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By W. H. W. Husband

Rock salt has been mined by the solution method for many years in many countries. Attempts have been made in the past in Canada and various other countries to produce potash by the' same method. However, only Kalium Chemicals Limited (1) has been successful, possibly because the conditions in Saskatchewan are the most favorable conditions to be found so far for the development of a solution mining method for potash. There are significant differences in solution mining of rock salt and solution mining of potash. First, rock salt deposits are relatively pure in respect to soluble minerals, whereas potash is never found in the pure state and contains Substantial amounts of other soluble minerals, particularly rock salt. In comparison to rock salt, much less potash is dissolved and brought to the surface for the same amount of water circulated through the orebody. The amount of water to be evaporated per unit weight of product is a major difference. Much greater amounts of water must be evaporated when producing potash and the treatment of the brine is more complicated because other dissolved salts have to be separated. Secondly, the rock salt deposits, particularly the domes, are much thicker. Bed thickness is of prime importance because it determines the yield of a well and consequently the economics of the process. Furthermore, as rock salt provides a strong roof structure, larger cavities can be developed and this prolongs the life of the rock salt well.

Jan 1, 1971

By G. A. Parkison

The sequential copper analysis method is a particularly useful technique to semi-quantitatively define the geologic, mineralogic, and metallurgical types and zonations commonly associated with porphyry-type copper deposits. The method is based on the partial dissolution behavior displayed by the prevalent copper minerals malachite, chrysocolla, chalcocite, and chalcopyrite to solutions containing sulfuric acid and sodium cyanide. Results from sequential analyses of the sample and analytical residue using sulfuric acid followed by sodium cyanide and then aqua regia solutions when compared with conventional total copper analyses can determine the amounts of leachable oxide minerals, leachable secondary sulfide minerals, and primary copper minerals, respectively. Sequential assay analytical results and interpretation are presented for copper deposits in Chile, Mexico, and the United States.

Jan 1, 1995

By John E. Caffrey

Mr. William. J. Montgomery in his book "Theory and Practice on Mine Ventilation stated "Ventilation is vitally important to underground mining for three reasons: First, it sweeps all workings with a plentiful supply of air and drives to the outside the smoke, gases, and contaminated air which would be injurious to the miners; second, it dilutes and renders harmless the explosive gases emitted from the strata, thus eliminating the dangerous conditions caused by the accumulation of these gases; third, it keeps the mine air as nearly as possible of the same composition as the outside air, thus giving to the miner the healthiest possible condition in which to work...." Specific methods to achieve the above basic reasons for mine ventilation were established in the Federal Coal Mine Health and Safety Act of 1969. Sections 303(y)(1); (y)(2), and Section 317(f)(4) of the Act, which can be broadly described as entrapment features, are controversial and debatable in the minds of many mining engineers in their intent and method for affecting, 303(y)(1) in certain cases prohibits the use of belt haulage entries as an intake for face ventilation, This is to say that air traveling in a belt entry will be placed into the returns and not used for face ventilation, 303(y)(2) limits the velocity of the air on trolley haulage entries. The regulations, as published in the Federal Register, have set this limit at 250 feet per minute unless a higher velocity is approved by the District Manager.

Jan 1, 1972

By I. J. Jansen

Successful soil construction involves preparation of an adequate base, selection of high quality soil materials, and placement of those materials by means which will establish a continuous macropore network and modest to low soil strength. Where such has been accomplished, experiments reveal row crop productivity on reclaimed land which is very competitive with that on undisturbed land. Inferior productivity and sensitivity to drought stress are experienced where the soils are excessively compacted during construction. Some deep tillage practices have been quite successful in improving the compacted soils, but it is preferable to avoid compaction as the soil materials are handled.

Jan 1, 1987

By J. Y. Kim

Lead ions originating from galena during processing of complex sulphide ores migrate to "cover" the surface of sphalerite and iron sulphide mineral particles, and cause poor selectivity in differential flotation. Generally in sulphide ore processing, the lead-activated minerals float in the Cu/Pb rougher circuit. Subsequently, surface lead complicates the zinc flotation circuit by lowering the concentrate grade due to the co-flotation of lead-activated iron sulphide minerals. The effect of lead in the differential flotation of sphalerite from Cu-Pb-Zn and Pb-Zn ores is discussed. Plant and laboratory test data are interpreted by determining the surface composition of individual grains of sphalerite and iron sulphide particles using two surface analytical techniques, Laser Ionization Mass Spectrometer (LIMS) and Time of Flight-Secondary Ion Mass Spectrometer (TOF-SIMS). Cationic and anionic species on the surface were analyzed to elucidate the phenomena.

Jan 1, 1995

By G. Van Weert

Separation of minerals by shape has received little attention, since minerals normally do not break into different shapes during crushing and grinding. However, comminution of consumer wastes generates opportunities for novel separations based on particle shape. For instance, ductile plastics are broken into longer curved shapes, whereas brittle plastics yield angular particles. Using spouting beds for particle separation in water requires controlling the spout's instability. The preferred geometry for such redesigned spouting beds is reported. Plastic cylinders, discs and spheres were separated as a function of rising water velocity and amount of particles in the system. By using 5 mm particles, differences in settling behavior could be video recorded.

Jan 1, 1999

By E. Milosavljevic, C. H. Bucknam, K. L. Gabby, T. C. Eisele

"Since mercury is chemically similar to silver, it tends to dissolve along with the silver and gold during cyanide leaching. Ultimately, mercury is recovered along with the silver as mercury/silver/gold amalgam, which requires retorting to remove the mercury prior to refining the silver and gold. A possible approach to separating mercury from silver and gold in cyanide leach solutions is to take advantage of the replacement reaction between [Hg(CN)4]2- and Ag2S, which results in precipitation of mercury as HgS while dissolving silver as [Ag(CN)2]-. Results are presented demonstrating that mercury can be removed from cyanide solutions with high effectiveness while, at the same time, recovering additional silver in solution. Initial experiments with static flasks in the laboratory showed a high degree of mercury removal could be achieved. Results using actual metallurgical plant products in bottle roll tests indicate the process works on a larger scale, but also results in significant gold losses if the solution being treated has high gold levels, such as carbon stripping pregnant eluent solution. IntroductionThe dissolution of mercury along with precious metals during cyanide leaching is a long-standing problem, which can result in significant mercury toxicity issues (Washburn, 2003). Mercury is first dissolved by the cyanide solution, and then, since it has a great deal of chemical similarity to silver, it follows silver throughout the concentration and recovery processes, ultimately being recovered as a silver/ mercury amalgam when the metal is precipitated by either the Merrill-Crowe process or by electrowinning.While it would be desirable to either prevent mercury dissolution entirely while still allowing silver dissolution, or to selectively capture mercury before the precious-metals recovery step, there is not yet an effective and economically practical approach to doing this (Grosse, 2003; Ravichandran, 2004; Misra, 1998; Pai, 2000). There are a few processes that have been proposed, such as differential adsorption. While activated carbon, as used in the carbon-in-pulp process, is not highly selective between mercury and silver (Washburn, 2003), it may be possible to achieve some separation by selective elution of the carbon to produce high-mercury and low-mercury eluates (Bunney et al., 2010). Certain synthetic resins were shown to be selective for gold but are more expensive than carbon, requiring special equipment, and have not yet been shown to be selective for mercury (Grosse, 2003). There may be potential for differential dissolution approaches, as thiosulfate leaching does not dissolve mercury sulfides as readily as it dissolves gold (Oraby et al., 2010), and it is possible that it may be similarly more selective for dissolving silver relative to mercury. Some work has also been done with selective precipitants, such as sodium polythiocarbonates (Bucknam, 2007), and 1,3-benzenediamidoethanethiol (Matlock, 2002). Common problems with these approaches include introduction of a solid:liquid separation step, reagent costs, the need to measure the mercury concentration for process control for minimizing silver losses, and regulatory requirements to retort otherwise stable mercury concentrates."

Jan 1, 2015

By Grażyna Dzik, Adam Mirek, Krzysztof Król

The Upper Silesian Coal Basin is located in the area of the Upper Silesian Syncline and belongs to one of the most complex tectonic units in Europe. It occupies 5,650 km2. In 2020, there were 20 hard coal mines operating in the area. Seismological research in this area consists of observation of precursors/symptoms of shock generation and understanding of their effects. Studies (Teisseyre R. 1972, Mutke G. & Stec K. 1997, Stec K. 2007, Dubiński J. & other 2010, Idziak A. 2010) of complex impacts of rock mass provided a background for determining the conditions for the formation of exploitation and regional seismic shocks. Issues related to tectonic and exploitation stresses, successive extraction of coal seams at higher depths, operation in the vicinity of fault zones, often complex geological and organic conditions result in the activation of a discontinuity surface due to stress caused by deformation of rock layers, which, as a result, causes the emergence of strong shocks above 107 J. The article was based on analyses of extraction value, high-energy shocks, both of mining and tectonic-mining (so-called regional shocks) origin, against the background of changing operating conditions, which, as a result, creates an image of periodically changing seismic activity and location of strong shocks. Observation results show that, with an increase in exploitation depth and declining extraction, the number of strong shocks caused by tectonic stress (107 - 109 J) and exploitation stress (≥105 J) has been steadily increasing over the last 25 years.

Apr 26, 2022

By J. B. Lott

The authors' company has recently undertaken a development programme aimed at exploring the relationships between the variables of greatest importance in the design of mixer-settlers for metallurgical solvent extraction applications. Such applications vary from relatively small scale plants treating copper mine waters, nickel containing effluents, etc., where the total flowrates may be of the order of a few hundreds of gallons per minute, to very large scale plants treating several thousands of gallons per minute of leach liquors containing copper, uranium or other metals. This paper outlines the physical and mechanical factors which must be taken into account when designing mixer-settler systems for large scam. solvent extraction plants. The performance of the equipment will also be dependent upon the chemistry of the system, including the kinetics and thermodynamics of the ion exchange reaction itself, the effect of impurities flocculants, surfactants, temperature, etc., but these will not be dealt with here. Much of the laboratory work has been carried out using copper containing solutions and either LIX 64* or LIX 64N* as the solvent dissolved in various grades of kerosene. For simplicity, all the graphs and tables of results which are presented and discussed here will refer to the LIX-copper system, although the conclusions will in many cases be generally applicable to other systems also. The LIX-copper process is now sufficiently well known to obviate the need for a full description, however, an outline flowsheet of the process is shown in Figure 1. The ultimate objective of a laboratory programme for a particular extraction application is to provide data upon which a mixer-settler system can be designed to handle a given throughput of leach liquor and extract from this liquor the maximum quantity of metal for the minimum cost. In other words, the objective is to determine the design and operating parameters which achieve the optimum balance between capital and operating costs. * Trade-marks for General Mills solvents.

Jan 1, 1971

By Steven W. Hunt, Glen R. Frank

Assessment of abrasivity and cutter life are necessary to properly manage risks when tunneling in mixed face ground which includes ground with cobbles and boulders. Maximizing cutter life requires: (1) abrasivity and strength parameters for soil matrix and rock clasts, (2) methods of combining both, (3) proper selection of cutters and (4) modified TBM operation including use of boulder detection methods from the TBM to help make operation decisions. This paper presents approaches for addressing these factors sufficiently to improve tunneling success in mixed-face and cobbly-bouldery ground. Current laboratory abrasivity testing will be assessed along with equivalent quartz content correlations to soil matrix and rock clast abrasivity. New approaches to combining abrasivity testing of both the soil matrix and rock clasts for various cobble and boulder volume ratios will be suggested to estimate cutter life and intervention intervals. Methods for detecting boulders and using detection data to modify TBM operations to minimize boulder impacts are provided.

Jun 13, 2021

By Roger C. Wilmoth

The most common method of treating mine drainage to prevent water pollution consists of neutralization and aeration. This process removes the acidity, iron, aluminum, and some other heavy metals, but does not render a water suitable for domestic or industrial use because of the high dissolved solids, hardness, and sulfate in the treated water. The Environmental Protection Agency (EPA), has been sponsoring and conducting research since 1966 on the use of reverse osmosis (R.O.) for the treatment of mine drainage. This process has been found to be highly effective in the removal of nearly all the dissolved solids. In addition, since R.O. is a concentrating process, potentials for recovery of valuable heavy metals are possible. This paper is a review of the state-of-the-art on the treatment of mine drainage by reverse osmosis.

Jan 1, 1972

By Steven I. Olson

Since the introduction of froth flotation, the Florida Phosphate Industry has faced the challenge of coarse particle -850 +425µm (-20 +35 Tyler mesh) beneficiation. Several techniques have been used to upgrade this difficult size range. This paper discusses one approach that has met with success; namely, improved fractional recoveries through enhanced areation and improved material transport characteristics via larger than standard flotation cell mechanisms.

Jan 1, 1981

By Wiston Rocher

The Minera Ojos Del Salado (MINOSAL) concentrator is located 20 km (12 miles) southeast of Copiapo, Chile. It processes copper ore provided by its Santos and Resguardo mines at a capacity of 4.2 kt/d (4620 stpd). In 1982, Phelps Dodge acquired the majority interest in MINOSAL to explore the property's potential. At that time, the concentrator plant was a small, antiquated installation with a capacity of 674 t/d (740 stpd). At the time of the pur¬chase, the majority of the ore was produced from the Santos and Resguardo mines, but custom ores of copper, silver and gold were also treated. The acquisition occurred at a crucial time in the copper business, since the price had fallen to nearly 50 cents/ lb. In 1985, Phelps Dodge purchased the outstanding interest in MINOSAL and acquired 100% of the property. Today, after numerous improvements and two expansions, the concentrator is a combination of old and new equipment. The regrind mills, for example, have been in service for about 50 years, while the ceramic concentrate filter represents the latest technology.

Jan 1, 1993

By Andrzej Wala, Tom Altman, Tom Hughes

The University of Kentucky Mine Ventilation Manager (UKMVM) is a system that contains Level Five knowledge bases and comprises an expert mine ventilation management system. The package uses production rule language (PRL) to interpret data monitored from sensors, e.g., for airflow, temperature, and concentration of gases, in an underground mining environment. Activated from the PRL knowledge bases are Pascal subprograms which (1) organize the monitored data to set up emergency consultations, (2) display graphic representations of a mine's ventilation network with the latest sensor readings, (3) provide interactive updating of mine ventilation parameters, e.g., resistance changes, revised flow requirements, and new regulator and fan settings. Also activated from these knowledge bases are programs which (1) monitor airflow, temperature and gas concentrations from a physical mine ventilation model and (2) adjust regulator openings and fan rpm's. Thus, as an expert system the UKMVM not only presents advisory consultations for underground environmental emergencies, but also serves as an interface between the monitoring and responsive control aspects in the continuous maintenance of normal mine ventilation.

Jan 1, 1989

By D. M. Hausen

Carbonaceous gold ores are ubiquitous to virtually all of the Carlin-type gold deposits along the Carlin gold belt in north central Nevada, representing the unoxidized "zones" of presumably extinct thermal spring systems of mostly Tertiary age. A period of subtropical weathering resulted in deep sub-lateritic zones in most deposits to several hundred feet below surface. Carbonaceous ores below this supergene profile of weathering have been investigated by various methods, including petrographic study, standard geochemical and organic carbon analyses, carbon and hydrogen isotopic ratios, electron-spin resonance spectra, infrared spectra, and DTA techniques. Results have been integrated with recent findings by other investigators utilizing fluid inclusion and thermal brine data to indicate a first phase hydrothermal solution temperatures and pressures at a minimum depth of 6 km under normal geothermal gradient. This phase resulted in the quartz-barite-calcite vein filling of the host rocks. Gold mineralization took place later at shallower depths. Primary organic material in carbonaceous ores from the Carlin and other mines appears to be a pyrobitumen residue derived from an old oil pool that had been heated by the thermal solutions, and from which the light hydrocarbon fractions were removed. Some of the bitumen was remobilized along silicified veinlets in the ore, but its role in the emplacement of the gold, itself, is not clear. The gold was localized submicroscopically in fine pyrite, mostly in framboids, and as fine metallic particles, but does not appear to be concentrated within the carbonaceous matter per se. However, reducing conditions associated with bituminous residues are believed to have been favorable for gold deposition.

Jan 1, 2013

By R. S. Kinasevich

As part of other work related to the studies of kinetic factors that influence the flotation of specific sulphide minerals, specially designed kinetic flotation experiments at Cominco included work done on -65 + 100 mesh and -100 + 150 mesh, high purity galena. The flotation collector used was sodium isopropyl xanthate containing radioactive sulphur-35. Radiation monitoring of the galena fractions from stage flotation tests indicated that the adsorbed radioactive xanthate was uniformly distributed among the floated fractions and the non-floated, or residual portion of the galena. This anomalous behaviour could not be correlated to changes in Seebeck coefficients, to lattice distortions, or to the nature of the mineral surface as revealed by infrared spectroscopy and by microscopic measurements.

Jan 1, 1970

By David K. Sitler

Continuing advances in manufactured diamond materials used in rock cutting tools have created a new generation of high production tools for mining. This paper will review the three major manufactured diamond products available for the mining industry as supplied by General Electric Company, Specialty Materials Department, and examine the ways in which these materials are employed. As an integral part of this examination, the economic impact of manufactured diamond tools will be evaluated. Time and again, one will find that the premium price of these tools is economically justified when compared to traditional tools.

Jan 1, 1985

By Eckl, Martin, Stefan Lemke, Martin Londschien

"Tunnels are built with a design life expectancy of over 100 years. One key component of such a design is the waterproofing system, which must reliably fulfil its function during the whole service lifetime of the tunnel structure. This paper deals with the determination of test criteria for the durability assessment of geosynthetic products in tunnel sealing systems. Hereby the understanding of the individual aging processes is crucial along with the long-term experience with these materials to ensure the transfer of the laboratory results and performance to site practice (test calibration) and vice versa. To verify the results of the new test procedure the material properties of geosynthetic products samples removed from older tunnels are investigated. Based on the presented results of the still ongoing research programs some preliminary conclusion regarding the updating of regulations for tunnel sealing systems are given. INTRODUCTION Watertightness is directly related to the durability and serviceability of the concrete lining. Therefore, modern traffic tunnels and shafts (Figure 1) are generally protected against mountain/ground water and water penetrating through rock fissures by a sealing system, for example with a loose-laid polymeric sheet membrane. Hereby the waterproofing sealing systems must be reliably fulfilling their function during the whole service life of the tunnel structure, regularly of more than 100 years. In consequence, the quality and lifetime performance of the waterproofing materials—beside the correct professional and careful installation in a tunnel infrastructure, is of great importance. The challenge for the industry, owners, operators and designers is ultimately the development of qualification testing and requirements (acceptance criteria) for products to ensure the design lifetime performance. Hereby the qualification procedure is seen as a routine integrated in standards, norms or guidelines, wherein test procedures should cover typical environments for the specific application fields. Polymeric synthetic raw materials are increasingly used in products with long service lifetimes (e.g. in injections, gaskets, waterbars, spray-applied and sheet waterproofing membranes). During service they are subjected to chemical (e.g. oxidation processes) and physical (e.g. changes in morphology) influences from the environment, which affect their mechanical properties—and they age. Hereby organic materials are more affected than inorganic materials. Also, polymers show strongly temperature-dependent properties compared with other construction materials. However, their long-term aging behavior is not given per se and has to be explored extensively by suitable tests, which simulate—under accelerated processes—real exposures and loads. Hereby the understanding of the individual aging processes is crucial along with the long-term experience with these materials to ensure the transfer of the laboratory results and performance to site practice (test calibration) and vice versa."

Jan 1, 2016

By Negar Elhami Khorasani, Anthony Tessari, Nan Hua

Fire hazards can cause severe and irrecoverable damage to reinforced concrete (RC) tunnel linings, threatening the serviceability and resilience of transportation networks. This paper first examines the existing methodologies that are used to classify damage to tunnel linings from fire. These approaches are then supplemented with the results of advanced modeling and inputs from industry experts to propose new fire damage/ repair classifications with the associated thresholds. The results of the presented research can be used to guide fire risk assessment as well as the performance-based design of tunnel fire protection.

Jun 13, 2023

By P. James

"INTRODUCTION Dissolved salts build up in leach solutions over time as leach solutions mature. Iron can be particularly problematic for hydrometallurgical copper production as it can compete with copper for separation during solvent extraction (SX), leading to iron bleed through and reduced electrowinning (EW) efficiency. In its ferric form (Fe+3) it precipitates as a hydroxide at fairly low pH and can promote clogging and disrupted flow within leach pads as a result of localized pH deviations – such as might result from weather events. The solids formed can cause relatively irreversible degradation to pad productivity. The precipitation pH point for solids formation falls as the ferric (Fe+3) concentration increases, making the issue more prevalent as leach circuits for ore bodies containing appreciable iron get older. It can also be more of a concern when leaching lower grade ore like tailings where lower copper content may increase iron/copper ratios which may increase iron accumulation rates. The precipitation pH point for solids formation falls as the ferric (Fe+3) concentration increases, making the issue more prevalent as leach circuits for ore bodies containing appreciable iron get older. It can also be more of a concern when leaching lower grade ore like tailings where lower copper content may increase iron/copper ratios which may increase iron accumulation rates. Control of ferric (Fe+3) levels could be used to lower ferric (Fe+3) levels and keep the ferric hydroxide [Fe(OH)3] precipitation pH sufficiently high to avoid the associated solids formation and potential leach pad occlusion. Control of ferric (Fe+3) and ferrous (Fe+2) tenors and ratios may also provide benefit for improving sulfide ore leaching or bioleaching performance and effectiveness. Traditionally options for such control were rather limited with bleeding contaminants off or chemical dosing treatments being prominent methods. Now Blue Planet Strategies introduces a new option. Blue Planet Strategies (BPS) focuses on improved resource utilization targeting electrolytic treatment and waste conversion into resources and has now demonstrated that its proprietary DeMet™ (Dynamic Electrolytic Metal Effluent Treatment) platform is highly effective at efficient low-cost conversion and control of iron content in leach streams in addition to targeted dilute metal recovery.[1-6] This powerful new capability provides a new treatment opportunity to control leach solution ferric (Fe+3) and ferrous (Fe+2) tenors to enhance leach operation production."

Jan 1, 2015