. Five oil samples were taken at four separate oil seeps. The API gravity of the oil ranged from 8.90 to 21.4° and the sulfur content was from 0.12 percent to 0.59 percent. Four of the seven gas samples obtained revealed fair high caloric values, ranging from 746 to 924 Btu/cu ft, and averaging 844 Btu/cu ft. A total of 44 water samples were obtained. Bitumen content of the water was as high as 9,773 mg/l at one seep, but averaged less than I mg/l where the seep-drainage water entered the Gulf of Alaska.

Jan 1, 1976

By S. L. Windes

"INTRODUCTION For a number of years the bureau of Mines has been engaged in the detection, recording and interpretation of earth- and air-transmitted disturbances, man-made and natural, related to mining operations. For the measure¬ment of such disturbances, special equipment was developed (1, 2, 3, 4, 8) 3/ and results of the measurements have been reported (5, 6; 7,9).In general, the ranges of amplitude end frequency of vibration encountered and recorded in the earth-transmitted disturbances were 0.00005 to 0.1 inch and 5 to 5,000 cycles per second; in the air-transmitted disturbances, pressures ranging from 0.001 to 100 pounds per square inch and 0 to 20,000 cycles per second were recorded.One characteristic of the earlier tests was that either the arrival time of the disturbance to be recorded was predictable or the recording speed was slow enough so that the record covered extended periods of time (for example, 4 hours). As the investigations continued, it became apparent that a recording device was required that would respond to transient vibrations arriving at indeterminate times and at the same time provide a permanent record of displacement or acceleration versus time on a scale that would permit the analysis of waves having frequency components up to 10,000 cycles per second. A film or paper speed of 720 inches per second was found to be adequate, as this provides approximately 3/4 inch of record for each 0.001 second."

Dec 1, 1947

By Irving Hartmann

Modern mechanized mining with high-speed machines, multiple-entry systems, multiple blasting, high-velocity air currents, and rapid haulage has brought many economic benefits and has on the whole enhanced safety in the coal-mining industry. It has, however, also introduced some added hazards, the control of which requires concerted effort and ingenuity. Mechanized mining has greatly increased the production and dissemination of fine coal seam or in mine entries. Use of high-speed machines has increased the probability of formation of incendive sparks, which are produced by frictional contact between moving metals and certain mineral substances in the coal seam or in the adjoining rock strata. In gassy seams rapid extraction of coal has increased the rate of gas evolution. These facts have made more urgent the need of preventing the ignition of coal dust and the development of widespread mine explosions. The ignition hazard can be controlled best by eliminating all potential igniting sources and by careful attention to ventilation designed to prevent accumulation of gas capable of triggering a coal-dust explosion. Frictional spark ignition by mining machines and suggested safeguards are discussed in a recent publication. Extensive research and long experience have shown conclusively that the propagation of coal-dust flames can be arrested and the development of widespread explosions prevented by properly applied, generalized rock dusting.

Jan 1, 1956

By K. R. Becker

The addition of a force gage and a reaction detector to the Bureau of Mines drop-weight impact apparatus made it possible to examine the details of the force exerted on the specimen and make estimates of the time to reaction. With the current setup the force was found to be oscillatory and not reproducble. However, single well-defined pressure pulses can be delivered to the explosive sample by modifying the drop-weight tools. With a modified test arrangement, the time to reaction and the peak force and energy at the time of reaction were determined as a function of drop-weight height for several different explosives. All these parameters were found to decrease as the rate of force application was increased. The same parameters were also found to vary with the thickness of the test sample. The implications of these results are discussed in terms of practical drop-weight testing.

Jan 1, 1972

By A. B. Hooker, L. C. IlsLey

"Field inspections and data relative to the use of rubber-sheathed trailing cables in mines show that much cable is ruined or its probable life shortened by being overheated in service.The length of cable required to make connection from a source of supply to a machine at the face workings may be 100 to 500 feet. As a rule, the cable is carried on a reel and unreeled as required; and thus in most cases soma of the cable is not removed from the reel. The overheating generally occurs in that part of the cable which is left on the reel.Factors that determine the heating of trailing cables are:1. The size of the conductors in the cable.2. The maximum energy to be supplied through the cable, based upon the horsepower of the motor and the degree to which the motor is loaded.3. The voltage of the supply and the variation of the voltage at the receiving end.4. The time length of current flow and whether continuous or intermittent.5. The kind of current (direct or alternating).6. The amount of ca· le left or the reel.7. The type of cable used.8. The kind of reel used.In connecti0n with an investigation of the general performance of rubber-sheathed trailing callas, the Bureau of Mines has made a limited study of some of these factors, including the following points:"

Jul 1, 1931

By D. L. Pool

To increase metal recoveries and to minimize pollution by improved extraction technology, the Bureau of Mines investigated a hydrometallurgical technique to recover copper, lead, nickel, and cobalt from lead smelter mattes. The metals were converted from insoluble sulfides to soluble chlorides using a HCI-CI2-02 leaching system. Parameters studied in a 50-gallon, glass-lined reactor were the ratio of hydrochloric acid to chlorine, chlorine consumption per pound of matte, oxygen reaction pressure, and temperature. The matte material used contained, in percent, 19.7 Cu, 52 Pb, 2.9 Ni, 1.5 Fe, 0.38 Co, 0.19 As, 0.41 Zn, and 0.12 Cd. Extraction of Cu, Pb, Ni, Co, and Cd ranged from 92 to 98 pct, with concomitant extractions of Fe and As of <0.1 pct. The Cu and Pb were recovered as electrowon metals, while the Ni, Co, and Cd were recovered as mixed hydroxides.

Jan 1, 1981

By David K. Denton

There are no active mines in the Mt. Eddy RARE II area. Chromite, gold, and stone prospects were examined. The RARE II area contains no identified mineral resources; however, a sample of a 260 ton occurrence contained 38.1 percent chromium oxide (Cr203) at the Ratero Prospect (fig. 1, no. 3), which has low potential for chromium resources. The Johnson Mine (fig. 1, no. 6) produced a small unrecorded amount of chromite during World War IT, but only a low potential exists for chromium resources. A low potential exists for gold resources at the Half Century Prospect (fig. 1, no. 2). At a borrow pit northwest of the study area (fig. 1, no. 1), sheared serpentinite is quarried for road metal; similar rock occurs in the RARE II area, but better material is more readily available elsewhere. Sand and gravel occurrences are too inaccessible and distant from markets to be considered resources. Mineral fuels and geothermal resources were not evaluated during this Bureau of Mines study. There currently are three unpatented lode mining claims in the study area. INTRODUCTION The Mt. Eddy RARE II area is 7 air-mi west of Mt. Shasta City, California, and straddles the Siskiyou-Trinity county line. The roadless area includes 7,200 acres of rugged, glacially carved, ridges and drainages which comprise Mt. Eddy. Elevations vary from 6,000 ft along the North Fork Sacramento River to 9,025 ft at the summit of Mt. Eddy. The area is covered with conifer forest below 8,000 ft elevation.

Jan 1, 1983

By G. Nuñez, M. A. Pathak, C. F. Stanley

"A 1986 report by the U.S. National Committee on Blomechanlcs (1) describes lung disease as a major national health problem. The report cites three areas that would benefit from a better understanding of the vibratory patterns of the lung. These areas are outlined below.1. In cases of respiratory distress, pressure driven artificial respirators are used. A new technique using high frequency respiration is quite promising, but the pressure distribution in the lung as a function of frequency is not yet known. At these frequencies of 1 to 60 Hz, the lung expands asynchronously (2) and a better understanding of these expansion nonunlformltles could provide valuable Information about the mechanics of high frequency ventilation.2. Listening to the sounds In the lung can yield valuable Information about the state of the lung. To improve the technique, a better understanding of how acoustic waves propagate through the lung is needed.3. The response of the lung as It Is subjected to acoustic excitation, dynamic loading or shock waves is not well understood. A better knowledge of these responees can lead to improved treatment for patients subjected to either explosive pressure waves or car crashes.4. Researchers are measuring the acoustic Impedance of the Iung to detect early states of dysfunction. Sneckenberger and Whitmoyer (3) have reported Impedances obtained at acoustic frequencies up to about 6000 Hz. However, It la not certain which parts of the lung are responding to the acoustic excitation.To Investigate the vibratory characteristics of the lung, excised rat lungs were excited via the trachea with acoustic waves at frequencies up to 6000 Hz. Thie paper describes an Instrumentation system, utlllzlng time-averaged holographic Interferometry, to detect and quantify the response of the lung surface to the acoustic excitation."

Jan 1, 1989

Avoid errors in determining the amount of trace elements in overburden when core drilling samples, particularly as required by PL 95-87, the Surface Mining Control and Reclamation Act of 1977. Reason Metal additives present in certain drill stem joint lubricants appear to contaminate overburden samples. If these lubricants are used in assembling the drill string, they can interfere with the analytical methods used to establish concentration of trace metals. Errors In trace element determination appear to be as much as 30 times true concentration, and may falsely Indicate that the amount of trace element in the overburden exceeds the

Jan 1, 1981

By Stephen P. Signer

This paper presents an overview of laboratory and field tests on approximately 250 fully grouted roof bolts instrumented with strain gauges in order to study loading behavior. Laboratory work included pull tests, time-dependent tests, and shear tests. The field tests were conducted in 14 different mines extracting different commodities. However, because of the focus of this publication, only the results of tests in 9 coal mines are reported here. In the field tests, all but 14 bolts were loaded by rock movement; these 14 bolts were tested using pull gear. The variables studied included anchorage length, mechanical interlock, time-dependent behavior, shear, installation load, loading rate, and maximum load level. Such information will improve the understanding of the behavior of resin-grouted bolts, which in return will enhance the safety of miners by reducing the occurrence of rock falls. The influences of geology, overburden depth, entry width, mining-induced stresses, and bolt spacing are not described.

Jan 10, 2000

By E. J. Kloos

The Bureau of Mines devised a new machine-test method for measuring carbon dioxide inspired by a wearer of self-contained breathing apparatus. The new method compares favorably in speed and precision with standard man-tests in which the apparatus is tested while actually worn, and is scheduled for use in future approval tests for facepiece carbon dioxide &apos;measurements. However, man-tests will still be used to measure the efficiency of the carbon dioxide sorbent materials in closed-circuit breathing apparatus.

Jan 1, 1966

By Raja V. Rarnani, Robert L. Frantz

"Co-Directors, Generic Mineral Technology Center for Respirable DustEarly in the 1980s, the U.S. Bureau of Mines initiated the concept of the Generic Center, incorporating it into its mining research program, and in 1983, the Generic Mineral Technology Center for Respirable Dust was established. The Generic Center concept was first envisioned by the U.S. Bureau of Mines as a way to bring together the various different scientific, engineering and medical research interests in the respirable dust area to effect a coordinated and efficient organization for advancing knowledge in that field. The result was a combination of the collective talents and skills of more than 100 scientists, engineers, medical personnel and graduate students, through the formation of a consortium of five major research universities, including medical facilities, to perform respirable dust research. The Generic Mineral Technology Center for Respirable Dust consortium comprises The Pennsylvania State University (with its Hershey Medical Center) and West Virginia University (with its Medical Center) as the lead universities and the University of Minnesota, Massachusetts Institute of Technology and Michigan Technological University as affiliates.Although respirable dust-related disease remains the nation's worst industrial hazard, the fundamental understanding of all aspects of respirable dust associated with the mining and milling industries, including the interaction of dust and lungs, has grown significantly over the past near-decade toward the larger effort to reduce the incidence and severity of disease caused by respirable dust. Continued progress toward making the mine work environment cleaner and healthier remains the immediate objective of the Respirable Dust Center.The Respirable Dust Center's research program and technology transfer activities, described in this paper, exemplify the Generic Center concept first envisioned by the U.S. Bureau of Mines. Interdisciplinary and interactive studies continue to result in significant progress toward making mine atmospheres cleaner and healthier."

Jan 1, 1995