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By C. A. Herbert

"The Bureau of Mines for a number of years has conducted experiments at its experimental mine near Bruceton, Pennsylvania, on the explosibility of coal dust, with particular reference to dust explosions in coal mines, and the knowledge so rained may well be applied to the handling of coal dust at industrial plants and elsewhere.Powdered coal is coming into use more and more as a fuel, and the dangers incident to its use should be recognized and guarded against, as a number of accidents have occurred in recent years due to ignorance of this danger or to carelessness.Within the past three years two very serious accidents, under almost identical circumstances, have occurred on the surface at two different coal mines in Southeastern Iowa, due in each case to the sudden ignition of a cloud of fine coal dust.The first accident resulted in the burning of six men, three of them fatally; the second burned eleven; three men died as a result of their burns.The mines in the Southeastern part of Iowa, where these two disasters occurred, are operating in a thin coal bed averaging about three feet in thickness, and are worked on the long-wall advancing system similar to that of Northern Illinois.The miners in this section are paid on a screened coal basis; in other words, receive no pay for the fine coal. As a result they use forks in loading the coal into the mine cars, and naturally a considerable quantity of coal is left along the roadways. Subsequently this fine coal, together with the roof rock that is taken down to give sufficient height on the roadways, is loaded into cars and dumped in piles on the surface. This roof rock is a block, oily shale and the contribution of fine coal and oil shale gives ample combustible material to thoroughly burn the rock as it is dumped."

Jul 1, 1923

By Joseph E. Matta, John C. LaScola, Fred N. Kissell

The Bureau of Mines investigated coal storage silos to determine how gassy coal must be for methane accumulations in a silo to become hazardous and where such accumulations are likely to occur. Methane concentrations were measured in the open space above the stored coal pile, in the pile, and in the reclaiming area. No methane layering was found in closed-top silos. Reclaiming areas were as gassy as the top part of the silos. Coal samples were collected from the conveyors entering the silos in order to assess the gassiness of the coal. No simple correlation was found between the gassiness of the coal stored and the measured methane concentrations. However, at mines where the average 24-hour gas emission from the conveyor belt samples was 14 ft3/ton or more, fans or open tops were used. It appears that a large fraction of the methane released during storage remains in the void space between the coal particles.

Jan 1, 1981

To assist coal mine operators and regulatory agencies in selecting the most appropriate method to treat coal mine drainage utilizing expert system computer technology. The software package is called the Coal Mine Drainage Treatment PRO. Approach Experts in the field of coal mine drainage treatment were interviewed to determine their methods of assessing mine drainage treatment problems and their rationale for selecting a treatment protocol. These diagnostic, selection, and design criteria were codified in an interactive set of computer programs. Expert systems permit the user to input specific site data and receive treatment advice customized to the user's site and treatment objectives. How It Works The Coal Mine Drainage Treatment PRO package developed by the U.S. Bureau of Mines (USBM) consists of four programs or modules: (1) a control module, (2) a mine drainage treatment tutorial module, (3) a treatment advice module, and (4) a reference module (figure 1). A context-sensitive HELP Facility is also provided.

Jan 1, 1996

By Foster Fraas

In this Bureau of Mines report, use of the photoemission of electrons to produce electric charges for the electrostatic separation of sonic dispersed minerals, which had previously been ground to pass a 43µ-opening sieve, is demonstrated. It appears that many of the oxides, carbonates, sulfides, and arsenides will respond to photoemission. Minerals least responsive are the oxides of silicon, the oxides of aluminum, and minerals that have a high concentration of these oxides. Although several synthetic ore mixtures did not yield to complete separation in a one-stage operation, it is probable that preliminary neutralization of the initial electric charges produced by powder dispersion will provide complete separation. That the separation can be carried out in air and without the use of reagents or heating, which are required in the present practice of electrostatically separating coarse granular feeds, is of special significance.

Jan 1, 1972

By Kenneth M. Earl

The purpose of this investigation was to obtain subsurface information on the John Burdette barite-fluorite deposit, Garrard County, Ky. The deposit was intersected in each of five inclined diamond-drill hales aggregating 1,163 feet. All holes were drilled from the hanging wall of the deposit; the inclinations varied from minus 41° to minus 75°. Disseminated metallic sulfides were noted in the drill cores from holes 1, 2, 4, and 5. The deepest drilling was hole 5, which intersected the deposit at approximately 490 feet down dip. Visual inspection of the cores did not indicate mineralization of economic importance; therefore, no chemical analyses were conducted. Condensed logs of diamond-drill cores are included in this report. All drill cores were shipped to the Bureau of Mines core library in Minneapolis, Minn., for future reference,

Jan 1, 1959

By Fred N. Kissell, J. E. Matta, J. C. LaScola

The methane gas emitted from coal samples collected from the conveyor belts dumping into silos was measured by the Bureau of Mines. Approximately 50 pct of the total gas desorbed into a sealed can within 1 week was released during the first 24 hours. No simple correlation between the gassiness of the coal stored and the methane concentration in the silo open space above the coal was found. This was probably because the gassier coals were stored in open-top silos, which were better ventilated. Although the methane concentration in the open space above the coal pile was less than 1 pct for all 34 silos investigated, a methane measurement in the coal pile showed that high methane concentrations can exist. The methane released in the pile appears to accumulate and not liberate freely into the open space above the coal pile. Probably this gas is released during reclaiming operations, but further research is required to substantiate this claim.

Jan 1, 1978

To improve a miner's chance of survival during an emergency by providing immediately avail-able breathable air and protection from toxic gases until a longer-duration breathing apparatus, stored nearby, can be reached. Approach: A belt-carried apparatus which can provide a closed-circuit atmosphere for ten minutes breathing has been developed under a Bureau of Mines contract. How It Works: Water vapor and carbon dioxide in the user's exhaled breath are removed, and oxygen is supplied, by chemical reactions. When the user exhales into the mouthpiece, water vapor in his breath reacts with potassium superoxide (KO2) stored In the canister to produce oxygen. The other product of this reaction (KOH) reacts with carbon dioxide and removes it from the air. The oxygen-enriched air then flows from the canister into two breathing bags. When user inhales through the mouth, that air is drawn out of the bags, makes a second pass through the chemical-containing canister, and flows into the mouthpiece tube. A nose clip is worn to seal off the nasal passages.

Jan 1, 1975

By C. M. K. Boldt

This U.S. Bureau of Mines report presents a study of three typical tailings samples as potential cemented backfill in underground mines. The testing series was unique in that the pulp densities of the samples were all above 75 pct solids. Test results included dry density; slump; percent settling after 28 days of curing; tensile strength after 28, 120, and 180 days of curing; and unconfined compressive strengths after 7, 28, 120, and 180 days of curing. The physical properties of the various test mixtures were further analyzed using linear and nonlinear statistical methods to produce correlations and mathematical equations. Physical properties were used to determine the influence of mix additives and as input for numerical modeling studies of backfill. The mathematical relations were used as a predictive tool in determining the suitability of various materials as backfill.

Jan 1, 1989

By A. N. Styler

As part of its water-jet assisted rock cutting research, the Bureau of Mines has initiated a study into the mechanism of rock fragmentation by water-jet-assisted mechanical tools. The objective of this research is to increase coal extraction efficiency by seeking an improved understanding of the synergistic relationship between mechanical cutters and water jets, enabling the design of more effective cutterheads. Rock chips collected during laboratory traverse speed jet-assisted cutting tests were analyzed with respect to the size distribution of the chips and the forces measured during cutting. As the water-jet pressure was increased, the size distribution of the product became coarser with V-face type cutting tools producing less fine material than conical cutting tools. Fracture mechanics theory accounted for less than 10 pet of the energy consumed during fragmentation of the rock. The energy consumed by processes other than rock breakage decreased with the use of water jets and increasing advance rate.

Jan 1, 1987

By Sabri Ergun

The method of constant compositions involves the determination of the time required for the attainment of a given conversion at various temperatures. Heretofore, it has been used in evaluating the energy of activation only. A development of the method, made in the present study, makes possible the evaluation of the functional dependence upon composition and the frequency factor in addition to the energy of activation. INTRODUCTION Kinetics of reactions are best analyzed in the light of the mechanism, energy requirements, and forces involved in the reaction. Such physico-chemical information is not often available in solid state phase transformations. The reaction rates are followed by changes in a physical property during the course of the reaction, and repeating the experiment at different temperatures permits the determination of activation energy only. The possibility of a complete kinetic analysis by such a purely "phenomenological" approach has been questioned.4/ In this report a method is developed making possible the evaluation of the functional dependence upon composition and frequency factor in addition to the energy of activation. The application of the method to a study of solid state order-disorder changes is demonstrated.

Jan 1, 1960

By R. L. Montgomery

The heats of solution of erbium chloride in water and in hydrochloric acid and of erbium oxide in hydrochloric acid were determined. The results reveal a discrepancy of 10.5 kcal. per gram-atom between the heats of combustion and solution of erbium reported in the literature, the heat of combustion being more negative. The heat of combustion of erbium t4)4 and its heat of solution in hydrochloric acid (1, 18) have been reported in the literature. The heat of solution of erbium chloride was determined in two studies (2, 19). The present work was undertaken to check the reported heats of solution of erbium chloride and to determine the heat of solution of erbium oxide in hydrochloric acid. The latter quantity permits the heats of combustion and solution of erbium to be compared for mutual consistency. It was also desired to determine the degree of similarity between the thermochemistry of yttrium and erbium.

Jan 1, 1961

By A. Visnapuu

The Bureau of Mines investigated carbonyl processing techniques for the recovery of the critical metals Ni, Co, Mn, and Cr from domestic primary and secondary sources. In most cases, the source materials require reductive precarbonylation treatment to metallize the contained Fe, Ni, and Co compounds to render them reactive with CO. The critical metals were recovered either by direct conversion to the respective carbonyls or as upgraded products by carbonyl removal of an undesirable metal. Best metal-to-metal carbonyl conversion was under CO pressure, from 80 atm upward, and at 1400 C. Carbonylation was accelerated by the addition of HzS in small quantities. CO pressure, temperature, promoter and pretreatment trends, and other factors enhancing metal carbonyl formation are presented.

Jan 1, 1987

By Oliver Bowles

"Waste Granite in the Barre, Vermont, District: Waste in the great granite center at Barre, Vermont, consists of three types of material, the rough blocks rejected at the quarries on account of imperfections, the chips or spalls resulting from trimming and dressing at the cutting plants, and the granular and pulverized material from the dust collectors. The waste piles at the quarries of are immense proportions and constitute a serious handicap to quarrying in that they cover up good rock deposits, and are also so large that waste disposal becomes more and more expensive. The problem of utilization of such waste material is a topic of keen interest to all granite producers.Barre is not situated on a water route, and thus transportation costs prohibit the shipment of waste blocks for rip rap or ballast. Crushing plants use a small amount of this material for road construction, but aside from this, the waste is practically valueless.Investigators of waste utilization problems are awaiting with interest further information concerning an enterprise undertaken at Montpelier, Vermont, to utilize crushed granite for the production of brick similar to sand-lime brick. Granules of granite are mixed with lime, moulded, and hardened under steam Pressure, The brick produced are said to be of excellent quality for structural Purposes.There seems to be no logical reason why waste granite could not be utilized for the manufacture of building stone, and paving blocks, for many of the defects which condemn a stone for monumental purposes are not at all detrimental for building or street paving. F or the most part, monumental stone workers are not particularly interested in other branches of the granite in-dustry, and a combination of industries such as that suggested"

Jan 1, 1920

By W. E. Lamont

The Bureau of Mines studied the potential for recovering marketable barite concentrates that meet oil well drilling-mud specifications from barite waste pond materials. The study was conducted as part of the Bureau's research program to conserve domestic mineral resources by advancing mineral recycling technology. The samples, which were obtained from Georgia, Nevada, Missouri, and Illinois, varied widely in character, particle size, and barite content. The samples were treated with sodium silicate and sodium cetyl-stearyl sulfate and then floated. The flotation flow sheet was modified to reject barren coarse and/or slime fractions from some of the samples, and one feed sample had to be scrubbed prior to flotation to remove residual flotation reagents. The cleaned concentrates had BaS04 contents ranging from 95.0 to 96.9 percent, while recovering 81.2 to 95.9 percent of the barite in the feed. The specific gravity of each concentrate exceeded the specification of 4.2. The removal of the flotation reagents from the flotation concentrate was not investigated.

Jan 1, 1982

Design and test a high-production coal mining machine that generates less respirable dust. Background Current coal cutting systems generate excessive amounts of airborne respirable dust and fines during the mining process. Dust control technologies, including dust dilution by ventilation and suppression by water sprays, are not always able to reduce dust levels sufficiently. The U.S. Bureau of Mines (USBM) has designed a cutting system that reduces respirable dust generated by the cutting action of the drum. This cutting system, based on geometric principles developed in the 1500's, makes use of a constant depth, linear cut to remove coal at deeper cut depths and at lower rotary speeds than a conventional rotary drum. A comparison of the linear and rotary cut paths is shown in figure 1. Approach A full-scale prototype of the linear cutting concept was valuated under laboratory conditions to determine its performance relative to standard rotary drums. Results of these evaluations show production of fewer fines, or more uniform product size, a significant reduction in the amount of airborne dust, and reduced torque and power requirements (figure 2). On the basis of these results, a contract effort was undertaken by McCracken and Associates of Bristol, TN, to design a linear cutting head for underground testing.

Jan 1, 1995

Remotely monitor overburden response to longwall mining using time domain reflectometry (TDR) and a combination of hardware and software, as part of the U.S. Bureau of Mines (USBM) program to characterize subsidence. Background TDR was developed in the 1960's as a method to locate, discontinuities in coaxial transmission cables. In this method, voltage pulses sent along a cable are reflected by cable defects. The pulse reflections are used to determine the type and magnitude of the defects. The TDR concept was extended to material property measurement by embedding cables into particular materials and evaluating the cable's dielectric behavior as material properties were modified. This technique was adapted by the USBM in 1978 for use in monitoring rock movement during underground mining. The same concept is utilized today. A coaxial cable is grouted into a rock mass that is expected to deform. Progressive rock movement causes the cable to deform, as shown in figure 1, and changes to occur in the cable's electrical properties, which then produce changes in TDR reflection signatures. The technology has advanced to the point where it is now possible to distinguish shear deformation from tensile deformation and to quantify rock mass displacements by analyzing the TDR signatures.

Jan 1, 1995

By E. J. White

Data from oil well logs and core analyses were used to quantitatively evaluate formation porosity and water saturation of heterogeneous carbonates and to study the pore geometry and performance characteristics of cores from these formations. Logs and cores from the Madison limestone from 233 wells in three fields in the Williston basin were used in the investigation. A comparison of log and core analyses shows that log porosities are consistently larger than core porosities, and the differences are correlatable with core porosity ranges. Water saturations from logs are usually smaller than the corresponding core saturations by summation of fluids, but the difference is attributable to mud filtrate invasion into the cores during drilling. Petrophysical studies show that the low permeabilities and high residual water saturations in these reservoir rocks are due to their fine crystalline texture and complex pore geometry (heterogeneity). It is concluded that both log and core analyses must be used for reliable evaluation of these carbonate formations.

Jan 1, 1971

By Powell. Alfred R.

"An investigation has been made of the applicability to a variety of coals, other than those from Illinois, of the Powell and Parr method of analysis for the forms of sulphur in coal.A complete study was made of the sulphur in the following coals:- Upper Freeport, Pa.; Pittsburgh seam, Pa.; Pocahontas No. 3, W, Va..; Letcher Co., Ky.; Morgan Co., Tenn.; and Cherokee Co., Kan.The method of analysis gave excellent results when applied to these coals. In the determination of pyrite, the iron-sulphur ratio checked in every case with the theoretical. After the extraction of the pyrite and sulphates, the remaining sulphur was proved to be organic in nature.This work indicated that sulphur exists in coal in three typical forms: - pyrite or marcasite, sulphates, and organic sulphur. A study of the changes which these forms undergo during coking has been made on a variety of coals, and the following five classes of reactions established.First. Complete decomposition of the pyrite and marcasite to ferrous sulphide, pyrrhotite, and hydrogen sulphide. This reaction begins at 300°C., is complete at 600 °C., and generally reaches its maximum between 400 and 500°C."

Mar 1, 1920

By Rose L. Ballard

This chapter summarizes data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are the tables that show the principal nonfuel mineral commodities exported from and imported into the United States and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of Volume I and in the State chapters of Volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing, the stage of measurement used in this chapter is what is normally termed "mine output.? It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1985

By S. P. Howell, M. W. Von Bernewitz

"Introduction. The first short—flame explosives were made in the United States during the year 1902, then the mount was 11,300 pounds. In 1902 they were designated ""permissible explosives"", and were required to meet specific tests. By 1912 the total consumption thereof had increased to 24,630,000 pounds, equal to 5 per cent of the total quantity of all kinds of explosives produced in this country; while in 1922 the total was 43,429,000 Pounds, or 10 per cent of the production, and 18 per cent of the explosives used for the mining of coal.Each year the Bureau compiles statistics of explosives, one important object of this being to show the extent to which permissible explosives are replacing other classes of explosives in coal—mining operations, and the influence of such replacement in reducing the number of accidents caused by explosives in this class of mines. The consumption of permissible since 1916 has considerably exceeded the quantity of high explosives (dynamites, etc.) used in coal mines. While the increase in use of permissible is good, the replacement of other explosives therewith is not nearly as good as with be, considering the known general efficacy and safety of permissibles."

Mar 1, 1924