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By R. S. J. Toit

Discussion: T. L. Gibbs,* (Honorary Vice-President and Fellow): In terms of the Pneumoconiosis Compensation Act of 1962, a Pneumoconiosis Risk Committee was established whose function it is to estimate (by whatever means the committee deems fit) in respect of every controlled mine the pneumoconiosis risk to which persons employed in a dusty atmosphere at that mine are exposed. In estimating such risk the committee may estimate different risks in respect of individual mines or parts of mines or classes or groups of mines or occupations or localities at mines. The pneumoconiosis risk may be reviewed and re-estimated at any time. The Act provides further that the General Council for Pneumoconiosis Compensation shall apportion the levy imposed on owners of controlled mines on the basis of the pneumoconiosis risk determined by the risk committee and the numbers of persons employed in a dusty atmosphere. The task of the risk committee is a most responsible one and also a very difficult and complex one in view of the many different types of mines, rock formations, dust conditions, etc. Quite obviously, comparisons between mines cannot be made on dust concentrations alone as different mineral dusts have different toxicity or pneumoconiosis response factors. However, with its present knowledge, the risk committee is satisfied that the risk at mines, other than coal mines, is related to the mean quartz-equivalent dust concentration to which persons are exposed and the estimation of risks is based on this relationship. From the above, it will be clear that the work done by Dr du Toit on the problem of basing the current rate of levies to provide for pneumoconiosis compensation on the current dust hazard at mines has been of immense value to the risk committee. Up to now the risk committee has not been able to obtain complete and accurate information on the dust exposure of persons at all mines - and, in fact, it is doubtful whether it will be economic or practicable to obtain this in the foreseeable future - but reasonable assessments have been possible from routine dust sampling in some cases and from periodic comprehensive dust surveys in others. As a temporary measure the risks of some mines were estimated initially on a group basis relating to average dust conditions and the type of rock and mineral mined, but as more information became available, differentiation between individual mines became possible. It is the aim of the risk committee to eventually apply such a differentiation in all cases and to ensure that within the bounds of practicability each mine pays for its risk and for its risk only. In this connection, the relationship between the levies and the amounts actually paid out in compensation are examined regularly. In conclusion, I wish to add my congratulations to the author on his excellent paper. His findings will assist materially in the just administration of that very important piece of beneficial legislation, the Pneumoconiosis Compensation Act. G. K. Sluis Cremer MD (Visitor): Dr du Toit has made a valiant attempt to relate dust hazard and the rate of collecting funds for the purpose of paying compensation for Pneumoconiosis. In doing so he has had to make a number of assumptious, some of which touch on the medical aspects of pneumoconiosis. It is worth discussing whether these assumptions are justifiable. Pneumoconiosis is defined in our Pneumoconiosis Act as permanent disease of the cardio-respiratory organs which is caused by the inhalation of mineral dust. To a non-medical person this definition has probably a clear cut meaning. The doctors however have to deal with such conditions as silicosis and asbestosis where there is a well defined dose response relationship to the inhalation of quartz and asbestos respectively and on the other hand chronic bronchitis where the relationship to dust inhalation is poorly defined and where certainly no clear dose response relationship has emerged after many investigations in this country and overseas. Nevertheless since 1953 about half of our certifications for Pneumoconiosis are on the grounds of chronic bronchitis i.e. the X-rays show no evidence of silicosis, asbestosis or other relevant disease. This fact must affect Dr du Toit's computations. The next assumption we should examine is the manner in which toxicity factors have been allocated to the various mineral species. These allocations have in part been based on a restricted number of animal experiments carried out overseas but mostly in South Africa by Webster at the Pneumoconiosis Research Unit. To extrapolate the findings in a relatively small number of animal experiments to the expected reactious in man is a notoriously dangerous exercise. Furthermore the bracketing together of all silicates (except asbestos) and the insoluble metal oxides is entirely unacceptable. Talc (a hydrated silicate of magnesium) and muscovite mica (a silicate of aluminium and potassium) cause pneumoconiosis in their own right. On the other hand

Jan 3, 1970

By S. A. Hosseini, O. Asghari

"The quantification of mineral resources and evaluation of process performance in mining operations at Gole Gohar iron ore deposit requires a precise model of the spatial variability of three variables (Fe, P, and S) which must be determined. According to statistical analysis there are complex multivariate relationships between these variables such as stoichiometric constraints, nonlinearity, and heteroskedasticity. Due to the impact of these complexities in decision-making, they should be reproduced in geostatistical models. First of all, in order to maintain the compositional and stoichiometric constraints, additive log-ratio (alr) transformation has been applied. In the next step cosimulation, using stepwise conditional transformation (SCT) and sequential Gaussian simulation (SGS) has been used to simulate multivariate data. Through statistical and geostatistical validations it is shown that the algorithms were able to reproduce complex relationships between variables, both locally and globally. IntroductionThe key steps in mining projects are the quantification of mineral resources, definition of mining reserves, and production scheduling. They rely on the construction of a block model that is used to represent basically the spatial distribution of ore grades (Montoya et al., 2012). The determination of grades and tonnages affects risk assessment and economic evaluation of mining projects. Evaluation of process performance in mining operations requires geostatistical modelling of many related variables (Barnett and Deutsch, 2012). Iron ore quality is characterized by multiple variables: not only the iron grade but also the contaminants that interfere in the subsequent steel manufacturing processes. Consequently, the spatial variability of multiple variables must be determined. Key variables are frequently correlated, and such correlations must be honoured during estimation and simulation. Data from iron ore deposits constitutes compositional data; furthermore, relationships the between assay data are often heteroskedastic."

Jan 1, 2016

By R. M. Lamya

A semi-empirical kinetic model was developed for the atmospheric leaching of a Ni-Cu matte in copper sulphate-sulphuric acid solution. Kinetics of the leaching process was studied as a function of initial copper ion concentration, initial acid concentration, temperature, stirring rate and particle size distribution. The kinetic model was developed on the basis of the leaching mechanism and chemical reactions of the leaching system investigated, and was evaluated by comparing the model predictions to experimental data. The model was found to satisfactorily fit the trends in the leaching of the metals, namely copper, nickel, cobalt and iron.

Jan 1, 2009

By M. Krasowska, W. Skinner, R. K. Asamoah

Understanding chemical interactions at solid-liquid interfaces have played a pivotal role in improving mineral flotation performance, increasing the rate of mineral crystallisation and profitable leaching of valued minerals and metals. This paper highlights gold leaching with links to surface and interfacial chemical processes occurring, and opportunities to maximise extraction while reducing usage of more recent scarce resources. From the review, there is a significant link between surface and interfacial processes and gold leaching performance. Evidently, gold leaching kinetics could be increased by changing leaching conditions, including manipulating the surface and interfacial interactions. Control of surface and interfaces during gold extraction could enhance rapid, smarter gold extraction and mitigate formation of passivation layers. Keywords: Surface and interfaces, refractory ores and concentrates, gold leaching, reaction mechanism and kinetics

Jan 1, 2020

By P. Maais

This paper gives an account of the development of a plant for the differential flotation of mixed sulphide ore, special reference being made to the separation of copper and zinc sulphides. The uniqueness of the geology, mineralogy, and metallurgy of each complex ore-body is stressed. Consideration is given to the scale-up of laboratory data, and to some of the factors involved in the design of milling and flotation plants for this type of ore. Process control and development are discussed, as are the human requirements for the optimum operation of a concentrator.

Jan 1, 1980

By J. Ojeda, R. Kuyvenhoven, M. Ziemski M

This paper focusses on the identification of operational opportunities in a 1100 tph pellet plant to reduce the specific energy consumption in its comminution circuit, which is designed to process magnetite ore and produce pellets to be used as raw material in the iron and steel industry. The assessment is carried out through a frequency analysis for three of the four processing lines of the plant, consisting of one ball mill each with an installed power of 4.5 MW and 280 tph of mill throughput design capacity. The methodology, as described in this paper, facilitates the visualisation and quantification of plant performance and provides a good first approach to prioritise alternatives for optimisation. In a pellet plant, grinding is a critical stage due to its high energy consumption and its major impact on the physical properties of the iron pellets, which quality depends to a large extent on grind size and Blaine index. From the evaluation that was performed it can be concluded that production line 2 has the lowest specific energy consumption of 15.1 kWh/t, while line 1 has the highest with an average of 16.6 kWh/t for the same type of ore. On the basis of the results and current operational practices, it is recommended to increase the average mill throughput from 240 tph to 265 tph, translating into specific energy reduction of 10%, without affecting the chemical and physical properties of the final product. The implementation of an HPGR for regrinding the magnetic concentrate is proposed to assure adequate specific surface area in case grinding coarser becomes an alternative, which would also be beneficial for the subsequent water recovery stages. Keywords: Iron ore pelletisation, grinding circuit, energy efficiency, particle size, frequency analysis

Jan 1, 2020

By D. Govender

Theoretical flotation models suggest that there is a positive relationship between bubble-particle collision rates and turbulent kinetic energy dissipation. Fine particle flotation performance is generally enhanced by increased collision frequency and hence higher energy dissipation. Contrarily, increased turbulence in the rotor-stator region is related to higher detachment frequency of the coarser size range. Therefore, the optimal modes of recovery for the ?fine? and ?coarse? size classes appear to be diametrically opposed. Industrial applications have previously confirmed that applying greater power to flotation slurries yields significant improvements in fine particle recovery. However, recovery of the coarser size class favours a different flotation environment. An improvement in the flotation kinetics of the fine and coarse size classes, provided there is no adverse metallurgical influence on the intermediate size ranges, is obviously beneficial to the overall recovery response. Managing the local turbulent kinetic energy dissipation, and hence the power imparted to the slurry, offers the benefit of targeting the particle size ranges exhibiting slower kinetics. FLSmidth recently introduced the practical implementation of this concept. In principle, it decouples flotation regimes where fine and coarse particles exhibit preferentially recovery. In the case of naturally aspirated machines (Wemco®), it is referred to as Hybrid Energy Flotation? and incorporates at least three phases: ? Standard flotation machines (standard energy input, rotor speed (r/min), rotor size/type) at the beginning of the row, where flotation is typically froth-phase limited and operational and set-up parameters have a limited influence on the recovery ? Higher-powered flotation machines (high rotor speed, high-power rotor size/type) at the end of the row to improve fine particle recovery ? Lower-powered flotation machines (low rotor speed, low power rotor size/type) to enhance coarse particle recovery. A CFD-based flotation model is used to highlight the effect of turbulent dissipation energy on attachment and detachment rates. Preferential collection zones for ?fine? and ?coarse? particles are predicted for both forced-air and naturally aspirated machines. The greater predominance of UG2 ore types, coupled with the skewed feed distribution of platinum group metals (PGMs) to the finer size fractions, suggests that PGM flotation circuits are not designed for optimal recovery across the size distribution. The application of the hybrid energy concept to PGM flotation offers a possible shift towards a more efficient flotation circuit solution through a managed distribution of energy.

Jan 1, 2012

Abstract A new approach is introduced for study of the behaviour of geotechnical strength parameter prior to slope analysis to ascertain whether strength parameters of slope materials are homogenous or heterogeneous at different mine depths. The strength parameters used for the study are uniaxial compressive strength, tensile strength and shear strength. The analysis is based on statistical analysis of variance technique for one-way classification. The application of the technique is given through a case study in an openpit mine. Auszug Eine neue Annäherung wird für Studie des Verhaltens des geotechnischen Stärke Parameters vor Steigunganalyse eingeführt, um zu ermitteln, ob Stärke Parameter der Steigungmaterialien homogenous oder an den unterschiedlichen Grube Tiefen heterogen sind. Die Stärke Parameter, die für die Studie verwendet werden, sind einachsige zusammenpressende Stärke, Dehnfestigkeit und Scherstärke. Die Analyse basiert auf statistischem varianzanalytische Technik für Einwegklassifikation. Die Anwendung der Technik wird durch eine Fallstudie in einer openpit Grube gegeben. Abstrait Une nouvelle approche est présentée pour l'étude du comportement du paramètre géotechnique de force avant l'analyse de pente pour établir si les paramètres de force des matériaux de pente sont homogenous ou hétérogènes à différentes profondeurs de mine. Les paramètres de force utilisés pour l'étude sont résistance à la pression uniaxiale, résistance à la traction et résistance au cisaillement. L'analyse est basée sur statistique la technique de l'analyse de variance pour la classification à sens unique. L'application de la technique est donnée par une étude de cas dans une mine à ciel ouvert.

Jan 1, 2003

By R. L. Castro

Currently, in several caving operations, the spacing between the drawpoints is determined by consulting Laubscher's design guide (Laubscher 1994, 2000), a methodology based on the gravity flow characteristics of the caved rock. Laubscher's methodology is based upon the height of interaction between adjacent flow zones, but does not allow calculation of primary recovery for a given layout. In this paper the authors present a technical and economic methodology based on the flow that occurs near the drawpoint and the associated development costs to estimate the optimal spacing. The flow model at the drawpoint was validated at the El Teniente mine, which extracts coarse caved rock. To validate the flow model, small-scale simulations using drawpoint clusters were conducted and results compared to extracted grades, marker recovery, and drill holes to determine ore remnants that are part of the production control programme at the mine. The results indicate that primary recovery depends on the height of interaction, which varies with the friction angle of the caved rock and the spacing between adjacent drawpoints. Primary recovery estimations indicate values from 85 per cent to 97 per cent depending on the drawpoint spacing used. Extrapolations were then conducted to estimate the primary recovery for different drawpoint configurations planned to be used in the New Mine Level of the mine. The results indicate that the optimal drawpoint spacing is 32 m x 20 m with a through length of 18 m. The methodology developed may be used to estimate optimal drawpoint spacing for block caving mines under different metal prices and mine cost conditions.

Jan 1, 2012

By D. Duncanson, R. J. Davidson, C. G. S. Schmidt, G. A. Brown, J. D. Taylor, N. W. Hanf

The development of a cyanidation route for the treatment of gold-plant gravity concentrates is described. This work was carried out as a natural consequence of earlier improvements to the recovery of gold in the gravity sections of existing gold plants. Concern about the environmental aspects of the conventional amalgamation process was further motivation in the development of an alternative procedure. It was found that the partial pressure of oxygen in solution was the most critical reactionrate determining factor. The rate of gold dissolution was shown to be controlled by the reaction rate below approximately 25°C and by diffusion above that temperature. Thus, the efficiency of pulp agitation and oxygen partial pressure permitted a high degree of control over the rate of gold dissolution. The use of oxygen rather than air significantly increased the dissolution rate of both gold and silver. The solubilities of sodium, calcium, and potassium aurocyanide complexes under simulated reaction conditions were studied, and it was established that the values for the sodium and calcium complexes were limited, requiring the use of lower pulp densities and higher reaction temperatures for the treatment of very high-grade concentrates. The presence of excessive amounts of tramp iron in such concentrates of up to 25 per cent by mass was found to result in poor gold dissolution owing to the cementation of gold under certain reaction conditions. The maintenance of high oxygen partial pressures, together with high cyanide concentrations, high pH levels, and the presence of calcium in the system, all aided in passivating the tramp iron. Copper, gold, and iron were shown to be the main cyanide-consuming elements. Optimum gold dissolution was obtained in a closed bench-scale reactor incorporating a flotation-machine type of agitator for effective pulp agitation and oxygenation, the oxygen being recirculated. The reactor was designed to operate under a very small positive pressure. After reaction times of 2 to 6 hours at temperatures in the region of 30°C, both the gold and the silver dissolution averaged 99,S per cent. In the case of very high-grade concentrates, it was shown that gold could be floated in the same reactor by drawing off the flotation concentrate through a port in the reactor. A flotation recovery of 87,4 per cent of the gold in 3,9 per cent by mass was obtained. The recovery of osmiridium from cyanide-leach residues and the electrowinning of gold from the pregnant liquors were also considered as processing aspects in the treatment of gold-plant belt concentrates. Final table tailings with a gold concentration of 10to 12 gft were obtained. The results of the investigation strongly suggested that an alternative cyanidation route for the treatment of gold-plant concentrates was technically feasible, provided the system included effective agitation and oxygenation. In the case of lower-grade concentrates, cyanidation followed by the electrowinning of gold appears to be the simplest route, while, for high-grade concentrates, flotation and smelting of the concentrate followed by cyanidation of the flotation tailings are suggested. The use of oxygen rather than air for sparging the pulp would depend largely on the grade of material to be treated. A preliminary comparison of the costs related to the amalgamation and cyanidation processes for the recovery of gold from such concentrates indicated very similar capital and operating costs. It was concluded that other considerations, e.g. toxicity, safety, and lower labour requirements, were more important than such small cost differences. Furthermore, the 'opening' of the gold-plant gravity circuit, which would be made possible by a cyanidation route, would further reduce the operating costs because of the subsequent decrease in the tonnage to be treated.

Jan 1, 1978

By Monica M. Cole

The Empress nickel/copper deposit west of Gatooma in Rhodesia occurs within gabbro and amphibolite, disposed at the contact of a granodiorite stock (Barebottom Hill) and the surrounding greenstones of the Archaen Bulawayan System. The orebody has a pipelike form and a poor surface expression due to plantation of the area by Miocene (Africa) and later Victoria Falls erosion cycles. Barebottom Hill represents a monadnock remnant in the geomorphological surfaces while traces of the once larger Empress orebody have been removed. Limitations in soil geochemistry necessitated both studies of the vegetation ecology and the biogeochemistry of the area, both of which were anomalous. The use of geobotany was found to be restricted but biogeochemistry offers a most effective prospecting tool and was found to define the sub-outcrop of the ore-body more precisely than soil geochemistry since these methods reflect and differentiate anomalies emanating from bedrock mineralisation and those due to surface phenomena.

By A. van den Berg

Mining of sand in South Africa is rapidly growing to sustain an increasing demand for sand for building purposes. Although mining of sand is regulated by environmental legislation, such as the National Environmental Management Act 107 of 19981, previous bad mining practices have left areas of land degraded and vulnerable to erosion. This study was conducted in the Seringveld Conservancy, where mining of sand has left the landscape with a degraded and unsightly appearance, and where little rehabilitation of the original vegetation has taken place. The aim of the study was to develop rehabilitation techniques for the degraded mined soils on two sand mines, Boekenhout Sand and Krokodil Sand, and to develop an overall strategy of revegetation by regenerating key plant species. Techniques for regenerating indigenous tree species cover, using modified mined sludge if topsoil is not available, were used to develop a practical and cost-effective strategy to be used in revegetation. A comparative trial was used to cultivate indigenous tree species in different soil mixtures. The study is important as it provides new information on the rehabilitation and revegetation of sand mined areas in the Seringveld Conservancy. This study will determine if alternatives could be used to replace topsoil on mined areas where none is available. The study is needed to determine whether revegetation of the mined areas would be possible using indigenous plant species that are difficult to grow. The overall results indicate that replacing topsoil was successful for various modified soil mixtures that could sustain the growth of indigenous vegetation on the sand mines. Different indigenous tree species require different modified soil mixtures for successful propagation. A revegetation strategy was developed to complement and enable the rehabilitation of the mined areas in the Seringveld Conservancy. Keywords Rehabilitation, revegetation, Seringveld, sand mines, Burkea africana, topsoil, germination trials.

Jan 1, 2011

By A. Karadogan

Decision making can be defined as the selection process of the best routes from the alternatives in order to achieve a goal, and mostly involves uncertainty. Additionally, mostly qualitative variables (weak rock, massive ore deposit, etc.) are in question. Mine planning engineers often use their intuition and experience indecision making. As fuzzy set theory has been used since 1970, these uncertainties are easily evaluated in the decision-making process. Real world study is decision making under vague constraints of different importance, involving uncertain data (qualitative variables), where compromises between antagonistic criteria are allowed. This paper presents a new approach in the selection of an underground mining method based on fuzzy set theory for the Ciftalan Lignite Site located close to Istanbul in Turkey. The physical parameters such as geology and the geotechnical properties of ore, hanging and foot wall, economic effects, environmental effects, are established with field and laboratory tests together with the determination of other qualitative variables. Meanwhile, some qualitative variables dealing with the matter was described according to the view of a number of experts. Then fuzzy set theory is applied to these parameters, considering the available underground methods in order to choose the proper method. At the end of the evaluations, the room and pillar method with filling was determined as the most suitable method for the test site. Keywords: Decision making, fuzzy set theory, underground, mining, method selection

Jan 1, 2008

By J. H. Cloete, S. M. Bradshaw, D. K. Chibwe

"The primary function of a tundish in the steelmaking industry is to serve as a buffer tank, accepting molten steel from the batch ladle process and allowing it to be cast continuously. However, modern steelmaking has more stringent demands for the quality of the steel product, requiring increased control over the properties of the molten steel before casting. For this reason tundishes have been developed as metallurgical reactors to serve as the final step in refining of the molten steel by removing non-metallic inclusions, preventing the formation of new inclusions, and promoting chemical and thermal homogeneity. In this study the flow behaviour in a four-strand tundish was investigated by means of a half-scale water model as well as numerical modelling. Both the numerical study and physical model were used to characterize residence time distribution (RTD) in the vessel and calculate properties pertaining to the tundish flow regime. Three different tundish configurations were investigated: a bare tundish with no flow control devices, a tundish with a turbulence inhibitor and a tundish with both a turbulence inhibitor and a dam.The physical and numerical models showed that a tundish without flow control devices was prone to significant short-circuiting. A tundish with a turbulence inhibitor was shown to be successful in preventing short-circuiting and provided surface-directed flow, which aids inclusion removal in the slag. Despite the benefits of the use of turbulence inhibitors, it was observed that the upward-directed flow increased the maximum turbulence kinetic energy near to the surface by approximately 120% compared with the bare tundish. Therefore the potential for slag entrainment should be considered during the design and operation of tundishes utilizing turbulence inhibitors."

Jan 1, 2014

By J. Yianatos, P. Vallejos

In the last decades, the exponential increase in the cells’ volume resulted in significant advantages such as investment costs, footprint and energy savings. However, in larger size cells, despite the increased diameter/height ratio, new constraints arose related to the need for decreasing the larger froth transport distances to enhance the froth recovery. Thus, the use of froth crowders and internal launders became compulsory to maintain the froth transport distances but decreasing the ratio between gas and collected mineral flowrates. Consequently, the bubble load will increase until reaching a critical bubble surface coverage. In this paper, the concentrate carrying capacity (tph/m2) is described in terms of the bubble surface coverage (bubble loading) at the pulp-froth interface and the froth recovery (froth transport) and is evaluated as a function of the cells’ volume and operating variables. A sensitivity analysis, based on industrial operating and design conditions, such as superficial gas rate, particles size, froth crosssectional area and cells’ volume, was developed for evaluating the metallurgical performance of cells from 100 to 630 m3. Results show that limiting carrying capacity can arise for the whole range of cells’ volume, depending on critical operating conditions, particularly in first rougher cells and cleaning stages of industrial flotation circuits. The increase in cells’ volume consistently increases the bubble loading (bubble surface coverage) under all conditions, approaching the limiting conditions more rapidly in the case of cells without internal launders. Otherwise, the limiting condition was achieved when the particle size DPS decreased from 50 to 20 (μm) and for superficial gas rates significantly less or larger than 1 (cm/s). The use of internal launders allows for increasing the range of the operating conditions needed to reach a certain carrying capacity. Keywords: Bubble carrying capacity, flotation cells, bubble surface coverage, cells’ volume

Jan 1, 2020

By A. J. Barrett

Backfilling at Vaal Reefs during the experimental phase has been carried out using cyclone-separated tailings which are transported underground hydraulically by means of a borehole. The selected tailings are piped from the borehole to the stope and then, after the addition of a flocculant, deposited in place via single or multiple nozzles. The successful performance of the backfill/stope system relies not only on the actual quality of the placed material, but also on the effective operation of stope filling. The success of stope filling relates to the complex, time- dependent interaction of backfill, stope and barricade materials, and the transport and placement procedures used. A comprehensive laboratory testing programme was carried out on backfill materials at Vaal Reefs in conjunction with the experimental stope- filling operation. The range of testing techniques corresponds to the requirements of each stage of the backfilling process. Where necessary, new or alternative techniques were sought during the course of the experiment to satisfy and facilitate better understanding of the different processes. These techniques comprise both routine quality control testing and research-oriented testing. The laboratory testing techniques appropriate to each stage of the backfill process are briefly discussed. This paper presents the main conclusions of the study and identifies areas for further research.

Jan 1, 1988

By G-L. Wu, X-B. Liu, C-Y. Zhou

"The static recrystallization behaviour of Ti-Nb microalloyed high-strength steel during hot deformation was studied by conducting double-hit hot compression experiments using a Gleeble-3500 thermomechanical simulator. The effects of deformation temperature, strain rate, strain, and initial austenite grain size on the static recrystallization fraction are discussed. The static recrystallization kinetics were modelled, and the results show that the static recrystallization fraction increased with deformation temperature, strain rate, and strain and interpass time. The static recrystallization activation energy Qs was 326.05 kJ mol-1. Comparison of the experimental results and predicted results indicates that the effects of deformation parameters on the static recrystallization in multistage hot deformation are significant. The predicted results are in good agreement with the experimental results. IntroductionIn hot-forming processes, complex microstructures are often induced by multiple hot deformation mechanisms (Zhang et al., 2014; Liang et al., 2015). The softening behaviour during hot processing has generated considerable interest because component properties are influenced significantly by the corresponding microstructural evolution (Wu et al., 2010). It is well known that dynamic recrystallization (DRX); metadynamic recrystallization (MDRX), which occurs by the growth of DRX nuclei during intervals of deformation; and static recrystallization (SRX), which occurs by nucleation and growth during the intervals of deformation, can significantly alter the austenite grain size (Chen et al., 2015. Chen, Sui, and Cui, 2014; Mao et al., 2014). The long interpass times allow complete SRX to take place if the steel is being rolled above the interpass recrystallization stop temperature (Tnr), i.e. in the absence of carbonitride precipitation (Siciliano, 2000). In recent research, microalloying technology coupled with new-generation thermomechanical control processing (NG-TMCP) has proved efficient in achieving the proper balance between strength, toughness, ductility, and formability by means of a suitable combination of chemical composition and thermomechanical treatment parameters (Shukla et al., 2012; Bandyopadhyay et al., 2011). The alloying elements Nb, V, Ti are widely used in high-strength low-alloy (HSLA) steel to achieve the desired strength and toughness properties with solid-solution strengthening, precipitation hardening, grain refinement, and dislocation strengthening (Opiela, 2014; Chen and Yu, 2012). The wide applicability of alloying elements in HSLA steel is due to the fact that heat treatments are not required after forming of the parts, which results in time and cost savings."

Jan 1, 2017

By T. van Heerden

A range of supported gold catalysts was prepared by ion exchange, varying many of the preparation variables, including concentration in the precursor solution, washing procedure, as well as drying and calcination procedures. These catalysts have been characterized extensively. TEM images show essentially the same crystallite size distributions, between 2?5 nm, for almost all catalysts, the only exception being catalysts not washed in ammonia, which did not show any small crystallites. Additional characterization with SEM yielded an interesting discovery. Catalysts that appear identical on the TEM also contain some large crystallites in the range of 50?500 nm. Differences in dispersion due to the drying procedure not seen on the TEM can now be observed. Oxygen chemisorption is being investigated as an additional method to characterize gold based catalysts to complement the typically used electron microscope techniques.

Jan 1, 2012

By C. Tokoro, T. Kato

The objective of this study is to improve the shrinking core model for particles with a particle size distribution and clarify the activation mechanism of rare earth elements dissolution by mechanochemical activation. To achieve this objective, the method, called the doubly integrated micromodel, was applied for a shrinking core model in this study. This method consists of integrating the batch leaching rate of a single particle over the distribution of both feed particle size and reactor residence time to arrive at the fraction unleached. The usefulness of the shrinking core model improved by doubly integrated micromodel was confirmed by comparing it with a shrinking core model. To apply the shrinking core model improved by doubly integrated micromodel to rare earth elements dissolution from weathered residual rare earth ores by mechanochemical activation, leaching experiments were performed for grinding samples by planetary ball milling. The reaction equation of mechanochemical reaction by planetary ball milling for weathered residual rare earth ores was investigated by x-ray absorption fine structure analysis. As a result of a kinetics study, the rate-determining process of leaching changed from reaction to diffusion reaction control by planetary ball milling. Based on these results, it was revealed that the main mechanism of activated rare earth elements dissolution from weathered residual rare earth ores was a mechanochemical reaction by planetary ball milling. Keywords: Mechanochemical reaction, particle size distribution, shrinking core model

Jan 1, 2020

By M. Kumral, S. Hmoud

Optimising the configuration of infill drill holes is an important step during mineral exploration campaigns. However, this optimisation process encompassing all possible drilling configurations within a mineral deposit is highly combinatorial and hard to solve in a reasonable time. This paper proposes using spatial clustering algorithms to divide the orebody into contiguous zones and target the best zones with infill drilling in order to reduce the size of this optimisation problem. Several clustering algorithms are assessed in a spatial context on hypothetical datasets. This evaluation shows that the hierarchical density-based spatial clustering application with noise (HDBSCAN) algorithm can be used in combination with the uniform manifold approximation and projection (UMAP) dimensionality reduction algorithm to identify contiguous zones in the orebody.

Sep 1, 2021