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By J. Larose, E. Irissou

The aerospace business has always been driven by innovation. A significant portion of the overall business technology development strategies is still based today on improved materials and coatings. In this highly regulatory business environment, large amounts of funding are required to increase the maturity level of novel technologies, but the evolution process still remains a delicate endeavor. The technical risks involved during technology development obviously need to be managed and mitigated throughout the development cycle, but other hurdles almost inevitably get encountered, such as budget limitations, transition from lab scale to production scale, loss of focus, intellectual property negotiations and supply chain integrity. This presentation will cover some of the issues raised when a great idea is slowly morphed into an aerospace production part.

Jan 1, 2010

By A. C. Atenas

The majority of refineries that operate with traditional starting sheet technology ?starting sheet- uses a relatively low current density of 250 A/m2. Industrial tests at high current density with conventional technology were carried out in Refinery of Potrerillos, getting satisfactory results that are similar the results obtained with permanent cathode technology. The series of copper refining electrolyses electrolysis trials were carried out between 300 to 325 A/m2. Electrolysis conditions, in accordance with industrial practice, were kept constant in all sets of experiments and were as follows; 45 g/L Cu 2+, 210 g/L H2SO4, 62 °C, electrolyte circulation of 14-18 L/min. The same Dosing dosing of Additives additives used in permanent cathode technology was required in these tests. In general, only not importantminor operational modifications were necessary in comparison to normal practice in the Refinery to assure the good results. Different quality of starting sheet and anodes were examined. The test included starting sheets from smelter and laminated process. Results indicate that the charge physical quality of the electrodes and the control of the process during the two first days of operation are the keys to get the best results.

Jan 1, 2007

By S. Kawai

Natural convective flow of the electrolyte solution plays an important role in several electrochemical systems. Copper refining electrolysis is the most important industrial process to produce high purity copper on large scale. Turbulent natural convection develops along vertical plane copper electrodes installed in an unstirred electrolyte accompanying with the electrochemical deposition and dissolution of copper during the electrolysis. It introduces the electrolyte stratification phenomenon. Thus, the electrolyte is circulated in a special way depending on each electrorefining tankhouse. The theoretical discussion is indispensable to understand the coupling phenomenon between the ionic mass transfer rate and the morphological variations of electrodeposited copper. In present study, the mass transfer rate of both Cu2+ and H+ ions as well as the momentum transfer rate is numerically analyzed accompanying with the turbulent natural convection along 1 m high Cu metal electrode surface.

Jan 1, 2007

By Z. -E. Nakagawa, O. Yamamoto

After the formation of a concentration gradient of SiC within C-C composite, either zircon or mullite thin films were coated on the surface by sol-gel process. Oxidation resistance tests of as-prepared composites with a couple consisting of a ceramic thin film and a SiC-gradient were then carried out in air at the temperature range from 600 to 1600°C. By the coating of zircon with a thickness of 1.5 µm, a pronounced oxidation resistance was observed; the mass loss by oxidation was almost negligible at 1000°C and one hundredth of original composite at 1400°C. In the case of the coating of mullite with a thickness of 1.0 pm, the marked improvement in oxidation resistance over the whole temperature range examined, from 600 to 1600°C, was found with the combination of a SiC-gradient and a mullite thin film

Jan 1, 2004

By Heinrich Möller

The electro-oxidation of 0.1 M ethylene glycol at gold, platinum and gold-platinum alloy electrodes in different heat treatment conditions has been studied in 0.5 M NaOH, at room temperature. Poisoning of all the electrodes occurs. However, the alloy electrodes poison at a faster rate than the pure gold and platinum electrodes. This indicates that the initially higher activity of these electrodes cannot be the result of decreased poisoning through a "third-body" effect.

Oct 1, 2003

By Premil Agarwal, Alok R. Patnaik, Pulak Dhar, Prakash C. Patnaik

In this study, a physics based model has been presented, considering the growth of the thermally grown oxide (TGO) layer on the bond coating of a thermal barrier coating. Using diffusion equations, a model has been developed to physically describe the oxidation process. The mathematical equations representing the diffusion formulations have been solved numerically. The computed results show the depletion of Al in the bond coating as it diffuses both towards the super-alloy substrate and towards the TGO produced in between the bond coating and the ceramic TBC top layer.

Jan 1, 2004

By J. P. Bennett, W. E. Lee, S. Zhnag, K. S. Kwong

An EAF slag properly saturated in MgO results in increased refractory service life and steelmaking efficiency. A computer model was developed using phase equilibrium data from the MgO-CaO-SiO2-FeO, MgO-CaO-Al2O3-SiO2 and SiO2-CaO-Al2O3-FeO systems to predict MgO saturated slag chemistry. This model has been successfully applied to a commercial EAF, although disciplined plant practices are required to achieve benefits from slag chemistry control.

Jan 1, 2004

By R. J. Bowell

Mineralogical controls exert significant control over the extraction of uranium from its ores. Uranium speciation, associated mineralogy, deportment and uranium mineral availability are all factors of consideration when assessing leachibility. This study presents data from laboratory uranium extractions undertaken on several contrasting uranium ores from a wide range of orebodies. The results provide insight into the mineralogical factors of importance when considering uranium extraction. These results are presented within the wider context of geometallurgy and demonstrate how geometallurgical assessment, even at an early stage of mine development, can greatly assist in the design of a suitable extraction scheme.

Aug 1, 2010

By Yoshitaka Mitsuda, Masao Miyake, Masafumi Maeda

A leaching treatment was investigated to recover metals including rare earths from the mixtures of hydrogen storage alloys and nickel hydroxide. A potential-pH diagram of the La-Ni-H20 system including the domain of stability of LaNi5 was drawn to find appropriate leaching conditions. Alkaline solutions containing ligands that form complexes with nickel ions were supposed to be available to separate hydrogen storage alloys from the mixture. When the mixture was leached with ammoniacal alkaline aqueous solutions, the nickel hydroxide was dissolved and the hydrogen storage alloy was recovered as its original alloy.

Jan 1, 2004

By D. L. Chen, Q. Zhang

The effect of particle sizes on the low cycle fatigue (LCF) life of discontinuously reinforced metal matrix composites (DR-MMCs) has been widely studied. However, how the particle size affects the LCF life of DR-MMCs quantitatively is still lacking. The aim of this investigation is, therefore, to present an analytical model linking the LCF life to the particle size. This model, based on the enhanced dislocation density in the matrix and the load bearing effect of particles, showed that a decreasing particle size results in a longer LCF life, and the results predicted are in good agreement with the experimental data.

Jan 1, 2004

By M. J. Baker

Energy and Minerals Australia Ltd are undertaking a study of the recovery of uranium from the Mulga Rock Deposits in Western Australia. Approximately 80-90% of uranium identified to date is present as tabular layer up to 5 m thick within a lignite seam 30 m to 50 m below surface. Other metals are also present. Metallurgical studies at ANSTO Minerals laboratories in Sydney have focused on identifying a suitable uranium leaching process and assessing the possible downstream impacts of the organic material in the ore. The extraction of other metals has also been examined. This paper provides the results of testwork performed at ANSTO to date.

Aug 1, 2010

By V. C. Pandolfelli, S. F. Santos, L. A. Rodrigues

Under conditions of stable crack propagation at room temperature, the elastic energy stored in ceramic materials is converted mainly to surface energy. However, at high temperatures, creep may also occur in such materials, in which case it will present a ductile behavior. This paper discusses the brittle-ductile transition of a refractory material. Stable crack propagation and creep tests were carried out under a three-point bending device. A commercial ceramic containing 63 wt-% of SiO2 and 31 wt-% of Al2O3 was used as testing material. The results revealed that the change in behavior from brittle to ductile was caused by softening of a vitreous phase present in the material's microstructure.

Jan 1, 2004

By M. L. F. Gameiro

The aim of this study was to check the feasibility of non-dispersive solvent extraction to recover copper from ammoniacal solutions using hollow fibres as contactors. Data of mass transfer using the B3-diketone LIX 54 as extractant was obtained. The influence of tube and shell hydrodynamics on the extraction rate of copper was studied. The overall mass transfer coefficient of copper was calculated from the experimental data by performing steady state material balance. Simultaneous extraction and stripping experiments were carried out using different volume ratios of feed phase to stripping phase. The results obtained showed that practically all the copper content was removed from the ammoniacal feed solutions. The recovery of copper reached nearly 100% in several extraction-stripping experiments.

Jan 1, 2007

By Mauricio Olivares

About Largest combined Phosphate and Potash company in the world Corporate headquarters in Plymouth, Minnesota Publicly traded on NYSE under MOS

Aug 1, 2013

By Frederick Biery

Outline ? Project Challenges ? Results from 100 recent projects ? What factors are driving the best and worst projects ? A look at recent mining projects ? Conclusions

May 1, 2009

By G. C. Weatherly, D. S. Wilkinson, A. M. Limarga

Competition between stress generation and relaxation mechanisms during the oxidation process has been observed. However, the nature of the intrinsic growth stress in thermally grown scales is not well understood. In this talk, we will propose a conceptual model to calculate the intrinsic growth stress based on the analysis of stress-driven diffusional process of oxygen ions along the oxide grain boundary. The calculated stress, which is considered to originate from the constrained lateral expansion of the oxide, is in agreement with a range of experimental observations.

Jan 1, 2004

By M. Bavand-Vandchali, F. Golestani-Fard, S. Khalili, S. Rowshanfekr-Fallah

In the secondary metallurgy of steel, the availability of ladles plays an important role in decreasing the production cost. The refractory lining, therefore, should satisfy optimized quality to grant higher heats. This paper reports the results of an investigation carried out in Iranian Mobarakeh Steel Company in order to increase the lining life of ladles by employing different types of MgO C and Al203 - Mg° - C. The zoning concept was used in replacing the conventional refractories either in slag line or the lower parts of ladle. The number of heats could be improved to almost two times as before. The results are explained in terms of refractory quality as well as zoning approach. The economical impact of this improvement will also be analyzed.

Jan 1, 2004

Introduction Gold Mining is an Important Economic Activity in Canada n Total value added during 1990-99 was $15.5 bn n The gold price is an important factor in the value added process n The gold price affects gold mining output, profits, exploration expenditures, employment, etc. Some Factors that Affect the Gold Price n The value of the US Dollar affects the US Dollar price of gold: a weaker US$ correlates with a higher gold price n Supply affects the gold price: the higher the supply on the market each year, the lower the average gold price that year Central Bank Gold Sales n Yearly central bank gold sales add to supply, and affect the price of gold negatively n The negative impact on the price of gold reverberates through the Canadian gold mining industry n Despite the modest amounts, even Bank of Canada gold sales affect the Canadian gold mining industry

May 1, 2003

By Y. Qi

A cell-level nonlinear dynamic model of solid oxide fuel cell (SOFC) based on physical diffusion principles is built in this note. It demonstrates that reactant diffusion processes from gas flow bulks to triple phase boundaries (tpbs) play an important role in the dynamic behaviors of SOFC. The simulation shows that under certain condition, the effect of the double layer capacitance may be neglected. The phenomenon of slow rise of voltage in current interrupt experiment may be explained by the dynamic behaviors of partial pressures in the vicinity immediately above tpbs.

Jan 1, 2005