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By J. R. Cobble

Dissolution of chalcopyrite with acidified ferric sulfate produces a sulfur layer on the unreacted chalcopyrite surface that interferes with further dissolution. The U.S. Bureau of Mines has developed a process to improve the leaching kinetics of these types of diffusion-controlled systems. The system features the Bureau-developed turbomill, an attrition grinder that scrubs the reaction product coating away from the unreacted mineral grains during leaching. The system can be operated continuously at any temperature up to the boiling point of the leaching agent. This method is a hydrometallurgical alternative to chalcopyrite smelter technology and eliminates sulfur dioxide emission problems with its associated costs. Batch testing at 900 C with the chalcopyrite-ferric sulfate system resulted in copper extraction exceeding 99 pct. At an optimal energy consumption of 1,520 kW· hjst, 95 pct of the copper was extracted. The pregnant liquor was clarified and tested for typical solvent-extraction recovery of the copper. Two-stage extraction and two-stage stripping recovered 96 pct of the copper in an electrolyte suitable for copper electrowinning.

Jan 1, 1993

By Jos. R. Guiteras

This paper is one of a series published by the Bureau of Mines on mining and milling methods and costs. It describes operations in the Alma district of Colorado in September 1937, supplemented by some additional data collected in July 1938. ACKNOWLEDGMENTS The author wishes to express his appreciation of the friendly cooperation extended him by the mine operators in the district. The greater part of the information was obtained from mine and mill superintendents to whom individual acknowledgment is made in the text.

Jan 1, 1940

By J. K. Whyatt

Assuring ground control safety in many mining and tunneling projects depends, at least in part, on an understanding of in situ stress conditions that will be encountered. Yet it is rarely practical to conduct more than a very limited number of stress measurements. Stresses along the route of a proposed excavation are typically interpolated from available measurements, often assuming a linear variation of stress with depth (or elevation). However, projects where multiple stress measurements are conducted often report more complex variations of in situ stress, usually in apparent relationship to geologic structures. These structures often include lithologies of contrasting elastic properties. A method is proposed for estimating stresses in these cases by first back-calculating regional loads from available stress measurements and then modeling the distribution of stress throughout the rock mass. The method has been successfully applied to a set of in situ stress measurements from the Coeur d’Alene Mining District of northern Idaho, USA. Results provided new insights into district stress conditions and the distribution of rockburst hazards along mine drifts and between various mines. This success should transfer readily to suitable deep tunneling projects.

By L. B. Pankratzt

The heat capacity of dimo1ybdenum carbide (Mo2C) was measured from 51° to 298° K, and the entropy at 298.15° K was evaluated. Heat content measurements above 298.15° It were conducted for dimolybdenum carbide (M0caY) and monotantalum carbide (TaC). The results were combined with known heats of formation and the 298.15° K entropy for TaC to obtain values of the heat and free energy of formation from 298.15° K to 1,400° K for MoaC and from 298.15°K to 1,800° K for TaC.

Jan 1, 1966

By Oliver Bowles

The mineral asbestos, because of its unique fibrous character, is allied to cotton and wool but has the advantage of heat and fire resistance; therefore, it supplies many industrial needs for which no substitutes are yet available. This report covers the essential features of the asbestos industry, including occurrence, production, mining, milling, utilization, international trade, and marketing. The United States leads all countries in the manufacture of asbestos products, but domestic sources furnish only a small fraction of the raw material required. As the United States is dependent to so great an extent on foreign supplies of raw materials, the bulletin deals at length with the asbestos industry in foreign lands. Several reports now available deal with the industry in individual countries. Among them are Chrysotile Asbestos in Canada, by J. G. Ross; Asbestos in the Union of South Africa, by A. L. Hall; and a series of articles on the Russian industry, by Walter A. Ru Keyser. These have been drawn upon freely, and full acknowledgment is hereby made for the helpful information thus secured. The file of the magazine Asbestos also has furnished many valuable data touching all phases of the industry. Many other books and articles listed in the bibliography at the end of this bulletin have been utilized and have been supplemented by the author's intimate acquaintance with the industry for about 20 years. The intent is to present a concise, world-wide, historical, technical, and economic treatment of the asbestos industry.

Jan 1, 1937

By Alan D. Hartman

Instabilities in electric steelmaking furnace arcs cause electrical and acoustical noise, reduce operating efficiency, increase refractory erosion, and increase electrode usage. The U.S. Bureau of Mines is investigating methods to stabilize these arcs. To perform experiments to test new hypotheses, Bureau researchers designed and instrumented an advanced, experimental single-phase furnace. This report describes this furnace, which was equipped with high-speed data acquisition capabilities for electrical, temperature, pressure, and flow-rate measurements; automated atmosphere control; ballistic calorimetry; and view ports for high-speed cinematography. Precise environmental control and accurate data acquisition allow the statistical design of experiments and assignment of rigorous confidence limits when potential furnace or procedural modifications are tested.

Jan 1, 2010

The Bureau of Mines, U.S. Department of the Interior, devised a flotation technique for upgrading chromite in chromium ores and gravity concentrates. The technique consisted of cationic flotation of chromite from a slime-free pulp acidified to pH 2.5 or lower using H2S04 modifier. Flotation results showed that ore containing serpentine as the primary gangue mineral was more amenable to concentration by this technique than ore containing the readily floatable olivine as the primary gangue mineral. Rougher flotation of a chromite ore containing abundant serpertine increased the grade form 19 to 41 percent Cra03 at a chromite recovery of 89.6 percent. Rougher flotation of ore containing abundant olivine upgraded the chromite from 23.4 to 29.6 percent Cr203 at a recovery of 89.4 percent. The technique was also applied to chromite gravity concentrates to further upgrade chromite and to reject silicates. Flotation of a gravity concentrate containing 40.9 percent Cr203 and 4.4 percent SiO2 recovered 90 percent of the chromite in cleaner products containing 44.9 percent Cr203 and 0.63 percent Si02. The combined recovery by gravity and flotation was 87 percent. An economic evaluation of this technique will be undertaken to deter-mine its feasibility for commercial use.

Jan 1, 1980

By M. H. Kersten, G. A. Brady, Jerry W. Ramsey

Anthracite samples were oxidized with nitric acid to prepare products representing intermediate stages of oxidation . Similar oxidizing conditions affected different anthracites to varying degrees as characterized by peptization behavior with 0.1 N NaOH . Techniques used in attempts to separate and characterize the products included esterification , absorption spectrophotometry , sublimation , chromatography , electrophoresis , metal salt formation , and solvent extraction . Mellitic acid , either free or in the form of metallic salts , was identified in the acid- soluble products from 10 tests in which the anthracite was treated with nitric acid for periods varying from 24 to 1,000 hours . pentacarboxylic acid was also found in some products . Other benzene carboxylic acids were not present in amounts detectable by the methods used in this study . The acid- insoluble residue from nitric acid treatment varied significantly in solubility behavior toward different classes of solvents . The most effective ones tried included polar oxygenated solvents and pyridine . Infrared spectra of the extracted material indicated that similar compounds were extracted by the different solvents . Aliphatic amines and aniline peptized the residue and o- toluidine reacted with it . Organic material separated from the residue by peptization with dimethylformamide contained 1 percent ash , consisting of more than 50 percent zirconium .

Jan 1, 1964

By Lloyd A. Morley, Alan M. Christman

General Six open-pit metal mines, five copper and one molybdenum, were visited during the course of the research. Four were investigated twice, in summer and in winter, in order to determine the effects of seasonal variations In temperature and moisture upon the measured parameters, Permission to enter the fifth mine was received too late to make an examination during the summer months. The sixth mine was visited to confirm the results obtained from the other five and specifically, to observe how the project recommendations (as will be presented in this chapter) would apply to open-pit metal mines in general. Information gathered during the ten plant visits is sufficient to form an adequate data base for the report. A complete presentation of all field trip data is given in Appendix 1. Further, a detailed description of the electrical distribution and grounding practices at each mine is also contained there. Typical System. At a typical mine as shown schematically in Figure 62, one or more substations with resistance-grounded secondaries are employed to transform the incoming utility-voltage to the lower potential used by the mining machines, generally three-phase 4160 V. At this level, pit distribution is carried on overhead lines, supported by wooden poles, to supply switchhouses located in benches near the particular piece of equipment. A switchhouse is a small portable (often skid-mounted) structure at the termination of an overhead line which contains disconnect

Jan 1, 1976

By G. H. Martindill

Complex chemical and physical changes occurring during carbonization result in a heterogeneous system composed of gaseous, liquid, and solid phases, whose relative proportions and chemical compositions change constantly as temperature increases. Studies in which the participating variables are isolated and controlled should be useful in formulating the mechanism of coal carbonization. The most characteristic property of a coking coal is its ability to form a plastic mass at a certain stage of the carbonization process. During this period it is believed that fluidity of the coal influences the properties of the resultant coke. This report gives results of an investigation by the Federal Bureau of Mines of the influence of the maximum fluidity attained by the charge on the physical quality of the coke or char produced. As a first approach to the problem, researchers investigated high-melting-point pitches, which are relatively simple carbonaceous materials. The plastic properties of these pitches, prepared specially for this work, varied greatly; their fluidities, as measured by the Gieseler plastometer, covered most of the fluidity range characteristic of coking coals. Blending these pitches with increasing pro-portions of fine coke progressively reduced their fluidities. Coal-pitch and coal-coke blends also were treated; their fluidities were varied by changing their blending ratios. The various blends were carbonized in a small-scale carbonizer and the resistance of the carbonized residue (char) to abrasion was determined in a small-scale tumbler test, using the Roga drum.

Jan 1, 1960

By M. E. Kundick, W. E. Dieter, L. Cohen

The major details of design and maintenance of a seamless stainless steel fume hood system , developed by the Bureau of Mines , are described and illustrated . Operating and housekeeping routines are outlined .

Jan 1, 1964

By James P. Ulery, Frank E. Chase

Clay veins found in coal mines have caused numerous injuries and fatalities. These structures plague all phases of mining, including entry development, pillar recovery, and panel extraction. Clay veins also increase production costs and may disrupt or halt mining. These detrimental aspects have prompted the Bureau of Mines to investigate the physical characteristics of and roof instability problems associated with clay veins. This was accomplished by observing and mapping clay veins in surface and underground mines. The occurrence and origins of clay veins were also investigated to determine predictive capabilities. The investigators found that clay veins normally occur in more stable, less rapidly subsiding coal basins. Clay veins result when tensile stresses develop fissures which are later infilled. These fissures can be propagated by compactional processes and/or tectonic stresses active during and subsequent to coalification. The Bureau also found that associated faults, fractures, and slicken-side planes commonly parallel clay veins and disrupt the lateral continuity of the immediate and, sometimes, main roof. When clay veins parallel or subparallel the direction of face advance, the roof is segmented into cantilever beams, causing unstable conditions. Consequently, the strata on either side of the clay veins should be bolted and strapped together to form a beam.

Jan 1, 1987

This project, "Analysis of Men, Materials and Supplies Handling Systems in Underground Metal and Nonmetal Mines" documents the productivity and safety aspects of the existing equipment and systems utilized in transporting personnel and supplies from the surface to the underground production work place. The Present Systems Study (this text -Volume II) documents the productivity and safety of existing men and material movement systems for six representative underground metal and nonmetal mines. Identification of common problem areas was performed using recognized industrial engineering techniques. The back-up data for the industrial engineering analysis of each mine is included as respective appendices (Volume III). A summary of the study background material, six mines' problem areas, comparison of problem areas, problem analysis, and solution recommendations are included as the project final report (Volume I), bound under separate cover.

Jan 1, 1975

By Rustu S. Kalyoncu

Nonoxide ceramics with improved high-temperature properties could substitute for high-temperature alloys and reduce toe Nation's dependence on imports of Cr, Co, Ni, and Mn. To meet this objective, the Bureau of Mines conducted research to synthesize u1trafine reactive boron nitride (BN) powders BN powders were prepared at temperatures ranging from -75? to 750? C. Low-temperature reactions (-75? to 200? C) between boron halides and N compounds led to formation of e1emento-organic compounds that were thermally decomposed to u1trafine (approximately 100-to 150-A particle size) reactive BN powders. BN powders were also prepared through the reaction of a 10w-me1tinginorganic B compound (boric acid, borax) with an organic N compound (carbimide and thiocarbimide) in N2 and/or ammonia (NH3) atmospheres at temperatures between 500? and 750? C.

Jan 1, 1986

By Will H. Coghill

The jig men of the Tri-State (Joplin-Miami) zinc district complain about the flakiness of their mill feed. They believe that the flakiness of the composite grains of gangue and mineral are to blame for losses of zinc; that is, that the flaky grains in the jig tailings have higher zinc tenor than the cubical grains. Although the evidence which follows contradicts this belief, no effort is made to give a final and conclusive answer. On the other hand, there is outlined a positive and mechanical method which the operator may use to pursue this and similar investigations. DISCUSSION OF SCREENING METHOD Hand-sorting is obviously not satisfactory for separating cubical grains from flaky grains because the personal influence can not be removed. Screens, however, may be used with success. A set of each of two types of screens is required; namely, the square-hole type and the rectangular (rectang, oblong) type. The square-hole screens must be of the double Tyler scale; that is, the order of the sieves should be after the fourth root of two instead of the customary square root of two; close sizing is important. The size of the rectang screens may be selected by trials so that a part of the material already closely sized on the square-hole screens, will pass the oblong holes. Obviously, the cubical grains will remain on the rectang and the flaky grains will pass through. Hence the mode of operation is to screen first on square-hole screens and then split the products on the oblong-hole screens.

Jan 1, 1928

By H. C. Hamontre

[The Bureau of Mines well-bore caliper was designed to provide an instrument that could be operated through 2-inch tubing, which 'a used particularly in many input wells on water-flooding projects of eastern, Kansas and northeastern Oklahoma. It should find wide application elsewhere under many other conditions where it has not been possible previously to make caliper logs with the larger probes used on other instruments. The caliper has three additional advantages over other instruments of this type: (1) It measures 4 radii (up to 18 inches) 90° apart with an accuracy of ± 1/4 inch; (2) the measuring arms can be opened and closed at will by remote control; and (3) it is run and operated on a single-conductor, armored electric cable (Amergraph, type 1-H-0). The caliper probe is 1-3/4 inches in diameter and approximately 6 feet in length. The electrical control and measuring circuits are encased in a stainless-steel tubular case. Measuring arms, made of 5/16-inch aluminum tubing, are attached near the lower end of the instrument. Distances the arms are extended are indicated t the surface by a meter calibrated to read directly in inches. Depths at which the radii measurements are taken are indicated by a wireline depth indicator on the cable-reeling. The instrument is not affected by pressure or temperature, it can be run open hole or under pressure through a lubricator. This paper describes and illustrates the instrument and outlines the operating procedures. A bibliography at the end of the report gives references to articles and patents on the development and use of other well-bore calipers.]

Jan 1, 1954

By Jr. Norman

The Bureau of Mines investigated the thermoelectric properties of yttrium selenides and tellurides from room temperature to 900° C. X-ray crystallographic data were determined for the yttrium-selenium and yttrium-tellurium compounds that were orthorhombic with a cubic substructure. The yttrium selenides and tellurides exhibited semimetallic to insulator conduction properties with figures of merit of 10-9 to 10-4 °C-1. The mono-selenide and monotelluride behavior was partially degenerate; unsatisfied bonds were the source of the large number of charge carriers. The higher stoichiometry selenide compounds were intrinsic semiconductors) but with high electrical resistivities. A critical defect or impurity ionization energy for carrier activation appeared to exist in the majority of telluride compounds. Mobility and energy band determinations are required to interpret completely the observed effects in most of the compounds studied.

Jan 1, 1966

By J. P. Dunford

This U.S. Bureau of Mines report describes the development of a yielding steel post for underground mine support. The report covers concept development, laboratory tests, modifications, and field evaluations. The objective of this work was to develop a stiff support member capable both of supporting high loads and yielding when excessive amounts of mine entry closure were present. The 6-to 7-ft steel post was designed to yield nearly 2 ft while maintaining a 45-ton (force) load. The post is a three-piece unit consisting of top and bottom telescoping legs and a separate foot bracket. It develops its load-carrying characteristics when the lower pipe, with an attached interference ring, is forced into the larger top pipe. Laboratory tests were used to determine critical loads and post performance for various post lengths. Field tests showed that the posts could perform in actual mining conditions. The post has the ability to provide support in highly yielding ground and also, because of its slender profile, enhance ventilation and provide more area for travelways and escapeways. The design is simple enough to allow for fabrication at most mine shop facilities.

Jan 1, 1989

By W. F. M. GOSS

The locomotives in service on the railroads of this country consume more than one-fifth of the total coal production of the United States. The amount is so large that any small saving that can be made effective in locomotive practice at once becomes an important factor in conserving the fuel supply of the nation. For this reason the United States Geological Survey gave attEmtion to the special problems of combustion in locomotive boilers. It approached this task from several different directions. The facts presented herewith constitute one series of results. In the fall of 1906 the locomotive-testing laboratory of Purdue University, at Lafayette, Ind., entered on a series of tests, one purpose of which was to determine in precise terms the degree of efficiency with which a modern high-class American locomotive utilizes the heat energy of the fuel supplied to it. The general interest in the subject, the elaborate plans which had been formulated for conducting the work, and the substantial character of the support which had been pledged to maintain it justified the Geological Survey in aiding the investigation. a The cooperation of the Survey consisted in detailing experts to assist the regular staff of the laboratory in the chemical and calorific work of the tests. These experts, working under the general supervision of the director of the Purdue laboratory, became responsible for the sampling of smoke-box gases, of the fuel used, of the cinders caught in the front end, of the sparks discharged by the stack, and of the refuse caught in the ash pan. The gas analyses were made by them at the university laboratory. The analyses of all solid samples and the calorific tests of the fuels were made at the government fuel-testing plant at St. Louis. The representatives of the Survey were not concerned with other phases of the work.

Jan 1, 1911

By John Jordan, Tesarik, Steven J. Knoll, Theodore J. Williams, David K. Denton, Douglas F. Scott

Highly stressed rock in stopes continues to be a primary safety risk for miners in underground mines because this condition can result in failures of ground that lead to both injuries and death. Personnel from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health studied two methods for identifying stress in rock. A seismic tomographic survey, finite-difference analysis, laboratory measurements of compression wave (ultrasonic) velocities in rock cores, and site geology were integrated to evaluate the use of seismic tomography for identifying induced pressures in an underground pillar at the Edgar Mine, Idaho Springs, CO. Electromagnetic (EM) emissions were also investigated in the Galena Mine, a deep underground mine in Idaho, in an effort to determine if these emissions could be used as indicators of impending catastrophic ground failure. Results of this research indicated that (1) seismic tomography appears to be a useful tool for determining relative stress in underground pillars, while (2) EM emissions do not appear to be significant precursors of impending catastrophic ground failure.

Jan 1, 2004