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By R. Lodha, C. Oprea, G. Oprea, H. Zargar, T. Troczynski

"The basic refractories used in non-ferrous industry contain chrome ore for improving the thermal shock resistance, thus reducing the penetration of molten metal and fayalite-type slags into the lining. The current study aims to replace chrome ore with Me4+ ions along with Fe3+ ions in order to form MgO-Al2O3- FeOx-Me4+O2 based complex spinel systems that could perform similar to the complex chromia-bearing spinel in the magnesia-chrome refractories. This system allows for lower temperatures of synthesis and sintering. In our study, compositions with 60% MgO were fired below 1500°C and resulted in complete formation of complex spinel, and open porosity less than 5%. The in-situ formation of the complex spinel from the fine mix of oxides in the MgO-Al2O3-FeOx-Me4+O2 system offers a suitable alternative of binding system to produce basic refractories at lower temperatures and of similar physical and mechanical properties with magnesia-chrome bricks fired above 1750ºC. INTRODUCTIONThe synthesis of magnesium aluminate spinel (MgAl2O4) (Maschio, Fabbri, & Fiori, 1988) or magnesium chromate spinel (MgCr2O4) from their respective oxides is diffusion controlled resulting in a sluggish reaction even at high temperatures. For instance, the diffusion of Mg2+ and Al3+ ions in the intermediate spinel layer during reaction is slower than the diffusion of Mg2+ in corundum and Al3+ in periclase. The interfacial layer of spinel formed during the reaction increases the diffusion path for the spinel forming cations. This accompanied by ~8% volume expansion retards further reaction resulting in incomplete spinel forming reaction during sintering and hence densification during the reaction cannot be achieved. In order to assess sintering studies with fine particulate oxides that would result in a lower diffusion path, a mechanical mixture of the hydroxides of aluminium and magnesium calcined at 1400ºC to 1600ºC for 1 hour does not result in complete spinel formation (Sarkar, Das, & Banerjee, 2003), which indicates that reaction sintering of stoichiometric magnesium aluminate spinel is retarded by initial reaction forming the interfacial spinel layer. The basic bricks used as linings in non-ferrous pyro-metallurgical convertors are manufactured using magnesia and chrome ore, the sintering of which produce spinel solid solution. This solid solution is a mix of both normal and inverse spinel structures that sinters at temperatures in excess of 1800ºC in air."

Jan 1, 2012

By S. Akhlaghi

In many electronic/optoelectronic devices, interaction between the metal stack and solder is undesirable. If a reaction happens, a nonuniform joint containing spikes and voids is likely to form and as a result the heat dissipation deteriorates significantly, which in turn, leads to the degradation of the bond. In the present work the interaction between Ti/Mo/ Au metallization system, which was sputter deposited on AlN substrates, and Pb-Sn solder was studied by using scanning electron microscopy (SEM). Also, an EDX system was used to trace the changes in chemical composition of the layers after solder tests. The microstructural examinations show that the Ti and Mo layer from the Ti/Mo/ Au metallization system are not impermeable enough and thus Ca from the surface of the substrate moves all the way up to the interface of Au/Mo and forms an intermetallic at the interface, which grows over time.

Jan 1, 2006

By M. Santaluce

"The revamp of critical process assets that require a significant plant outage (shutdown) presents a unique and demanding set of challenges for plant operators. They are executed in a more complex Brownfield environment, typically with limited working space and often involve unknown conditions or scope. For plant operators, such a project is often a high cost event both in terms of opportunity cost of lost production and the resource cost of labor and materials. It can also be a high risk event in terms safety, environment, and future plant reliability/availability. This impacts current and future performance or Overall Equipment Effectiveness (OEE). In our experience, the sequential nature of the EPCM approach does not provide the proper framework to facilitate the level of coordination, stakeholder cooperation and detailed planning required to adequately address the construction and shutdown complexity of a critical asset revamp projects. This paper proposes a more integrated approach to handling shutdown revamps of critical assets. Its main thesis is to involve the key performing stakeholder groups early in the project lifecycle (engineering team, procurement team, construction team and plant operations) to form an integrated shutdown management team that is focused on ensuring delivered results are aligned with project objectives. In this model, the construction team executing the shutdown/construction is preparing the detailed shutdown/construction planning concurrently with detailed engineering and procurement planning. This allows construction/shutdown requirements to influence engineering and procurement, with the desire to optimize safety, speed, quality and cost. The paper also discusses how to overcome the procurement hurdle in applying such an approach. The outcome of this integrated approach is better planning, coordination, communication and alignment between the project stakeholders, a shutdown/construction driven planning approach that more fully addresses the challenges of these projects and delivered results that are aligned with project objectives."

Jan 1, 2015

By R. O. Loutfy, J. C. Withers

"Titanium powder is produced from a small fraction of sieved sponge, HDH of sponge or gas blown from a melt produced billet. Ore from foreign sources is chlorinated in a very high temperature fluid bed to make TiCl4, then vacuum distilled purified and then reduced to sponge by Kroll processing. Domestic ores of ilmenite or perovskite can be carbothermically reduced to Ti2OC which can be chlorinated at low temperatures of 250–400°C to produce TiCl4 which can be electrolyzed in a fused salt to Ti powder, or the Ti2OC used as an anode in electrolysis to produce Ti powder. The electrolysis process can be operated continuously to produce Ti powder at a lower cost than Kroll processed sponge including produce control size powder. Electrolysis processing was scaled up and operated at the commercial demonstration stage on a continued basis that verifies the potential of a low cost process to produce Ti powder.INTRODUCTIONTitanium and alloys of titanium powder have been elevated to strategic status resulting from a focus of producing meltless titanium components as well as a feed for additive manufacturing processing. However, the high cost of titanium powder has limited wide scale implementation of using titanium powder as a feed to any process to produce titanium components. Titanium powder free of alloying is available as sponge fines from the Kroll process as illustrated in Figure 1. Titanium alloy powder is much more expensive, also illustrated in Figure 1 produced from an alloy ingot or mil product as the feed and then transformed into powder by one of several melt form processes which accounts for the high cost of titanium alloy powder at approximately $60–150/lb. Ton lots of titanium alloy powder (i.e. Ti-6Al-4V) from one source is quoted at $120/lb. in the U.S. It appears that alloy powder production cost by current processing is not sensitive to volume."

Jan 1, 2016

By J. O. G. Posada

Magnesium derived foams were prepared by using the so-called baking of powder blended precursor material method. This method comprises mixing magnesium powder with a small fraction of blowing agent (ZrH2, Cs2CO3 and CaH2) and Ni like catalyst, compacting this mix and creating a foam by heat treatment above the magnesium melting temperature. The resulting samples were characterised by microscopy, gas adsorption (BET method) and by small angle neutron scattering. Several mathematical models were used in order to determine particle size distribution, fractal dimension and total pore volume fractions.

Jan 1, 2005

By K. E. Waters, C. Marion, T. Grammatikopoulos, A. Jordens

"The Nechalacho deposit, located in the Northwest Territories, Canada, is a heavy rare earth element (REE) deposit. The main REE-bearing minerals in the deposit are zircon, allanite, bastnäsite, synchysite, columbite (Fe) and fergusonite. Previous work investigated the use of gravity and magnetic separation in the processing of this ore and showed that coarse particles following grinding were enriched in zircon, suggesting the potential for selective comminution. The current work investigates the possibility to selectively comminute gangue minerals and concentrate REE-bearing zircon into coarser size fractions. The ore was ground wet in a laboratory rod mill for various lengths of time (0, 10, 20, 30, and 40 min). The resultant products were analyzed using ICP-MS, to determine the distribution of zirconium and REEs in the different size fractions produced after grinding, and QEMSCAN, to identify mineral phases, mineral liberation and the distribution of minerals. Optimum grind sizes for the upgrading of zircon due to selective comminution were then proposed, and dense medium separation was investigated as a means to further concentrate zircon.It is important to note that this process is not representative of the currently selected process design or recovery for the Nechalacho deposit. Any application of this process to this deposit would require optimization in order to ensure appropriate grade and recovery targets are met.INTRODUCTIONThe rare earth elements (REEs) are the fifteen elements in the lanthanide series of the Periodic Table, as well as yttrium (scandium is excluded in this work). Traditionally, REEs are categorized into two groups: the cerium sub-group of “light” rare earth elements (LREEs); and the yttrium sub-group of “heavy” rare earth elements (HREEs) (Golev et al., 2014). The LREEs comprise the first six lanthanides (lanthanum through samarium) and the HREEs comprise the remaining nine lanthanide elements (europium through lutetium) coupled with yttrium (Golev et al., 2014). HREEs are much less abundant in the earth’s crust and on average are more expensive than LREEs (Seredin, 2010). Of the fifteen REEs, the production of neodymium, europium, terbium, dysprosium and yttrium has been determined to be most critical due to their scarcity, high demand and criticality in many high-technology and clean energy applications, such as in illuminated screens for electronic devices and permanent magnets in wind turbines (Seredin, 2010; U.S. Department of Energy, 2011). These five elements are classified as critical rare earth elements (CREEs) (U.S. Department of Energy, 2011)."

Jan 1, 2016

By G. M. Ritcey, S. H. Lucas

"On the north shore of the St. Lawrence River, in Quebec, are located orebodies of low-grade titaniferous magnetite. The Quebec Mining Exploration Company (SOQUEM), who have an interest in the deposits, believed that beneficiation of the could generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility. A joint research project of SOQUEM and CANMET investigated alkaline roasting of a magnetic concentrate, followed by leaching of the calcine and separation and recovery of Cr and V by solvent extraction. Aluminum was recovered by precipitation.The present paper describes the roast-leach bench-scale and pilot-plant work leading to the development of the optimum conditions f or the integrated process.A plant flowsheet was developed for the treatment of 5 x 106 tons of magnetic concentrate per annum. Estimates of capital and operating costs were made.Based on a recovery of approximately 90% V, 85% Cr and 75% AI, the total hydrometallurgical plant fixed capital costs, including mining, concentration and shipping, are estimated at $1.021 x 109; the operating costs are estimated at $131.92/ton concentrate. Annual revenue from the Na2CrO4.H2O, V2O5 and A12O3 produced is calculated to be $421 x 106.IntroductionThe Quebec Mining Exploration Company (SOQUEM) acquired in 1968 an interest in four titaniferous magnetite orebodies located in Eastern Quebec. 85 miles north of Mingan on the north shore of the St. Lawrence River. The Mingan deposit, with an estimated tonnage of one billion tons, has a reported average grade of 43% Fe, 6.3% Ti , 1.60% Cr, 0.19% V and 6.1% Al with minor amounts of nickel. SOQUEM, on the basis of previous bench-scale data, believed that the recovery of chromium, vanadium and alumina by alkaline roasting would generate sufficient revenue to defray the mining costs and the costs of transporting the ore to a steel production facility on the coast. One of the approaches selected by SOQUEM for beneficiation of the ore consisted of a combination of magnetic concentration followed by alkaline roasting of the calcine."

Jan 1, 1980

"RésuméDans la première partie de cet article on discute Ie mode d'écail age aetueJJement en usage dans des mines souterraines. Par la suite, on presente la problematique d'écaillage à l’aide de barres conventionnelles et on discute les plus recénts développements des outils d'ecaillage portatifs et mécanisés ainsi que les techniques de détection des roches branlantes. Plus tard, on analyse la tâche d'écaillage avec des barres conventionnelles. Dans les chapitres qui suivent on présente un concept d'un outil d'écaillage portatif et mécanisé développe à l'Université Laval, ainsi que les résultats des essais de cet outil, effectués dans quelques mines au Québec. On constate que Ie nouvel outil d'écaillage démontre un potentieJ intéressant tant au niveau de l'effort requis pour effectuer la tâche d'écaillage que de la sécurité des mineurs.On conclut que l’application de cet outil fera un pas important sur Ia voie d'amélioration des conditions de travail dans les exploitations souterraines, tout en assuarnt une qualité accrue de l'écaillage.AbstractThe first part of this paper discusses the type of scaling operations presently in use in underground mines and derma; a scaling factor which is expressed as the:: area necessary to scale to extract one ton of ore. Subsequently, the problems associated with conventional scaling methods are discussed as well as recent developments in mechanized hand-held scaling devices and methods of loose detection. The elements of the scaling process are further analyzed. In subsequent sections of this paper, the conception and design of a mechanized scaling device, developed at Universite Laval is described. The results of field tests conducted in Quebec hard rock mines are presented. The experimental findings show that the mechanized hand-held scaling device shows great potential in improving the productivity and safety of underground mining operations."

Jan 1, 1995

By W. Wallace

The aerospace industry celebrated 100 years of powered flight in 2003, and the remarkable achievements that have occurred during the past 100 years are in no small way due to major developments in materials. Modern alloys for airframes, engines and other major sub-systems have evolved through the intelligent application of new processing concepts involving melting, casting, hot and cold working, heat treatment and more recently vapour phase processing. Alloy design has evolved in parallel to allow maximum benefits to be achieved from these processing advances. However, the pace of development seems to be slowing and future gains are likely to be made by learning how to extract major value from aerospace assets. Understanding the modes of deterioration and establishing cost effective lifetimes by holistic life cycle management seem to be the way of the future. Extending component lifetimes by repair, rejuvenation and refurbishment are all viable possibilities and they offer great opportunities for Canada, which, traditionally, has been a major user of modern aerospace materials rather than a supplier. The challenges for metallurgist, physicists and engineers will be no less than in the past and should create new business opportunities for Canada. The scenario described above will be developed by calling upon examples drawn from the author's experience.

Jan 1, 2004

By F. Richards

"The property of the Cariboo Gold Quartz Mining Company; Limited; is in the Wells-Barkerville district of Cariboo mining division. It consists of a group of 106 Crown granted mineral claims and fractions; and extends for over 6 miles along what is termed the Barkerville gold belt. The main portal and mine camp are half a mile south of Wells; which lies at the northeast end of Jack of Clubs lake and is reached by a 55-mile motor road from Quesnel; the northern terminus of the Pacific Great Eastern railway.Gold-bearing quartz veins were discovered on the surface in various parts of the property by different prospectors as far back as 1877, but the work that led to the formation of the present company was performed by Al Sanders in the year 1926. Sanders dug trenches and drove small adits on quartz veins containing gold above what is now known as the Sanders zone. Very little underground work has been done beneath the earliest known discovery-the B.C. vein. The Cariboo Gold Quartz Mining Company was formed in the autumn of 1926. The total production of gold from its beginning in 1933 to the end of 1944 has been as follows:"

Jan 1, 1954

By J. P. Grieco, F. W. Grieco

"Manufacturing of Jaw CrushersOriginIn 1858 Eli Whitney Blake invented the first successful mechanical rock breaker-the Blake-type jaw crusher. Blake adapted a mechanical principal, the powerful toggle linkage system used to transform rotating motion and energy into oscillating mot ion and tremendous compressive forces. Today these same principals apply and the basic Blake-type jaw crusher is one of the leading machines of its class for heavy duty primary crushing service.In 1881 Philetus W. Gates patented a design for a crusher, the forerunner of the modern gyratory crusher which dominated the field from the late 1800s to the early 1900s. In 1910 the largest gyratory crushers built had 48-inch openings. However, about this time the jaw crusher came to life when the Power and Mining Machinery Co. built an even larger sized opening crusher-a giant 84-inch by 60-inch jaw crusher for a trap rock quarry in Pennsylvania. A 24-inch gyratory crusher became the ideal sized secondary machine for this size jaw. From that time on jaw crushers were looked on favourably as primary breakers and lines were brought up to date to parallel the already developed gyratory lines.FunctionMost heavy duty Blake-type jaw crushers work basically the same way. They are ruggedly designed and capable of crushing material in some cases in excess of 80, 000 p.s.i. compressive strength. They are very simple machines with few moving part s and, with the exception of replacement of renewable parts, are relatively maintenance free. It is quite common to have these machines in product ion for 20 to 30 years. The following will de scribe how these machines work. Large-diameter high-inertia flywheels which are connected to the main eccentric shaft, rotate inside a connecting rod type mechanism called a Pitman. It transforms rotating motion into vertical oscillating motion. This vertical motion is in turn transformed into reciprocating mot ion by means of a system of 2 toggles, each connected to the Pitman. The rear toggle is connected to the fixed rear head, and the front toggle is connected to the swing jaw which is hinged at the top of the crusher. With each rotation of the eccentric shaft the swing jaw opens and closes on rock which is fed into the crusher chamber, crushing the rock in a series of bites. These bites, or strokes as the y are called, usually vary between 1/2 inch to 1 1/2 inch at speeds of 120 to 200 strokes per minute. The reduction ratio of feed input to discharge is usually about 8 to I. Output capacities can vary from 100 tons/hour to 1200 tons/hour depending on the size of machine and its discharge opening. Horsepower requirements can vary from 75 hp to 400 hp.The entire crusher chamber is lined with replaceable 14070 manganese steel liner plates. This material is ideally suited for the job since it hardens as it wears during crusher operation. Manganese is also used in the high wear areas at each end of the toggle plates."

Jan 1, 1985

By W. E. Newton

THE following notes are offered primarily to show that industrial minerals or their products have a much more important place in the metallurgical industry than is perhaps generally realized, and with the hope also that some statement by the metallurgical consumer of the relative merits of various materials for particular requirements or services will l;>e of value to the industrial mineral producer. These notes are not in any way presented as complete. Also, some of the statements made may be debatable. The grouping adopted is as follows: (1) Refractories; (2) Fluxes; (3) Construction materials; and ( 4) Miscellaneous applications. Fuels are not dealt with in the present paper. REFRACTORIES GENERAL: Refractories are materials which will withstand high temperatures with-out melting or becoming markedly soft or pasty. While their primary function is to withstand heat, they are usually called upon to resist one or more of the following destructive influences: abrasion, pressure, corrosion by slags or fluxes, and rapid changes in temperature. Refractory materials may be conveniently divided into three classes: (1) Acid refractories-consisting of silica, or containing silica as their chief constituent. They combine more or less readily with metallic oxides, forming silicates, and are hence termed 'acid'. The most important of these are quartz, quartzite, siliceous sand, tripoli, Dinas rock, and ganister. Most fire-clays, although generally considered neutral sub-stances, contain relatively small amounts of free silica and are, to that extent, acid. (2) Neutral refractories-the term is merely relative in most cases, since, at high temperature, many of the refractories that are classed as neutral will react chemically with a strong base, functioning as a weak acid; or, conversely, with a strong acid, functioning as a weak base. Chrome and graphite are the most nearly neutral of all the commonly used refractory materials.

Jan 1, 1936

"Beneficiation of low grade ores is the process of increasing the grade of a mineral through unit operations that remove and separate the waste (or gangue) material from the valuable mineral that can then be used for further processing or direct use. Important factors when deciding upon a beneficiation program are the feed grade, mass yield and the metal recovery. As lower grade ores are being processed beneficiation is a critical process. How predictive is laboratory test work for “as built” operating projects? Beneficiation includes all or some of the available unit operations to produce a beneficiation flow sheet i.e. associated unit operations including but not limited to optical sorting, radiometric sorting, crushing and screening, coarse cobbing, jigging, dense media separation (DMS), spirals, magnetic separation, flotation, thickening, filtering and drying. Reference to specific projects and the approach developed in formulating a beneficiation flow sheet and a comparison of difficult and simple beneficiation flow sheets are cited. INTRODUCTIONReserves of high-grade iron ores are reducing all over the world, at an alarming rate, over the years as a result of the rapid increase in demand for steel particularly from Japan and then China. The recovery of mineral value from the low-grade ores using present technology is more expensive than DSO ores due to high energy and capital costs. Beneficiation is defined as a variety of processes whereby extracted ore from mining is reduced to particles that can be separated into mineral and waste.Various physical properties of an ore can be exploited to separate a low grade fraction including variation in hardness, density, reflectance, conductivity and magnetism.""Beneficiation"" of iron ores includes concentration, generally by physical removal of unwanted gangue. Also considered beneficiation is the regulation of product size, or other steps such as agglomeration to improve its chemical or physical characteristics prior to smelting."

Jan 1, 2012

By Michael R. McPhie

Topics of Discussion 1. The Global Mining Initiative (GMI) and MMSD North America (Brief) 2. Task 2 of MMSD North America ? A Test for Sustainability 3. The Seven Questions and their Application 4. Key Recommendations and Next Steps GMI = Global Mining Initiative Significant international collaborative effort supported by more than 30 of the world?s largest mining/minerals firms which sought to involve all communities of interest. Three major streams of activities: 1. Mining, Minerals and Sustainable Development Project (MMSD) ? 4 regional Process (North America, Southern Africa, South America, Australia) 2. Creation of ICMM (formerly ICME) 3. Major conference in Toronto in May, 2002

May 1, 2002

By R. W. Pauls

"Many tens of thousands of hectares of forested land will be disturbed and reclaimed in the surface mineable Athabasca oil sands area during the next few decades. The surface area disturbed by Syncrude’s Mildred Lake development alone exceeds 10 000 ha to date. It is not clear that reforestation of disturbed areas will best accommodate the aspirations of all stakeholders, particularly traditional users of the land. A five-year research program by Syncrude Canada Limited and the Fort McKay First Nations has examined the feasibility of raising bison on land reclaimed after disturbance by oil sands development. Forage productivity and carrying capacity for bison was comparable to that of grasslands elsewhere in Alberta. Concerns regarding compaction of newly rebuilt soil by bison traffic proved unfounded. Bison demonstrated weight gains typical for ranched bison and calving rates averaged 90%, a value typical for ranched bison. The animal husbandry problems encountered were typical of those occurring on bison ranches elsewhere in Alberta. An economic analysis indicates that a 1000 ha bison ranch on reclaimed land has a net present value that compares very favourably with a similar area supporting commercial forest. Subject to approval by Alberta Environmental Protection, the current research project will be expanded as a pilot commercial ranching venture in order to explore its commercial viability as a business venture by the Fort McKay First Nations. At the same time, measures will be implemented to resolve various regulatory issues associated with commercial bison production in the oil sands area.BackgroundSyncrude Canada Ltd. (Syncrude) is proposing, in its land reclamation strategy, a feature that is, depending on one’s background and perspective, regarded as an innovative approach to land reclamation, a threat to the regional forest industry, a creative response to aboriginal stakeholder concerns, a reneging on reclamation commitments, an opportunity to provide an ongoing economic base for postoil sands regional economy, or an environmentally unsound use of the land. These diverse and sometimes strong reactions have been generated by the proposal to introduce bison, either free-ranging or commercial ranched, to the reclaimed landscape."

Jan 1, 1999

By Randy Settgast, Daniel Moos, Hyunil Jo, Ghazal Izadi, Christine Baba

"Analyses of production logs of multiply fractured horizontal wells in unconventional plays show that only a small percent (~30%) of perforation clusters contribute to production. We present in this paper one possible approach to mitigating this problem, based on use of a fully 3-D numerical model of fracture propagation through a heterogeneous medium, by studying the influence both of spacing and of perforation friction on the initiation and propagation of simultaneous hydraulic fractures from a horizontal wellbore. The results indicate that while limited-entry perforating can help to equalize the lengths of fractures simultaneously growing from multiple clusters, it cannot equalize their widths. Both fracture width and fracture length can be equilibrated by combining non-even cluster spacing with limited-entry perforating. This has obvious benefits as it allows equalized placement of proppant across the entire series of perforation clusters, resulting in similar fracture widths and conductivities which enhances the likelihood that all clusters will contribute equally to production.INTRODUCTIONThere is substantial evidence from production logs and other information that during the hydraulic stimulation of horizontal wells, not all perforation clusters within a given stage will produce. One possible cause is the interaction between the hydraulic fractures emanating from each perforation cluster. Typically fractures created at the outer perforation clusters create “stress shadows”, i.e. increases in compressive stress in the minimum principal stress direction, which limit the growth of fractures growing from interior clusters; this is confirmed by modelling [1, 2, 3]. An example of this can be seen in Figure 1 which shows the final configuration of simultaneously propagating fractures from multiple, evenly spaced clusters when there is no perforation friction. The inner fractures are substantially shorter, reproducing the results by Bunger and Peirce [3]. The inner fractures also have substantially smaller widths.One approach to equalize the growth of simultaneously propagating fractures from a horizontal wellbore is by using limited-entry perforating as a method to equilibrate the flow rates into each of the different perforation clusters. Perforation friction is caused by the finite diameter of the entry points into the formation, and leads to a pressure drop across each perforation which is proportional to the flow rate squared. Fractures that take more fluid have a higher fluid velocity through the perforations than fractures receiving less fluid. This causes a larger pressure drop between the wellbore and more rapidly growing fractures, compared to the same pressure drop between the wellbore and the fractures that grow more slowly. Because pressure within the wellbore is approximately the same at each entry point, the larger pressure drop leads to less pressure being delivered to rapidly growing fractures, thereby decreasing their ability to propagate and reducing the amount of fluid they are able to receive. Because the mass rate of injection into the wellbore is constant, this forces more fluid into the fractures that were propagating more slowly, increasing their growth rate. It also increases the pressure required to drive fluid injection. The balance of these effects makes the system largely self-regulating and delivers more balanced fracture growth. While this effect is well known, it is often neglected in current numerical models."

Jan 1, 2015

By J. U. MacEwan

Introduction The equilibrium between copper, zinc, and chlorine may be considered as the simultaneous equilibrium of the two separate chemical reactions of formation of the stable chlorides of copper and zinc at the temperature of the reaction i.e., l440°K. (1,167°C., 2,133°?F.)§ [Zn(g) +Ciz(g) ZnCl2z(g). ... (1) ] [2Cu(l)+Cbi'g) Cu2Cl2(l 1 ....... (21 ] Subtracting, [Zn(g) +Cu2(Clz(l i ZnClz(g) +2Cu!l) ... . (3) ] If this reaction is carried out with a copper-zinc alloy at some constant temperature above the melting point of brass, and at a total pressure of one atmosphere, the equilibrium concentrations obtained will depend on the free energy decrease .of the reaction as written in (3) and on the activities of the various components in. the reaction mixture. If the equilibrium is examined from the point of view of the phase rule, it is a three-component system, and if it exists in two phases (liquid and gas) it will have three degrees of freedom. If the restrictions of constant temperature and pressure are imposed, the degrees of freedom are reduced to one. This means that, in a two-phase system under these conditions, each different alloy phase will be associated with a gas phase of constant composition.

Jan 1, 1951

By J. P. Grieco, F. W. Grieco

"Manufacturing of Jaw CrushersOriginIn 1858 Eli Whitney Blake invented the first successful mechanical rock breaker-the Blake-type jaw crusher. Blake adapted a mechanical principal, the powerful toggle linkage system used to transform rotating motion and energy into oscillating mot ion and tremendous compressive forces. Today these same principals apply and the basic Blake-type jaw crusher is one of the leading machines of its class for heavy duty primary crushing service.In 1881 Philetus W. Gates patented a design for a crusher, the forerunner of the modern gyratory crusher which dominated the field from the late 1800s to the early 1900s. In 1910 the largest gyratory crushers built had 48-inch openings. However, about this time the jaw crusher came to life when the Power and Mining Machinery Co. built an even larger sized opening crusher-a giant 84-inch by 60-inch jaw crusher for a trap rock quarry in Pennsylvania. A 24-inch gyratory crusher became the ideal sized secondary machine for this size jaw. From that time on jaw crushers were looked on favourably as primary breakers and lines were brought up to date to parallel the already developed gyratory lines.FunctionMost heavy duty Blake-type jaw crushers work basically the same way. They are ruggedly designed and capable of crushing material in some cases in excess of 80, 000 p.s.i. compressive strength. They are very simple machines with few moving part s and, with the exception of replacement of renewable parts, are relatively maintenance free. It is quite common to have these machines in product ion for 20 to 30 years. The following will de scribe how these machines work. Large-diameter high-inertia flywheels which are connected to the main eccentric shaft, rotate inside a connecting rod type mechanism called a Pitman. It transforms rotating motion into vertical oscillating motion. This vertical motion is in turn transformed into reciprocating mot ion by means of a system of 2 toggles, each connected to the Pitman. The rear toggle is connected to the fixed rear head, and the front toggle is connected to the swing jaw which is hinged at the top of the crusher. With each rotation of the eccentric shaft the swing jaw opens and closes on rock which is fed into the crusher chamber, crushing the rock in a series of bites. These bites, or strokes as the y are called, usually vary between 1/2 inch to 1 1/2 inch at speeds of 120 to 200 strokes per minute. The reduction ratio of feed input to discharge is usually about 8 to I. Output capacities can vary from 100 tons/hour to 1200 tons/hour depending on the size of machine and its discharge opening. Horsepower requirements can vary from 75 hp to 400 hp.The entire crusher chamber is lined with replaceable 14070 manganese steel liner plates. This material is ideally suited for the job since it hardens as it wears during crusher operation. Manganese is also used in the high wear areas at each end of the toggle plates."

Jan 1, 1985

By D. A. Brown, C. Lowe

"Abstract -A multi-sensor (electromagnetics, magnetics, gamma-ray spectrometry, and VLF) geophysical survey was recently conducted in the Purcell Basin of southeastern British Columbia in an area encompassing the world-class Sullivan Sedex deposit. The purpose of the survey was to geophysically characterize the known mineral occurrences and to develop strategies to enhance future mineral exploration in the basin. Follow-up investigations of geology and measurements of rock physical properties helped constrain interpretations of the geophysical data sets.Despite extraction of more than 90% of the ore from the Sullivan deposit, it is clear that the mineralization there, as well as at other Sedex occurrences surveyed, is characterized by high conductivity values, strong bedrock conductors, and elevated magnetic anomaly values. The albite-sericite alteration which accompanies this mineralization yields high potassium and low thorium-potassium ratio values. Associated Moyie gabbro is characterized by low electrical conductivity and radioelement concentrations and by high magnetic anomaly values. The study has also aided exploration for other mineral deposit types including stratabound Cu-Ag, placer gold, vein and disseminated basemetal deposits. In addition, the geophysical data have helped constrain geological interpretations of the basin."

Jan 1, 1998

By Robert B. Parsons

"One of the disadvantages of the federal government's idea of ""taxation by consultation"" is that it seems to take longer to enact new legislation. The proposed new rules for taxing automobile benefits is one example. Here is a ball which has been batted around between government and the public several times and still has not come down to earth. Fasten your seatbelts, there may be more to come. IntroductionThe draft legislation released on April 13 contains the details of the government's current proposals on car expenses and benefits. They differ significantly from the last announced position. Finance Minister Wilson has indicated that the release in draft form will provide an opportunity for the Commons Standing Committee on Finance and Economic Affairs (the Blenkarn committee) and other interested persons to comment before the legislation is introduced in Parliament. Accordingly, there may yet be revisions.Notwithstanding the prospect of further changes, the proposed rules generally come into force in 1988. While taxpayers may welcome some of these changes, particularly the increase in the tax-exempt allowance, many must be frustrated that, at this late date, the rules for the current taxation year are not yet finalized."

Jan 1, 1988