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By B. K. Shibler, I. S. Solet, H. W. St. Clair

"This study was undertaken to provide a more adequate knowledge of the chemistry of the sulfide volatilization process for recovery of tin from low-grade Bolivian ores. The investigation was partly supported by the Department of State under its program for scientific cooperation with South American republics.The results of this investigation demonstrate the conditions under which cassiterite (Sn02) may be converted to stannous sulfide by reaction with pyrite or sulfur vapor. Quantitative data are given on the rate of sulfidization and on the vapor pressure of stannous sulfide.INTRODUCTIONAlthough the United States is the world's largest consumer of tin, virtually no tin ores occur within our national borders. Most of the world's tin supply comes from alluvial deposits in the Far East and in Africa, The major sources of tin ores are Malaya, Indochina, Bolivia, Belgian Congo, Nigeria, Thailand, Burma, China, and the United Kingdom. Bolivia is the only important source of tin in the western hemisphere. It was the chief source of tin f or the United States during World War II. The Government-owned tin smelter at Texas City, Tex., was built primarily for smelting Bolivian ores and depends largely on Bolivian ores for its operation. Bolivia is the only major tin-producing country in which the tin ores occur as vein or lode deposits requiring underground mining. Most of the tin from the Far East and Africa is mined by dredges from alluvial or placer depos its. It is recovered as a high-grade concentrate of cassiterite relatively free from impurities. The tin minerals in the lode deposits are more intimately associated with other minerals and more difficult to separate into a clean concentrate. Furthermore, a large part of the tin in the original ore is lost during concentration. The ores as mined contain only a few percent of tin, so they must be milled to separate the gangue minerals and produce a concentrate containing 30 to 40 percent tin before they are shipped to the smelter. The losses of tin that occur during milling vary from 18 to 65 percent. The average recovery of tin from Bolivian ores is probably 50 to 60 percent."

Dec 1, 1954

By C. E. Saxon, F. E. Cash

"Adequate lighting for all mining operations would unquestionably tend to promote both safety and efficiency; this would be true not only for men but also for the animals that man impresses into service in mines. The Markeeta Coal Co. and the Alabama Fuel & Iron Co. both operating mines in Alabama, have found that equipping mine mules with portable electric lights is more efficient, much more humane, and far more safe for both men and animals then the more or less usual method of forcing the animal to do its work essentially in darkness.This report is intended to give the mining industry data, that will aid in trying to bring about safe and efficient operation of mines.The authors desire to thank Charles F. DeBardeleben, president, Fred R. Bell, general manager, Hewett Smith, C. H. Shepherd, and R. A. Sensing, superintendents for the Alabama Fuel & Iron Co.; and Charles F. DeBardeleben, Jr., president, and H. M. House, superintendent for the Markeeta Coal Co., for their cooperation in furnishing the data for this paper.The eight mines operated by the Alabama Fuel & Iron Co. and one operated by the Markeeta Coal Co. in Jefferson and St. Clair Counties, Ala., are the only mines in Alabama where mules are provided with portable electric lights, and there are few if any mines in other States in which this system is in use.These two companies are convinced that equipping all mine mules with good lights decreases underground haulage cost by animals by prolonging the useful life of the animals, increasing their efficiency, lessening haulage wrecks and delays on haulage, and increasing production. Last but not least of the advantages would be the more humane treatment of the animals.The nine mines are developed by slopes along the dip of the coal bed, with double-room entries on 200- to 300-foot centers turned right and left off the slopes and with approximately 1 per cent grade in favor of the loads. Rooms are driven up or diagonally up the pitch from these entries.A surface hoist delivers the empties from the surface to the entry sidetracks at the slope and pulls the loads to the surface. From these sidetracks, mules pull one to four wooden cars, each of which holds 1-1/2 to 2-1/2 tons of coal, deliver the empties to the rooms and entry faces, and pull the loads to the slope sidetracks. The mule haul varies from 100 to 3,000 feet; there are no locomotives or trolley wires in any of these nine mines, seven of which are rated as gassy and two as nongassy by the Alabama state Mining Department."

May 1, 1933

By L. C. Marchont

This Bureau of Mines report tabulates data on nitrogen-gas reservoirs and isolated occurrences of inert gases in several Williston basin oilfields. Recoverable reserves of nitrogen gas in the Minnelusa nitrogen interval within the areas of five oilfields on the Nesson anticline in North Dakota are estimated at about 1.27 trillion standard cubic feet, based on computer analyses of logs from over 300 wells. This volume of nitrogen represents a large source of high-pressure inert gas and warrants consideration of possible application in oil-production operations. Drill-stem tests made in two of the fields indicated that nitrogen can be produced at rates up to 28 million cubic feet per day.

Jan 1, 1966

By E. H. Denny

A most interesting safety record has been made by the Colorado Fuel and Iron Co. s. Robinson ho. 1 mine located at Walsen, Cola. Mr. J. L. McBrayer has been superintendent of the Robinson No. 1 and 2 mines for the past 2 1/2 years, and Mr. David Muir has been foreman of the Robinson No. 1 mine since June, 1913. The last fatal accident at Robinson No. 1 mine occurred on July 27, 1915, and the tonnage produced at this mine since July 28, 1915, has been as follows:.

Jan 1, 1929

By A. C. Fieldner

In preparing this paper, an attempt was made to obtain results of plant-scale carbonization tests on washed and unwashed coal from the same mine. A letter. in which the following questions were asked was sent to some 50 coke-oven superintendents and others who might be interested; "What is the influence of washing coal on: (1) The chemical and physical properties of coke, as for example, the size the amount of breeze, the fracture, strength, cell-structure, etc. (2) The quantity and quality of gas and by-products. (3) The capacity of the ovens. (4) The composition of the coal. "Your general opinion, as well as any specific data or results of tests, on this important subject will be arc greatly appreciated."

Jan 1, 1930

By JOSEPH F. CULLEN, Dorsey A. Lyon

In connection with its investigation looking to the prevention of waste and the increase of safety and efficiency in the mineral indus- tries the Bureau of Mines has undertaken a study of the possible uses of the electric furnace in metallurgy. This bulletin presents a com- pilation of such data as seem to be useful for the information of persons who may be interested in the matter. In the application of electricity to metallurgy three kinds of processes are involved, namely, mechanical, thermal, and electrolytic. Under the mechanical application of electricity come those proc- esses of dressing and concentrating ores that are known as either electrostatic or electromagnetic processes. In electrothermic processes the current is used as a source of heat. The fundamental differences between the various types of electric furnace that are at present in commercial use relate to the manner in which the electric current is applied, as may be noted by reference to that part of this report in which the subject is discussed. In electrolytic processes the electric current is used for depositing metals from solutions. The process may be conducted in one of the following ways: (1) The material to be treated may be put into solu- tion and then electrolyzed, the material thus treated forming the electrolyte; (2) the material to be treated may form the anode or be placed in contact with the anode; or (3) the material to be treated may form the cathode or be placed in contact with the cathode. This report treats of electrothermic processes, with the possible exception of those for the reduction of aluminum from its ores. Moreover, of the processes used in the so-called electrochemical in- dustries only those for the reduction of an ore to metal, or to a com- pound of the metal that is of value in itself, or is an aid in metallurgical work, are here discussed.

Jan 1, 1914

By John Campbell, E. S. Baker, G. W. Jones

"INTRODUCTION In previous reports 5,6./ results were given showing the amount of natural ventilation that takes place in manholes (capacities, 74.1 to 308 cubic feet) when the number of ventilation openings in the manhole cover ranged from no openings to a maximum of 4g.The tests warranted the general conclusion that the ventilation or air changes taking place in, a manhole increase as the area of openings in the cover of the manhole is increased, and are proportional (with the exception of a few erratic tests) to the area of the openings in the cover. The area of the openings was the chief factor that affected ventilation.The results did not show any marked change in rate of ventilation due to increased capacity or shape of manhole, when the results were expressed in terms of air changes per day versus area of ventilation openings in square inches per 100 cubic feet of manhole space.It was observed during these investigations that in certain tests that showed erratic results (that is, did not agree with the general average for a given set of test conditions) the wind velocity during the test period was also abnormal. In view of these findings it was decided to conduct a series of tests in which the wind velocity across the openings in the manhole cover could be controlled accurately to determine the effect of wind velocity on ventilation rate."

Aug 1, 1938

By Wilbert T. Malenka

In its search for a highly productive mining system for anthracite beds pitching from 100 to 200, where conventional mobile equipment cannot be used) the Bureau initiated a longwall project by introducing a shearer drum cutter loader of European origin. Because of the undulating nature of the roof and floor and changing bed thicknesses, the machine proved inflexible and extra work was required in lifting bottom coal and blasting top coal.

Jan 1, 1966

By J. M. Kuchta

Experimental data are presented on the autoignition temperature (AIT) characteristics of the hydrocarbon jet fuel, JP-6, in various oxygen-nitrogen atmospheres under conditions of constant volume and constant pressure. AIT's of this fuel in air varied little with fuel injection pressure but increased greatly with decreasing fuel content at low fuel-air-ratios. They also increased with decreasing oxygen content of the fuel vapor-oxidant atmosphere. Consistent with thermal ignition theory, the ignition temperatures increased with decreasing initial pressure, ignition delay, and vessel radius; expressions are given which define the observed variation of AIT with these variables for JP-6 fuel vapor-air mixtures. The significance of autoignition temperature data obtained using various ignition criteria is discussed to show the usefulness of such data in evaluating fire and explosion hazards. In addition, data are presented on the extent of oxidation that occurs prior to autoignition of this fuel in air at various temperatures.

Jan 1, 1965

By E. C. Lane

During the past 15 years the Bureau of Mines has made and published several hundred analyses of typical petroleums and has developed a system of interpreting the analyses and of classifying crude oils. In describing crude petroleum frequent reference is made to the "base" of the oil, a usage the petroleum industry has found convenient. As part of its general study of the characteristics of crude oils, therefore, the Bureau of Mines has developed a system of classifying them according to "base." This system as first published in 1927 was limited to four classes and in its original form is no longer considered adequate. Since the system was first published the Bureau has analyzed a large number of crude oil, including representative samples from nearly every important producing field in the world, and has found that the system of classification could be revised and amplified to advantage. The revised system is presented herein.

Jan 1, 1935

By E. G. King

Many of the rare-earth oxides are now commercially available in pure form and they have a variety of potential technical uses. Thermodynamic data for these oxides, however, are rather sparse. It is one of the functions of the Bureau of Mines to fill the need for this type of information. This report gives the results of low-temperature heat-capacity and high-temperature heat-content measurements by the Bureau of Mines of lanthanum sesquioxide. The entropy at 298.15° K. was evaluated and heat-content and entropy increments above 298.15° K. were obtained to 1,800° K. The results were combined with the known heat of formation at 298.15° K. to derive heats and free energies of formation at higher temperatures. Sufficient information is now available to permit reliable thermodynamic calculations involving lanthanum sesquioxide within the temperature range 298° to 2,000° K.

Jan 1, 1961

In the interest of safety in metal mining, the Bureau of Mines recommends: That underground metal mines be equipped with a main fan in a fireproof housing, located preferably on the surface. The fan installation should be designed to ventilate the mine adequately throughout and to permit prompt reversal of direction of air flow. Many metal mines depend for ventilation upon natural flow of air, assisted by the exhaust from pneumatic drills and by compressed air blown into the workings. Others also ventilate separate headings or sections with fans and blowers. Relatively few have o mechanical ventilating system that controls the coursing of air throughout the mine.

Jan 1, 1939

By M. J. Ferrante

The standard enthalpy of formation, low-temperature heat capacities, and enthalpy increments above 298 K were determined by the Federal Bureau of Mines for synthetic dawsonite [NaA1C03(OH)21. The enthalpy of formation was determined by hydrochloric acid solution calorimetry, with the result ?Hf°298 = -469.4±0.7 kcal/mole. The low-temperature heat capacities were determined from 6 to 307 K by adiabatic calorimetry. Tabulated are low-temperature values of Cp°, S°, and H.-Ho° from 3 to 298 K. The derived entropy at 298 K is S298 = 31.55±0.3 cal/deg mole. Enthalpy increments above 298 K were obtained by copper-block drop calorimetry. Tabular data of Cp°, S°, H°-H°298, -(G°-H°298)/T, ?Hf°, ?Gf°, and log Kf are given from 298 to 477 K. Enthalpies and Gibbs energies of decomposition are also reported.

Jan 1, 1976

By R. H. Thompson

Six different types of blasting caps, mainly of the type used in coal mines, were evaluated to determine both their 1lF and DC characteristics. Two of the caps were of foreign manufacture. All the American made caps had "no-fire" (0.1% firing probability with 95% confidence, as determined by the Bruceton test) levels above 0.04 watts. One of the caps of foreign manufacture had a "no-fire" level of 0.023 watts. A worst case analysis of blasting cap pick up of RF power in coal mines was performed and safe distance curves were generated.

Jan 8, 1973

Improve ground control in longwall gate entries by developing a practical method for evaluating longwall pillar designs. Background Longwalls have emerged as the most important technology to be applied to underground mining since the continuous mining machine. Longwall mines currently produce more than 30 pct of all the underground coal mined in the United States, up from less than 5 pct just 15 years ago. Safe longwall mining depends on maintaining ground control in the gate entries, the lifelines that provide access to the longwall face. In multientry retreat mining as practiced in the United States, rows of chain pillars are left to protect the gate entries (see figure 1). Chain pillars are subject to severe and complex abutment loads during the process of longwall panel extraction. The design of these pillars is often the single most important element in gate entry ground control and has been the subject of intensive Bureau of Mines research.

Jan 1, 1991

By Daryl E. Radcliffe

This report describes an instrument system developed by the Bureau of Mines to continuously monitor and record changes in roof displacement during underground mining activity. The instrument consists of a single-wire extensometer coupled to a mechanical-drive chart recorder mounted in an aluminum frame installed in the roof. The unit is small and simple to install and meets safety requirements for use in underground coal mines.

Jan 1, 1977

By F. E. Cash

The Holmes Safety Association , organized and named in honor of the late Dr. Joseph A. Holmes , first director of the United States Bureau of Mines , has for its object the prevention cf accidents , the improvement of health conditions at work, in the home , and in public places , and the promotion of the general welfare of its members . As a means of preventing accidents and advancing health and safety , the Holmes Safety Association disseminates information , gives instructions on subjects related to safety , and promotes first -aid and other forms of protective and accident - prevention training . This organization is intended to work and cooperate in the closest possible way with existing mine or plant safety organizations in conducting educational , social , and recreational activities for the promotion of health , safety , and efficiency .

Jan 1, 1929

By D. E. Shanks

The Bureau of Mines investigated the effects of HCI concentration and solution temperature on the solubility and crystal form of the chlorides of Co, Mn, and Ni when sparged with HCI gas at temperatures of 20°, 40°, and 60° C. Increasing HCI concentration in solution caused the chlo-rides of Co, Mn, and Ni to crystallize (salt out) because of the common ion effect. The salting-out crystallization was most effective for NiCI2, which had a solubility of 0.7 pct at 20° C and maximum HCI concentration. COCl2 salted out to a minimum solubility of 9.4 pct at 20° C and 22 pct HCI concentration and increased in solubility at greater HCI concentrations because of the formation of chloride complexes. MnCl2 was intermediate in behavior. The effect of temperature on solubility was greatest for CoCl2 and least for NiCI2, 15 and 7 pct change, respectively, over the temperature range of 20° to 60° C. The salted-out chlorides of cobalt and nickel formed the hexahydrates and those of manganese formed the tetrahydrate in saturated metal chlo-ride solutions at 20° C and low concentrations of HCI. Increasing the temperature or the HCI concentration caused a 108s in waters of hydra-tion. At 60° C, the salted-out crystals of NiCl2 formed the tetrahydrate in HCI concentrations up to 18 pct and the dihydrate at higher concentrations, while cobalt and manganese chlorides formed the dihydrates, even in water.

Jan 1, 1985

Are you afraid of the dark? Of course not, at least not since you were about six years old, anyway. But early man was - afraid of the dark, and he had good reason to be. Since he had no illumination other than fire and moonlight, he was at a disadvantage when it came to mixing it up with some of his fellow creatures. Sabre-toothed tigers, for example, could probably see quite well In the dark, and they were very real enemies. Sabre-toothed tigers haven't been seen in mining country for some time now; but it's st111 dark In a mine and, make no mistake about it, there are still enemies in the dark. The enemies are all the things that can injure you if they are not seen. Modern mines can be safe places to work for the trained miner who follows good work practices. But there are mining machines that make sabre- toothed tigers look like pussycats, and if you can't see well enough they can be ten times more dangerous.

Jan 1, 1976

By John B. Bennett

This Bureau of Mines report presents a method of standardizing forecasts of mineral consumption that attempts to resolve the problems caused by the use of different data bases, different definitions of minerals consumption, and different base years for making projections. Using this method, forecasts of U.S. and world mineral consumption, in the year 2000, for nine commodities (aluminum, chromium, cobalt, copper, manganese, nickel, tin, tungsten, and zinc) are standardized and compared. Also selected forecasts or associated growth rates are used to generate implied values of consumption for 1980-83, which are then compared to actual values of consumption for 1980-83. The economic growth predictions underlying the forecasts are examined, and some general conclusions are drawn. A description of each methodology used to generate these forecasts is given in an appendix.

Jan 1, 1986