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By W. Y. Liu

A sulfate reducing bacteria strain (named SRB-A) is isolated from sanitary wastewater by using anaerobic technology of Hungate. The studies of physiological, biochemical and phylogenic of the isolated strain are carried out. The colonies of the strain are circle. Cells that are slightly curve, rod-shaped with the size of 1.0~3.0µm in length and 0.8~1.0µm in width. The optimum temperature for growth of the organism is 30~35°C. The optimum pH for growth is 7.0~7.2. Strain SRB-A can use sodium lactate, sodium citrate, sodium acetate, ethanol and acetone as electronic acceptor but can not use glycerol, glucose, sucrose and sodium oxatate. The isolated strain reduces sulfate, sulfide, sulfur, DSMO and FeCl3, then nitrate and nitrite can not be used. The strain has higher tolerance of NaCl, and the optimum growth occurs in the presence of 5%~8% (w/v) NaCl. The result of 16S rDNA sequence analysis indicates that the isolated strain SRB-A is the most similar to Desulfo-vibrio halophilus, and the level of the similarity was 98.4%. The isolated strain has a stronger ability to reduce sulfate, and the level of sulfate reduction reaches about 90% at pH 7 in the liquid medium. 0.6 to 0.8 is the optimum COD/SO42- in the medium for the isolated strain to show better ability to reduce sulfate. At pH 2.5 the level of removal of Cu2+ reaches 96.3%. Under the condition of pH 3.5, the level of removal of Zn2+ reaches 92.6%. When the value of pH reaches about 7, the Fe3+ is precipitated by the formation of Fe(OH)3, and Fe3+ is removed up to 89.4% at last.

Jan 1, 2014

By F. Boylu

In this study, Ca-bentonite was subjected to a series of systematic hydrocyclone tests with the aim of developing separation procedures and in turn achieving optimum recoveries. In hydrocyclone tests, vortex and apex diameters and also feed pressures were investigated. In each hydrocyclone set, vortex diameter was kept constant while the other two parameters varied to produce bentonites con-centrates of various smectite contents. The separation efficiencies were evaluated based on the cation exchange capacity (CEC), particle size and swelling index. The detailed hydrocyclone tests showed that, upgrading of Ca-bentonites require procedures different from the bentonites reported in the literature. Sodium and mixed bentonites are easy- to-disperse and easy-to-separate whereas calcium types need to be scrubbed rigorously for disintegration. Scrubbing properties of ca-bentonite were investigated as a function of scrubbing time and percent solids by weight (PS). The scrubbing conditions at 700 rpm for 1.5 hours and percent solids of 30 % were found more effective for achieving a better quality bentonite. In addition to the parameters mentioned above, the effect of percent solids on hydrocyclone separation was also studied. Although Ca-bentonites permit studying at higher percent solids, increasing solids content of the pulp deteriorated the quality of the clean products. Application of an appropriate separation scheme enabled the development of a unique separation procedure involving stage wise scrubbing followed by hydrocycloning which yielded calcium bentonite concentrates with CEC of 90 meq/100 g and high swelling indexes of 12 mL from the original bentonite of 65 meq/100 g and 7.0 mL, respectively. These results indicate that upgraded bentonite products can be conveniently used in various diverse industrial applications including bleaching earth, desiccant, cat litter, paper etc.

Jan 1, 2014

By Heramb M. Bal

This paper will underpin the future development of intellectuals having greater understanding of patent law and legislation, IP rights, and innovation. To understand this idea, I present a case study of China?s progress in the last 31 years in the rare earth research, innovation, and simultaneously patents area. Rare earth elements (REE) are at the centre of high technology and are the next wave of world innovation. Much of modern society depends on rare earth elements through their use in computers, lasers, telecommunications, iPods, medical technology, military applications, and so on (Long et al, 2010). The rare earth research, a large research body is being provided by Chinese sources. China devoted three or four university centers to the study of rare earths (Lifton, 2009). These measures are all designed to keep China at the forefront of REE production, materials, technology, and innovation. As a result in the last fifteen years there has been a shift from a US-dominated REE industry patents to Chinese patents. The world must identify strategic areas of rare earth innovation and provide funding to firms and universities that conduct such research. Not only research and innovation is vital but filing patents and preserving IP rights for research and innovation is even more important. We (rest of the world) need a comprehensive strategy to guide the development of patent and IP rights for research and innovation. To achieve this, the development of intellectuals with superior knowledge of patents and IP rights are the future need of minerals industry. Keywords: innovation, rare earth, patent, IP rights

Sep 1, 2012

The ultimate goal of a mineral processing plant is to recover as much of the target mineral(s) as possible from the ore being treated to achieve the best economics. Selection of the mineral processing techniques is the most important step in achieving this goal. However, due to the complexity of the ore, the recoveries of valuable minerals may be not satisfactory even when the mineral processing technique(s) are well chosen. In other words, minerals of interest can be lost to the tailings for mineralogical reasons. For example, gold is mainly extracted from the ore by gravity, flotation, cyanidation, or a combination of these processes, and high recovery (>90%) can be achieved when gold occurs as coarse grains. However, when a refractory ore is being processed, gold extraction will be challenged by mineralogical factors, which often cause gold losses to various tailings. Mineralogical factors affecting gold recovery mainly include grain size, shape, surface coatings and rimmings, presence of cyanicides, oxygen consumers and preg-robbers, presence of slow-dissolving gold minerals and the refractory nature of submicroscopic gold. Among these factors, locking in sulphide, silicate and other minerals as fine-grained gold inclusions and/or as invisible submicroscopic gold is by far the most common factor leading to poor gold recovery encountered in gold ore processing. Processing of PGE ores faces the same challenges as gold. Small grain size and locking of PGM in sulphide and non-sulphide minerals often cause PGM losses. When silver ore contains significant amounts of pyrargyrite, proustite and stephanite, silver recovery by cyanidation can be very low because of the slow dissolving kinetics of these minerals. In the processing of base metal ores, high content of pyrite, intergrowth of chalcopyrite with sphalerite and presence of clay miner-als may cause problems in recovering Cu-, Pb- and Zn- bearing minerals. Process mineralogy helps address all issues and problems related to mineral processing with predicting and trouble-shooting being two major objectives. It provides useful information on process selection, flowsheet development, recovery improvement and reagent consumption optimization. The information acquired from a process mineralogical study can be used as a guide for a metallurgical testwork program for process design or optimization.

Jan 1, 2014

By Dmitriy Kim, Natalya Ibragimova, Galina Sedelnikova

Gold and copper are lost in flotation tailings in mineral processing of copper-zinc-pyrite ores. Large resources of precious and base metals have accumulated in tailing ponds of Russian plants. Object of the study is the sample obtained from Ural Mining and Metallurgical Company in Russia. The main constituents in flotation tailings are Au, Ag, Cu and Zn with content 1.4 g/t, 12 g/t, 0.66 and 0.5% respectively. The flotation tailings are a refractory material. Gold, as main metal, is fine encapsulated in sulfides, mainly in pyrite. Gold extraction from tailings is 34.0 and 42.7% at P42 and P90 of 0.074mm particle size respectively. In this work heap bioleaching of tailings was studied for oxidation sulfides (pyrite and chalcopyrite) with using mesofilic and moderately termofilic bacteria in acidic solutions. The tailings had low filtration property (< 0.3 m/day) and pelletization was used before bioleaching. Copper containing converter slags flotation tailings and calcium oxide were used as binding material for increasing filtration property of tailings. Copper was extracted in sulfate solution and was precipitated by cementation after cleaning of bacterial solution from iron. Copper recovery was 56.8% at content 61.4% in precipitate. The biooxidation of pyrite was 80%. Cyanidation, leaching with thiourea and heap leaching by cyanide were tested too. Gold extraction from solid bioresidues was 82, 75.3 and 77% respectively. The results of this investigation were recommended for pilot test.

Jan 1, 2014

By V. I. Ryaboy, I. V. Ryaboy, E. D. Shepeta

"The problem of separation of copper minerals and arsenopyrite remains relevant because of environmental requirements. The selective action of reagents with the thioamide group (thioamides) is known in iron sulfide’s flotation of pyrite and pyrrhotite. The aim of this study was to reduce the arsenic content in the copper concentrate when using thioamides by reducing the flotation of arsenopyrite in the flotation of the sulfide part of the skarn scheelite-sulfide ores. We have chosen the most widely used thioamides for the study, such as Z-200. We also synthesized new reagents with the thioamide group. The most selective and the most powerful thioamide copper collector were used for further studies. Reduction of arsenic content in copper concentrates is achieved in the following way: You need to apply a strong thioamide collector with a selective but weak dialkyldithiophosphate collector, or vice-versa, a selective, but a weak thioamide collector should be used with the dialkyldithiophosphate reagent with strong collective properties. The proposed combination presents industrial interest because of its accessibility. The application of thioamides in copper minerals and arsenopyrite selection has showed that these reagents have fewer selective properties than dialkyldithiophosphates. To achieve the comparable recovery of copper using dialkyldithiophosphates requires markedly greater consumption of thioamides, due to their lower hydrophobic ability. The application of a composition of thioamides and dialkyldithiophosphates allows to increase the recovery of copper and to obtain a lower arsenic content in copper concentrates compared to their individual use. The lowest arsenic content in the copper concentrate is obtained in the composition consisting of the newly synthesized thioamide with strong collective properties and selective dialkyldithiophosphate. The addition of even small amounts of xanthate to the composition of thioamides and dialkyldithiophosphates causes a sharp increase in the arsenic content in the copper concentrate without a notable increase in copper recovery."

Jan 1, 2018

By D. W. Lui

Tangdan copper oxide deposit, the largest independent copper oxide deposit in China so far, is located in the northeast of Yunnan province, southwest of China. The ore from this deposit is characterized by: low grade, high oxidation ratio, and fine-grained disseminated, resulting in poor flotation recovery. The analysis of plant flotation data reveals that the loss of copper minerals into tailings is mainly with coarse size fraction due to insufficient liberation and fine size fractions, especially minus 10 microns fraction, which proved to be very difficult-to-float with conventional flotation. In order to improve the performances of plant flotation of this ore, laboratory flotation tests were conducted with the pure malachite, which was the principle copper oxide mineral in Tangdan copper ore deposit. The results obtained suggested that a finer grinding (up to -325 mesh or even -400 mesh) be needed to decrease the loss with coarse size fraction, and vacuum flotation is a promising way for the recovery of the fine malachite effectively.

Jan 1, 2014

By Y. H. Tang

For its surface features, micro-sized hematite is usually difficult to recover by magnetic separation; especially, the existing high gradient magnetic separator in industry can not utilize collecting matrix with thin silky rods for its property of being easily blocked; the lower size limit for recovery of micro-sized weak magnetic minerals is about 0.019mm, some even is 0.037mm. This paper introduces the application of the combined new technique of water-air joint discharging of concentrate and collecting matrix with different diameter silky rods in the field of recovery of micro-sized hematite by high gradient magnetic separator. The commercial test result for recovery of a certain hematite with size about ?0.037mm shows that the recovery can be promoted by 16.81% with basically same concentrate grade.

Jan 1, 2014

By Jun Xiao, Jianwen Yang, Yanhong Dong, Daixiong Chen

"MANGOTE Surface oxidizied mine is a gold-bearing deposit in Congo's Mai-Ndombe Province. In the past decades, the ore has been exploited in a crude way by local farmers, which directly causes the severe processing difficulty and lack of economy of cyanide leaching. Hunan Research Institute for Non-ferrous metals (HRIM) is currently investigating options to recover gold through understanding the mineralogical characteristics of MANGOTE surface oxidized ore. Chemical analysis , X-ray diffraction(XRD) and Quantitative Evaluation of Minerals by SCANing electron microscopy (QEMSCAN ) were conducted on samples from mine site. The bulk analysis results showed that gold separation of gold from gangue minerals was feasible after grinding the ore samples to 86.53% -74µm and adjusting the pulp specific weight at 100g/L, and gravity separation was conducted with using spiral chute after grading of fine particles. The research results highlight relationship between mineralogical characteristics of abandoned ore and economy of comprehensive utilization that might be directive experience to similar cases. INTRODUCTION The occurrence state of gold in natural gold minerals determines the basic recovery and recovery effect of gold(Komnitsas, C., & Pooley, F. D. 1989). The occurrence of gold in the ore refers to the form of gold in the ore.Generally the existing state of gold can be divided into four major categories according to the viewpoint of the dispersion system: independent minerals and gold, a coarse dispersed system;colloidal gold, a colloidal dispersion; solid solution gold, is atomic ion dispersion; adsorptive gold, according to the adsorbed particle is the micelle or ion, respectively is a colloidal dispersion or ion dispersion(Mao, S. D., & Yang, R. S. 2009; Liu, J. J. et al. 2007; Horisberger, M., & Rosset, J. 1977; Li, Y., & Audétat, A. 2013).With the increasing technology of comprehensive utilization of resources,varied plants can now process different gold ores with various occurrence states(Neesse, T. 2014; 7. Ogundare. et al.2014)."

Jan 1, 2018

By M. Brozek

The constant of flotation velocity is the value characterizing the kinetics of cyclic flotation. In the statistical theory of flotation its value is the function of probabilities of collision, adhesion and tearing off the grain from the air bubble. The grain ? air bubble collision plays a key role since there must be a prior collision before the grain ? air bubble adhesion happens. The probability of such an event to occur is proportional to the relation of the grain diameter to the bubble diameter. When the grain sizes are given, it is possible to control the value of collision probability by means of the size of air bubbles. Consequently, it is significant to find the effect of physical and physicochemical factors upon the diameter of air bubbles in the form of a mathematical dependence. In the pneumo-mechanical flotation machine the air bubbles are generated by the blades of the rotor. The dispergation rate is affected by, among others, the rotor rotational speed, the amount of air transported to the flotation chamber an time and the liquid surface tension, depending on the type and number of applied flotation reagents. In the proposed paper the authors will present the distribution of air bubble diameters on the grounds of the above factors, according to the laws of thermodynamics. The correctness of the de-rived dependences will be verified empirically.

Jan 1, 2014

By Bertil I. Pålsson, Sture V. Persson, Kent T. Tano

"Grinding is one of the most energy consuming unit operations and is also a very inefficient and costly process. Therefore, it is of great importance to run the grinding process as efficiently as possible. The most common way today to control grinding processes is by measuring the power draw of the mill and try to keep it at a maximum level. However, some studies (Kawatra, 1989, Koivistoinen, 1989, Moys, 1989) have shown that this measurement doesn.t reflect everything that takes place inside a mill. Among other parameters like slurry rheology, temperature and charge behaviour, the volumetric filling of a grinding mill seems to have a large influence on the grinding efficiency (Herbst, 1988, Koivistoinen, 1992, Vermeulen, 1988). A problem in attempting to measure those parameters has been to get a sensor that is both robust and sensitive enough for continuous on-line measurement.This paper presents a method for the measurement of the apparent filling level in a pilot ball mill equipped with the Metso Continuous Charge Measurement system (CCM). In this technique a strain gauge sensor is mounted on a flat steel spring which is fitted into a recess underneath a lifter bar. In addition, a conductivity probe, the Boliden Grinding Measurement System (GMS), is mounted in another lifter bar with the purpose of comparing the two measurements. To visualise the behaviour of the charge a DEM modelling technique is used.The results indicate that the system is capable of following the normal variation that occurs in the mill. The signal also very well reflect changes in operating variables such as ball charge level, pulp density and rotational speed. By studying the nature and different features of the signal one can get a better understanding of milling circuit dynamics. Another feature of the technique is the possibility for an operator to continuously follow the grinding process and thereby run the process under optimal conditions."

Jan 1, 2003

By Dongyun Liang

Process mineralogy focuses on the chemical components and mineral composition of ore, dissemination size of valuable minerals, the occurrence of valuable and detrimental elements as well as the behavior of each mineral in the process. Through determining process mineralogy parameters and analyzing the characteristics of minerals, the results of process mineralogy study can provide mineralogy data for making a reasonable mineral processing technology program and optimizing the process. A detailed process mineralogy study is carried out for a complex rare metal ore in this paper and the results show that niobium mainly exists in the form of ferrocolumbite as well as nioboaeschynite and zirconium primarily occurs as zircon. The valuable minerals including Th-nioboaeschynite, ferrocolumbite, zircon, etc. have the characteristics of fine dissemination size, wide size range, complex chemical composition and variable physical properties, which mean it is a refractory ore. According to the results of mineral composition of ore, chemical composition of minerals, dissemination size of minerals, magnetism ranges of minerals and the distribution of niobium and zirconium, the process of ?desliming-Nb-Zr bulk flotation? is designed for this ore and the niobium-zirconium bulk rough concentrate with the grade of Nb2O5 9.43%, ZrO2 24.95%, Ta2O5 0.36% and the recovery of Nb2O5 77.66%, ZrO2 76.70%, Ta2O5 75.13% to crude ore can be obtained in the whole process closed-circuit test.

Sep 1, 2012

By Sanjay Chaudhuri, V. K. Kalyani, Pradeep Kumar Singh, T. Gouri Charan

"Indian coal industry is the world's third largest in terms of production and fourth largest in terms of proven coal resources. Indian coal deposits are generally of high ash content varying from 24 to 50%. The coking coal reserves of India constitute about 12% of the total coal inventory, and the coals are washed in washeries, before being used for metallurgical purposes. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells. Extensive studies were carried out for understanding the performance of an operating conventional flotation plant. The performance studies revealed that appreciable quantity of clean coal is being lost in the tailings due to varied reasons and the required quantity and quality was not achieved. In this study, laboratory Flotation experiments were carried out to examine the cleaning characteristics of the said tailing and to determine the effective process parameters for recovery of clean coal at desired ash level ( 16-17%). Response Surface Methodology was applied to investigate the operating conditions of the Froth Flotation for modeling and optimization. Primary study reflects that there is a possibility to recover clean coal at 16-17% ash level with a yield of about 60-70% from that Flotation tailing of feed ash about 28%.INTRODUCTIONMost of the Indian coking coals are difficult in cleaning characteristics and high ash content due to its drift origin and its age of formation for more than 225 million years. Indian coking coal reserve is limited about 12% of total coal reserve. The minerals are homogeneously mixed with the coal macerals. The open cast mining practice and mechanized mining methods are being adopted to meet the increasing demands of coals resulting in generation of more coal fines and subsequently the quality is deteriorated. Indian good quality coking coal reserves of higher seams are fast depleting and hence coking coals of difficult cleaning characteristics of lower seams (LVC) are being now explored. Due to increased mechanization of coal mines to cope up the increased demand and followed by size reduction of lower seam coals in search of better liberation , the coal fines are increasing by leaps and bounds. The processes used for washing coking coal is Jigs, Heavy medium bath and Cyclones for the sizes upto 0.5mm, while the coal fines are washed in spirals and conventional flotation cells."

Jan 1, 2018

By M. M. Kulkarni1

Kaolin clay is used as a filler and pigment in various applications such as paper, paint, rubber, plastics, adhesives, ink and ceramics etc. Major mineral content in crude kaolin clay is kaolinite along with some accessory minerals as quartz, hematite, mica, feldspar, anatase, rutile, illemnite etc. The Fe and Ti bearing minerals play very important role in determining quality of the kaolin, as these minerals impart yellow, pink or darker color to the white kaolin. Conventional beneficiation methods used in kaolin processing are de-gritting, classification and sodium dithionite bleaching, which improves the optical properties of kaolin, wherein reduction of color imparting constituents such as Fe2O3 and TiO2 is marginal. In the present study, these coloring impurities are separated using selective adsorption of water-soluble polymers. Degritted kaolin samples after passing through 45 micron sieve is used in the study for selective flocculation by polyacrylamide based polymers. The effect of pH, zeta potential, and polymer dose on the reduction of impurities is studied. Analytical tools such as XRF, XRD, SEM, and TEM techniques are utilized and results are discussed in detail.

Sep 1, 2012

Datun Concentrator currently processes complex sulfide ores in Gejiu Municipality, Yunnan Province, China. The ore contains much higher arsenic than other ores. The run of mine ore is fed to the concentrator to recover copper and tin by bulk flotation and gravity concentration, and then the other sulphides, such as pyrite, arsenopyrite, etc. didn?t get utilized and are discarded as tailings due to the high arsenic content. In order to utilize the pyrites in the tailings, a series of tests have been conducted for finding the solution of arsenic removal from high arsenic-bearing pyrite concentrates through simple flotation process. By means of orthogonal experimental design, the optimized levels and main factors have been found out for the roughing stage. Through selection of the effective in-organic depressants for the arsenic-bearing minerals, the arsenic in the pyrite concentrate can be removed to meet the requirement of sulfuric acid plant (As%=0.5%) by the open flotation process, i.e., one-time roughing and two-time cleaning.

Jan 1, 2014

By X. Q. Ma

The beneficiation test on low grade phosphate ore from a state of Russia is carried out. The rougher-cleaner ? re-cleaner system is used in the flotation process, The fineness of grind is 39.07% minus 200 mesh. The result indicates that concentrate containing 31.25% P2O5 can be obtained from the flotation feed assaying 6.18% P2O5, with 93.54% P2O5 recovery. The test result is also a guideline for further development of some currently operated phosphate beneficiation plants.

Jan 1, 2014

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper, molybdenum, rhenium and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2014

By Felipe Henríquez, Daniel Silva

"Traditionally, the implementation of an automated advanced process controller in any mineral processing complex is a challenge, mainly due to the quality of resources and technologies required, the uniqueness of each control solution and the uncertainty of the engineering hours needed to complete the task. Thus, the use of advanced and proven control technology becomes a key factor when deploying the control strategy. However, success would still not be possible without the presence of common sense, process knowledge and fundamental process data. Minera Los Pelambres, taking advantage of such factors and its accumulated process experience, implemented a novel and successful combination of MPC (Multivariable Predictive Control) and advanced control for secondary grinding and regrinding stages at its copper concentrator plant. In both cases, the control objectives are: being capable of processing a variable feed from the upstream process while at the same time avoiding to become a process bottle neck and yet, maintaining an adequate product quality (in terms of size distribution) to the process downstream. Additionally, for the case of the vertical regrinding mill (vertimill), the control system should also be capable of keeping an adequate circulation load and making an efficient use of the available grinding power. In either case, extending hidrocyclones availability while maintaining their performance is a must, since both factors are required for process and maintenance purposes. Thus, the process control problem becomes one with a multi-variable type of process with multiple control objectives to satisfy simultaneously. In trying to solve it, many mineral processing operations have implemented basic or conventional control or even better yet, expert systems. Minera Los Pelambres believes that better and faster results can be achieved using a combination of MPC and advanced control. Such strategy was successfully implemented, reducing considerably process variability while maintaining high throughput and keeping the process well within constraints limits. Their control philosophy, implementation process, main results and their key performance indicators are discussed here."

Jan 1, 2014

By W. Z. Yin

It is investigated systemically in this paper that the granularity of the precursor, ZnC2O4?2H2O, is influenced by synthetic conditions. Instantaneously adding of precipitation agent is able to control the mean size of precursor ZnC2O4?2H2O under 300nm, which has great function to obtain well-dispersed ZnO nanoparticles in the next step, pyrolysis. The pyrolysis kinetics model of ZnC2O4?2H2O powder is obtained. Two steps take place during the pyrolysis. The first is dehydration, which the pyrolysis kinetic model is 2(1-a)2/3(chemical reaction), A=8.3×108s-1, E=(75.82±3.00) KJ/mol. The second is formation of ZnO, which the pyrolysis kinetic model is (1-a) (random nucleation and latter growth), A=8.45×1028s-1, E=(360.54±12.00)KJ/mol. ZnO nanoparticles obtained by pyrolysis take on self-growth behavior. It is resulted that for precursor ZnC2O4?2H2O pyrolysis time takes obvious influence on the partilces size under 420?, 500? and 600?. Finally, a new flow sheet for synthesis of ZnO nanoparticles is investigated, in which blendes is used as raw material and hydrometallurgy is introduced into it. The whole flow sheet has no industrial wastes, that is all byproducts can be used in the flow sheet recycled, resulted in the de-crease of productive cost and industrial wastes.

Jan 1, 2014

By K. Anand Rao

Extensive exploration for uranium metal by the Department of Atomic Energy in India led to the discovery of new carbonate host rock uranium deposits Tummalapalle and Gogi, which are located in southern part of India. Alkaline leaching at elevated temperature and pressure using autoclave is the central unit process in the overall strategy for extraction of uranium from these new ore deposits. Autoclave leaching is affected largely by intrinsic nature of the ore and by the process variables and the equipment settings. In order to understand such a complex process and also to be able to predict the process performance under randomly (ore grade, uranium mineralogy, gangue mineralogy etc.) and consciously perturbed variable settings (partial pressure of oxygen, temperature, concentration of leachant, stirring speed and time), sound and robust mathematical models are needed with analytical and/or numerical solutions. Present investigation attempts to develop a variant of kinetic correlation based on shrinking core model for batch alkaline leaching process in an autoclave. The leaching model incorporates particle size distribution according to popular Gates-Gaudin-Schuhmann equation, rather than assuming a single mean size for all the particles participating in the leaching reaction. Kinetic experimental data generated in autoclave leaching of Gogi uranium ore was used to evaluate various constants of the model developed. The ore sample used for experiments assayed 0.21 per cent U3O8. The partial pressure of oxygen was varied between 0.15 to 6.5 atm, temperature from 343 K to 438 K, concentration of sodium carbonate leachant in the range 0.47 g mol/L to 0.94 g mol/L, and the stirring speed from 573 rev/min to 900 rev/min in the experiments. The goodness of fit of the leaching process model is found to be >0.95. Morphological studies carried out on leached and unleached particulate matter using Scanning Electron Microscopy with Energy Dispersive X ray analyses are included in the present study.

Sep 1, 2012