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By A. N. Lazaridi, S. I. Afanasenko, S. A. Safonov

"This scientific work presents the results of comparative tests of centrifugal concentrators with a vertical and horizontal axis of rotor spinning. The article also describes a qualitative analysis of the behavior of mineral particles in a centrifugal field with fluidization for concentrators with a horizontal axis. The analysis was aimed at studying the effect of the quantity of fluidization holes in the basket on the degree of magnetite recovery and the effect of the basket rotation speed. The experiment demonstrated that concentrators with a horizontal axis are not inferior in terms of the qualitative recovery indicators to concentrators with a vertical axis. The researches also provided facts about the wide practical application of concentrators with a horizontal rotor arrangement. INTRODUCTION Methods of gravity concentration, attractive for their ecological purity, see their revival. First of all, this is due to the invention of centrifugal concentrators with the fluidization of the layer of mineral particles. The creation of a new generation of gravitational centrifugal concentrators made it possible to achieve a tangible breakthrough toward the direction of reducing the grain size of mineral particles effectively divided by density, up to 10 µm at a high production capacity of the vessels reaching 500-600 tons per hour. Such separators enable dressing a crushed ore of flotation grade and in some cases replace the flotation process, especially in primary operations, in joint cycles. In the long term, this method of concentration should significantly expand the scope of application, replace partial flotation processing, ensure the introduction of environmentally friendly energy-saving technologies at ore-processing plants. Summarizing the international experience for the last 30 years, it can be confidently asserted that centrifugal methods of concentration have become widely used in processing schemes for the separation of finely dispersed products in the mining industry. An interest in the creation of installations using centrifugal acceleration for the separation of mineral particles by density has particularly grown. Dozens of centrifugal concentrator designs have been created and continue to be improved. Centrifugal concentrators have a number of obvious advantages, which are especially relevant today. Losses of fine gold during the process of mining are well known. Gold washers screw, spiral separators, jigging machines and sluices traditionally used in the production processes do not solve the problem of fine gold recovery. Table 1 shows the results of comparative tests of a centrifugal concentrator (ITOMAK) and other concentration equipment. According to the research conducted by the company GMRS, Krugersdorp, South Africa (2000), the initial material was gold ore crushed to 150 micrometers (90%)."

Jan 1, 2018

By S. Carsten, S. Subramanian, R. Vasant Kumar, S. Vimalnath

"The effect of EPS components namely protein, polysaccharide and biosurfactant purified from Pseudomonas fluorescens was investigated for the bioremediation of Pb(II) ions in aqueous solution. Two parameters, namely the amount of EPS component and the concentration of Pb(II) ions were optimized for maximum Pb(II) ions uptake. The EPS components interacted with Pb(II) ions were characterized using energy dispersive X-ray analysis (EDAX) to ascertain the presence of Pb and by attenuated total reflection-Fourier transform infrared spectroscopy (ATR–FTIR) to reveal the functional groups involved in Pb(II) binding. The maximum Pb(II) binding capacities of protein, polysaccharide and biosurfactant were found to be 11.4, 0.55 and 0.11 mg mg-1 respectively. The biosorption processes followed the Langmuir model. The Gibbs free energy (?G0) values of -23.6, -20.9 and -23.2 kJ mol-1 for Pb(II) biosorption by protein, polysaccharide and biosurfactant respectively, attested to spontaneous, chemisorption processes. The ATR–FTIR results revealed the presence and involvement of amino, hydroxyl, carboxyl, phosphate, and methyl functional groups in Pb(II) binding and EDAX analysis confirmed the interaction of Pb with EPS components. The Pb(II) binding mechanisms of EPS have been discussed. The results demonstrate the potential of the purified EPS components of P. fluorescens for removal of Pb(II) ions from aqueous solution INTRODUCTION Waste water containing toxic metals from various industries pose a serious threat to human health and ecosystem. For treating such waste water, conventional methods like chemical precipitation, coagulation, evaporative recovery, electrodialysis, floatation, flocculation, ion exchange, reverse osmosis, nanofiltration, ultrafiltration are used (Lakherwal et al., 2014). These methods have some disadvantages like toxic sludge generation, incomplete metal removal and high cost (Singh and Gadi, 2012), necessitating the search for cheaper and efficient alternative methods. Bioremediation is one of the emerging alternatives where bacteria, fungi, yeast, algae and other biological substances are used as sorbents to remove toxic heavy metals (Vijayaraghavan, et al., 2015). Recently, the bioremediation potential of extracellular polymeric substances (EPS) of microbial origin has attracted attention. However, for Pb(II) removal, there is a paucity of literature focusing on EPS."

Jan 1, 2018

By Lj. D. Andric

Development of modern devices for mechanical and mechanochemical materials activation has been dated since the beginning of last century. Rapid development of high-energy mills that are different in type, size, design and performances, has been occurred during the last four decades. Because of complete understanding of mechanical processing, entire knowledge of theoretical principles of high-energy mills is necessary. These principles are main causales of process that are happened in materials during the mechanical activation. This paper is occupied by theoretical principles of operation of high-energy mills. Conventional high energy mills with balls, high-energy planetary mills and high-energy vibrational mills are particularly considered in the paper.

Jan 1, 2014

By S. Q. Zhu

Coal Water Mixtures (CWMs) are densed suspensions of coal particles in water. Viscosity is one of the most important rheological properties of CWMs and it is desired to be as low as possible. The slurry viscosity was influenced significantly by additive formation, the particle size distribution and the ash content of the coal. However, the influence of dispersants is most obvious. At present, there are several kinds of dispersants such as polymeric styrene sulfuric sodium, lignin sulfonate, humate, polycarboxy salt, ethylene epoxide surfactant. In this paper, a newly synthesized CWM dispersant has been reported, which is an efficient anionic surfactants of polycarboxylic acid type. The synthesis process includes three steps. At the beginning, the polyglycol acetate ester has been performed by acetic acid and polyethylene glycol (PEO) on the condition of acetic-acid/PEO ratio 1:1.1, at 368~373K for 30 minutes. Then the macro-monomer is prepared through the esterification of 85.71% acrylic and 14.29% polyglycol acetate ester, at 368~373K for 10 minutes. After that, the polycarboxylic acid CWM dispersant is polymerized using proper proportion macro-monomer, acrylic (AA) and sulfonic styrol sodium, at 368~373K for 1 hour. This new dispersants are used in the coal water mixtures formulation. Four kinds of coal used in the experiment are Shuang Yashan, Tunliu, Luning, Changcun samples. ? The highest concentration for shuanyashan coal is 70% when the dosage of dispersant is 0.4%, and the content of -200 meshes particles is 75.53%. As the dosage of dispersant de-creases to 0.25%, the Shangyashan CWM concentration is 67%. ? For Tunliu coal CWM concentrations are in the range of 76% to 75% when dosage of the dispersant changes from 0.4% to 0.25% at the same particle size distribution of 83.5% minus 200 meshes. ? The highest concentration for Luning coal is 69% when dosage of the dispersant is 0.4%, and the content of -200 meshes particles is 88.86%. ? For Changcun sample, the coal concentration of CWM is 73%~75% when dosage range of the dispersant is 0.35%~0.5%. The experiments show that the synthesied dispersant is quite promising for some coals CWM preparation, but a little bit coal-dependent. The Proximate and Ultimate analysis, surface characteristic measurement have been made to investigate the interactions between coal and additives.

Jan 1, 2014

By Lj. D. Andric

By the micronization-milling of the material, the size and the structure of its particles are changed and it comes to the increasing of the potential energy of the system as well as to the chem-ical activity of the material what is the result of an increased free surface and of the concentration of the grate defects, that is of the internal energy of the system. All these changes that are reached, show that new characteristics of treated materials are got by micronization process. Controlling the process of the micronization and by purpose directing of the new characteristics of the activated materials, we can have the positive effects and use them in more technologies. Talc is important nonmetallic mineral raw material that is widely used as either the basic raw material, or as filler. This has stimulated its technological investigation, as well as the investigation of its physical-chemical characteristics. In this paper are shown experimentally reached results of the physical-chemical characteristics of the talc during the process of the micronization in high energetic mill. In this paper, the optimum conditions of miconization of talc in high-energy-speed rotary mill and its influence micronization on a degree of Fe2O3recovery by hydrometallurgical methodes, are presented. The X-ray analysis of the obtained products showed that high quality talc with low content of can be obtained by these physical-chemical processes In this paper, the principles and application or fine and ultra-fine grinding high-energy attriton mill with small balls, enabling fast, efficient grinding, low energy consumption, short grinding time and easy handling will be described.

Jan 1, 2014

By Alban Lynch, Benigno Aquino, Hakan Dündar, Alexander Kalugin, Marco Delgado, Alberto Palomino, Ali Türkistanli

Dynamic separators are efficient dry classifiers because new designs during the last 50 years have reduced the by-pass and improved the partition curve. By contrast cyclones have been used as classifiers in wet grinding circuits for 50 years but without serious change and the early problems which were caused by high and variable by-pass, and different mineral specific gravities, still exist. High frequency screens are now used for wet separation and the operating characteristics of closed grinding circuits using cyclones or screens are discussed. Data come from circuits at the Condestable, Cerro Lindo, El Brocal and Catalina Huanca mines in Peru, the Eczacibasi mine in Turkey, and the Apatit mine in central Kola Peninsula in Russia. All classifier data are described by their partition curves and all mill data by their breakage rates. With cyclones the by-pass, d50, and sharpness of the partition curve change as operating conditions change but with high frequency screens the values vary little because the by-pass is low, the sharpness is high, and d50 depends on the aperture size. Data from all plants indicate that lower by-pass and sharper separation improve breakage rates and throughputs. An initial model of the screen is proposed.

Jan 1, 2014

By S. Narra

Converting biomass into valuable fuel requires various preprocessing of the raw materials. Biomass densification is one of the conversion processes for its utilization. The aim of densification is to produce biomass pellets, which can withstand regular handling stresses and exhibit high densities with uniform size and shape. Physical properties, such as the particle size distribution after comminution is of highest importance for the binding mechanisms in the pelletisation process. Durability and strength of the pellets play an important role indicating the ability to withstand handling stresses. Particle size distributions of the cereal straws (Rye and Wheat) after specific comminution and liberation processes have been carried out with the help of three different image analysis (Microscope, Camsizer and Fibreshape). The durability of the pellets have been investigated as specified in the standards (ASAE standard S269.4) with a quadratic crate and the strength of the pellets with compression and tension testing machine (Zwick Roell type: ZMART.PRO). The particles size results showed differences in both length and width after different comminution processing. An exact comparison between the particle size analyses with the three different image analyses was not possible. The particle size distribution and the different comminution processes displayed influences on the durability and strength of the produced pellets. The particle size distribution displayed approximately 40 % of fines and 60 % of fibers. The particle size distribution displayed a direct relation to the durability of the pellets. Further durability and strength of the pellets displayed a good correlation.

Sep 1, 2012

By M. Brozek

The particle settling velocity is the argument of separation in such processes as classification and enrichment in jigs. It characterizes material forwarded to the separation process and belongs to the so-called complex arguments because it is the function of particle density and size. i.e. the function of two simple arguments. The affiliation to a given subset is determined by the values of two mag-nitudes and the distribution of such argument in a sample is the function of distributions of particle density and size. The paper will present a method of determining the distribution of settling velocity in the sample of spherical particles for the turbulent particle motion in which the settling velocity is expressed by the Newton formula. Because it depends on density and size of particle which are random variable of certain distributions, the settling velocity is a random variable. Applying theorems of probability, concerning distributions of function of random variables, the authors will present general formula of probability density function of settling velocity for the turbulent motion and particularly calculate probability density function for Weibull?s forms of frequency functions of particle size and density. Distribution of settling velocity will calculate numerically and perform in graphical form.

Jan 1, 2014

By Lei Pan, Roe-Hoan Yoon

"Direct force measurement for bubble-particle interaction has been difficult due to bubble deformation, which makes it difficult to know the separation distances between the two macroscopic surfaces. In the present work, we have developed a method of monitoring the deformation accurately, while directly measuring the interaction forces. In effect, we can ‘see’ bubbles interacting with mineral surfaces under different hydrodynamic and chemical conditions and determine both the hydrodynamic and surface forces involved. In the present work, a high-speed camera has been used to record the optical interference fringes of a thin liquid film (TLF) of water formed on a mineral surface. The recorded fringes are then used to reconstruct the spatiotemporal profiles, from which one can determine the hydrodynamic pressure using the Reynolds lubrications theory. From the forces directly measured in the present work and the hydrodynamic pressures obtained from the fringes, we have determined the disjoining pressure. The results show that air bubbles interacting with hydrophilic surfaces form stable TLFs with zero contact angles. The TLF formed on a hydrophobic surface thins fast, form a ‘pimpled’ film, and ruptures to form a finite contact angle. The new information obtained in the present work may be useful to better understand the role of hydrodynamic and surface forces affecting bubble-particle interactions."

Jan 1, 2014

By I. Grigoryeva, G. Voiloshnikov, V. Dementyev, N. Moskaeva, N. Voiloshnikova

"Adsorption processes with use of anion exchange resins are widely applied in the gold mining industry of Russia and the former Soviet Union. Anion exchange resin AM-2B and its analogs (with mixed basicity) are used as adsorbents. This paper focuses on the study of weak base anion exchange resin and its comparison with AM-2B resin. Different nature of the ion exchange groups of the adsorbents mentioned above provides essential differences in their properties both during adsorption and elution of gold and silver. Multistage gold elution and resin regeneration procedure is used for AM-2B resin whereas alkaline cyanide solution is used for weak base resin and allows for the reduction Capex and Opex in comparison with AM-2B resin. Anion exchange resins AM-2B and PuroGold S-992 were tested. Weak base resin is sensitive to pH of adsorption medium. Optimal pH value is 10.1-10.3 (at ?? >10.5 gold loading onto resin decreases dramatically). Adsorption isotherms for gold, silver, nonferrous metals, cyanide and thiocyanate ions from synthetic individual metal cyanide solutions were defined. Adsorption of all components onto PuroGold resin was lower than for ??-2? resin. Adsorption of metals from the solution with equal molar metal concentration (0.1 mg-equivalent/L of each metal) was also studied. The affinity of resins to cyanide metals complexes was established. Weak base resin has higher selectivity to gold in comparison with ??-2B resin and is less sensitive to ion composition of cyanide solution or pulp treated. Weak base resin was tested for gold recovery from gold ores. On the base of test results it was recommended to introduce this resin at some new plants in Russia. Commissioning and operation performance of gold plants confirmed efficiency of weak base resin use."

Jan 1, 2014

By A. D. Ramirez, L. E. Gutierrez, M. A. Garces

"Scarcity of freshwater in mining operations in arid zones in different parts of the world has led to the mining companies to think about using seawater as an alternative source in mineral processing operations. Examples of this situation are Minera Centinela (AMSA) and Minera Sierra Gorda (KGHM), both plants located in northern Chile. Previous studies showed that molybdenite flotation is depressed at high pH values in seawater as a result of the action of hydroxy-complexes of magnesium and calcium that attach to the faces of the molybdenite particles, reducing its hydrophobicity and as a result flotation recovery. In this work, a study of the interactions between molybdenite and kaolinite is presented. The effect of sodium hexametaphosphate (SHMP) dispersant on the recovery of molybdenite in the presence of kaolinite is studied in different aqueous media and it is correlated with induction time data. The results allow to conclude that kaolinite has a stronger depressing effect on molybdenite in seawater compared to its effect in freshwater. Magnesium and calcium are the cations that have the strongest effect in enhancing the interactions between molybdenite and kaolinite. SHMP reduces the negative effect of kaolinite on the floatability of molybdenite both in seawater and freshwater. The induction time data correlate well with the micro-flotation results.INTRODUCTION The need for water in mining processes in arid and semi-arid zones has led to the search for new alternatives for this resource, among which seawater has gained an important space. In Chile, most of the mining operations are located in the northern part of the country, an area that has limited availability of freshwater for the processing of copper and molybdenum sulfides (Castro and Laskowski, 2011, Castro et al., 2012 a). Seawater is an aqueous solution with high concentrations of ions such as Na+, K+, Mg2+, Ca2+, So42-, Cl-, and other less concentrated species which generate important effects in the flotation process as they modify the properties of the solid/liquid, and liquid/gas interfaces, and also increase the consumption of some important reagents used to depress pyrite such as lime. It has also been proposed that flotation of copper sulfides is negatively affected in seawater because of the reduction of oxygen solubility compared to freshwater (Millero et al., 2002; Duan and Sun, 2003). In contrast, it has been shown that the presence of ions in solution in the process of flotation of natural hydrophobic resources improve recovery as result of the compression of the electric double layer (Laskowski, 1974; Klassen and Mokrousov, 1963, Laskowski and Castro, 2008."

Jan 1, 2018

By Thenepalli Thriveni, Seong-Young Nam, Nam-Il Um, Joobeom Seo

In the present work, we report a novel microstructure of synthesized scalenohedral PCC (precipitated calcium carbonate) without any additives by a simple and ecofriendly carbonation process carried out in a liquid-gas system on the crystal growth of the scalenohedral calcite phase. Especially, the process parameters of Ca(OH)2 concentration and CO2 flow rates were investigated to enhance the sensitivity of the process. The highest average length of the scalenohedral calcite was obtained at pH 6.0, temperature 450C, Ca(OH)2 concentration 0.2M, CO2 flow rate 80mL/min, and total volume 1L. The utilization of flue gas-derived CO2 from coal fired power plants could be a form of carbon capture and storage using carbonation reaction with scalenohedral PCC. Finally, the synthesized scalenohedral PCC was used as a filer for ONP recycling. We demonstrated all these experiemnts at semi pilot plant scale.

Jan 1, 2014

By L. Gutierrez, R. Yepsen, F. Alarcón

Chile is the world's largest copper producer which is mostly in the form of sulfides for which froth flotation is the most efficient concentration process. As a result a concentrate that contains high concentrations of copper sulfides such as chalcopyrite, chalcocite and enargite is obtained. In the last decades processing of ores containing high concentrations of enargite (Cu3AsS4) has continuously increased in Chile, which is related to the fact that ore deposits nawadays are more heterogeneous and complex. Enargite is a mineral that contains arsenic and its presence in the copper concentrates implies severe penalties. In addition, the shortage of fresh water has driven the search for new alternative sources of water, among which seawater has proved to be one of the most attractive. The objective of this research is to study the behavior of the enargite in the process of flotation using seawater, and at the same time to compare its behavior with the results obtained using conventional water. The study was carried thorugh micro-flotation tests using pure samples of enargite, at pH values ranging from 4 to 11, both in fresh and seawater. PAX and MIBC were used as collector and frother respectively. Micro-flotation tests were also done at different redox potential conditions so that the effect of the surface oxidation of enargite was evaluated in seawater. The results indicate that the recovery of copper from enargite is reduced in seawater compared to fresh water, in particular at the pH values close to those of the formation of the first hydroxy complexes of Mg and Ca. In general, the experimental data indicate that the floatability of enargite is strongly affected when seawater is used, in particular at oxidizing conditions. These results suggest that Mg2+ and Ca2+ ions contained in seawater interact with the surface of enargite forming hydrophilic species.

Jan 1, 2018

By André Mans, Frans B. Waanders

Current losses of Ferrosilicon (Fe-Si), which is used in the dense medium separation (DMS) of iron ore at Kumba Resources, Sishen, South Africa occur due to adhesion to the separation products and also by being present in the effluent stream, due to abrasion. The losses contribute greatly to the running cost of the plant and the purpose of this project was to determine the characteristics of the unused Fe-Si and then to characterise the changes that occur during storage and the use thereof. A Scanning Electron Microscope (SEM) and Mössbauer Spectroscopy (MS) were used to investigate the characteristics of the fresh and used Fe-Si. It was found that the biggest loss of Fe-Si was due to the abrasion of the particles during the DMS process, which resulted in the liberation of Fe and subsequent formation of an oxihydroxide froth. A possible change in magnetic properties was also observed, leading to further losses that could occur during prolonged use of the medium. No clear changes to the Fe-Si occurred during correct storage methods, as was initially thought.

Jan 1, 2003

By A. V. Nguye, P. A. Harvey

Previous studies have reported that inorganic electrolytes can enhance floatability of coal. The research has shown that the enhancement, if any, is highly dependent on changes in solution pH, type of electrolyte, and electrolyte concentration. The reasons for this are still not clear. In this study the floatability of coal particles in mono and divalent salt solutions was investigated. The zeta potential and hydrophobicity of the coal was measured experimentally, and a modified Hallimond tube was used to determine the floatability of coal particles by single bubbles, where the collision efficiency was equal to unity. The experimental information was used in conjunction with the Hogg-Healy-Fuerstenau equation to quantify the electrical double layer interaction. It was found that for low electrolyte concentration (less than 0.1 M) solutions the flotation recovery of coal particles was less than that for distilled water, and decreased with increase in concentration. Conversely, at electrolyte concentrations above 0.1 M, flotation recovery increased with increasing concentration. Both of these results are consistent with previous observations, but are inconsistent with expectations when considering the possible influence of electrical double layer interaction. A possible mechanism, based on the existence of the pre-existing submicron-sized gas bubbles, known as bubstons (i.e. bubbles stabilized by ions), present in water in close proximity to the hydrophobic coal surfaces is discussed in line with the early observation of flotation improvements by microbubbles “nucleating” on hydrophobic surfaces. In particular, the dependence of the bubble-particle attachment efficiency on electrolyte concentrations supports hypothesis on the salt-dependent and ion-specific existence of bubstons. However, a theoretical explanation of the transition salt concentration (at about 0.1M) is deficient at present. The existence of these submicrobubbles in close proximity to hydrophobic surfaces is not trivial. They can (as can individual gas molecules or other solutes) mediate and extend the range and magnitude of the attraction between hydrophobic macroscopic surfaces. These bubbstons may explain the curious phenomena of the socalled long-ranged hydrophobic attraction measured with the Surface Force Apparatus and Atomic Force Microscopy, and the slippage at hydrophobic surfaces. Finally, the coalescence of bubbstons affects the rupture of liquid films at a very large thickness (over 100 nm), observed, but unexpected, by flotation chemists.

Jan 1, 2003

The reactivity of clay minerals and variety of these reactions are greater than any other known colloidal material. While it is acknowledged that clay minerals can cause problems in mineral flotation, the literature contains conflicting evidence, particularly with respect to the effect of clays on froth stability. It is well known that achieving and maintaining optimum froth stability is an influential factor in determining froth flotation performance. However, the presence of clay minerals in the ore is a major challenge to obtaining a stable froth. In fact, clay minerals could reduce froth flotation performance by both decreasing and increasing froth stability. The mechanism by which clay minerals affect froth stability is not fully understood and needs to be investigated further. In order to improve flotation performance, reliable knowledge of the effect of clay minerals on froth stability is essential which is discussed in this paper. Keywords: froth flotation, froth stability, clay, clay minerals

Sep 1, 2012

By John A. Rumball, Martin R. Houchin

Data from autogenous and semi-autogenous tests in a 1.67m diameter mill have been analysed in terms of a new model for rock abrasion. This model defines specific rate as the rate of production of fines (material less than 13mm) per unit mass of rock, where the term “rock” is applied to all ore pieces of ore coarser than the grate size. In most cases, an allowance for preliminary rounding and cleavage was made. A method has been developed to analyse steady-state data, using piecewise fitting to the cumulative size distributions. The model was compared to the well-established models, which are based on the population balance method. The specific rate increased for all rock sizes as the volume of 100mm balls in the mill was increased. Tests using a coarser feed and smaller balls provided further evidence that once rocks are rounded, abrasion is due to localised surface damage, caused by impacts, rather than rotational shear. An allowance for rapid rounding of jagged rocks, followed by less rapid abrasion of rounded pebbles was also tested, but the analysis was not conclusive. The average specific rate is a useful measure of the capacity of a primary mill. The effect of power intensity (kW/t of ore) was also investigated as a means of extrapolating the pilot-plant data to large production mills.

Sep 29, 2003

By L. Gutierrez, M. Jeldres, R. J. Jeldres

"Clays are present in a large number of mineral deposits and are commonly found as gangue. Its complex chemical structure, characterised by anisotropic surfaces, makes its presence a permanent challenge for flotation operations, increasing the reagent consumption, decreasing the quality of the concentrate, and changing the rheological properties of the system. In this context, the main objective of this research is to improve the floatability of chalcopyrite minerals in the presence of clays by using guar gum, a low molecular weight organic polymer, which acts as a surface coating agent for clays. Clay Minerals Society provided the kaolinite sample and the chalcopyrite sample was purified from mineralized rock specimens obtained from Ward’s Natural Science Establishment. Micro flotation tests were carried out in a 150 cm3 Partridge-Smith cell, using compressed air as the gas phase at a flow rate of 80 cm3/min. Potassium amyl xanthate (PAX) and methyl isobutyl carbinol (MIBC) were used as a collector and a frother, respectively. The results showed that the use of guar gum improves the recovery of chalcopyrite in the presence of kaolinite because it induces the formation of clay aggregates that settle by gravitational effects, preventing the 'coating effect' and decreasing excessive collector consumption. pH played a key role in the guar gum performance, which was most effective at highly alkaline conditions (pH 11), where the copper recovery improved from 73% to 90%. The work has significant implications for the mineral flotation in the presence of clay minerals.INTRODUCTION The mining industry is continuously confronted with challenges that alert the sustainability of the sector. There is little availability of water, the grade of the deposits are getting smaller, and the gangue is becoming more complex. Usually, clays are part of the gangue in numerous systems, including copper ore, porphyry, nickel, platinum, etc. (Senior & Thomas, 2005). The structure is mainly composed of layers of tetrahedral silica (T) and octahedral alumina (O) that join in certain proportions: 1: 1 (T-O) and 2: 1 (T-O-T) (Theng, 2012). Also, they expose two crystallographically different surfaces: the faces, which tend to be negatively charged, and the edges, which carry a charge that changes from positive to negative depending on the pH (Van Olphen, 1977). One of the most common clays in copper deposits is kaolinite, whose structure is composed of an octahedral sheet of gibbsite bound to a tetrahedral silica sheet in the ratio 1:1"

Jan 1, 2018

By A. Kamali Moaveni, A. Boehm

"The current research study addresses a physical separation process of basic oxygen furnace slag “BOF-Slag” (also called Linz-Donawitz “LD” slag) for the removal of phosphorous. In order to recycle the LD-Slag into the steelmaking process, the physical dephosphorization methods are considered. The systematic geometallurgical investigation carried out on particle classes of decreasing size, which were further subdivided into susceptibility classes, shows intimate intergrowth beyond 40 µm due to slag´s fast cooling rate. Generally, LD-slag is constituted of oxide and silicate phases, among which di-calcium silicate “C2S” dominates. About 0.5 mass% of phosphorous was detected in the LD- slag, which is exclusively situated in the lattice of the C2S. The comparatively high grinding resistance (Rittinger index 12.9 cm²/J) of the LD-slag reflects the energy demand to liberate the phosphorous carrying phase from the iron containing minerals, while separation efficiency decreases in the very fine particle size range. Hence, the conversion of the phase intergrowth pattern was considered alternatively to re-build the mineral phase structure of the material to a separable interlock pattern. Carbon dioxide, as the most convenient substance in the steelmaking plants, was applied to digest the C2S in the presence of water and to reduce the basicity of the slag slurry. As a result of C2S-CO2 chemical reaction, calcite and calcium silicate are precipitated at the surface of the oxide particles and carried between 25% and 75% of the total phosphorous, respectively. Accordingly, the mobility of the phosphorous content phase to the top of the grains serves the possibility to separate the precipitated layer by mechanical attrition process. This paper is focused on the impact of the intergrowth pattern alteration on the slag´s separability characteristics. Moreover, the operating conditions of the carbonization process, such as temperature and pressure, on the deconstruction kinetics of the C2S and the generated products will be considered. INTRODUCTION The steelmaking BOF-Slag is a stony aggregate waste from the steel manufacturing process. The investigated slag by the current research work was provided by voestalpine steelmaking plant in Linz, Austria. The current legislative situation in Austria restricts the historical application of slag as construction material, due to the high level of heavy metals content and corresponded land-filling and transportation costs of slag, therefore the demand for recycling of BOF-Slag to the steelmaking process has raised, as an alternative application. Statistically, voestalpine steelmaking plant produces about 130 kg BOF-Slag per ton of final steel product, which serves annual BOF-Slag production of 700,000 ton, approximately."

Jan 1, 2018

By Gaurav Soni, Roe-Hoan Yoon

A first principle flotation model has been derived from the basic mechanisms involved in flotation. The model consists of a series of analytical equations for bubble generation, bubble-particle collision, attachment, detachment, and froth phase recovery. The model can predict flotation from both hydrodynamic and surface chemistry parameters such as bubble size, particle size, energy dissipation rate, ?-potentials, contact angles (?), etc. The model predictions have been compared with the results of a series of laboratory flotation tests conducted using mono-sized glass beads of different particle sizes and contact angles under different operating conditions. Some of the experiments were conducted using a 1:9 mixtures if hydrophobic silica and hydrophilic magnetite, so that the product graded could be readily determined by simple magnetic separation. The model predictions are in good agreement with the experimental results both in recovery and grade. A computer simulator developed on the basis of the model is capable of designing a preliminary flotation circuit on the basis of feed characteristics, e.g., size-by-liberation data, and the hydrodynamic information on the flotation cells to be incorporated in the circuit.

Jan 1, 2014