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THE Synthetic Liquid Fuels Act (30 U.S.C., 321-325, and amendments) become law April 5, 1644, and a period of intensive research and development in this field was begun by the Bureau of Mines. As part of this program bulletins were published on a pressure hydrogenation,3 the Fischer-Tropsch synthesis,4 and oil shale.5 The Bureau also has published a short bibliography on coal gasification,6 mostly of a theoretical nature. Because coal gasification is prerequisite to Hither the Fischer-Tropsch or coal-hydrogenation processes, publishing this sizable, collection of technical information in this form will be valuable. The material is presented in three parts, as follows: I. United States Patents. II. United Kingdom, Australian, Canadian, and South African Patents. III. Belgium, French, German, Italian, and Swedish Patents. The domestic patents for this bulletin were collected between 1963 and 1955. Some of the Foreign Patents were collected at the same time and a few of them later in 1961. Part I was published in 1960; Part II was published in 1962.

Jan 1, 1964

By Charles B. Carpenter

The New Hope field was selected for study by; Bureau of lanes engineers because many problems met by, the operators during development and operation were unique to petroleum-engineering experience. Solving these problems is believed to have doubled the ultimate recovery of oil from the field. Since the discovery well was 'completed, in April 1943, an oil-productive area of 4,950 acres- has been delineated by the drilling of 64 wells, four of which were dry holes. Four oil-bearing reservoirs - the Bacon oolitic limestone, and the Hill, Pittsburg) and Elledge sandstones, all, in the Trinity group of the Lower Cretaceous series-- have been penetrated at depths ranging from 7,300 to 8,100 feet. Three of these reservoirs were found to be closed-type or solution gas-drive reservoirs, and one - the Hill - was an open-type or water-drive reservoir. During the course of the study, the Tide Water Associated, Oil Co. and -Seaboard al Co. of Delaware made available to the writers all well records, electric logs; and coring, production,, and pressure data. The ,writers performed Certain field and laboratory- tests on cores of ,the reservoir racks and' samples -of the reservoir Oils. Analyses of cores from the four reservoirs showed average .porosities ranging from 10 to 18 percent, average permeabilities of 17 to 297 millidarcys, and -average 'connate water contents ranging from 25.4 to 30.6 percent. Subsurface and recombined samples of reservoir oils indicated that the oils in the Bacon Hill, and Pittsburg reservoirs contained ,206 to 422 cubic feet of gas in solution per barrel initially, and that the, reservoir oils were undersaturated with gas. No samples' of oil from the Elledge reservoir were analyzed, and because of meager data this reservoir was not studied in detail. 4 The presence of free 'gas' or a' gas cap, however, indicated that the oil in the Elledge reservoir was saturated with gas. The rapid decline in pressures in- the' four reservoirs during the 'first year of operation alarmed the operators and provoked them to investigate the reservoir conditions to determine the cause.

Jan 1, 1949

By E. P. Youngman

Titanium ranks as one of the more abundant elements, is widely distributed, and occurs in concentrated form in numerous deposits. This substance was discoveres 140 years ago; but despite the efforts of metallurgists and chemists to find a place for it in industry, only within the last 10 or 15 years has the increased use of titanium pigments provided any extensive outlet for titanium ores. Even to-day titanium is confined to a few highly specialized industrial applications. The metal itself is now quoted regularly in trade journale, but scarcely yet can it be said that the production or use of the metal. has progressed very far beyond the laboratory stage. Ferroalloys containing the element were largely used for a time, especially in connection with the manufacture of Bessemer steel rails; but as American rail- ways adopted open-hearth rails in preference to Bessemer rails, the demand for the alloys in the rail manufacture gradually dwindled into insignificance. New outlets for ferrotitanium have been found in the steel industry; and the production of titanium alloys, both in the United States and in Europe, has increased in recent years. By far the largest use of titanium at the present time, however, is in pigments. The manufacture of titanium white began in Norway, but at present the United States is the leading producer. One of the two companies now operating in the United States is also the leading factor in European production. Although titanium occurs, in many minerals, the principal commercial sources are rutile (the natural oxide, Ti02) and ilmenite (iron-titanium oxide, FeO. TiO2). The latter is a coal-black mineral, but it is the one used in the manufacture of the titanium white of commerce, as well as in the manufacture of ferroalloys and arc-lamp electrodes. Rutile, the natural oxide, is not pure white and, being less common in nature, costs more; it is, therefore, reserved for use in the manufacture of titanium chemicals employed in relatively small amounts in dye works and bleacheries and for sundry minor purposes. This paper summarizes the titanium industry, with special reference to its economic aspects. It is offered as a survey of current trade literature and as a digest of material in the files of the bureau and is presented in response to numerous inquiries from prospective producers as to ways and means of exploiting deposits. (At present, much of the ilmenite consumed in this country comes from overseas, principally from British India..). A forthcoming circular, devoted to deposits of titanium-bearing ores, deals with foreign and domestic sources of supply.

Oct 1, 1930

REFERENCES AND FOOTNOTES 1. U.S. Department of the Interior, Office of Surface Mining. Surface Coal Mining Reclamation: 10 Years of Progress: 1977-1987. Washington, D.C. August 3, 1987.48 pp. (For sale by the Superintendent of Documents, U. S. Government Printing Office, Washington D.C. 20402.) 2. The Rural Abandoned Mine Program (RAMP), authorized by Section 406 of SMCRA, provides for the control and prevention o f erosion and sediment damages from unreclaimed abandoned mine lands. 3. The Small Operator Assistance Program (SOAP), authorized by Section 401(b)(1) and 507(c) of SMCRA authorizes up to 10 percent of the fees collected for the Abandoned Mine Reclamation Fund to be used for technical assistance to help qualified small mine operators obtain techincal data needed for permit applications. Operators who produce fewer than 300,000 tons of coal per year are eligible for assistance. 4. OSM regulations 30 CFR 816.42 and 817.42 require water from areas distrubed by mining activities be in compliance with all applicable state and federal water-quality laws and effluent limitations for coal mining established by the U.S. Environmental Protection Agency. 5. Sourse: Abandoned Mine Lands Fee Collection System, Data from OSM-1 form. 6. Sourse: Abandoned Mine Lands Fee Collection System, Data from OSM-1 form. 7. Source: OSM Field Office Annual Reports. 8. Johnson, W. and G.C. Miller, Abandoned Coal-Mine Lands: nature, extent, and cost of reclamation. U. S. Bureau of Mines, 1979,29 pp. PHOTOGRAPHIC CREDITS Front cover, pp. i, 1, 2 bottom, 7 right, 10 bottom left, l 1 top, l l bottom right, 12 top, 13 bottom, 14 bottom right, 15,16 bottom, 17 top, 17 bottom right, 18 bottom, 19, 20 bottom, 21 top, 22, 23, 24 bottom, 25 bottom, 26 bottom left, 26 bottom right, 27, 28, 29 top, 30 bottom, 32 bottom right, 33 top, 34 top, 35 top left, 35 bottom left, 35 bottom right, 36 top, 37, top right, 37 bottom, 38 bottom, 39, 41, 42 top, 43 bottom, 44 bottom left, 44 bottom right, 45, 46, 47, and 53: Chuck Meyers, OSM. Page 2 top and center: Tony Fuhs. Page 3: John Sharkowicz, OSM. Page 6 left: North American Coal Corp. Pages 6 right, 7 left, l l bottom left, 13 top left, 13 top right, 17 bottom left, 21 bottom, 25 top left, 25 top right, 29 bottom, 30 center, 32 top, 32 bottom left, and 38 top: Bob Welch, OSM. Page 10 top left: Donald Stump, OSM. Pages 10 right, 14 top right, 14 center right, 18 top, and 44 top: Ron Hill, EPA. Page 12 bottom: Texas Utilities Co. Pages 16 top, 20 top, 24 top: Tennessee Valley Authority. Page 26 top right and 26 center left: Richard Dick, U.S. Bureau of Mines. Pages 30 top, 33 bottom left, 33 bottom right, 35 top right, 36 bottom, 37 top left, 40 top, 40 bottom, 42 bottom, 43 top left, and 43 top right: Jim Boyer, OSM. Page 31 top left, and 31 top right: Bruce Wage, Western Energy Co. Page 31 bottom: Rex Wilson, OSM. Page 34 bottom: West Virginia Division of Abandoned Mine Lands. Page 35 center: William Weist, Jr., OSM.

Jan 1, 1992

By G. S. Scott, L. D. Schmidt, J. A. KELLEY, E. L. FISH

One of the war problems with which the Bureau of Mines is concerned is to increase production of iron and steel , in which coke is one of the major factors . The output of byproduct coke for use in iron blast furnaces is insufficient and is being supplemented by coke from beehive ovens (figs . 1 , 2 , and 3) . Some difficulties that cause a reduction in iron output have been reported in the use of some of the beehive coke.6/ About 20 years have elapsed since beehive coke was made on a large scale , and many of the skilled operators of those days are no longer available . Furthermore , in many instances the quality of the coal supplied to the ovens has not been as good as formerly. The ash and sulfur contents are often abnormally high; and in other instances they vary greatly in amount, so that a nonuniform coke is produced . To assist operators to improve quality and yield of beehive coke , the Bureau of Mines equipped a truck as a field laboratory ( fig . 4 ) and sent the authors with it into the Pennsylvania beehive district . The truck contains necessary equipment for sampling and analyzing coke oven gases , measuring temperatures , screen - sizing coal, and float -and - sink testing coal . Coal specimens may be sent to the Pittsburgh laboratory for analysis . Beehive plants producing good coke were visited first to observe details of operation and to collect data on the operating process . These covered temperatures , analyses of the exit ( or trunnel) gases , and coal quality, and were to be utilized in searching for faults in plants not producing good - quality coke and to assist in improving such plants or their operation .

Dec 1, 1943

By Alphonso Cornejo, Galen H. Clevenger

This bibliography was compiled in connection with an investigation of the Caron process for the treatment of manganese - silver ores , conducted by the T. S. Bureau of Mines in cooperation with the Netherlands East Indies Government . The object of this investigation was to develop a practicable method for treating the refractory manganese- silver ores found in these two countries . The results of the work will be published as a bulletin of the Bureau of Mines . This bibliography summarizes the available information on the subject previous to the investigative work embodied in the forthcoming bulletin, and may be useful to those metallurgists or others conducting work along this line .

Mar 1, 1923

By F. L. Wideman

This paper lists resources of sulfur in Wyoming, Colorado, Utah, New Mexico, and Arizons, an area comprising approximately 522,600 square miles, Sources of sulfur occuring within the region are sulfur are, pyrite and pyritic ores, and natural gases and petroleum. Data concerning these sources are presented on a statewide basis. Some of the known deposits of sulfur ore are surficial and of fumerole origin; other deposits have resulted from oxidation of pyrite or sulfide ores of copper, lead, and zinc. The deposits are small and the sulfur is distributed erratically in them. There is a small production from some of the deposits, and the material produced is used as soil conditioner.

Jan 1, 1957

By James R. Boyle

The value of mineral production increased 6.2% in 1976. With the exception of coal, practically all commodities registered an increase in production and value; most had an increase in unit value. Total value exceeded $1 billion for the first time. The increase in nearly all nonmetallic mineral production was a complete reversal of the 1975 experience. Alabama led the Nation in the production of crushed marble and was second in bauxite and scrap mica, third in oystershell, third in kaolin, and fifth in dimension limes-tone and dimension marble. International Trade.-The international trade passing through the Mobile customs district was valued at $2,524 minion in fiscal year 1976, up 20% from that of the previous year. Of the total value of trade passing through the district, 52% of the value of experts and 89% of the value of imports were handled through the port at Mobile. The major export Commodity was coal through McDuffie Coal Terminal which amounted to nearly 2.9 million tons, up from 2.4 million tons in 1975. Coal exports were to Japan, Italy, Turkey, the United Kingdom, and Brazil. Other exports were cement (114,000 tons) and [ ]

Jan 1, 1979

The Appalachian Mountains divide Pennsylvania into two distinct coal regions, bituminous and anthracite. The western region of the the state, where the majority of bituminous mines are located, is characterized by mountains and gently rolling hills. Bituminous coal seams underlie about 12,000 square miles in 28 counties. The anthracite coal region, located in the northeast, covers approximately 3,300 square miles. This area contains more than 20 different coal beds that vary in thickness from a few inches to 50 or 60 feet. The anthracite region is characterized by steeply pitching seams that require highly specialized mining techniques and present unique challenges for solving problems such as the mine subsidence associated with abandoned underground anthracite mines. For more than a century, coal has played a major role in the economic and industrial development of Pennsylvania, particularly the steel industry. Estimated bituminous reserves total 23 billion tons, or 5.3 percent of U.S. reserves, and anthracite reserves total 7.1 billion tons, or 97 percent of U.S. anthracite reserves. Pennsylvania received conditional approval of its regulatory program July 31, 1982. Pennsylvania's Abandoned Mine Land Program was approved on the same date.

Jan 1, 1992

By Gary A. Kingston

This examination of Pacific Northwest (Idaho, Montana, Ore on, and Washington) ferrous scrap-industry opera ions, principally those in Oregon and Washington, points out factors influencing the supply and consumption of scrap materials, such as the complete dependence of steel ingot producers in these States on scrap as a metal raw material and the sizable quantity of scrap exported from Seattle and Portland to Japan. The pattern of the industry is presented as a movement of materials from their diverse sources to the consuming market. The geographic locations of the consuming industries in relation to the area generating scrap materials and the movement pattern of the supply from source to destination strongly influences the cost of the commodity. The best measure of the scrap supply available in an area is experience in terms of how much scrap was withdrawn at a given price. Scrap availability is not finite, because the return of materials as scrap is secular and influenced by constantly varying market conditions. Steel ingot producers use 75 percent of the approximate 500,000 tons of scrap consumed in Oregon and Washington; steel foundries take 15 percent of the total; and iron foundries, ferroalloy plants, and other miscellaneous consumers utilize the remainder. Also, from 1955 to 1960 an average of about 200,000 tons has been exported annually from Oregon and Washington. The foreign exports are supplemented by lesser .shipments to other steel producing States, principally in the western United States. From 1955 to 1960 the preferred and higher value heavy melting scrap grades accounted for about 60 percent of total withdrawals which varied between 600,000 and 950,000 tons annually. Total scrap withdrawals from Oregon and Washington are projected to 1.8 million tons by 1985, 60 percent (1.1 million tons) of which will be heavy melting grades. No. 1 heavy melting scrap is most attractive to scrap consumers at $35 per ton or less. Price-supply relationships compared with projected scrap requirements indicate future prices possibly over $35 per ton. High prices over a long period could motivate the Pacific Northwest scrap consumers to produce steel from iron ore. However, technologic changes taking place at integrated steel plants could reduce scrap withdrawals from the Pacific Northwest, which might keep the scrap price sufficiently attractive to obviate production of competitive iron products by the Pacific Northwest scrap consumers.

Jan 1, 1964

By R. L. Brown

This report is the 18th in a series summarizing Bureau of Mines research and technologic work on coal and related investigations. The previous 17 reports have covered fiscal years, but this report covers not only the fiscal year from July 1, 1952, to June 30, 1953, but also July through December 1953, to bring the report to a calendar-year basis. Most of the material in this report relates to publications issued during the reporting period, Some work is mentioned briefly on which publications have not yet been issued or on which data are riot expected to be published, for security or other reasons, and in a few instances publications issues before the reporting period but not included in the previous report are mentioned.3/ Further details on the published work described herein may be found by referring to the publications cited in the footnotes. During the reporting period, the Bureau directed its research and technologic work on coal toward developing end encouraging increased conservation and more efficient use of our mineral fuel resources through more efficient and safer mining methods and improved methods of preparing and utilizing these fuels. Some significant advances, particularly in coal-mine safety, mining methods, and development and utilization of low-rank coma have been made.

Jan 1, 1954

Coal-bearing regions cover about 18,464 square miles or one third of Iowa, primarily in the south-central part of the state. Coal quality ranges from subbituminous to high volatile bituminous. Iowa's coal reserves are estimated to be 2.2 billion tons, less than one-half of one percent of total U.S. reserves. Coal beds are typically thin seams with a maximum thickness of five feet. Coal deposits in Iowa were fist mined in the 1840s for blacksmithing and domestic purposes. Demand for coal increased with the use of coal to fuel steamboats and railroads. Production peaked in 1917, when Iowaproduced9 million tons of coal. Since then, conversion to natural gas and fuel oil has decreased the demand for coal. Today, electrical power generating plants have created a continuing, but declining, demand for Iowa's coal. Coal production in Iowa is by surface mining methods. The Iowa regulatory program was conditionally approved January 21, 1981. Full approval was received March 28,1982, and the Abandoned Mine Land Program was approved March 28, 1983.

Jan 1, 1992

By William C. Cooley

A review was made of two Russian books and a chapter from a third book dealing with pipeline transport of coal. Emphasis was placed on hydrotransport of coarse coal in underground mines or surface pipelines. The books reviewed were: "Means of Increasing the Effectiveness of Hydrotransport," by V. N. Pokrovskaya (1972), "Parameters and Modes of Hydraulic Transport of Coal" by V. V. Traynis (1970), and the chapter "Calculations of Hydrotransport of Useful Minerals and Waste Rock" from the book "Hydromechanization of Opencast Workings" by G. A. Nurok (1970). All three are unique and useful additions to the world literature on hydrotransport. The Traynis book reveals the development and results of circular wheel stand tests to simulate hydrotransport in horizontal pipes, which is a potentially outstanding contribution to slurry pipeline technology. Graphical data and equations are presented which suggest that headlosses for coarse coal can be predicted with good accuracy for pipe sizes up to 14 inches in diameter. Wheel stands permit tests for pipe wear and lump degradation without recycling coal through pumps. Recommendations are made for wheel stand tests and for correlation of existing data.

Jan 1, 1976

THIS bulletin presents all analytical and lest methods regularly used by Bureau of Mines laboratories for characterizing coal and coke. To provide better service to coal producers and consumers, the scope of this bulletin has been expanded to include important test methods used to evaluate coal properties for commercial processing. The methods described will prove valuable to all persons interested in analyzing and testing coal and coke.

Jan 1, 1967

By Robert G. Bottge

The Bureau of Mines has engaged m a program to determine the availability of land for mineral exploration and development in Alaska. Land availability, based on ownership and Federal and State laws and policies, is compared with mineral terranes and mineral deposits. This is the fifth of six regional studies, which cover the State with a comprehensive set of maps and data compilations. This study covers an area of 112.3 million acres in western Alaska. In July 1986, 41.0 million acres, 37% of the study area, were available for mineral exploration and development; 14.6 million acres, 13%, were available with restrictions; and 56.7 million acres, 50%, were unavailable. Nearly 65% of the unavailable land is classified as national parks, preserves, wildlife refuges, and wild and scenic rivers. Of the 34.0 million acres of mineral terranes that underlie the study area, 12.9 million acres, 38%, are available for exploration and development; 3.6 million acres, 11%, are available with restrictions; and 17.5 million acres, 51%, are unavailable.

Jan 1, 1988

By F. W. Brown, F. C. Gibson

"INTRODUCTION There is urgent need for a satisfactory permissible multiple-shot blasting unit capable of firing 10 detonators in series and safe for use in underground mining where a. gas-ignition hazard may exist.. As there is at present no entirely satisfactory permissible unit of either the battery or generator type, tile described capacitor-battery type has been developed. Consideration of the Bureau of Nines approval schedule pertaining to the generator and magne to-type units and of the electrical characteristics of the unit described in this report indicate that this unit should meet Bureau of Mines permissible requirements.This report gives a detailed description of the design and operation and results of tests to determine safety of operation in gassy atmospheres.DESIGN AND OPERATION OF UNITOperation of the vibrator-type multiple-shot blasting unit is based upon utilization of the discharge energy from a capacitor charged to a given. voltage and having capacitance adequate to store enough energy to initiate 10 detonators in series. The primary source of energy is a 4-volt cap lamp battery such as is carried for illumination on the person of underground workers in nearly all mines. As this battery is already available and is recharged daily it is considered to be a reliable and convenient source of energy for a blasting unit. Figure 1 is a schematic diagram of the circuit for an improved unit, and figures 2 and 3 are views of the experimental unit. The battery potential is applied through a radio-type synchronous vibrator (8) to an 8-volt center-tapped primary of a small transformer (9) having a high-voltage center-tapped secondary. The vibrator introduces an alternating low-voltage potential into the primary and mechanically produces full-wave, rectified, pulsating, direct current from the secondary. A buffing condenser (11) across the secondary gives the proper wave form for long vibrator life: a resistor (12) its in series with this condenser across the total secondary to protect the transformer in case of• failure .of this capacitor. A voltage divider (10) with an adjustable slider permits accurate adjustment of the potential applied to the high-capacity firing condenser (5)."

Oct 1, 1947

The original work statement of this contract was entitles: 'A Accident Analysis Model for Use in Underground Coal Mines.' The contract was scheduled for a duration of 26 months and was to be in three phases: Phase I - Model Development, Phase II - Application of the Model, and Phase III - Installation, Monitoring and Evaluation of the Model. Alter three months in Phase I, it became apparent that much of the needed data for the model was nut available and could not be made available within the original study schedule. Proceeding as plumed would have resulted in a model of limited utility. Personnel from Theodore Barry and Associates and the Bureau discussed the problem in detail and mutually decided to utilize the majority of remaining funds to assist the Bureau in solving these data problems and develop a stronger ongoing capability for safety analysis within the Bureau. Both tie contractor and the bureau officials involved believed that this decision greatly enhanced the Bureau's ability to develop future accident prediction models, whose rigor would greatly exceed what was currently possible.

Jan 1, 1972

By John D. Foulkes

A study to categorize and characterize underground metal/non-metal mining operations from the viewpoint of telecommunication requirements and practices. The objectives were to: ? Gather and analyze data; ? Identify communication requirements; and ? Recommend systems for operational emergency and post-disaster telecommunications.

Jan 1, 1979

By Richard D. Miller

The helium resources base of the United States was estimated by the Bureau of Mines to be 1,070 Bcf as of January 1, 1985. These resources are divided into four categories in decreasing degree of assurance of their existence: (1) helium in storage and in proved natural gas reserves, 280 Bcf, (2) helium in probable natural gas resources, estimated at 243 Bcf, (3) helium in possible natural gas resources, estimated to be 287 Bcf, and (4) helium in speculative natural gas resources, which makes up the remaining 260 Bcf. These helium resources are further divided into depleting, non-depleting, and stored classifications. The depleting resources are those associated with natural gasfields that are, or will be, produced for the natural gas they contain. Almost all of the helium in potential (probable, possible, and speculative) natural gas resources is included in this classification. These depleting resources are estimated to contain 900 Bcf of the total helium resource base. Helium resources contained in nondepleting natural gas resources, those in shut-in, abandoned, or otherwise nonproducing natural gasfields, are estimated to total 133 Bcf. There is 37 Bcf of helium in storage in the Federal Government-owned Cliffside Gas Field near Amarillo, TX.

Jan 1, 1987

By Michael R. Norland

This U.S. Bureau of Mines report on U.S. and Canadian 1iterature pertaining to soil characterization and the use of soil amendments as a part of the reclamation process of coal surface-mined lands contains 1,280 references. The references were published during the 1977 to 1988 period. Each reference is evaluated by keywords, providing the reader with a means of rapidly sorting through the references to locate those articles with the coal mining region and subjects of interest. All references are annotated.

Jan 1, 1991