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By A. B. Whitehead

A spectrographic method for the determination of 18 impurities in cerium is presented. The carrier distillation technique is utilized to separate the spectra of impurities from the complex spectrum of cerium. Metal samples are ignited to the oxide, mixed with silver chloride carrier containing an internal standard, and excited with a 20-ampere direct-current arc. An additional exposure, made after carrier depletion, provides for the determination of refractory elements. Experiments to determine the best carrier, sample-carrier ratio, electrodes, arc current, exposure conditions, internal standards, and any matrix effect are described. The relative standard deviation of the method at the 20- and 200-part-per-million levels is about 25 and 15 percent, respectively. The average relative error is about 20 percent in the 10- to 1,000-part-per-million concentration range.

Jan 1, 1962

By James V. Kelly

During the spring and summer of 1947, the Bureau of Mines conducted an investigation and core-drilling program in the vicinity of the Rodham mine, approximately 4 miles north of Shullsburg, Wis. This work was undertaken as a part of a general study of the zinc and lead-producing area of southwestern Wisconsin. Work in the Rodham-mine area was done to investigate further a mineralized area frilled in part by the Puritan Exploration Co., a Delaware corporation, with offices in Galena, Ill. Some significant lead-bearing samples were obtained, but no continuous ore body was disclosed as a result of the Bureau of Mines work.

Jan 1, 1949

By O. C. Blade

This report on the properties of motor fuels sold through service stations In the United States was made In accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Department of the Interior. By agreement with the American Petroleum Institute, identification of the items Is confidential. 1t presents analytical data for 4, 802 samples, representing the products of 117 companies. The samples were collected during December 1954 and January and February 1955. As in previous surveys, the gasolines covered 6y this survey Include those from both large and small suppliers. The data were obtained by laboratories of various refiners, motor manufacturers, and chemical companies and submitted to the Bureau of Mines for compilation, A list of the National Motor-Gasoline Survey reports published during the past 10 years is given on page 5.

Jan 1, 1955

By Russell R. Trengove

The Bureau of Mines developed by core drilling the Cove Meadow copper property, also known as the Patterson property, from May 6, 1949, to August 6, 1949. It is in the Cove Meadow mining district, northwestern Humboldt County, Nev., 102 miles northwest of Winnemucca. The purpose of the work was to determine possible reserves in a mineralized shear zone in andesite that has been partly explored by several surface cuts and two shallow underground workings. Production from this zone to August 1, 1,949, was 98 tons of hand-sorted copper ore assaying 5.1 percent. The development work performed by the Bureau of Mines comprised a study of the geology, mapping the area, sampling the outcrops, and exploring by diamond drilling the shear zone adjacent to the fault. Seven holes were drilled for a total of 1,246 feet. Mineral reserves indicated by the project are confined to a length of 500 feet along the strike.

Jan 1, 1950

Spectrochemical methods were developed to determine beryllium in the concentration range 0.0015 to 4.0 percent in siliceous mineral beneficiation products. Two methods are described. They are (1) a fusion-pellet-spark procedure (spark method) and (2) a sustaining alternating-current arc procedure (arc method). In the spark method the sample is fused with lithium tetra-borate and vanadium pentoxide. The resulting bead is crushed, mixed with powdered graphite, and briquetted. This is analyzed spectrographically using controlled high-voltage spark excitation. In the arc method the sample is diluted with germanium metal, graphite, and vanadium pentoxide. Weighed charges are packed into cupped graphite electrodes and subjected to excitation with a sustaining alternating-current arc. Vanadium serves as internal standard for both methods. Effects due to matrix variations in samples and standards are eliminated either by fusion with lithium tetraborate in the spark method or by dilution with germanium and graphite in the arc method. Beryllium determinations show deviations from accepted chemical values of approximately 5 and 8 percent for the spark and arc methods, respectively. Analyses can be made more rapidly by the arc procedure with a sacrifice in precision and accuracy. Either method can be applied to the determination of beryllium in silicate rocks.

Jan 1, 1962

By M. Kanefsky, A. Q. K. Rajput

Two channel polarity coincidence and polarity difference statistics are analyzed. The signal, common to both channels, consists of sinusoidal bursts where the exact frequency of the signal is nearly known, but other parameters such as amplitude, phase, and pulse starting time are unknown. The noise inputs are dependent, narrow band, Markov processes. It is shown that the performance depends not only on the signal uncertainties but on the precise shape of the cross-correlation functions between the noise inputs. By using two polarity difference statistics in addition to the polarity coincidence statistic, it is shown that the decrease in performance, as well as the cost of hard limiting due to correlated inputs, can be made small.

Jan 11, 1981

By H. E. Perlee

The concentration limits of flammability and autoignition temperatures of trichloroethylene in atmospheres of air, oxygen, and nitrogen tetroxide have been determined in a spherical vessel. The autoignition temperatures of TCE in atmospheres of air, oxygen, and nitrogen tetroxide were found to be 419°, 396°, and 221° C, respectively. The flammability zones of TCE-air, TCE-oxygen and TCE-nitrogen tetroxide mixtures at 100° C were found to be 10.5 to 41, 7.5 to 91, and 13.5 to 69 volume percent TCE, respectively. In addition, maxi-mum combustion pressures of 50 ps and 140 were recorded for constant volume combustion of the lower limit mixtures of trichloroethylene in air and oxygen, respectively.

Jan 1, 1966

By Bruce I. Thomas

The Fairbanks mining district forms an arc 40 miles long and 8 miles wide on the north side of the Tanana Valley in central Alaska. This is a region of broad valleys and rounded hills that range in elevation from 600 to 2,600 feet Lode-gold production started in 1910 and has continued sporadically to the present, but the largest single mine produced only 40 tons per 24-hour day. Total recorded lode-gold production of the district is 241,000 fine troy ounces of gold from ore that averaged 1.32 fine ounces per ton. The ore was mined chiefly from narrow veins and veinlets alined along anticlinal folds at Ester Dome and the Pedro Dome-Cleary area. The only proven reserves are reported to be at the Ryan Lode at Ester Dome and at the Keystone Mines, Inc., holdings in the Pedro Dome-Cleary area. An inferred lode-gold resource for the district of approximately 4,000,000 ounces is considered to indicate only the order of magnitude of the lode-gold potential because of the absence of detailed data needed to evaluate the numerous deposits.

Jan 1, 1973

By D. Bienstock

The Fischer-Tropsch synthesis is practicable in a reactor where the exothermic heat of reaction is removed by circulating large quantities of recycle gas through a catalyst bed of high-voids content. At an hourly space velocity of 1100, the feed gas, a mixture of 1.5 parts hydrogen to 1 of carbon monoxide, was converted 90 percent, producing hydrocarbons predominantly in the gasoline range. At these conditions a recycle-to-fresh gas ratio of 40:1 was enough to give excellent temperature control with a pressure drop of 1.5 p.s.i. per foot of bed using a steel catalyst in the form of lathe turnings. Steel parallel plates, although offering lower resistance to gasflow, were less reactive and less durable. INTRODUCTION The Federal Bureau of Mines has been engaged in a research and development program since 1944 on the synthesis of gasoline from coal. Gasification of coal with steam and oxygen to yield a synthesis gas--a mixture of carbon monoxide and hydrogen--is being investigated at Morgantown, W. Va.; and the synthesis of gasoline by catalytically reacting the carbon monoxide and hydrogen over iron by the Fischer-Tropsch reaction is being investigated at Bruceton, Pa.

Jan 1, 1960

By J. O. Lewis

"The significant facts in the problem of the relation between the production of crude petroleum, and the ever-increasing demand for petroleum products are that in spite of continually increasing production, improvements in methods of refining and utilization, and heavy increases in imports, demands grow still more rapidly and we seem always faced with a shortage at hand or lust ahead. On the other hand, our foremost authorities warn um of entirely inadequate domestic reserves. Looking abroad we find some large fields and many of speculative promise, 'tut the situation is complicated by international relations and demands by other countries which promise to be even more insistent than oars. This is the situation, then. We can not rely upon our own Crude Petroleum to meet the Ever Increasing Demand for Petroleum Products.I wish to follow this somewhat alarming statement by saying at once that the Bureau of Mines is not pessimistic in facing this situation. To my mind those who discuss the oil situation may be placed in three categories; the pessimists, the optimists, and the super-optimists. The pessimists I call those who see darkly and will concede no possibility of solution. According to them a few years will see the automobiles piled in windrows of 'dilapidated junk, I have no sympathy with this point of view and deem it vicious and entirely unwarranted.The optimists I term those who believe that there is a solution and that we shall be able to meet all of our reasonable requirements for as far into the future as can be foreseen, yet who recognizes that this desired end can not be attained without prevision and energetic effort.The super-optimists are those who will say to you, ""There is nothing to this talk of shortage, whenever we have needed oil we have always found it and always will."" To these gentlemen the possibility of an inadequate supply of oil is as incomprehensible as the possibility of the extinction of the passenger pigeon was to the early settlers who saw flocks that hid the sun for days during their passage. The passenger pigeon disappeared within two generations thereafter, and I deem this point of view as being perhaps more vicious than that of the extreme pessimist. It seems to me it is nothing less than improvidence lulling us into a false sense of security. There is an old proverb to the effect that ""The Lord helps him who helps himself."" I believe that we shall solve the oil problem, but I do not think it will be solved by vague optimism. It is going to call for our most energetic efforts and I believe we shall have to do a lot of ""helping ourselves."""

Oct 1, 1920

By David C. Oyler, Paul B. Stubbs

The Bureau of Mines and United States Steel Corp. are conducting a joint project to monitor formation pressures at a large (23-well) coal- bed gas drainage field near Oak Grove, AL. Three monitor holes were drilled in late 1981, and pressure monitoring began in December 1981. The Bureau of Mines direct method was used to obtain gas content data from cores taken in the monitor holes. Comparison of the 1981 gas con- tent data from the monitor holes with initial gas content values obtain- ed from the production wells in 1977 indicates a 50-pct reduction in ad- sorbed gas content inside the pattern and a 29-pct reduction at one point 500 ft outside the pattern. The combination of pressure and gas content data has also allowed an in situ isotherm curve, relating the formation pressure to adsorbed gas content, to be developed for the area of the production wells. From the current rate of pressure decline (1 lbf/inz per month), the observed changes in gas content, and the isotherm curve, it appears that most of the early gas production came from within the pattern, but since 1981 (and possibly earlier) most of the gas produced has been migrating to the wells from outside the pattern area.

Jan 1, 1985

By James P. McGee

Preliminary calculations show an economic advantage in using nuclear energy to supply the endothermic heat required for gasifying coal. It should be noted that the various assumptions used in preparing these calculations must undergo further evaluation through additional engineering design and research. The proposed system for gasification is the indirect process cycle with helium heated in a nuclear reactor and passed through an exchanger-type gasifier for the reaction of coal and steam to form CO (carbon monoxide) and H2 (hydrogen gas).

Jan 1, 1960

By Charlie Wyche

The principal minerals produced in the Dominion of Fiji in 1982 were unrefined gold, silver, and tellurium. The combined value of these commodities was about $16 million,2 representing over 85% of the total value of mineral output. Cement, sand and gravel, and quarry products were the other minerals produced in Fiji. Despite the small part played by minerals in Fiji's economy, exploration on land and in the coastal areas was carried out by several international mining companies representing Australian, British, Canadian, West German, and U.S. interests. At the end of 1982, 30 prospecting licenses covering 2,300 square kilometers were issued. Most licenses were for copper, zinc, gold, and silver. Total expenditure on mineral exploration was $3.5 million.

Jan 1, 1984

By John R. Benham

The West Pioneer RARE II study area, No. 1-006 (fig. 1), has Figure 1.--NEAR HERE a high molybdenum resource potential. Two molybdenum-bearing areas are being explored by Utah International and by Cyprus-Moly Corp, Inc. using geophysical exploration and diamond core drilling. The study area also contains potential resources of gold and silver at six prospects: the Bear Paw (Ibex), Black Bear, Coeur d'Alene, Franklin No. 1, Martin, and Maynard. In addition, the Black Rear and the Martin contain possible copper, lead, and molybdenum resources. Most of the workings are caved.

Jan 1, 1981

By Eugene T. Sheridan

This circular presents data on individual plants of the fuel-briquet and packaged-fuel industries that responded to the Bureau of Mines annual economic survey and reported production for 1959. The companies named herein represent virtually all producers of processed fuels of mineral origin. A few small companies may not have been canvassed or failed to respond, however, as some plants operate intermittently, and the survey is voluntary. No consideration was given to size of the plant and all plants that reported commercial production were included. Specifically excluded were plants that manufactured briquets from wood charcoal. Fuel briquets and packaged fuel are manufactured solid fuels, fabricated from fine-sized mineral fuels by mixing with binders and compressing into small individual shapes. Briquets usually are produced as small, pillow-shaped pieces, 2 to 4 inches long, weighing 2 to 4 ounces. Packaged fuel consists of 3- to 4-inch cubes, 6 or 8 of which are wrapped in heavy kraft paper to form a package weighing 10 to 15 pounds. The overall size of a popular package is 10-112 x 7 x 3-1/2 inches. Briquets are durable, may be stored outdoors, and shipped and used as bulk fuel. Packaged fuel is fragile, and must be stored indoors to keep it from deteriorating. Whereas briquets are consumed in many areas as a general residential fuel, packaged fuel is more of a specialty item, used at times as a supplement to other fuels. Package fuel is burned without removing the paper and referred to as the "white-glove" fuel.

Jan 1, 1960

By D. E. Fogelson

In a factorial experiment, blasting caps were detonated in three sizes of shotholes in mortar with three types of stemming--dry sand, wet sand, and hydrostone. Free-surface displacement pulses were recorded with a capacitive-displacement gage at a distance of 15 inches. The effects of decoupling and the type of stemming on the amplitude and the duration of the displacement pulse were determined. Both the amplitude and the duration of the displacement pulse were significantly decreased by increasing the decoupling, but they were little affected by the type of stemming.

Jan 1, 1965

By E. L. Burwell

Application of the in situ recovery process to oil shale was tested during two field experiments near Rock Springs, Wyo. The results of these tests demonstrate that a self-sustaining combustion zone can be created in an oil shale body, that this zone can be moved through the oil shale, and that the process will produce shale oil. Evaluation of the combustion process by monitoring produced fluids for physical and chemical properties and volumes is described. The material and energy balance obtained is compared with a second evaluation based on extensive coring of the test area after the test was terminated. Several side results of the research are noted such as ground surface heating by underground burning and production of low-to medium-Btu gas during retorting.

Jan 1, 1973

By G. P. Sturm

This work was undertaken by the Bureau of Mines in cooperation with the Environmental Protection Agency to determine photochemical specific reactivities of emissions from automobiles using leaded-premium-and regular-grade fuels and prototype lead-free fuels of comparable octane quality. Emissions were photoirradiated in a 100-ft3 environmental (smog) chamber constructed of aluminum and Pyrex glass at three sets of initial hydrocarbon (HC) and oxides of nitrogen (NOx) concentrations. Reactivity was measured and expressed in terms of rate-of-NO formation (RNo2) and dosages of oxidant, peroxyacetyl nitrate (PAN), peroiypropionyl nitrate (PPN), and formaldehyde (HCHO). The results indicate that the evaporative emission samples and the evaporative plus exhaust emissions samples from the lead-free fuels have, in general, higher reactivities per gram than those from the leaded fuels. For the samples containing only exhaust emissions, the only trend observed was the lower specific reactivity exhibited by the leaded premium fuel exhaust. These differences in specific reactivity are taken to reflect the differences in hydro-carbon composition of the fuels and their evaporative and exhaust emissions rather than any difference in lead content per se.

Jan 1, 1973

By W. E. Lamont

Flotation studies of phosphate-bearing waste pond materials, low-grade washer products, and raw ores, all from the Tennessee brown phosphate district, showed that these types of materials could be treated without des liming to recover high-grade phosphate concentrates. The investigation showed that fine grinding before flotation was a requisite for increased recovery of the phosphate values and that the optimum pH conditions were in the range of 10.0 to 10.5 when using anionic collectors. Multiple-cleaning of the rougher phosphate concentrate was required to produce high-grade concentrates. Phosphate recoveries ranged from 60 to 82 percent and were inversely related to the grade of concentrate produced.

Jan 1, 1972

Develop an improved downhole geophone system with enhanced signal/noise ratio for collecting cross-hole seismic data used in tomographic reconstructions. Background The Bureau of Mines is conducting research in the use of cross-hole seismic tomography for detecting and monitoring leach solution flow during in situ mining. This technique requires the use of a downhole seismic energy source in one borehole and a downhole wall-locking receiver (geophone) in another borehole separated from the first by the region to be investigated. Bureau research personnel chose a commercially available air gun for use as the downhole seismic energy source. Unfortunately, commercially available downhole wall-locking geophones that the Bureau tested were difficult to operate in the field, often unreliable and generally inadequate in terms of their signal/noise ratio. Therefore, research personnel began to experiment with an alternative down-hole geophone design that could be used to collect adequate data in a wide variety of borehole and cross-hole field situations. Approach An attractive alternative geophone design would be one that would incorporate a pneumatically operated wall-locking system. As an integral part of the Bureau's existing field system, a portable, high- pressure/low-volume air compressor would have sufficient capacity to operate the air gun as well as several small high-pressure pneumatic linear actuators. This approach was the simplest and most compatible with the research activities being conducted at the site.

Jan 1, 1991