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By Pierre Bénard

To achieve penetration on the energy market, hydrogen must overcome obstacles in the areas of storage, safety and infrastructure. One of the most important is the onboard storage of hydrogen for transportation applications, where large performance gaps exist between the current state of the technology and user expectations. In order to develop and demonstrate viable hydrogen storage technologies for cars, a set of gravimetric and volumetric system targets have been proposed by the US Department of Energy, based on achieving a driving range of 500 km for a hydrogen powered vehicle. A factor of 2 to 3 improvement in both hydrogen storage capacity and energy density is needed along with several other performance goals. Another key issue is safety. Although some of the safety issues can be arguably assigned to misperceptions, hydrogen has specific properties that have to be addressed, particularly in confined geometries where the risk of hydrogen detonations becomes an issue.

May 1, 2007

By Mahmoud Shakeri1

Various types of thin-walled structures have been frequently used as energy absorbers to mitigate the adverse effects of impact and hence protect the vehicle structure under consideration when subjected to different loading conditions. Compression tubular structures that buckle in a progressive manner, can be used to advantage, providing inexpensive and versatile, but nevertheless weight and stroke efficient energy absorbers. In this paper quasi-static nonlinear finite element simulations are performed to study the effects of number of corners of the cross-section, wall thickness, plastic hardening rate of material, foam-filler and load angle on deformation mode and mean crushing force of tube. Crush strength increases as the number of corners of the cross-section increases, though it almost saturates for the number of corners beyond 11. Higher plastic hardening rate stabilizes the collapse pattern. Foam-filled tubes seem to have higher critical load angles in oblique loading and display a more stable and gradual decrease in mean load over the transition region. Substantial decrease in the initial peak load and dynamic load at any a given deflection was observed as the load angle increases. The investigation of bitubal arrangements and Multi-cell tubes reveals that these may be preferable to monotubal specimens due to the presence of the inner profiles. In addition, a comparison is conducted between the numerical and experimental results of the mean forces of some special angle elements. Good agreement is obtained.

Oct 1, 2011

By Jorge M. C. Soares

The CO oxidation reaction has been studied on Au/TiO2 catalysts prepared by incipient wetness (IW) and deposition-precipitation (DP) methods. Additionally the assessment of activity was also conducted on simple gold compounds (Au2O3 and Au(OH)3) and their physical mixtures with TiO2. We have found that there are three types of CO2 production from fresh catalysts, which are only dried, namely: Non-catalytic Type I (low temperature CO2 production); Non-catalytic Type II (higher temperature CO2 production) and Catalytic Type III. The DP catalysts are far more active for Type III reaction, showing activity already at room temperature, whereas the IW catalysts generally do not show steady state conversion until T>673 K. This is due to both large particle size and the presence of residual chlorine for the latter. No truly catalytic activity was found for low temperature CO oxidation on gold precursors on their own, although both Au2O3 and Au(OH)3 react well with CO even at room temperature in an irreversible manner (Type I reaction). Despite that, catalytic activity was obtained by mixing Au(OH)3 or Au2O3 with TiO2 which gives further emphasis on the importance of a good contact gold/support and the absence of chlorine.

Oct 1, 2003

By A. Yoshida, H. Miura, S. Yamaguchi, Y. Oyama

A discussion is given on the ionic equilibria and precipitation reactions in seawater based on thermodynamic analysis, in order to understand the solubility of nutrient salts from dephosphorization slag for marine phytoplankton. Solubility of constituent ions in aqueous solution in equilibrium with solid phases are determined using thermodynamic data. It is proposed that CO2 potential defined as log Pco2 should be considered as an additional parameter to the Eh- pH diagram for the ionic equilibrium of slag components in seawater, since magnesium and calcium carbonate precipitation reactions determine the solubility of ligand ions in nutrient salts, such as phosphates, silicate, and sulfate.

Jan 1, 2004

By J. Aguilar-Santillan, H. Balmori-Ramirez, R. C. Bradt, I. Vernet-Patiño, F. Cunha

Kyanite is an alumino-silicate mineral that has been widely used for the production of refractory products for industrial applications. Kyanite provides a high alumina content, it readily produces mullite during firing, good hot strength of products and can be adapted to produce dimensional stability of products during firing. This research addresses the application of kyanite in mixes to produce (0 dense mullite aggregates with the addition of alumina, (ii) dense composite refractory aggregates of forsterite / spinel with additions of magnesia, and (iii) dense cordierite aggregates with the addition of talc. Effects of attrition milling and conventional ceramic processing are addressed as they affect the properties of these unique aggregates.

Jan 1, 2004

By W. Beres, Li. J.

The finite element method (FEM) has been applied to investigate the stress fields and deformation of a TiN/Ti-6A1-4V coating/substrate system subjected to nanoindentation. MSC Patran and MSC Marc were used to prepare the three-dimensional finite element models and to perform the simulations of the Vickers nanoindentation experiments. Pure silicon and TiN/Ti-6A1-4V coating/substrate system were analyzed. The properties of the materials were assumed to be homogeneous and isotropic with a linear hardening behavior. The reverse method was used to extract material properties, such as the yield stress and strain hardening coefficient, from the numerical results by comparing the simulated indentation load vs. penetration depth (P-h) curves with those obtained experimentally. Both non-linear elastic and non-linear elastic-plastic analyses were carried out for the coating/substrate system. The results are given for four different coating thicknesses.

Jan 1, 2004

By George Carico

Research and related demonstration projects are being conducted in West Virginia on both existing and former coal surface mine lands to determine potential post-mine land re-use options that offer the greatest likelihood of future benefit and success. Examples of projects include renewable energy considerations that incorporate solar, wind, and/or biomass options, and contain components designed to educate business, government entities and the local community on renewable energy options and potential opportunities Multiple property re-use options are being researched and evaluated, based on site-specific conditions and characteristics, including infrastructure, local community needs and regional economic conditions. Re-use options being explored include innovative uses and needs, such as specialty housing, unique business and industrial needs, and an extensive variety of recreational and small business opportunities that best fit the specific needs of the local community and regional economic structure.

Aug 1, 2013

By P. Henry

Hydrometal provides an adequate technology to reintroduce lost metal units into the industrial cycle, thereby saving resources and energy, while keeping the environment cleaner. Two case studies of our integrated hydrometallurgical recycling facility (Hydrométal) in Belgium are discussed.(I) Recycling of Cu-Co cement generated at the second purification step of zinc sulfate solution. (II) Recycling of lead complex materials from the lead industry.

Jan 1, 2008

By J. Erik Scheel

Overview ? About Hard Creek Nickel ? Turnagain property ? Proposed power line ? Recent Preliminary Assessment ? Favourable economics ? Property Geology ? Mineralization and metallurgical characteristics of major lithologies ? Development of the acNi (ammonimum-citrate H2O2) technique ? Overview of necessary steps ? Results of the technique ? Conclusions

May 1, 2008

By M. A. EI Zeky, A. E. El-Nikbaily, M. A. Shahin

"Possible mechanisms of microsilica dust formation and factors affecting its quantity have been discussed. General mathematical models to predict the dust quantity based on electrical and coke consumptions, and flue gas temperature as functions of silicon recovery in the process and silicon content of the alloy have been established. It has also been shown that the flue gas temperature can be used as an additional process control parameter. Comments are made on the effect of the dust formation on the whole process economics and it is pointed out that the formed microsilica dust is a valuable by-product and not an industrial waste. INTRODUCTIONFerrosilicon is produced in electric arc furnaces with submerged electrodes. The charge mixture consist s mainly of quartzite, coke as the reducing agent and iron chips. The products are ferro silicon and carbon monoxide, various other volatile materials, water vapour and silicon monoxide gas. Carbon monoxide and silicon monoxide oxidize at the charge surface when mixed with air entering through the furnace hood openings. The off-gas contains a considerable amount of dust, which is mainly very fine particles of silica formed as a result of oxidation. The emission of dust containing gases to the atmosphere causes serious pollution problems to the environment. Therefore, the control of the formation of the dust, preventing it from escaping to the atmosphere, and dealing with this very fine dust collected from the flue gases represent important technological and economical parameters in the ferrosilicon production industry.This paper is concerned with the relations between the quantity of formed micro silica dust, as a function of both silicon recovery and silicon content in the alloy, and various other technological parameters; and their possible effects on the energy consumption and economics of the whole process."

Jan 1, 1989

By M. D. Viera

The purpose of the study is to show, through real cases of companies in Chile, the different problems concerning valuing or economically appraising a mining ore resource with the traditional techniques. The study demonstrates that, with the risk analysis and real options theory application, one could determine the most probable value for a mining resource or mining business, and the risks cover of uncertainty scenarios. The study discusses different methods and criteria employed in the ore resource evaluation or mining assets. It also shows a comparative analysis of the different methods in order to explain various distortions, errors, risks and imprecisions of each of them. the companies are becoming aware of the risks' importance and the impact they have on the commercial value and resource estimation models. Now, the real options are the techniques that somehow make it possible to value and control the risk cover of the business. The company valuation could help respond questions like: ? How much is my business worth? ? How much has the investment profitability of my business been? What could be done to improve this profitability and create value?

Jan 1, 2007

By H. T. Michels

Recent laboratory studies show that several bacteria, known to be human pathogens, die when they come in contact with copper and copper alloy surfaces. The amount of live bacteria drops by several orders of magnitude, to zero, on copper alloys in a few hours. In contrast, no reduction is seen in the concentration of live organisms on stainless steel during the six-hour test period. Aluminum painted and coated surfaces and plastics would show behavior similar to stainless steel and show no effect. Coatings and other surfaces claiming to be antimicrobial showed little to no effect. These results suggest the selection of copper alloys for surfaces exposed to human touch can materially assist in reducing the transmission of infectious organisms. In order to make antimicrobial claims in the United States, the approval of the US Environmental Protection Agency (EPA) is required. The EPA-required efficacy testing is described and the test results are summarized. It is anticipated, that once regulatory approval is obtained, that this will facilitate the introduction of antimicrobial copper alloys in hospitals, nursing homes and other healthcare facilities, as well as schools, and public buildings. Some of the application and barriers, to entry into the healthcare markets are mentioned.

Jan 1, 2007

By Par G. Jönsson, Joachim von Scheele, D. S. Sarma, Mukul Goyal

Dust from flue gas cleaning systems at iron and steel production is frequently considered as a waste problem, but it is actually a potential raw material source. By using a technology like the oxyfuel based OXYFINES technique, it can be melted into a suitable form. The product from this processing, however, needs to meet the requirements of a recyclable raw material, here particularly a top-charged blast furnace feed. The present work has been focused on characterization of the product produced from these dusts by OXYFINES technology. The investigation has been carried out on samples of processed dusts from a European integrated steel mill. It was done by means of chemical analysis, density measurement, light optical microscopy, X-ray diffraction, scanning electron microscopy combined with energy dispersive spectroscopy, and micro indention hardness measurement. Special attention was paid to the presence of zinc, an element that might be harmful while recycling the material (e.g., in a blast furnace). The results show that the product contains four different regions with different morphologies and properties in the material, which are discussed in detail. The overall conclusion is that by processing the dusts in this way, a raw material suitable for recycling in a blast furnace can be obtained.

Jan 1, 2004

By G. R. Guillet

Important resources of kaolin, refractory clay and lignite, not found elsewhere in Ontario, occur with quartz sand of glassgrade quality in unconsolidated Mesozoic sediments of the Moose River Basin in northeastern Ontario. These materials comprise the Mattagami Formation of Lower Cretaceous age, which overlie in some places a thin Jurassic unit and a thick Paleozoic section, and underlie as much as JOO m or more of glacial and marine sediments and a uniform capping of muskeg. The Mallagami Formation is known from deep boreholes to exceed 100 m in thickness and to consist of two phases: an earlier Type A unit of dark-coloured carbonaceous clays and lignite, and a later light-coloured (Type B) unit of kaolin-bearing quartz sands and bright-coloured refractory clays. Remoteness, poor access, and difficult physical environment have inhibited the exploration and development of these resources.

Jan 1, 1984

By F. Duan, J. Pfarr, J. M. Goris

"The U.S. Bureau of Mines, in cooperation with the Homestake Mining Co. and the University of Utah, is conducting a field demonstration to evaluate the behaviour of rock masses supported with cable bolts. One of two rock masses being studied is supported with both conventional and birdcage cables. This rock mass is located between the 6500 and 6650 levels of the 45-48N stope, 21 ledge. The second rock mass is the hanging wall of the D-limb stope between the 3500 and 3650 levels near the Ross Shaft and is supported with conventional cables. The primary objectives of the project are to monitor the behaviour of the two rock masses during mining using extensometers and cable support strain gauges, after which the rock will be modelled using the finite-element code UTAH III. Field data will be used to verify the modelling. In addition, a comparison between the effectiveness of conventional and birdcage cables will be made.45-48N StopeThe 45-48N stope is located in the 21 ledge between the 6500 and 6650 levels and contains about 233 000 short tons of mineable ore. The orebody lies within the Homestake Formation and is very irregular being approximately 200 ft long and 75 ft wide. Between the 6500 and 6650 levels, it dips from 35 degrees to 60 degrees east with a near-vertical plunge to the south. Mineralization is characterized by arsenopyrite and pyrrhotite with minor gold. The contact between the Homestake and the overlying Ellison Formation creates a plane of weakness along localized graphitic layers. The footwall dips at approximately 60 degrees but between 100 ft and 120 ft above the 6650 level , the hanging wall flattens to almost 20 degrees causing a significant mining problem."

Jan 1, 1991

By K. Fukuda

The volatilization behavior of heavy metal in electric ash melting furnaces has a strong relation with its distribution between molten salt and slag. In this study, the distribution ratios of heavy metals between molten salt and slag phases were measured using a hermetic cell. The experimental results showed a relatively rapid loss of Pb and Zn from the salt in the first few hours followed by slow heavy metal vaporization with an almost fixed metal distribution between molten salt and slag. The distribution ratios of Pb and Zn decreased with increasing slag basicity. The mechanism of this effect can be explained by the chlorinated reaction of PbO and ZnO by CaC12.

Jan 1, 2004

By Brian Hall

For some years, the mining industry has been consistently delivering returns below the market average. One of the causes is a disconnect between what is perceived to drive value creation by many industry analysts and senior corporate executives, and what actually drives the intrinsic value of mining operations. The perverse effect is that strategies that should increase value are perceived to have the potential to drive share prices down, and vice versa. This paper challenges common perceptions of what drives a mining company?s value. Anecdotal evidence suggests that the key drivers of value in the market, and hence in many boardrooms, are such things as increasing the reserves and production rate, and reducing unit operating cost. However, while the quoted reserves may satisfy ore reserves reporting code requirements to be economic, this does not imply that they are optimal. Often, a proportion of the quoted reserve reduces the potential value of the operation. Metal price increases, increased production rates, and operating cost reductions are all seen as conditions or actions that can improve value, and lead to cutoff grade reductions, thereby increasing ore reserves. However, modern cutoff theory and studies conducted by the author and his colleagues show clearly that, while breakeven cutoff grades will fall in these circumstances, optimum cutoffs may be much less volatile, and may even increase. Results from case studies indicate that value is maximised by right-sizing, not maximising, the production capacities, and by optimising the cutoff strategy. Values of many existing underground mining operations can be increased significantly by a substantial cutoff grade increase. Also, an increase in downside risk, and hence reduced returns, can occur using typical life-of-mine planning strategies if prices received are lower than predicted. Since this is often the case, low industry returns may be a direct result of typical strategic mine planning processes. Relatively simple cost-effective techniques are available to provide senior decision makers with information needed to assess the tradeoffs between their many conflicting corporate goals, and the balance between risk and reward. Often this information is not being generated at all. If it is, decisions affecting the value of the company are occurring by default at relatively low levels within the hierarchy, with senior executives apparently unaware of them or their potential impact. The paper concludes that without a re-evaluation of the way mining projects are valued, to demand proven value optimisation from mining plans by boards and mining analysts, the industry will continue to deliver below average returns.

May 1, 2003

By Gilles Carrière

"The Huntingdon mine of Quebec Copper Corporation is situated 3 miles south of the village of Eastman, in the Eastern Townships of Quebec. The copper deposit consists of several pyrrhotite-chalcopyrite replacement bodies or bands.The first mining operations on the conspicuous surface gossan of the Huntingdon deposit started in 1865. They were suspended in 1883. The .mine was again active from 1890 to 1893 and from 1912 to 1924. These operations were carried to a depth of 500 feet, and it is estimated that some 150,000 tons of ore were extracted, of a grade reported as varying between 3 Yi and 7 per cent copper.In 1950 a program of exploration was initiated in the area of the old mine, and resulted in the finding of 500,000 tons of ore with a grade of 2 per cent copper. A new shaft was sunk to a depth of 1,160 feet, and by February 1954 the mine was extracting 800 tons of ore daily.General Geology and StructureThe mineralized zones are on the west side of a band of altered volcanic rock, locally called andesite, adjacent to a sill-like body of serpentinized peridotite which lies west of the andesite. The bands of andesite and serpentine extend several miles north and south of the mine. Their strike is generally north 15 degrees east, and they dip steeply east. Their widths vary very considerably along the strike, but in the mine area each is about 450 feet wide on surface. They are enclosed in sediments of the Caldwell series, consisting of greywackes, quartzites, slates, and shales. The andesite belongs to the same series, which is thought to be of Cambrian age (1). The ultrabasic intrusive is post-Ordovician.At p\aces along the serpentine contact the andesite shows a pronounced schistosity; it is parallel to the contact and rarely extends farther than a hundred feet from it. No evidence of strong folding or faulting has been found so far in the mine workings. Some apparent distortions and irregularities in the strike of the contact may all be due to the intrusive nature of the serpentine. In the mine area, transgressive tongues of serpentine point southward in the andesite.A few vertical lamprophyre dykes, not more than five feet thick, cut the other formations at right angles."

Jan 1, 1949

By Jean A. Bastien

Cette présentation décrit les étapes de développement et l?exploitation souterraine au puits Penna chez Agnico-Eagle division Laronde. Les sujets suivants sont touchés : le fonçage du puits, le développement des niveaux, la méthode d?exploitation, la manutention de la roche brisée, le méthode de remblayage et la ventilation. En résumé : le fonçage du puits s?est fait sur 2,240 mètres de novembre 1995 à mars 2000. Le développement des niveaux a débuté en octobre 1998. Les opérations de minage ont débutés en août 99 dans le premier horizon situé au dessus du niveau 122. Les chantiers sont exploités par longs-trous d?environ 25 mètres de long avec un diamètre de 10 cm. Les accès à la zone minéralisée sont transverses. Le minerai est soutiré des chantiers et acheminé au passe-minerai a l?aide de chargeuses navettes. Par la suite, le minerai passe sur un marteau, est concassé et transporté sur un convoyeur, jusqu?au silo de 4,500 tonnes au-dessus de la station de chargement automatisée du niveau 152 d?ou les skips sont alimentés. Le remblai en pâte est envoyé de la surface par des trous ayant un revêtement d?acier. Le diamètre intérieur est de 15 cm. Le réseau de ventilation est principalement alimentée par des ventilateurs de surface (système aspirant et souflant) conçus pour acheminer sous-terre un maximum de 640 mètres cubes par minutes (1,350,000 pcm).

May 1, 2001

By Gilles Carrière

"The Suffield mine is situated five miles southwest of the city of Sherbrooke, in the Eastern Townships of Quebec. lt is the property of Suffield Metals Corporation Limited, a wholly owned subsidiary of Ascot Metals Corporation Limited.The old Suffield or Griffith mine had been worked intermittently from 1863 to 1906, without ever producing much ore. In 1951, diamond drilling done by Ascot Metals proved over one million tons of ore in three new bodies. The average grade of this ore was 0·018 ounces of gold per ton, 2-40 ounces of silver, l ·28 per cent copper, 0·59 per cent lead, and 6-45 per cent zinc. Since then the mine has been active, producing between 300 and 700 tons daily. More recent exploration has found continuations of the ore zones.General GeologyThe ore of the Suffield mine is found in porphyritic rhyolites of the Sherbrooke group (Silurian), at or close to its contact with sediments of the Beauceville group (Ordovician). The contact shows pronounced folds as well as irregularities due to erosion of the sediments prior to the outpour-ing of the lavas. On surface the general strike is north, and the dip is steeply east.The footwall sediments consist of interbedded black graphitic slates and. dark-coloured chloritic quartzite, overlain in many places by a thin bed of magnetite-hearing quartzite.The rhyolite host rock is a light grey rock, containing very abundant quartz and feldspar phenocrysts in a microcrystalline matrix of the same minerals. Some sericite is always present, especially in the vicinity of the ore zones, where the rock shows a pronounced schistosity.Several narrow basic dykes, with an easterly strike and vertical dip, cut all other formations. Most are lamprophyres, of either the monchiquite or camptonite type, but one has been identified as a diabase."

Jan 1, 1949