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By C. Zangerl, H. Lechner

"Large scale rock slides in deeply incised Alpine valleys are common hazards that can endanger human life, settlement areas and critical infrastructure such as highways, railways and reservoirs (Bonzanigo et al., 2007). In order to perform reliable forecasts of the behaviour of rock slides influenced by large dam reservoirs the geometry, the kinematics, the deformation behaviour and the hydrogeological situation need to be understood profoundly. Based on generic rock slide models the influence of the rock slide geometry on the stability as well as the impact of the buoyancy forces and water load of the reservoir at the toe of the slope are the main focus of this study. Various assumptions of hydraulic conductivity, groundwater conditions of the rock slide and impoundment depth of the reservoir are analysed using limit equilibrium approaches.Generally, deep seated rock slides are characterised by deformation along one or multiple shear zones where most of the measured total slope displacement localizes. Many large rock slides, especially those observed in foliated, mica-rich crystalline rock masses (e.g. paragneisses, mica schists, phyllites), do not fail suddenly or reach high velocities. Instead, many of them move slowly and reach velocities of centimetres per year or even less. Some show episodic accelerations, sometimes reaching alarming levels, but then subside to non-critical levels again. However, there is a potential that deep-seated rock slides fail rapidly, develop into far-reaching run-out rock flows, and cause catastrophic events. Whereas the role of triggers in promoting phases of acceleration is often understood, the same cannot be said regarding the kinematics and dynamic processes by which the rock slide mass decelerates, re-stabilises or accelerates to a catastrophic degree once the trigger impetus has been removed. Thus key questions of the presented work concern the geotechnical, geometrical and hydrogeological conditions under which a slowly moving rock slide is triggered to accelerate to irreversible, maybe dangerous velocities. The development of the sliding zone is generally influenced by pre-existing discontinuities such as brittle fault zones, shear and tensile fractures, foliation and bedding planes. These geological structures determine the geometry of the sliding zone which can either be rotational or translational. During the gravitationally induced failure process the geometry of the rock slide undergoes a change.Several observed post-failure geometries in metamorphic rocks show a concave topography in the middle to upper part of the rock slide and a typical convex or bulge-like topography at the toe of the slope (Zangerl et al., 2012). Whereas the sliding zone of the upper part of such a rock slide mass is rather steep and planar, the inclination of the sliding zone at the toe can be close to zero and act against the driving forces (Alonso et al., 2010). A shear zone that meets alluvial deposits at the foot of the slope encounters a stabilizing impact on the mechanical behaviour. This buttressing effect of alluvial sediments has a remarkable influence on the slope stability."

Jan 1, 2015

By Michel Aubertin

Les rejets miniers sont communément utilisés, depuis plus de 60 ans, comme matériau de remblayage des chantiers souterrains. Les roches stériles et les rejets de concentrateur sont employés comme remblais car ils sont disponibles sur les sites miniers à un coût réduit pour aider au support de terrain. Le remblayage des ouvertures est également avantageux car il permet de réduire la quantité de rejets entreposée en surface. Dans les mines souterraines, le remblai des chantiers doit aider à maintenir un espace de travail sécuritaire, tout en favorisant la récupération du minerai et le contrôle de la dilution. Il est alors essentiel d'évaluer précisément les pressions exercées par le remblai sur les murs et sur les barricades installées près de la base des chantiers. Dans cette présentation, des solutions existantes pour évaluer les pressions dans les chantiers sont brièvement revues. Les auteurs présentent ensuite des solutions analytiques récemment développées à cette fin, qui permettent de tenir compte du transfert des contraintes du remblai aux parois des chantiers et des galeries. Les solutions proposées, qui sont basées sur la théorie de l?effet d?arche, prennent en compte l'influence de la géométrie des ouvertures et de la position des barricades. La méthode de calcul permet aussi de calculer l?effet des pressions d?eau pour un remblai partiellement ou totalement submergé. Les solutions s'appliquent au cas d?un remblai récemment mis en place, alors que l?effet de la pression interstitielle ne peut pas être négligé, et aussi à plus long terme sous une condition drainée. Des résultats expérimentaux et des simulations numériques sont utilisés pour valider les équations proposées. Les résultats analytiques et numériques montrent notamment que la pression totale sur une barricade peut être grandement augmentée par la pression d?eau, tandis que la contrainte effective peut être réduite par les pressions interstielles (par rapport à la condition drainée ou sèche). On discutera aussi des implications pratiques de ces résultats pour l?application des remblais souterrains.

Nov 1, 2008

By Z. Mubarok

An overview of the problems encountered the electrorefining of copper anodes containing high levels of nickel and antimony is presented. Our investigations have been focusing on the passivation behaviour of the anodes with high contents of Ni, Sb, Sn, and Pb, the formations of kupferglimmer and floating slimes. The results of linear voltammetry, chronopotentiometry and electrolysis test revealed a noticeable lower resistance of the anodes to passivation in comparison to those with lower contents of Ni, Sb, Sn, and Pb. Anode containing kupferglimmer exhibited oxygen gas evolution during the passivation state. Scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) indicated that tin can replace and/or join antimony in the kupferglimmer structure. Under specified experimental conditions, floating slimes precipitations took place with high Ni, Sb, Sn, and Pb anodes prior to the end of one anode period.

Jan 1, 2007

By Sergio Fuentes

During the past fifteen years, mines utilizing the block caving method have improved performance and systematically reduced total mining costs. This paper describes improvements in mine design, mine planning and mine management, including methods enabling the Chilean and International mining industry to ensure cost savings and productivity growth while using the block caving method. These improvements have encouraged the re-evaluation of underground operations at operating and closed open pits, and challenge surface mining applications as the only low cost mining method. This paper describes a strategy to estimate the optimum open pit to underground transition time during the life of a mine.

May 1, 2003

By P. A. Riveros

Antimony is commonly found in copper electrolytes and can contaminate the cathode deposit. Several methods, such as ion exchange, solvent extraction and precipitation, have been developed to remove antimony from copper electrolytes. However, past research has been carried out almost exclusively with Sb(III), whereas the presence and behavior of Sb(V) in the electrorefining circuit have been largely ignored. In this study, the behavior of Sb(V) species was monitored and compared to that of Sb(III) species, using specially developed analytical and SEM-EDS techniques. Significant differences in the behavior of the two species were noted. Although the solubility of Sb(III) increases with temperature in synthetic copper electrolytes, the solubility of Sb(V) appears to be constant over the range from 30 to 80°C. Whereas Sb(III) forms several crystalline oxy-sulphate compounds, Sb(V) appears to remain as an amorphous oxide. Both Sb(III) and Sb(V) are extracted by aminophosphonic resins, and Sb(III) is readily eluted by HC1 or complexing agents. By contrast, concentrated HC1 elutes Sb(V) inefficiently and complexing agents, such as EDTA and tartaric acid, do not elute Sb(V) to any significant extent. This observation implies that in industrial practice, unless special measures are taken, Sb(V) will accumulate on the resin, eventually impeding the ion exchange process.

Jan 1, 2007

In semi-enclosed coastal areas in Japan, phosphorus is often observed in the level of limiting phytoplankton growth, causing alteration of species composition from useful diatoms to nuisance dinoflagellates. On the other hand, the sediment quality is still degraded with organically rich reduced conditions. The latter is the major cause of oxygen-depleted bottom water formed in summer, and it makes benthic organisms difficult to live. Steel-making slag can be a source of phosphate and silicate that induce growth of diatoms, and further may remediate the reduced condition of the sediment through the formation of iron hydroxide that works as a kind of oxygen pool.

Jan 1, 2004

By B. T. Lu, J. L. Luo, T. Yu, C. W. Chen

In this paper, the synergism in erosion-corrosion process occurring in oil sand wastewater transportation caused by the interaction of mechanical and electrochemical factors was experimentally investigated. The erosion-corrosion tests were conducted with A1045 steel in synthetic slurries comprising tap water and silica sand. The material loss due to corrosion-enhanced erosion was assessed with the chemo-mechanical model developed by the authors recently. The results indicate that the material loss produced by corrosion-enhanced erosion at the open circuit potential can be formulated as a linear function of logarithm of corrosion current density. The wastage caused by the erosion-enhanced corrosion was analyzed based on the concept of non-equilibrium thermodynamics. The material loss induced by the erosion-enhanced corrosion is approximately a linear function of overall erosion rate measured in synthetic slurries, indicating that erosion-enhanced corrosion could be reduced by adopting surface strengthening techniques to improve the resistance to the plastic deformation in surface layer.

Jan 1, 2004

By H. R. Manouchehri

"It is well understood that, apart from particle hydrophobicity, the flotation process is strongly influenced by the cell hydrodynamics. Once the chemical conditions were optimized and fixed, the flotation rate is essentially determined by impeller speed and the air flow rate.The collection efficiency in flotation is a product of collision, attachment and stability/detachment efficiencies. The collision efficiency for a given particle diameter is increased by decreasing the bubble size and bubble velocity as well as increasing the power input to the cell. The attachment efficiency, however, is defined by bubble size and its velocity. The detachment/stability depends on the relative magnitudes of the attachment force between the bubble and particles and the detachment force acting on the bubble-particle aggregates. For the particles having specific contact angle, the stability decreases as the energy input increases. Therefore, there must be an optimum energy dissipation to maximize recover of defined size fraction.A comprehensive laboratory study was devoted to determine the effect of power input in recovery of finely grind Cu-Ni bearing ore. Several flotation tests were conducted to define the hydrodynamic parameters for a laboratory scale Runge cell under different impeller speeds. An increase in flotation recovery of finely ground ore was observed when the impeller speed was increased from 450 to 1,200 rpm. The experimental results have shown increasing in water recovery and improving in flotation kinetics of fines by increasing the power input to the flotation cell. Implementation of the Wark flotation model to the experimental data revealed a good correlation between the experimental data and the model. For the particles having enough hydrophobicity the flotation rate increases by increasing the impeller speed due to a higher value for collision efficiency within the cell."

Jan 1, 2016

By M. P. Rennick, D. M. Burton

The Murray Brook massive sulfide deposit, which was the first geochemical discovery in the Bathurst camp, is one of the largest sulfide deposits in the area. The massive sulfides are hosted by quartzose metasedimentary rocks in the lower part of the Ordovician Tetagouche Group. This thick succession of sedimentary rocks is overlain conformably by felsic volcanic rocks, and is structurally overlain by mafic volcanic rocks. The massive-sulfide body is polydeformed, but primary metal zoning is still discernable and may permit future exploitation of discrete lead-zinc and copper zones. Although it was discovered in 1956, the deposit was not developed until 1989, when Murray Brook Resources commenced processing of gossan containing precious metals. Recovery of gold, silver, and mercury is accomplished by indoor vat leaching on a year-round basis.

Jan 1, 1992

By B. MohammadSadeghi, S. Bakhshivash, M. Haghshenas, F. Rahimi

"Spring-Back/Forward in sheet metals is defined as recovery of elastic strain upon unloading in a deformed sheet specimen. Since this phenomenon can cause alternation in the dimensions of a part, leading to irrecoverable compensations, the operative parameters need to be investigated, thoroughly. To assess spring-forward and effective bending parameters, V-shaped bending dies are the most commonly used experimental approach. In the present research, the effect of bending angle and punch tip radius on the spring-forward behavior of an Al-Mg-Si alloy sheet specimen is studied. To this end, a V-shaped die with four bending angles (i.e. 30°, 45°, 60°, and 90°) was designed and fabricated. Specimens with thickness of 2 mm were cut with dimensions of 50 mm×10 mm. Results show that by increasing the bending angle, the spring-forward angle decreases. In addition, smaller punch tip radiuses lead to further spring-forward. The effect of these parameters on the amount of spring-forward angle, strain distribution and homogeneity along sheet thickness was assessed using finite element analysis (FEA). Simulation results show that as the bending angle increases, the strain is developed more homogenously. Finally, micro-hardness test was used to study the effect of strain hardening caused by bending operation on strength evolution. Results show higher hardness trends for the zones in which the maximum plastic strain occurs.INTRODUCTIONPrecise production plays a significant role in the durability of a part. When it comes to sheet metal forming, this issue should be taken into account as an important factor. In order to predict the alternations, bending dies with special geometric parameters (i.e. V-shaped, U-shaped and L-shaped dies) are commonly used (Wagoner, Lim, & Lee, 2013)."

Jan 1, 2016

By K. Reinharter, J. Schmidl, D. Gregurek, A. Spanring

Copper smelting furnaces are typically lined with magnesia-chromite refractories, which are exposed to multiple and complex stresses. The selection of the processing route, furnace type and slag system will be dictated by the specific ore type available, this will determine the individual refractory wear. This paper evaluates the common refractory wear mechanisms as observed in the copper Peirce-Smith converter and in the copper anode furnace. The chemical factors include corrosion caused by fayalite type slag and sulfur supply, as well as, by Cu-oxide attack. Changes in the temperature during the furnace operation (thermal-shock) create stresses in the brick lining which can only be absorbed in limited extent. Mechanical factors include erosion, caused primarily by the movement of the metal bath, slag and charging material, as well as, stresses in the brickwork due to punching. Finally improper lining procedures can also effect the service life. All these wear parameters lead to severe degeneration of the brick microstructure and a decreased lining life. Therefore, a detailed investigation and understanding of the wear mechanisms through “post mortem studies” together with thermochemical calculations by FactSageTM software is an important prerequisite for the refractory producer. Based on these research results, combined with specific process knowledge, appropriate brick lining solutions for copper processing furnaces can be recommended. INTRODUCTION The refining of copper includes converting of matte or black copper into blister copper for final fire refining process in the anode section. Typically Peirce-Smith (PS) converters are in use. Other technologies include Hoboken Converter, TBRC but also Flash Converting Furnace and bath smelting furnaces (ISA, Ausmelt) (Davenport et al., 2002). For fire refining two types of furnaces are used – the rotary furnace type is dominantly used in the primary production route while secondary smelters tend to use hearth refining furnaces which are more suitable for scrap melting. Installed working linings are based on magnesia-chromite bricks but especially in the anode refining section the application of alumina-chromia bricks have become more popular in the recent years. It comes without saying that, to some extent, large variations in the slag composition can be observed from the data provided to RHI Magnesita during post-mortem studies of used refractory samples and this needs to be addressed properly during the selection process of refractory linings.77

Jan 1, 2019

By Y. Konishi

This paper reviews the mechanism and kinetics of bioleaching of chalcopyrite by the thermophilic archae Acidianus brierleyi in batch and continuous-flow reactors. Rate data for the batch bioleaching of chalcopyrite concentrate were collected to clarify mechanism of the chalcopyrite bioleaching with A. brierleyi. The chalcopyrite leaching was markedly accelerated in the presence of A. brierleyi, and greater than 90% copper leaching was achieved within 10 days. Chalcopyrite leaching took place predominantly as a result of direct attack by adsorbed bacteria on the sulfide surface, the chemical leaching with ferric iron being insignificant. Batch rate data collected under a variety of operating variables were analyzed with our batch bioleaching model, in order to estimate microbial kinetic and stoichiometric parameters for the microbial growth on chalcopyrite. The batch model and the estimated parameter values were used to find optimum operating conditions. Moreover, the batch model was extended to describe the bioleaching in continuous-flow stirred tank reactors. Simulations based on the continuous reactor model and the estimated parameter values were used to predict the leaching fraction as a function of the number of reactors connected in series.

Jan 1, 2007

By H. Dundar

The first application of High Pressure Grinding Rolls was in 1985 at a cement plant, for the purpose of capacity improvement. Then various circuit configurations were derived to achieve a reduction in overall specific energy consumption, by transferring more of the grinding required to the HPGR. In most circuit configurations, the recycle of fines is required for effective breakage between the rollers. By increasing the fines amount in the feed material to a specific level within the recycling load, a uniform material bed is created and a higher pressure gradient along the roller width is obtained, resulting in compact flakes, including more fines. The fines recycle results in enhancement of the interparticle breakage. This paper will discuss the effect of the feed size distribution on HPGR performance.

Jan 1, 2012

Ni and samaria-doped ceria (Ni-SDC) cermet are desirable materials for making a solid oxide fuel cell anode working at intermediate temperature (800°C or lower) due to its good ionic/electronic conductivity at the reduced operating temperature. An advantage of the use of a Ni-SDC anode is the enlargement of the effective reaction zone in the interfacial area between the anode and the electrolyte. As a result of the mixed ionic/electronic conductivity of the anode, the electrode reaction rate is enhanced. Investigations into the properties of the ceria-based anode reveal that the performance of the anode is closely related to its microstructures, which are dependent on the composition and fabrication conditions of the ceramics. In this paper, a method for quantitative characterization and correlation of Ni-SDC cermet microstructures to the performance of an anode is investigated. A series of Ni-SDC anode samples are prepared by screen-printing (SP) and spin-coating (SC) techniques, and different microstructures of the samples are obtained through controlling the SP or SC conditions and the sintering temperature. Individual phases (Ni, SDC and pore) in the tri-phase boundary (TPB) microstructures in the electrode are differentiated and segmented from each other in optical and SEM images based on the differences in refractivity and atomic contrasts among the phases. The geometric properties of the segmented phases are characterized using image analysis methods, so that a quantitative skeleton illustrating the TPB microstructures of the Ni-SDC electrode is obtained. Statistical analysis of the distribution of the three phases in the TPB microstructures is performed and the relationship of the microstructures with the optimum electrode is interpreted in terms of the microstructure analysis data.

Jan 1, 2005

By Mohammad Mehdi Salarirad

Fouling of activated carbon by different organic species is a great concern in carbon in pulp and carbon in leach circuits. The rate of gold adsorption onto activated carbon from synthetic gold solutions which contained different amounts of potassium ethyl xanthate (PEX), potassium isobutyl xanthate (PIBX), and methyl isobutyl carbinol (MIBC) were evaluated through batch adsorption tests. The results of these experiments showed that the gold sorption rate rapidly decreases by increasing the concentration of collectors including PIBX and PEX up to 20 mg/L and at higher concentrations, the kinetic rate constant (i.e., k value) gradually leveled off to 53 h-1 for PIBX, which is 46% lower than the 99 h-1 for PEX. At low concentrations of up to 15 mg/L of MIBC, a gradual decrease of the rate constant was observed, while at higher concentrations, the decrease was found to be more pronounced. The gold loading capacity and the rate of gold adsorption onto activated carbon from a gold cyanidation pulp in the presence of flotation reagents were also evaluated. The results of these experiments showed that the flotation reagents have no significant effect on the gold loading capacity of activated carbon at prolong adsorption period, meanwhile the rate of gold adsorption continuously decreases by increasing the concentration of flotation reagents in the leaching solution.

Oct 1, 2011

By Steven R. McCutcheon

"The Bathurst-Newcastle district, a subcircular area approximately 50 km in diameter, contains 37 massive-sulfide Zn-Pb-Cu deposits that have defined tonnages, and has 58 additional significant occurrences. The largest deposit is Brunswick No. 12, with total reserves (including past production) of 148 million tonnes grading about 12.5% combined Pb-Zn. The deposits/ occurrences are spatially associated with a felsic volcanic pile that contains a significant sedimentary component. In the vicinity of the Brunswick deposits the pile is divisible into lower and upper sequences. The lower is characterized by megacrystic rhyolite (QFAS) and coarse- to fine-grained quartz (± feldspar) wackes and/or tuffites (QAS); the upper sequence is characterized by aphyric to sparsely porphyritic rhyolites (HWR), micro-breccias, and acid hyaloclastites with interbedded dark gray sedimentary rocks. A greenish gray to dark gray siltstone (GGS) separates the two sequences and hosts the sulfide deposits. Lithogeo chemistry of least altered samples shows that the QFAS and HWR have an igneous character, whereas the QAS and GGS have a sedimentary signature. The two types can be distinguished on the basis of total alkalies (Na2 + K2O) versus SiO2/Al2O3 and Ti02 versus Fe/(Fe +Mg). Some trace elements, such as Sr and Y, also help differentiate the two types. The QFAS differs from HWR by having higher La/Yb ratios but lower Zr and Th. The Bathurst deposits do not show a close spatial association with rhyolites but rather are stratiform bodies Oacking clastic textures) within fine-grained sedimentary rocks. The scarcity of barite and other sulfates indicates that there was little mixing between the metal bearing fluids and cold seawater. High Fe/(Fe+Mg) ratios in chlorites also indicate the fluids did not contain a significant seawater component. These features and the large size of many deposits suggest that the deposits formed from metal-rich pore waters that were released catastrophicallyfrom an acquifer in the footwall stratigraphy."

Jan 1, 1992

By David L. Huston, Wouter Bleeker, Bruce E. Taylor, Ron Cook, Bob Stewart, Elizabeth R. Koopman

"Abstract-Detailed oxygen isotope mapping of rhyolites in and around the Kidd Creek mine indicates that the orebodies are associated with relatively low (<12‰) whole rock values that extend up to 200 m laterally from ore. The zone of low d18O values is overlain stratigraphically by a carapace of higher (>13‰) values that extends up to 1.5 km laterally from and 300 m to 500 m above ore. Immediately above the stratigraphically highest orebody this carapace is cut by a zone of lower d18O values extending from the ore zone. Zones of higher d18O values also occur in massive rhyolite bodies that occur in the footwall of the orebodies.The zone of low d18O values partly coincides with a Na2O depletion anomaly associated with hydrothermal alteration, except that the Na2O depletion anomaly has a greater lateral extent, and the low d18O anomaly extends farther into the stratigraphic hanging wall. These data suggest that d18O mapping may detect hanging wall alteration above massive sulfide bodies more effectively than conventional lithogeochemistry. Zones of high d18O values, which define zones through which large quantities of low-temperature hydrothermal fluids have passed, may also have usefulness in exploration.Oxygen isotope variations at Kidd Creek record three stages of a hydrothermal system that evolved in temperature with time, as follows: (1) an early, low-temperature event that produced rocks with high d18O values, (2) a high-temperature event that produced rocks with lower d18O values, and (3) a later, low-temperature event that also produced rocks with high d18O values. The high d18O sig- nature of the massive rhyolite was recorded during early-stage, low-temperature (<200°C) alteration, and was probably preserved owing to decreases in permeability associated with low-temperature silicification. The low d18O signature of cherty breccia and chloritite was recorded during the thermal peak at >300°C. High d18O values in the carapace above the deposit were recorded as the hydrothermal system waned."

Jan 1, 1995

By Jorge Loredo, Jesús Garía Iglesias

"Abstract - The Asturian fluorspar district consists of vein and stratiform deposits where mineralization is controlled by a combination of lithological and tectonic factors.It is postulated that these fluorspar deposits have been formed under disequilibrium conditions created during circulation of ascending hydrothermal solutions along faults and other high permeability conduits. Mixing of solutions is inferred from fluid inclusion studies. Cavity filing and replacement processes are very important in localizing the ore deposits and in determining their morphology.Permian volcanic rocks in the area yield a regional positive geochemical anomaly in fluorine implying that Permian vulcanism may be a possible primary source of fluorine.On a regional scale a relationship can be established between some of the ore deposits and important tectonic lineaments. The stratiform deposits preferentially occur within a calcareous-detrital facies located at the margins of basins. These basin margins are related to important synsedimentaryfaults.Fluorite is the only economic mineral in these deposits. Quartz, carbonates, barite and pyrite are comnmon minerals accompanying fluorite. Other minerals that may occasionally be present as minor components are: marcasite, chalcopyrite, fahlore, sphalerite, galena and related supergene minerals."

Jan 1, 1994

By Linruo Zhao, Qi Yang, Akihiro Sato

TiN coating has a wide range of tribological applications from wear reduction of cutting tools to erosion protection of gas turbine engine compressor components. The performance of TiN coating depends on its microstructure, mechanical properties and adhesion strength which are influenced by the coating deposition process. In this study the effects of cathodic arc deposition conditions on the microstructure, hardness, adhesion and erosion resistance of TiN coating were investigated experimentally. It was found that varying deposition temperature, substrate bias and N2 pressure could derive a processing window in which TiN coating with superior erosion performance can be fabricated.

Jan 1, 2010

By George P. Demopoulos, Amani Al-Othman, Terry C. Cheng

One critical issue in chloride hydrometallurgy is the regeneration of the lixiviant HCl that is currently achieved by pyrohydrolysis. In this paper, a low temperature HCl regeneration process was investigated which regenerates HCl and produces saleable gypsum. This process promises to reduce the generation of wastes by the reaction of spent calcium chloride leach liquors with sulfuric acid solution at low temperature. Experiments were performed to determine the optimum conditions of the reaction in terms of temperature, reagent concentrations, rate of reagent addition, mixing and seeding/recycling to produce marketable gypsum and HCl with practical strength.

Jan 1, 2004