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By B. McFadzean

Thiol collector mixtures are commonly used in the flotation of base metal sulfides and platinum-bearing ores. There are synergistic benefits claimed for these collector mixtures, with mixtures lowering total dosage requirements, improving coarse particle recovery and the rate of flotation. Some of the secondary collectors are known to have frothing effects. Therefore, a previous study aimed to decouple froth and pulp effects and considered only the bubble-particle attachments in the pulp. This was achieved through microflotation experiments, where various ratios of the ethyl and isobutyl chain lengths of xanthates, dithiocarbamates and dithiophosphates were used as collectors. Results from these experiments showed a marked increase in galena recovery using mixtures of xanthate with either dithiophosphate or dithiocarbamate. In the current study, the froth phase was introduced in the form of batch flotation studies to determine whether benefits noted during microflotation experiments would be carried through to a more realistic froth flotation scenario. The findings show that there was no significant difference in the flotation recovery between the best single collectors and mixtures of these collectors. In addition, single collectors that behaved poorly in microflotation experiments showed good flotation performance in the batch flotation experiments. The differences between the microflotation results and the batch flotation results are attributed to differences in particle froth stabilizing properties and/or differences in energy input between the microflotation and batch flotation cells. In addition, galena and pyrite showed marked differences in frothing effects and in their preferences for collector type. Keywords: froth flotation, collector mixtures, sulphide minerals

Sep 1, 2012

By N. N. Ngoepe

Positron Emission particle tracking (PEPT), which makes use of a radioactively labeled tracer particle, a positron camera and a tracking algorithm has been shown to be a viable method for studying flow properties in both the pulp and froth phases of flotation cells. Detailed velocity measurements of 300-400 µm glass beads were extracted to assess turbulence from velocity fluctuations in a micro flotation cell. The effects of particle speed and orientation at the instant of attachment events were studied. A minimum speed of 0.16 m/s was needed for a collision to lead to attachment. The most attachment events happen when the particle is directly in line with the inlet tube at 90o.

Sep 1, 2012

By C. Y. Jia

Adsorption of Thiooxidans ferrooxidans and Mycobacterium Phlei on the surface of pyrite and galena was studied. From the experimental results, it was observed that Mycobacterium Phlei adsorbed preferentially on pyrite than on galena at neutral and alkaline pH values, while Thiooxidans ferrooxidans is not at all pH range, and the scanning electron microscopy photograph also indicated that. FTIR and XPS of two strains of bacteria indicated that there are much functional groups on surface of them, such as O?H, N?H, C-O, C?N, C?O etc, but S-O group occurred on Thioox-idans ferrooxidans cell surface and the P-O group appeared on Mycobacterium Phlei cell surface, and the content of C?O?H and C?O?C groups on Mycobacterium Phlei cell surface is higher than that on Thiooxidans ferrooxidans cell surface, this also been known from UVS investigation. The affinity of these groups to metal ions on sulfide minerals is able to explain the selective adsorption.

Jan 1, 2014

Flinders Power, formerly NRG Flinders, is considering the possible use of low rank coal from Lake Phillipson, South Australia (SA) in its power stations at Port Augusta, SA. Typically, this coal contains about 35% moisture and 10% ash. Unfortunately, it also contains high levels of sodium (1% Na) and chloride (0.95% Cl) with a Na2O level in ash of 18.9%. Such levels cause serious problems during coal combustion, making the use of as-mined coal impractical for power generation. This paper describes the development of an aqueous leaching technique to remove 90% of the sodium and chloride and to yield a product with a Na2 O level in ash of less than 3%. Small-scale agitation leaching tests with good quality tap water at ambient temperatures showed that the coal needed to be crushed to minus 5.6 mm to obtain maximum removal of water-soluble sodium and chloride in 30 min. Leaching kinetics, but not the ultimate removal of salt, were enhanced by the use of higher temperatures (up to 150°C), but this was deemed uneconomic. Varying the pulp density between 20% and 50% had little effect on extractions and there was no benefit in multiple stage water washing. The best results by water leaching were 69%~74% extraction for sodium and 95%~97% for chloride, meaning that the sodium removal was well below the target level. From SEM examinations of the leached product it was concluded that the remaining sodium was organically bound to the carbon atoms in the coal. Further tests using aqueous solutions containing cation exchange additives such as calcium chloride (CaCl2) or ammonium chloride (NH4Cl) or sulphuric acid (H2SO4) showed that significantly enhanced sodium extractions were possible and target specifications were met. Two options, namely a single-stage and a two-stage leach, were then investigated. In a single-stage leach with additive, minus 5.6 mm coal was leached at 33%~50% solids for 30 min at ambient temperature and then filtered and washed with fresh water. This gave a sodium removal level of about 81% and a Na2O level in ash of about 5%. These levels do not quite meet tar-get specifications. In a two-stage leach, the coal was first leached with water alone without an additive as in the single stage leach, and the washed residue re-leached under similar conditions for about 5 min with an additive (CaCl2), and then filtered and washed. This gave a cumulative sodium removal of 96% and a Na2O level in ash of 1.4%~2.4%. These levels are well within target specifications.

Jan 1, 2014

By G. P. Wong

"In the Inco matte separation process, a slow-cooled converter matte is separated into three main discrete mineral phases: chalcocite (Cc), heazlewoodite (Hz) and a Cu-Ni-Fe alloy. After magnetic removal of the alloy, Cc and Hz are separated by flotation at pH>12 with diphenyl guanidine (DPG) as both collector and frother. High selectivity is achieved in rougher flotation. However, in later flotation stages such as in the middlings circuit, as oxidation takes place, Hz becomes highly floatable, resulting in a very poor separation between Cc and Hz.Starch and dextrin as Hz depressants were evaluated on the middlings circuit feed and showed no positive impact on Cc/Hz separation selectivity. Ethylene diamine tetra-acetic acid (EDTA) extraction showed the existence of abundant surface Cu and Ni ions. The use of triethylene triamine (TETA) or EDTA in flotation did not improve Cc/Hz separation selectivity. Microflotation tests were carried out on pure synthetic Cc and Hz minerals. It was found that Hz did not float in the presence of DPG. However, Hz conditioned with either copper sulfate solution or in contact with Cc floated readily in the presence of DPG. It is concluded that the major reason for Hz flotation in the middlings circuit is due to Cc oxidation releasing Cu ions that adsorb on the Hz surface making it reactive with DPG thus rendering the Hz floatable."

Jan 1, 2003

By Smuts. E. M.

This paper describes a methodology used to develop a numerical model for the study of particulate suspension rheology. Initially, Computational Fluid Dynamics (CFD) models of different rheometer geometries were tested with both a Newtonian fluid (water), and a non-Newtonian Herschel-Bulkley slurry. Rheograms were reproduced from these models and compared to experimental values. Once a single-phase model had been validated, a coupled model combining CFD and the Discrete Element Method (DEM) was created. Two open source software packages were chosen. CFD is implemented using Open FOAM®, and DEM using LIGGGHTS. These two different codes were coupled via another program called CFDEM. This coupled model is currently capable of modeling spherical particles in a suspending liquid. DLVO forces have been included in some models to account for inter-particle forces due to the surface charge on the particles. The coupled model is currently being validated. Preliminary results show good qualitative behavior of the model. Keywords: rheology, cfd, dem, suspensions, modeling

Sep 1, 2012

By V. Hema

Granular materials are widely used in process industries, such as chemical, pharmaceutical, cement, food, detergents, and fertilizers. Mixing, blending, calcining, reduction, heating, and granulation of these materials are frequently carried out in rotating cylinders. In all of these processes, the mixing and segregation of these granular materials is important as this controls the secondary phenomena in the rotating kiln such as heat transfer to the material. A significant amount of work is available in the literature but to date these efforts have not been able to capture the important parameters affecting the mixing and segregation in rotating kilns. In addition, the range of parameter values studied so far is rather limited. Simulations of granular materials are based on either discrete elements or continuum models. The discrete element methods (DEM) combine semi-empirical models for the inter particle interactions with the equations of motion from classical mechanics to simulate the explicit paths of all granules in a rotary kiln, thus yielding realistic predictions of the mixing process. This approach is very demanding computationally, which strongly limits the number of granules and the number of revolutions in a simulation. Continuum models dispense with the discrete particles and can therefore be scaled up more easily. But the constitutive relations that serve as the foundation for continuum modeling are difficult to come by, and often only applicable to specific systems and conditions. Here we have chosen DEM simulation for investigating the mixing and segregation behavior of granular materials in a rotating cylinder. This work is directed towards demonstrating the capability of the prediction of the mixing and segregation behavior of granular materials in a horizontal rotating cylinder through discrete element simulation. Further the effect of particle size and rotational velocity on the mixing and segregation behavior is investigated. The simulation results are quantified in terms of mixing index, mixing rate, segregation index and percolation index. Keywords: DEM simulation, granular mixing

Sep 1, 2012

There are interactions between different minerals from the same ore, minerals and grinding media, and the electrochemical conditions present in the system. Grinding in steel rod and ball mills is a common practice in minerals processing. It is accepted, that the electrochemical interactions between the grinding media and minerals in a grinding mill, influence the corrosive wear of balls/rods and the surface properties of the ground minerals. A complex massive sulphide, Cu-Zn, TAKNAR, Iran, was used for all the experiments. The aim of this study was to investigate the effect of grinding media (dry or wet) on the pulp chemistry and recovery of Cu and Zn in bulk concentrate. 1100 g of ore samples were milled, and mill products with d80=85 and 75 micron in wet and dry grinding methods were produced. Rougher bulk flotation experiments were performed with 550g ore samples, at 30% solids. SIPX in conjunction with Aero238 in 1:2 ratio (48 g/t), was used as mixed collector system, and copper sulphate (200g/t) and MIBC (20 g/t) were employed as sphalerite activator and frother. Lime and High purity Oxygen gas were used for adjusting pH at 8.5 and aeration. The results showed that, more positive pulp potentials were measured when the feed had been ground in a dry environment, and the difference in pulp potentials between the dry and wet ground feed was approximately 250 mV after the grinding stage. In dry grinding method, the recovery of Cu and Zn increased approximately 5 and 10%, respectively. In addition, in dry ground samples, the volume of middling and coarse particles (+100 micron) were more and Dry ground flotation feed had better agreed with using a mixture of collectors. After using copper sulphate, pulp potential increased about 50 mV in dry and 75 mV in wet grinding methods. Keywords: grinding media, pulp potential, Cu-Zn massive sulphide, bulk flotation

Sep 1, 2012

By S. M. Wen

In mineral processing, the settling of mineral particles in water, the flow of ore pulp, the dewatering and filtering of concentrates and so on, are related to the pulp viscosity. While the interaction between mineral particle surface and water affects directly the pulp viscosity. Therefore, it is of great value to the development of mineral processing theory to research the effect of mineral particle surface on the water viscosity in boundary layer. In micro-fluid, the effect of mineral particle surface on the water molecules in boundary layer can not be ignored. The water viscosity in boundary layer and the effect of the nature of mineral particle solid surface on the viscosity are analysed based on the deduction of attraction potential energy formula of mineral particle surface to the water molecules in boundary layer. The results show that the attraction potential energy of mineral particle surface to the water molecules in boundary layer is determined by the properties of solid molecules and fluid molecules and varies inversely as the third power of the distance from mineral particle surface. The water viscosity in boundary layer consists of the viscosity of free water and the additional viscosity resulting from the attraction of mineral particle surface. The increment of the viscosity caused by the attraction of mineral surface is µs. This additional viscosity is also inverse ratio to the third power of the distance from mineral particle surface. The greater the dipole moment, the polarizability and the ionization energy of mineral particle solid surface molecules are, the higher the attraction potential energy of mineral particle surface to the water molecules and the water viscosity in boundary layer are. The thicker stationary water boundary layer is d0. The higher the µs is, in other words, the greater the attraction of solid surface to water molecules is, the thicker the stationary water boundary layer becomes when free water viscosity is constant.

Jan 1, 2014

By M. R. Tavakoli Mohammadi

Novel solvent extraction technologies in recent decades have made attempts to show the problems in applying this method for dilute solutions and find appropriate solutions to overcome them. Improving the equipments performance used in this method for dilute solutions, cause development of usable resources and reduction of operational costs. Furthermore, appropriate conditions provide for using dilute solutions produced in various industries as a new source of valuable elements. Thus, this proposal can be a very good solution for treatment of these solutions and reduce the environmental impacts associated with them. The purpose of this study is to introduce a new method of Column Floto Extraction (CFE), which has been invented in this regard. In this method, using spargers similar to Jameson cell downcomer in floatation process, the organic phase bubble dispersion has been used instead of its drop dispersion in aqueous phase for the two-phase mixture operation. This operation mode has caused a higher extraction percentage of solute in high aqueous to organic ratios due to enhancement of contact area. In this study, in addition to explaining the advantages and features of this method, we have dealt with its design and performance mode.

Sep 1, 2012

By Y. D. Gao

A new technique has been developed for comprehensively recovering tantalum niobium tungsten ore by adoption of stage grinding, stage separation, combination of flotation and gravity separation, gravity separation for coarse particles, flotation for fine ones, combination of ore-dressing and hydrometallurgy. The new type and high efficiency combinative collector mainly composed of benzyl hydroxamic acid is firstly used to treat tantalum niobium and tungsten slime, besides the new type equipment for gravitational separation ?YTF-C shaking table for fine particles is adopted to treat flotation rough concentrate, hence having notably enhanced both recovery and concentrate grade of fine tantalum niobium and tungsten minerals. The commercial test obtains the tantalum concentrate assaying Ta2O5 31.98% with recovery 43.44% and tungsten product assaying WO3 89.40% with recovery 76.02%. The developed technique provides a reliable approach and an effective way for comprehensive utilization of lean fine complex refractory tantalum niobium tungsten ore resource.

Jan 1, 2014

By S. H. Lau

Rapid 3D characterization of multiphase mineral particles in a variety of mineral processing applications is described, including: mineral liberation analysis, grain size, mineral exposure analysis, particle damage, and pore network structure for fluid flow simulation in heap leaching. While micro X-ray computed tomography systems (microCTs) have been used for many years, industrial adoption is limited due to a variety of reasons, including insufficient resolution, the general lack of imaging contrast to differentiate different mineral phases within a multiphase mineral particle and the lack of automated 3D mineral processing software. For example, resolution with industrial CTs and desktop microCT is of the order of tens of microns to a few microns at best, depending on specimen size and CT configuration. We describe a novel lab-based X-ray microscope, XRM, which overcomes these resolution and contrast limitations, notably as the industry is going towards finer grains and more complex ore bodies. Using lens-based optics and detectors (similar to its XRM counterpart in synchrotron beam lines), resolution of the lab based system is in the submicron range with contrast better than conventional microCTs. Hence, visualization, differentiation and segmentation of most mineral phases of interest to the industry are now feasible. Coupling these high resolution and high contrast tomography images with a suite of customized 3D segmentation algorithms and analysis software, applications in mineral liberation analysis for process control, particle damage assessment and other mineral processing applications can be achieved. This non invasive 3D technique which requires relatively little sample preparation is currently being considered for coal, industrial minerals, and base/precious metal ores, complementing existing microscopy techniques such as QEMSCAN and MLA for a variety of applications

Sep 1, 2012

By N. Vorob?ev-Desyatovskii

The process of gold(I) adsorption on activated carbon (AC) from aqueous Na[Au(CN)2] and the state of the adsorbed gold cyanide complex on the adsorbent surface was investigated by photometry, XPS, XANES methods. By DFT method, quantum-chemical calculations were performed of the gold cyanide species on activated carbon surface. It was established that the binding of gold(I) with the surface of carbon involved several simultaneous processes governing the selective adsorption of gold(I) from the cyanide solutions.

Sep 1, 2012

By B. K. Gorain

Mining of low grade deposits along with the necessity to design and operate flotation plants with high throughput presents unique metallurgical and environmental challenges that need to be addressed to reduce project risks, improve project economics and to sustain the profitability of operations over the life of a mine. Some of the key challenges include poor recovery of valuables and concentrate quality issues due to complex mineralogy, the need to use poor quality water such as brackish or sea water, reduce environmental impact from the process, integrate flotation with hydrometallurgy to maximize precious metals recovery, escalation of capital and operating costs, use of unproven technology and constant use of larger equipment, high ore variability, worldwide constraints on resource availability and an ever increasing need for reliable metallurgical input to financial models to evaluate economic viability of projects. The need to develop effective solutions to these problems in a short time frame is becoming a key to the success of any new project and for sustaining the profitability of a mining operation. An integrated multi-disciplinary approach to problem solving is crucial with the need for a more lateral thinking along with strategic partnerships and collaboration involving the right players. This paper presents some of the key findings based on experiences from a large number of challenging projects and operations focused on solving complex flotation problems Keywords: mineral processing, flotation, flotation problem solving, flotation optimization, plant design, innovation

Sep 1, 2012

By J. P. Dai

The Fankou Mine in Guangdong province, China, processes a polymetallic ore containing averagely 4.2% Pb, 8.5% Zn, and 90 g/t Ag. The main metal minerals including sphalerite, galena and pyrite are very finely disseminated and unevenly occurred in the ore, making it difficult to liberate them from each other. This paper presents the processing technology of the Fankou plant and the characteristic features of the novel technology applied.

Jan 1, 2014

By Carlos Pereira, Fábio de São José, Francielle Nogueira

Votorantim Metals Corporation is one of the leader companies in the extraction of zinc in Brazil. One of its mines, located in the city of Vazante - MG, was composed by zinc silicate ores, but recent studies have indicated a change in mineralization type with arise of zinc sulphide’s ore bodies with disseminations of galena (PbS) and silver. The liberation size between sphalerite and galena in this ore occurs in very fine granulometry (approximately 18µm), fact that has negatively influenced into the flotation process. Aiming to reduce this problem, studies about the use of dispersing in the flotation process have started. Thus, this study investigated the action of different reagents dispersing on the stability of the suspensions. The tests were carried out with samples of mineral galena and sphalerite using four types of dispersing within two different dosages and two pH. The reagents tested were sodium hexametaphosphate, sodium silicate, carboxymethiylcellulose, and sodium polyacrylate. The results of the dispersion tests were analysed in relation to dispersion index. The tests with hexametaphosphate showed high dispersion for both galena and sphalerite. The sodium polyacrylate and arboxymethiylcellulose showed a high dispersion index for galena and a low index for sphalerite implying that reagent can be used in the concentration process of galena.

Jan 1, 2014

By S. H. Morar

Froth stability is widely recognized as a key driver of flotation selectivity. It is well known that froth stability is affected by the type and quantity of surface active reagents present (frothers), and the concentration and hydrophobicity of solid particles present. While some studies have been performed on the effect of frothers on froth stability in three-phase systems and the hydrophobicity of particles present, very little work has been performed on the effect of solids loading on froth stability. This may be due to insufficiently robust measurement techniques. This paper investigates the use of a new machine vision measurement to measure solids loading, and the relationship between this measurement, bubble size, and bubble burst rate on the froth surface. Keywords: froth flotation, machine vision, solids loading

Sep 1, 2012

By Y. Rama Murthy

Around 90% of the chromite resources of India are concentrated in the Boula-Nuasahi Sukinda belt of Orissa state. In order to conserve these valuable ore resources strategically, several companies established chrome ore beneficiation plants in this region. The general beneficiation process in these plants consists of gravity unit operations such as Floatex density separator, spiral, wet shaking table etc. Most of these gravity circuits suffer huge losses of valuable minerals in the tailing. Any attempt towards decreasing these losses would not only increase the limited reserves in India but also make the economics of the operations more attractive. Apart from the liberation phenomena, in many of the operating plants considerable quantity of values are lost in the tailings, due to inconsistent feed quality, inappropriate selection of operating and design parameters. Mineral engineers in this regard have to play a proactive and continuous role to improve the performance of all separating units by modifying even small changes based on tests conducted in laboratory under controlled conditions followed by attempts to make necessary changes in the plant. For such improvements, accurate data collection and proper data interpretation followed by making necessary change which is implementable in an operating plant play a very critical role in performance of the circuit. Databank collected over a period of time under various conditions would also help in overcoming the future problems related to either variation in the feed characteristics or specific demand by metallurgical industries. The above concept was adopted in one of the operating chromite beneficiation plant at Sukinda. The approach adopted and practical problems encountered during the study were reported in this paper. The result of trial campaign has shown that, an overall product assaying 30.2% Cr2O3 from the feed (18% Cr2O3 ) can be produced to in single stage. The final discards of the process contain 12% Cr2O3. Keywords: chromite, chromite beneficiation, chromite losses, gravity concentration techniques, plant operating data bank

Sep 1, 2012

By M. Kargar Razi

According to the unique properties and many applications of nano gold powder, it was prepared from an acid leaching tail solution. The low value residual gold ions were existed in acid leaching tail solution in Mouteh gold mine in Iran with fellow heavy metals as pollutants (FeP2+P, Cu P2+P, and ZnP2+P). Preparation of nano gold particles is achieved by two steps. First, by addition of ammonia as separation step and second using suitable reagents for precipitation/extraction step. Conditions control includes pH, residence time, temperature, agitation, and molar ratio of reducing agents to reagents. The optimum results show that nano gold powder was prepared by temperature of 250 °C, urea to gold molar ratio of 3:1, and reduction time of 20 min. Also, heat treatment improves dispersion of nano sized gold particles. The properties of gold nano powders were evaluated by SEM, A.A, and UV- Vis spectroscopy methods. The size of prepared particles were about 80nm to 90nm.

Jan 1, 2014

By P. Somasundaran

Treatment of mineral surfaces with appropriate surfactants plays an important role in mineral processing operations such as flotation, flocculation and dewatering. Recently biosurfactants, in particular, have received a considerable amount of attention because of their unique surface active properties and biodegradability. In this work we examined the performance of biosurfactants, sugar based alkyl glycosides and sophorolipid esters as reagents to control the hydrophobicity of minerals with selectivity of adsorption on mineral surfaces for flotation applications. It was discovered that n-dodecyl-ß-D-maltoside adsorbs on alumina, titania and hematite but, interestingly, not on silica. The hydrophobicity obtained is governed both by the surface coverage as well as the nanostructure of the adsorbed layer in terms of orientation of the adsorbed species. Surprisingly, even though the above surfactants are non-ionic, their adsorption was pH-dependent. We have correlated this pH dependence to the type of species on the mineral surface. Also it is shown that mixing of these surfactants with traditional ones can help reduce the carbon footprint due to synergy between the reagents and help selectivity due to antagonism. The experimental results were analyzed to get information on optimal pH and dosage conditions, for mineral surface modification. The study provides guidance for mineral treatments using biosurfactants and the potential use of these next generation reagents in mineral processing.

Jan 1, 2014