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By Jr. Joyce

This report describes sulfatization of nickeliferous laterites from Puerto Rico and the Philippines for recovery of water-soluble nickel and cobalt sulfates. Temperatures ranging from 665 C to 710 C and a 10-percent sulfur dioxide-air reaction gas were employed during batch-roasting tests and during continuous countercurrent treatment in a 2-inch-diameter shaft furnace. A maximum of 69 percent of the nickel and 76 percent of the cobalt were recovered from one sample of Puerto Rican laterite, and a maximum of 96 percent of the nickel and 91 percent of the cobalt were recovered from the Philippine laterite.

Jan 1, 1965

By B. J. Dalton

The Bureau of Mines Helium Research Center has developed a computer program for solving two-phase equilibria data for binary mixtures and for evaluating thermodynamic functions of interest, including all critical points. This computer program was used to calculate equilibrium points on the PVTu surface for the helium-nitrogen system as predicted by the Van der Waals equation of state. Numerical values are tabulated and illustrations are presented for 1,279 equilibrium points and for quantities needed to construct Ponchon diagrams. Equilibrium ratios as a function of pressure at constant temperature and of temperature at constant pressure-are also shown graphically. In addition, saturated partial molal volume and partial molal enthalpy data are given. It is shown that the Van der Waals helium-nitrogen system exhibits retro-grade condensation of the second type for liquid helium concentrations of about 0.07 mole fraction or less and pressures below about 45 atm. It is also shown that the critical point is at a -maximum value of pressure (at constant temperature) and of temperature (at constant pressure).

Jan 1, 1971

By N. S. Dalal, X. Shi

"Electron spin resonance measurements provide evidence for the formation of long-lived Cr(V) intermediates in the reduction of Cr(Vl) by glutathione redtuctase in the presence of NADPH and for the hydroxyl radical formation during the glutathione reductase catalyzed reduction of Cr(Vl). Hydrogen peroxide suppresses Cr(V) and enhances the formation of hydroxyl radicals. Thus Cr(V) intermediates catalyze generation of hydroxyl radicals from hydrogen peroxide through a Fenton-like reaction. Thus the mechanism of Cr(VI) toxicity might involve the interaction between macromolecules and the hydroxyl radicals.C(Vl) compounds have been found to exert serious toxic and carcinogenic effects on humans and animals (1-3). In contrast, most Cr(III) compounds are relatively nontoxic, noncarcinogenic, and nonmutagenic (1,4). Cr(VI) and Cr(III) oxidation states are different in their metabolic pathways: Cr(VI) , ions are rapidly transported across cellular membrane (1,4,5), while Cr[III) moieties do not easily penetrate cells and are not oxidized by cellular constituents (!). Since it is known that the reduction of Cr(VI) ion is required for its reaction with DNA (1), the molecular mechanisms for the intracellular Cr(Vl) reduction has been the focus of current studies but the details are still not understood.Earlier studies on the mechanism of Cr(Vl) reduction include those on the reduction of Cr(VIJ by glutathione (GSH) .0,6-8), ascorbic acid (9), glucose (10), lactose (IO), galacturonic acid (11), microsome (12), and mitochondrial electron transport chain complexes (13). These studies have shown that the Cr(VI) reduction involves the formation of Cr(V)-containing species which are often considered to be the toxic form of chromium. Thus far, however, no information is· available on the subsequent fate of those biologically formed Cr(V) species, in particular employing well defined biochemical systems. In this context, we report here our investigations of the reduction of Cr(VI) by glutathione reductase (GSSG-R). This enzyme was selected because it is ubiquitously present in cellular systems and it has been postulated to be involved in the Cr(VI) reduction (14-17) but the underlying mechanism has not been clarified. We find that the reduction proces·s involves not only Cr(V) but also ·OH radicals. We further investigate the reactivity of Cr(V) and find that it catalyzes generation of OH radical from H2O 2 through a Fenton-like reaction. The role of ·OH in Cr(VI) carcinogenicity is suggested from this study."

Jan 1, 1989

By Paul T. Allsman

This paper describes metal- mining practices at the Harrington -Hickory lead - silver - zinc mine at Milford , Beaver County , Utah . The operations of the Harrington-Hickory incorporate a number of features that should prove of interest and value to other operators of small mines . These features include employee participation in profits , a well- laid -out electrical system, adequate financing , a well - balanced equipment and supply inventory , a well - organized system of bookkeeping , adequate roads , and good management . As crude ore is shipped directly to smelters and mills in the Salt Lake Valley , close attention is paid to see that the ore is segregated by classes and treated where it can bring the greatest not return . A combination of these features has resulted in maintaining relatively low costs, considering the grade and size of ore shoots at a time , during and following the war , when equipment , supplies , and labor were costly and difficult to obtain . The period covered in this report includes two war years and two years following , from April 1, 1944 to June 30 , 1947 .

Apr 1, 1949

By W. W. Adams

Reports received by the Bureau of Mines, Department of Commerce, from State mine inspectors, for November, 1930, showed that 219 men were killed in the coal mines of the United States during the month, an increase of 25 over the previous month and 33 over November, 1929. On the other hand the production of coal decreased, the output of 43,329,000 tons in November being 8,397,000 tons less than in October and 9,005,000 tons less than in November a year ago. The larger number of fatalities accompanied by a smaller output of coal resulted in a higher death rate4 per million tons in November than in the same month last year or in October, 1930. The November rate was 5.05, as compared with 3.55 for November, 1929 and 3.75 for October, 1930. The increase in the rate for the industry as a whole was chargeable entirely to bituminous mines,, as the anthracite mines had fewer fatalities in November than in either of the previous months to which reference has been made. Reports for bituminous mines alone 'allowed that accidents at class of mines resulted in a death rate of 5.12, based on 195 fatalities and a production of 38,122,000 tons. This rate indicated an increase of 55 per cent over the rate for October, of the same year, and 72 per cent over the rate for November, 1929. The October record was 146 fatalities and 44,150,000 tons, and that for November a year ago was 138 deaths and a production of 46,514,000 tons. Twenty-four deaths occurred at anthracite mines in November, 1970: the output of coal was 5,207,000 tons, hence the rate was 4.61 per million tons. During the corresponding month a year ago there were 48 deaths and 5,820,000 tons of coal produced, which indicated a death rate of 8.25. In October, 1930, the death rate was o.34; based on 48 deaths and 7,576,000 tons.

Jan 1, 1930

By A. C. Rice

Aminopolyacetic acid chelating agents were added to separatory-funnel-scale solvent-extraction systems to determine the effect on separating rare-earth elements. Average values for separation factors between adjacent elements obtained with Primene JM-T2 increase 36 percent when EDTA is added to the aqueous phase. Adding HEDTA or DCTA also improves separation factors for certain rare-earth elements. Percentage of extraction and the separation factors exhibit marked sensitivity to concentrations of amine, chelating agent, and hydrogen ion. The chelating agents improved separation in Primene JM-T, BHDA, and Primene 81-R extraction systems.

Jan 1, 1963

By G. R. Hopkins

The petroleum-refining industry established a. new record in fuel effieciency at refineries in 1936, when 597,000 B. t. u. of heat mere required to refine a barrel of crude oil, compared with an average of 615,000 B. t. u. in 1935 (see fig. 1). The principal factor in the 'indicated gain in fuel efficiency at refineries in 1936 was an increase in crude runs of 11 percent over 1935. A large part of the heat utilized at refineries is consumed elsewhere than under stills, or in ways quite independent of crude-oil distillation. In other words, as the operating ratio ( crude runs divided by capacity) for re- fineries increases toward tine maximum of 100 percent, the fuel requirements show progressively smaller increases and the average B. t. u. consumption per barrel of crude refined declines.

Jan 1, 1938

By Phillip R. Moyle

In 1985 the U.S. Bureau of Mines evaluated the mineral resources of the Sheep Creek West Wilderness Study Area (ID-111-36A), Owyhee County, ID, for the U.S. Bureau of Land Management. The Wilderness Study Area consists of 11,680 acres centered approximately 20 miles south of Grasmere, 10. It contains no mines, claims, or prospects. No mineral resources were identified; however, a geode occurrence within and adjacent to the Wilderness Study Area, and minor amounts of placer gold along Sheep Creek, may be of interest to rorkhounds and recreational gold panners.

Jan 1, 1986

By R. V. Ramani, W. Miola

"A relationship exists between the quartz contents in the underground coal nine airborne dust samples and those in the coal and host rocks that are mined [17, 18, 19] The prescribed method for quartz analysis in respirable airborne coal dust samples is the MSHA P-7 method. Accurate quartz analysis procedures are needed for bulk samples in order to predict the potential quartz content in airborne nine dust, which in turn will aid the design of quartz dust control procedures during mining. thereby reducing the airborne quartz dust in underground atmospheres. The requirements of this method are that the amount of quartz is the sample be less than 250ug, and the total sample weight less than 2,500 ug. Unlike with airborne dust samples, there are no limitations to the available mass of bulk samples. However, these are no standard procedures for the preparation of bulk samples for scanning or prescribed methods for quartz analysis. The NIOSH and MSHA methods are certified for roped* dust and the acceptance of these methods for bulk samples assumes that the bulk samples will be reduced to the conditions specified for respirable dust samples. An alternative method is X-ray diffraction, which provides higher average quartz values than those obtained from P-7 method for the same samples.An investigation was carried out to determine the optimal procedure for preparing the bulk samples for the IR and XRD analyses. In this paper, the investigations on the effects of calibration, particle sizes, matrix composition, interferrous, and behavior of the filter substances on IR, XRD and FTIR results are presented. The error introduced by the presence of kaolinite and a new sample asking procedure to reduce it are discussed. The problems experienced with conventional sample holders for scanning were eliminated with the design and development of a new hollow sample holder. Quantitative comparison of quartz determinations by IR, XRD and MR methods on coal, roof and floor rocks, and airborne dust samples are presented. The important factors affecting the results of quartz analysis methods are: 1) bulk sample preparation for obtaining representative and homogeneous analysis samples: 2) particle size distributions of the analysis samples and calibration standards; 3) qualitative matrix composition of the analysis sample; 4) matching calibration standards to analysis sample; 5) substrates for sample deposition during analysis sample preparation; 6) procedures for analysis sample mounting; 7) selection of proper portions of she response profile for insanity measurement; and 8) interferences of spurious phases with the critical analyses. The recommendations of this study are important to enable comparisons and interpretations of analysis and research results."

Nov 1, 1995

By Janke L. W. Jolly

Owing to an upsurge in export earnings. Cameroon made substantial economic Progress in 1978 and 1979. With a real growth estimated at 6%, the gross domestic product (GDP) for 1979 surpassed $5 billion.2 Crude petroleum production was providing a new potential in 1978 and 1979 for achieving national self-sufficiency. Among other benefits, crude petroleum exports were helping to offset the escalating costs of refined petroleum imports and to reduce the 14% to 17% annual rate of inflation. Over the 4 years prior to 1978, Cameroon's petroleum imports increased by 12.1% in volume annually, while the import cost increased by 24.5% annually to about $105 million. Total export earnings for 1978 were $805 million,3 to which crude petroleum contributed $25.3 million and crude aluminum product exports contributed $25.9 million. Petroleum exports had increased to about $240 million in 1979 and were in third place after coffee and cacao. Total imports for 1978 were valued at nearly $1 billion. The volume of petroleum imports decreased in 1979 to 552,000 tons, compared with 622,000 tons in 1978. The European Economic Community (EEC) countries purchased over 75% of total Cameroonian exports and provided most of the Nation's imports. The United States purchased $12.4 million in petroleum exports from Cameroon in 1978. Domestic consumption of aluminum metal from imported Guinean alumina continued. to grow; thus exports of this metal to France (valued at $2 million in 1978) and Japan

Jan 1, 1981

By Robert C. Johnson

Single crystal whiskers of ZrO2 and TiO2 were grown by solution and crystallization of these oxides in molten baths. Mixtures of Na2B407 and LiC1 were the most suitable growth media for zirconia. Sodium borate alone and Na2CO3 plus SiO2 were best suited for titania. The solubilities of zirconia and titania in molten sodium borate were determined, Whether zirconia whiskers were dendritic or nondendritic depended on the temperature used. The best single crystal whiskers were grown below 1,100° C. Titania whiskers always grew as single crystals. The tensile strengths of zirconia and titania whiskers were about 15,000 psi and 50,000 psi, respectively. Modulus of rupture was about 49,000 psi for zirconia whiskers and 75,000 psi for titania whiskers. Chemical analyses showed the zirconia and titania whiskers to be pure. The zirconia and titania whiskers were shown by X-ray analysis to be, respectively, baddeleyite and rutile.

Jan 1, 1965

By Michael S. Miller

The U.S. Bureau of Mines (USBM) conducted mineral investigations in the 1,227,000-acre Emigrant Trail study area of Nevada during 1992. During the USBM investigation of 25 areas of development interest, 190 mineral localities were identified and 260 rock and 50 alluvial samples were taken. At least 0.5 million troy ounces of gold, 2.3 million troy ounces of silver, 3.3 million pounds of copper, 10.9 million pounds of lead, 2.4 million pounds of zinc, 500 tons of alunite, 40,000 tons of sulfur, 9,000 pounds of mercury, and 21,000 pounds of tin have been mined from the area and vicinity. Adjacent to the study area, gold is being mined at large, open-pit gold mines, the Hog Ranch and Hycroft Resources, Inc., Sulphur mines, and new production is planned at the Rosebud LAC/Equinox. Hog Ranch mine is nearing depletion, but resources of more than 0.5 million troy ounces of gold and about 5 million ounces of silver are estimated for the Rosebud LAC/Equinox project and more than 0.4 million ounces of gold for the Hycroft Resources, Inc., Sulphur mine. Significant investigations are occurring at SP Ridge and other sites near Scossa and at the Dan claims in the Southern Calico Mountains. Precious opal, placer gold, and geothermal energy resources occur in the study area and vicinity.

Jan 1, 1993

By Z. T. Bieniawski, R. K. Zipf

"Zipf Jr., R.K. and Bieniawski; Z.T., 1989. A fundamental study of respirable dust generation in coal. Min. Sci. Technol., 9: 87-99Black lung disease in coal miners induced by the formation of fine fragments of coal imposes very high human and direct costs. A fundamental understanding of the fracture processes leading to fine-fragment formation in coal by applying principles of fracture mechanics is presented. A four-step hypothesis is proposed which sequentially describes the mechanics of fine-fragment formation during a generic coal material—coal cutting tool interaction. These steps include: (1) development of a crush zone under the tool tip, (2) macrocrack propagation. (3) shear movement along macrocracks, and (4) additional fragmentation from shear. This model contains two sources of fine fragments, namely crushing under the tool tip and shearing along the macrocrack surfaces. Three critical assumptions are made that require experimentation. First, the coal material must contain flaws of sufficient density and sufficiently small size to liberate fine fragments by crushing. The following conceptual relationships are proposed between flaw size, spacing and fragmentation: first, the active flaw size must be less than the desired particle size and second, the spacing (or density) must be in the order of the particle size. The second major assumption is that a mixed mode fracture theory will describe the initiation and crack growth direction for the microscopic inherent flaws. The third assumption is that some degree of roughness damage, and interlocking exist along the newly formed macrocrack surfaces such that a small amount of shear movement along that surface leads to additional particle formation at a microscopic scale. Preliminary analysis of the mechanical regime under a cutting tool tip places order of magnitude bounds on the stresses strains, cycle time, stress rates and strain rates. Even though the tool moves and loads the coal material with considerable speed, a quasi-static stress analysis is applicable in this region.Introduction.The generation of fine fragments (respirable dust) during various coal mining processes may lead to the incidence of coal workers pneumoconiosis (black lung disease). The human and direct cost of dust-induced illnesses in coal miners is very large. By several. accounts [1,2] the Federal Government paid out about $12 billion to almost 500,000 coal miners and their beneficiaries between 1970 and 1980. In addition, several states and many coal operators have established their own compensation programs at costs ranging from a few cents to several dollars per ton of coal mined [2]. Since 1980, 'the present liability of the Federal disability trust fund has approached $20 billion and the benefit payments exceed $1 billion per year. There .are also hidden costs due to dust, in the form of increased equipment wear and decreased operator productivity, both of which are due to the poor operating environment. Quantifying these costs may be difficult; however, they may be in the same range as the present pneumoconiosis costs. These high human and direct dollar costs may be prevented or reduced through long term research efforts directed at understanding the generation and control of respirable dust and the incidence of black lung disease."

Jan 1, 1989

By J. S. Malesky

"INTRODUCTION The Airdox method of breaking coal utilizes compressed air under high pressure and was developed to replace explosives. It is used in Illinois and Indiana mines to a large extent and also has been introduced in mines in a few other States.ACKNOWLEDGMENTThe author gratefully acknowledges the information and photographs furnished by the Cardox Corp.HISTORYIn the early 1920's, with the adoption of mechanical mining in States where on-shift shooting was prohibited, it became desirable to develop some means of breaking coal from the face without the use of explosives. At that time it was thought that a pressure of 20,000 pounds per square inch would be necessary to break the seal. It was impossible to obtain a compressor that would develop this pressure therefore, the 'patentees developed and applied the Cardox method, which utilizes liquid carbon dioxide as the blasting medium."

Aug 1, 1948

By Robert L. Virta

The Bureau of Mines examined a fibrous talc sample from the Gouverneur talc district in New York by transmission electron microscopy (TEM) and polarized light microscopy to determine the mineralogical relationship of the fibrous talc to the amphiboles present in the sample. Two am-phiboles, anthophyllite and tremolite, were present in the sample. Tremolite occurred as a separate mineral phase, which was blocky in habit. Only a few composite tremolite-talc grains were observed. An-thophyllite, however, was present only in the fibrous talc grains. Mi-crodiffraction study of the fibrous talc grains containing anthophyllite showed that the anthophyllite was intermixed with the talc on a fine scale and that there was a crystallographic relationship between the talc and anthophyllite lattices in the fibrous talc grains. A mechanism similar to the process that forms biopyriboles could explain the structural defects, the fibrous habit of the talc, and the structural relationship between the talc and anthophyllite in the fibrous talc grains. Because of these characteristics, phase contrast microscopy and a provisional TEM technique for monitoring asbestos exposure would not distinguish between fibrous talc and fibrous amphiboles. TEM techniques employing electron diffraction and energy-dispersive X-ray analysis are recommended to positively identify the fibrous phases for regulatory purposes.

Jan 1, 1985

By C. E. Armantrout, H. Kato, M. I. Copeland

The data collected during this investigation indicate that the chromiumgadolinium system has extensive liquid immiscibility and one eutectic point . Liquid immiscibility occurred at temperatures above the monotectic isotherm , 1,830 ° C , which extended from less than 0.25 to about 85 weight - percent gadolinium . The eutectic was at 96 percent gadolinium and 1,170 ° C. Gadolinium and chromium were the only phases in this system . There was a solid solubility of less than 0.25 percent gadolinium in chromium at 1,730 ° C and less than 0.10 percent chromium in gadolinium at 1,160 ° C. The alloys were prepared by nonconsumable - electrode arc - melting , and the alloy system was investigated by heat treatment , metallography , thermal analysis , and X- ray diffraction . All the melting , heat treatments , and thermal analyses were conducted in a vacuum or in helium because of the reactivity of chromium and gadolinium with the components present in the atmosphere at elevated temperatures .

Jan 1, 1964

By Don Belsher

Work on contract H0272007 is summarized for the period of 1 February 977 to 1 February 1978. The initial evaluation of two potential systems for the location of well casings, voids, and tunnels in coal are described. The pulse measurement equipment used for the evaluation of the antennas selected possible use with a pulse time domain system and an FM-CW system is described. A TEM horn antenna design potentially suitable for use with these systems is given. An operational comparative analysis between various antenna types is presented.

Jan 1, 1978

By Robert H. Peters

This U.S. Bureau of Mines report identifies the types of serious accidents that occur most frequently at small underground coal mines and describes the strategies that could help prevent these accidents. A wide variety of methods for improving safety are suggested, including improvements in the design of equipment, work procedures, work schedules, safety programs, and emergency response plans, as well as techniques for diagnosing the potential hazards associated with new technologies and work procedures. Some of the papers in this volume focus on preventing specific types of mining accidents--ones associated with materials handling (primarily back injuries), equipment maintenance, improper machine guarding, and ground failure during retreat mining. Although the recommendations in this volume are heavily influenced by research performed at underground coal mines in the Appalachian coalfields, most of the papers contain advice that is equally pertinent to almost any type of mine.

Jan 1, 1994

By W. P. Yant

Publication of lists of the devices for giving respiratory protection which have been approved by the U. S. Bureau of Mines is made periodically for the purpose of aiding consumers in procuring equipment .374/ The last published list , approved to March 15 , 1935 , appeared as Information Circular 6845 with the same title as this article . The schedules of requirements and tests which the devices must meet in order to obtain approval are published 2/6/1/8/ by the Bureau of tests the devices must Mines and are available to the public . It is pertinent to mention that the preparation of a schedule of requirements for fresh-air supply devices of the types commonly known as positive -pressure respirators , airline respirators , sand- blast helmets , and hoods , has been practically completed and will soon be ready for release to the public .

Oct 1, 1936

By R. L. Handy

The objective of this research was to devise and test an apparatus to rapidly evaluate the cohesive and frictional strength of coal in situ, in order to increase the safety and percentage of coal recovery from underground coal mines. During the first year device was designed utilizing the bore-hole shear test principle from soil shear strength testing: Two opposing corrugated plates are forced outward to exert a controlled contact pressure against the sides of a previously bared hole, and then the plates are very slowly pulled along the axis of the hole to cause shearing of coal in contact with the plates. Results with the device are expressed in terms of a friction angle[_] and a cohesion c. The [ ] angles obtained from an Iowa coal arc in close agreement with and fall between results from triaxial and direct shear laboratory tests on the same coal. The measured cohesion was found to be much less than from the comparable laboratory tests. It may be increased by pre-stressing and other techniques to embed the shear plate teeth for the first shear test point.

Jan 1, 1973