Search Documents

By K. E. Waters, J. E. Nesset, F. Rosenblum, J. A. Finch

An advanced laboratory-scale weathering apparatus has been developed at McGill University to study the effects of weathering (ambient temperature oxidation) on the self-heating of sulphides. Previous work by the authors has shown that the problematic self-heating of sulphides is inherently linked to the degree of oxidation (weathering) of the minerals: un-oxidized active sulphides exhibit little or no self-heating while the same material when weathered can generate extensive self-heating bringing temperatures well above 100 0C. In this study the effects of environmental conditions (weathering time, ambient temperature, sample moisture, relative humidity, and oxygen content) were evaluated with respect to the self-heating response of a pentlandite-pyrrhotite nickel sulphide concentrate.

Jan 1, 2015

By B. B. Meadows

"The Minto-Chipman Strip Mining Reclamation Project was initiated to re-vegetate the spoil piles remaining from strip mining operations.All available information was studied by the team responsible, and areas being reclaimed in the U. S. were visited, Methods applicable to the N. B. Project were noted for future use.We have both surface and underground mining operations in New Brunswick, Both deface the natural landscape and reclamation varies in difficulty, Surface operation disturbances are the most difficult to correct.Some of the surface mining is carried out next to two main highways and the results are definite eyesores, With this in mind, it was decided to landscape the spoil ground next to the highways and plant “as is"" the ground remote from the public view.The landscaping entailed various degrees of bulldozing from complete levelling to contouring, smoothing and topping, Bulldozing is, of course, the most expensive part of any reclamation project.There are two phases to the planting program; experimental and operational--experimental both prior and, later, in conjunction with the operational planting.Initially in the experimental project, the pH and composition of the spoil was determined using a grid sampling system. Soil samples were tested in a laboratory at the University of New Brunswick."

Jan 1, 1970

By A. Danaei, A. McLean, M. Barati, C. Ravindran

"The aluminum industry generates about 90 million tonnes of red mud each year. Previous research shows it could be utilized as a refining flux with a high capacity to absorb phosphorus and sulphur from hot metal in the steel industry. The present study was undertaken to evaluate the melting properties of such fluxes, as it affects the effectiveness of the flux. The results show that the melting behavior of red mud is strongly affected by lime addition and the characteristic melting/softening temperatures reach minimum VALUES (at 32.7 wt% CaO. From these findings, a correlation was established between melting behavior and optical basicity. This allows one to adjust the composition of the flux based on the process requirements. INTRODUCTIONThe aluminum industry generates about 90 million tonnes of bauxite residues each year. This residue is usually red in color because it contains a substantial amount of iron oxide. The red mud, as it is called, is a solid waste with a high concentration of sodium oxide, high pH (10 to 13), and high alkalinity, and thus is harmful to many forms of life. Traditionally, the material is stored in large tailings ponds within the plant’s vicinity (Power, Grafe, & Klauber, 2009). Development of solutions for safe disposal or preferably using this residue for other industrial processes or applications could help restore polluted locations and eliminate a negative impact on the environment (Haake, 1988; Power et al., 2009; Yan & Xuegong, 2010).The mineralogy and chemical composition of red mud depends on the quality of the bauxite and refining process parameters. In general, it consists of iron oxide (Fe2O3), aluminum oxide (Al2O3), titanium oxide (TiO2), sodium oxide (Na2O), silicon oxide (SiO2), and calcium oxide (CaO) (Power et al., 2009). Like most ores and soils, bauxite can contain trace quantities of metals such as arsenic, beryllium, cadmium, chromium, lead, manganese, mercury, nickel, and naturally-occurring radioactive materials, such as thorium and uranium. Most of these trace elements stay in the residue (Power et al., 2009)."

Jan 1, 2012

By Delio J-J Tortosa, Fred F. Langford

"The Cenex orebody occurs at the intersection of northwest and northeast-trending fault zones that formed during post-Hudsonian uplift. The ore is localized in breccia zones, along faults, and in veins and adjacent wallrocks. The host rocks are Tazin quartzo-fe/dspathic mylonites and ultramylonites and chloritesericite- quartz-graphite-feldspar mylonite schist. The uraniumbearing minerals are finely disseminated pitchblende and uraniferous titanate.The earliest mineralization may have been associated with /ate-stage retrograde metamorphism in the mylonite schist. The main stages of mineralization were associated with brecciation, hematization, carbonatization, and chloritization of the mylonites and ultramylonites. Uranium mineralization was clearly much later than any igneous or metamorphic activity associated with the Hudsonian orogeny.Late post-orogenic uplift, erosion, and deposition of the Martin continental clastics in fault basins were coeval with uranium mineralization. The deposit is consistent with a meteoric-hydrologic system constituting a source for orebearing fluids, hence the close spatial relationship of the uranium deposits in the Beaverlodge area with the basal unconformity of the Martin Group."

Jan 1, 1986

By George M. Douglas

The southeastern shores of Great Slave lake present a curious anomaly in geographical and geological exploration, in that an area so large and important, and withal so comparatively accessible, should nevertheless have remained unexplored, unmapped, and indeed almost unknown, until quite recent" times On their return from the famous journey to the mouth of the Coppermine, the band of Indians with whom he travelled led Samuel Hearne across Slave lake. He was the first white man to see that great body of water and it is rather curious that it should have been seen first from the north rather than from the south. Hearne's account of the lake is vague, and he made no attempt ?to map the part through which he travelled. About 30 years later John Franklin, on his first journey to the Arctic, crossed the lake from the mouth of the Slave river to the Yellow Knife river. Franklin's maps show all of his route in accurate detail, except that part of it which lay through Slave lake. In 1833-34, Captain, afterwards Sir George, Back made the first exploration of the eastern end of the lake. Captain Back was then on his way to the Arctic coast by way of the Great Fish river, and his Indian guides led him through Great Slave lake by the route they had followed from time immemorial. This route, partly because of its directness, and partly because of its sheltered character, lay through the great mass of islands in the middle of the lake to the Talthei narrows, and thence along the sheltered north shore with its many coves and harbours. Pere Petitot made extensive journeys in Slave lake as well as other parts of the far north.

Jan 1, 1929

By Pierre Buteau

Peat/ands distribution in Canada is widely spread thoughout the country and corresponds to a wide spectrum of wetland habitats which overlay peat deposits. The development and the evolution ofpeat/ands and peat deposits are closely linked together, since the vegetal remains of the peat deposits originate from the peatland habitats, and the peatland habitats constitute a response to many factors, including the properties of the substrate, which are the peat deposits. Peat/ands are defined as waterlogged terrains where the production of plant materials usually exceeds the rate of decomposition. The underlying peat deposits consists of organic residues associated to peatland vegetation, more or less decomposed, built up and kept under anaerobic conditions. Peat/ands evolution and distribution are determined primarily by climatic factors, but also by the geomorphology and edaphic conditions. All of these create particular hydrodynamical environments which will vary according to different regional settings, and sequentially to an evolutive time frame.

Jan 1, 2001

By Rosie Moore, Harvey Keats, Kerry Sparkes, A. J. Naldrett

"Abstract-The Voisey’s Bay Ni-Cu-Co deposit was discovered in late 1994 as the result of prospecting initiated in the summer of 1993. By July 1995, proven mineable reserves were 31.7 x 106 tonnes grading 2.83% Ni, 1.68% Cu and 0.12% Co, and current total resources in all categories are quoted to be in the order of 150 X 106 tonnes. The deposit is associated with a body of troctolite belonging to the Nain Anorthosite (1.35 Ga - 1.29 Ga) suite, which was emplaced across the boundary between the Proterozoic "Rae" Province to the west and Archean "Nain" Province to the east.The deposit can be described in terms of three geological settings. The "Ovoid" is a 600 m long by 350 m wide by 100 m deep lens of massive sulfide, covered by 10 m to 20 m of glacial overburden, and separated from the underlying country rock quartz-plagioclase-biotite gneiss by a breccia of gneissic fragments in troctolite known as the Basal Breccia Sequence. To the west of the Ovoid lies the "Western Extension", comprising disseminated and massive sulfides in a north-dipping sheet of troctolite which ranges from upper unmineralized troctolite down through troctolite with increasing amounts of sulfide (up to 50%), to massive sulfide (in some places only), and then to Basal Breccia Sequence. East of the Ovoid, the troctolite sheet broadens out into a troctolite intrusion, within which occurs the "Eastern Deeps", a zone of massive and disseminated sulfide up to 100 m thick that is currently being explored. The mineralization of the Eastern Deeps lies along the line of intersection of a feeder sheet with the base of the intrusion. The current interpretation is that the three geological environments represent different erosional levels through a single mineralized intrusion. In this model, the deepest erosional level lies to the west and exposes the feeder to surface, whereas the Ovoid represents the base of the intrusion at surface, and the Eastern Deeps the base of the intrusion overlain by 600 m to 900 m of troctolite. Sulfides and gneissic fragments were brought up by magma flowing quickly through the feeder, and settled out where the flow rate decreased as the sulfide-bearing magma mixed with magma already emplaced in the intrusive body."

Jan 1, 1996

By Linda Hodgson

1. Introduction ?Northgate Minerals Corporation is a mid-tier gold and copper producer with mining operations, development projects and exploration properties in Canada and Australia. ?Kemess Mine is Northgate?s principal operation. Where in the world is Kemess? ?Kemess is located in north-central British Columbia,430 kilometres northwest of Prince George. ?The Kemess South complex consists of an open-pit mine, a 52,000 tonnes per day mill and various ancillary support facilities including maintenance shops and housing for Kemess' 340 full-time employees.

May 1, 2010

By J. Bruce See

INTRODUCTION This symposium at Cu 2019 has been organised to honour and celebrate the career and achievements of Dr Phillip John Mackey, an internationally recognised expert in the production of non-ferrous metals, especially copper and nickel smelting and refining. Phillip was born in Epping, a suburb of Sydney, New South Wales, Australia on 19 April 1941 and is one of 4 children of Gilbert and Philomena (nee Bartlett) Mackey. After completing Primary School in Epping, he attended Marist Brothers High School in Eastwood, Sydney and graduated in 1957 as the Dux of the School. Phillip’s father, being on the staff of the Sydney Technical College, in Ultimo, Sydney had the opportunity in the early 1950s to meet the late Professor Sir Rupert Myers, Foundation Professor of the School of Metallurgy at the New South Wales University of Technology (later called the University of New South Wales or UNSW). Gilbert Mackey was impressed by the new young Professor of Metallurgy and encouraged his son to study metallurgy - at the time an expanding industry in post-war Australia. EDUCATION AT THE UNIVERSITY OF NEW SOUTH WALES Phillip commenced at UNSW in 1958, graduating with honours in 1963. His undergraduate education and training included a few years of part-time study while working at British Motor Corporation on sheet metal forming of car bodies. At University Phillip developed his talent for teamwork. He was a contributing writer to the University newspaper, Secretary of the UNSW Students’ Union and was active in the UNSW Metallurgical Society and co-editor in 1963 of “Metallurgical Review,” the annual journal of the UNSW Metallurgical Society. His diverse interests and curiosity about the world around him were likely nourished while at University. Upon completing his Bachelor’s degree, Phillip was awarded a Commonwealth of Australia Postgraduate Research Scholarship. He began his PhD in 1964 on the thesis topic “Studies in Heat Transfer between Dispersed Liquid Metals and Gaseous Atmospheres” working under the supervision of then Associate Professor Noel Warner, an outstanding Professor at the University. Professor Warner is now an Emeritus Professor at the University of Birmingham and is internationally respected for his pioneering theoretical and practical work on established and innovative smelting processes.

Jan 1, 2019

Automation Defined ?Using self-operating equipment to reduce human exposure to the mining environment and routine or repetitive work.?-Atlas Copco Terminology: ?Manual Operation ?A vehicle being operated by a person ?in the cab?. ?Radio Remote Control (RRC) ?A vehicle being physically operated by a person through a Line Of Sight (LOS) or Video-Remote equipment. ?Tele-Remote Control ?A vehicle being physically operated by a person at an operator station which is not necessarily located near the vehicle?s working area. ?Autonomous Operation ?A vehicle under self control with the possibility of human supervision and override.

Oct 1, 2010

By W. Jomaa, V. Songmene, O. Mechri, Laval Université, P. Bocher, J. Levesque

"A 2D finite element modelling (FEM), based on pure Lagrangian approach, is developed for studying the serrated chip formation during high speed machining (HSM) of 7075-T651 alloy. The solution was achieved using a commercial software package, ABAQUS/Explicit v6.13. The Johnson-Cooke (JC) constitutive equation is used to describe the work material behaviour. Moreover, the JC damage equation is implemented into the FEM to take into account for the shear localization during the serrated chip formation. Modified Coulomb friction model has been used to characterize the sliding/sticking effects on the tool-chip interface with the friction coefficient and shear flow stress determined by force calibration and machining data, respectively. The proposed FEM is validated using experimental data obtained in HSM of 7075-T651. The FEM was able to predict accurately serrated chip morphology. The intensity of chip segmentation was found to increase with cutting speed.INTRODUCTIONHigh speed machining (HSM) is one of the most used processes for manufacturing aircraft parts with aluminum alloys. For aluminum alloys, the use of HSM increases metal removal rate and reduces the formation of built up edges and burrs. However, it was found that serrated (also named segmented or sawtooth chip) and discontinuous chips can be produced during HSM of some high strength aluminum alloys, such as 7075-T6 alloy (Rao & Shin, 2001). Many parameters were found to affect the segmented/discontinuous chip formation during the machining of aluminum alloys.There are two cases in which the serrated chip can forms: the first is when machining hardened materials (Morehead, Huang, & Luo, 2007), and the second, when machining ductile materials with a cutting speed higher than a critical value (Barry & Byrne, 2002). Different theories and models were developed in order to explain the formation mechanism of such kind of chips. According to Astakhov (2006), the segmented chip formation is attributed to variations in stress and plastic deformation states, and resulting temperatures on the cutting zone. Liyao et al. (2013) stated that the segmented chip formation was mainly attributable to adiabatic shear instability/catastrophic strain localization. Others (Vyas & Shaw, 1999) suggest that the fracture/crack propagation mechanism is at the root of chip generation."

Jan 1, 2016

By Alan J. Wianwright

Introduction ??New world-class Upper Devonian porphyry Cu-Au system located in south Mongolia ??6.5 km NNE-trending mineralized corridor ? 4 discrete deposits ??Southern Oyu deposits: Chalcopyrite, deposits: bornite ??Hugo Dummett: Zone: Hypogene chalcocite in addition to chalcopyrite and bornite ??Total resource exceeds ~2 Gt@ >1% Cu, >0.25 g/t Au (0.6% Cu equivalent cut-off) (Ivanhoe Mines press release, 2005)

May 1, 2006

By W. Swidzinski

"Zelazny Most" post-flotation copper mine tailings pond is the only place to of storeing wastes for KGHM POLSKA MI EDZ S.A. The flotation tailings is are the main waste stream in copper mining in Poland. Sufficient storage capacity for tailings is crucial for , thus uninterrupted production of copper is crucially related to the possibility of storing wastes in the pond. The pond covers a Its over 14 km2 arca, almost 50 m high dams making this dame this construction one of the largest in the world. The risk assessment of potential damage due to un stable ility loss of dams or environmental contamination, as well as safely constructing damsincrease of dams within the design criteriaprocess, require quick access to a large amount of the monitoring data , which in vast amount have to be monitored, that needs to be analyzed and processed and reported, every day. This In the paper describes the numerical information system "SyZeM" , used for designated to the "Zelazny Most" pond, baseding on the Oracle database and Geographical Information System , to manage the graphical and descriptive data in coherent way., is presented. The main structure of the system, as well as the methodology of storing, processing and reporting the geological, geotechnical, hydrogeological, geophysical, chemical and survey data are shown. The aspects of Optimizing optimal and risk mitigation and safe management of copper wastes and risk mitigation with the help of "SyZeM" are discussed.

Jan 1, 2007

By G. V. Sirianni, G. E. Viens, R. A. Campbell, G. N. Banks, R. L. Sachdeva

"A combined shaft-electric furnace for the smelting of ores and the melting of metallized iron pellets is being developed. The materials are preheated, and in some cases pre-reduced, in the shaft before being transferred to the electric furnace, where melting or smelting is completed. It has been demonstrated that this combination of equipment will enable much of the relatively expensive electrical energy to be replaced by cheaper energy in the form of oil or natural gas, and preliminary experiments indicate that the total energy requirements for a melting or smelting operation are significantly reduced. Projections based on results obtained from the preliminary experiments indicate that further improvements will be possible when certain modifications to the equipment are completed."

Jan 1, 1968

By H. A. Wilson

Introduction Salt (sodium chloride) occurs naturally either in the solid state as rock salt or in solution as a component of natural brines. It is the major saline constituent of sea water, which contains about 4 percent salt-roughly 164 million tons, or enough to meet world salt demands for five years, per cubic mile. The great rock salt deposits of the world are generally regarded as having been formed by the evaporation of sea water over long periods of rime in wholly, partially, or periodically cut-off bays of ancient oceans. History and Occurrence of Salt in Canada We can speak today of the vastness of Canada's salt resources, but it was not always so. Settlement of our Atlantic seaboard and the Sr. Lawrence valley began in earnest in the early 1600's. The first small commercial salt works in Canada did not come into operation until 1866. Thus, for some two and a half centuries, the inhabitants of this growing country were entirely dependent on foreign sources for every pound of salt they consumed. The record shows that from at !east 1800 onward, the need for a domestic salt industry was clearly recognized by the governments of the day. It was during the Western Ontario oil-boom of 1866 that the initial discovery of rock salt in Canada was made, not far from Goderich, at a depth of 1,000 feet. A salt company was promptly organized, and with their operations there began the gradual and still uncompleted conquest of the Canadian salt market by the Canadian salt industry. Over the next thirty years many holes were drilled into the Salina formation both in Ontario and Michigan, and encountered rock salt. A vast salt-basin was disclosed, approximately outlined, and given the name Ontario-Michigan Salt Basin. The Ontario portion of the basin extends over at least 3,500 square miles, is met with at a depth varying between 800 and 1,600 feet, and has a thickness of 50 to 250 feet. No attempt has ever been made, so far as we know, to calculate the total salt reserves of this basin, but the minimum indicated in the Ontario portion by the figures just cited is just under thirty-five cubic miles. The specific gravity of rock salt is 2.2. From these data, those so inclined may calculate the tonnage.

Jan 1, 1947

By G. Shaw

IN recent years, most of the reconnaissance work of the Geological Survey of Canada has been mapped on a scale of 1 inch to 4 miles. Topographic base maps, commonly made from aerial photographs, were available to the geologist for such work. The advent of war curtailed aerial photography for civilian purposes, and by 1941 all areas already photographed had been geologically mapped. Nevertheless, the need for geological maps to assist post-war prospecting was so apparent, and the country to be covered is so vast, that some new method of rapid mapping had to be devised. It was felt that the need would be met if geological maps could be produced at a scale of 1 inch to 8 miles, provided they were sufficiently accurate in topographic detail to serve as guides to travel. Though in such maps there would be considerable sacrifice of geological detail, they would serve to outline, at least approximately, the major geological units, some of which might prove of sufficient interest to warrant later detailed study. It seemed that such mapping would be particularly useful in the northern regions of Canada which the work of early explorers has indicated are underlain largely by granitic rocks. These, so far as is known, are barren of mineral deposits, but within them are known to be areas or bands of 'greenstones' of the type that, in some localities, have been found to contain valuable orebodies. The problem, then, was to devise a method of mapping, particularly of such greenstone bands, that would make it possible to cover a relatively large area-say 30,000 square miles-in one season and at a cost below that of 4-mile mapping, with, of course, some sacrifice of accuracy. The problem seemed to be threefold: (a) to observe as much of the bed-rock as possible; (b) to produce a topographical map of as much of the area as possible, with particular reference to portions of geological interest; and (c) to cover as large an area as possible in a limited time, which meant faster modes of travel than have hitherto been used. The obvious answer to all three phases of the problem was the use of aircraft. If rock types could be broadly differentiated from the air, reconnaissance traverses by air would supply the answer to the first part of the problem. For topography, air photographs taken on reconnaissance flights appeared to be the answer. For the third phase of the problem, the use of aircraft was ideal.

Jan 1, 1943

By J. E. Udd, S. Bharti

"ABSTRACTMonitoring of stability conditions in underground mines permits management to assess the response of the rock mass to mining strategies. Monitoring of movements, if sufficiently early, may also permit operators either to avert potential failures or to develop alternative approaches to extraction.The Falconbridge organization has been a leader both in the uses of rock mass stability monitoring techniques and in the development of instrumentation.In this paper, the authors review the Falconbridge approaches to monitoring, and present case history examples to illustrate the application of the various instruments used.RESUMELa surveillance des conditions de stabilité dans les mines souter-raines permet aux chefs d'enterprises d'évaluer les réactions de la masse rocheuse aux méthodes d'extraction minière. Si le contrôle des mouvements du terrain est effectué assez tot, l'exploitant pourra prendre les mesures qui s'imposent, soit pour éviter les détériorations possibles ou pour mettre au point de nouvelles méthodes d'extraction.Le groupe de la Falconbridge a ére le premier a utiliser des techniques de vérification des conditions de stabilité de la masse rocheuse et a mettre au point l'appareillage requis.Ce document présente une revue des méthodes employées par la Falconbridge pour assurer la surveillance active de la stabilité de la masse rocheuse et illustre au moyen de cas concrets la manière d'utiliser les divers appareils."

Jan 1, 1987

By John A. C. Fortescue

There is a need for better communication between scientists who plan and carry out mineral exploration research in glacial terrain and the exploration geologists who look for mines. In this paper, four ways in which workshops could be used to close this communication gap are described and discussed in relation to the solution of this problem in Canada.

Jan 1, 1973

By Anton Gronningsater

AT the present time we hear a great deal about organization of labour, collective bargaining, workmen's councils, and company unions; about C.1.0. with its principle of vertical unions and A.F.L., largely based on craft unions; and about provincial and federal laws for protection of labour's right to collective bargaining. What we perhaps hear too little about is corresponding organization of the employers, although it recently is mentioned more frequently. I will only mention W. H. Davis, Chairman of the United States War Labour Board, who has had and is having plenty of experience in this field and has also studied labour conditions in Europe-in Sweden for instance. He has repeatedly expressed the opinion that where employer-employee problems are involved, a thing badly needed in America is organization of employers as well as employees to get some order in the present chaos. With this I agree. I believe a strong organization on one side necessitates a correspondingly strong organization on the other side; that has at least been the experience in the industrialized countries in Europe. I happen to be fairly familiar with conditions in Norway, where they have struggled with these problems for fifty years, and a talk on the history, development, and present state of employer-employee relations in that country might perhaps be of interest as giving a general picture of the development of such relations in the northwestern European countries as a whole. The talk was originally given to the Fourth Year students in Mining and Metallurgy at the University of Toronto. I have changed it somewhat to fit a different audience, but I hope you will make allowances if you now and then are reminded of the school auditorium. I will try to be as objective and factual as possible, but it is probably unavoidable that some of what is said is coloured by personal opinion.

Jan 1, 1943

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012