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By M. Illikainen

Limestone is used for neutralization of acid leachates in a number of hydrometallurgical processes. The aim of this study was to clarify how limestone ground to different particle sizes can neutralize sulfuric acid. The laboratory scale ball mill was used in grinding experiments carried out using ball sizes of 20, 30 and 40 mm and volumetric slurry densities of 30, 40 and 50 percents. Varied grinding times were used in order to produce limestone samples with different particle size classes on which the neutralization potential and rate were determined. The results of the study showed that the neutralization potential of limestone is not dependent on its particle size between 5 and 120 µm. However, the particle size strongly affected the neutralization rate of sulfuric acid: The smaller the particle size, the higher the rate of neutralization. Thus, when optimizing the cost efficiency of the process, the optimal degree of grinding should be considered taking in account the required residence time in neutralization phase.

Sep 1, 2012

By Y. Q. He

The dynamic behaviors of the air bubbles in the dense gas-solid fluidized bed have a significant effect on the performance of dry coal separation. The combined method of experimental measurement and numerical simulation were conducted to conduct the research of the mean diameters and rising velocities of the bubbles in the fluidized bed. The calculation models of mean diameter and rising velocity of the single bubble were proposed. The results indicate that the models of the mean diameter raised by Rowe (1976) and the rising velocity raised in this work could be used to predict the bubble dynamic parameters in gas-solid fluidized bed. With the Geldart B type of magnetite powder as the medium solids and while the gas velocity of 1.5Umf=U=2.2Umf, the mean bubble diameter along the bed height is 36mm<Db<45mm, and the mean rising velocity of the single bubble is distributed in 40~65cm/s. The results of experimental measurement, numerical simulation and model predication provide well agreements finally. Based on the uniform fluctuations of air bubbles diameters and their rising velocities, the separation experiments of 50~6mm dry coal using the mixture of 0.3~0.15mm magnetite powder and <1mm fine coal as medium solids were carried out. The results show that the probable error, E is 0.06, which indicates a good separation performance by using the gas-solid fluidized bed. Keywords: dense gas-solid fluidized bed, bubble dynamic behaviors, numerical simulation, separation performance

Sep 1, 2012

By S. Mohanta

In composite washeries optimization of operating parameters to achieve maximum clean coal yield at the desired clean coal ash level is a major problem. This problem is more acute in countries like India, which have predominant reserves of difficult-to-wash coals. The constrained operational parameters of washing for some equipments make it more severe. In addition to this, the dependence of separating performance of different equipments upon various variables aggravates the situation. Here an attempt is made to find a numerical solution to get maximum yield and minimize the difference between the actual and the theoretical yield. The solution is arrived through constrained non-linear optimization of a multivariable objective function that utilizes spreadsheet tools; the method accommodates any number of source coals or washing size fractions. By using a designed Ep value the predicted yield of composite clean coal has been calculated and the yield is optimized subject to constraints on both the ash and specific gravity. It is shown that operational constraints of different washeries in the composite plant that utilizes gravity separation methods can also be over-come. The technique offers the coal preparation engineer an effective and straightforward method for determining the optimum cut-points of separation for different coals or blended coals to obtain maximum product yield at a specified level of ash content.

Jan 1, 2014

By Vladimir Vigdergauz

"Electrochemical studies of metal sulfides in connection with their floatability are discussed. According Frumkin, sorption of electroneutral organic substances has a maximum near the potential of zero charge. This idea initiated attempts of application of electrochemical methods for the controlling of organic collector sorption and mineral flotation. The lecture reviews results of electrochemical studies of the processes taking place during sulfide flotation: redox-state of mineral surfaces and xanthate solutions, xanthate sorption and hydrophobic layer composition, surface wettability and flotation recovery of sulfide minerals. Redox-transitions of minerals, transport of ions and charging of mineral surfaces, electroreduction of dissolved oxygen and accompanying processes of oxidation of minerals and reagents-collectors, - all these matters became the subjects of detailed research. Cyclic voltammetry, rotating disk electrodes, spectro-electrochemical techniques and other modern experimental methods now routinely accompany studies of mineral processing. Relatively new electroanalytical techniques like the voltammetry of mineral particles immobilised on electrodes using polymeric binders have become extremely useful for studying weakly conductive minerals and dispersed flotation products. Full discussion of electrochemical studies of metal sulfides in relation to mineral processing must include bioelectrochemistry and electrocatalysis which open exceptional possibilities for selective leaching of gold and non-ferrous metals. At this time, the paper focuses on the sulfide flotation as a potential-dependent process; the problem of oxygen and its influence on the sulfide flotation; the electrochemical aspects of xanthate oxidation and sorption; theory of suspended electrodes as applied to the mineral slurries and experimental study of the effect of electrochemical pretreatment of flotation pulps."

Jan 1, 2014

By F. Karakas

Organo-bentonite production enjoys important applications including solvent based paints and, more importantly, the production of polymer/bentonite nanocomposites. Quarternary ammonium salts in this regard are still considered as the most versatile reagents in the process of hydrophobization. In this study, a purified form of Resadiye region bentonites, which is one of the most significant sodium bentonite deposits in the world, was used. The raw Na-Bentonite was typically characterized by chemical analysis, XRD and DTA analysis and more importantly for its cation exchange capacity (CEC). Other technological properties such as swelling index, pH, apparent viscosity, water absorption, oil absorption were also conducted on the raw bentonite. The mineralogical analysis of the raw bentonite reveals that it contains about 80 % montmorillonite together with other associated gangue minerals including feldspar, quartz, calcite, dolomite, coloured impurities and other clay minerals. The raw bentonite was subjected to two stage processing involving a series of hydrocylones. Different apex and vortex diameters and different pressures were employed in order to produce a bentonite concentrate with 95 meq/100g CEC from a CEC of 71 meq/100 g. This high quality concentrate was used in the production of organo-bentontonite. The modification was performed with two different quaternary amines, i.e. Trimethyl Phenyl Ammonium Chloride (TPAC) and Hexadecyl Trimethyl Ammonium Bromide (HDTMA-Br). In the modification procedure, three parameters, i.e., adsorption density, zeta potential, swelling index and apparent viscosity were studied simultaneous-ly from the same suspension to identify both the mechanism of the process and also the degree of hydrophobicity. Adsorption measurements were made as a function of conditioning period, pH, and reagent concentration. Simultaneous examination of the adsorption density, zeta potential and apparent viscosity enabled us to pinpoint the optimum region of hydrophobicity which was subsequently tested by settling and critical coagulation concentration in both water as polar and toluene as nonpolar solvents. The results are analyzed in the light of experimental data.

Jan 1, 2014

By Alan Bye, Nick Beaton, Wayne Stange, Emmy Manlapig, James Groutsch

"For over 50 years the JKMRC has applied a unique education-based research strategy to develop modelling and simulation tools that are "fit for purpose" for industrial application. These tools are widely used for the analysis and optimisation of mining and mineral processing systems. As the mining industry context evolves to deal with declining head grades, falling commodity prices, professional skill shortages, and an exponential growth in the volume of data, a re-evaluation of what "fit for purpose" means in the future is required. It is contended that future industry needs for simulation-based decision support requires tools and systems that incorporate: • Multi-component modelling, • Models of complex sensor behaviour, • Integration across the physical value-chain e.g. resource to market, • Financial analysis including risk and uncertainty assessment, • Enabling multi-criterion decision making (technical, financial and environmental), • Ore-body knowledge at multiple scales, • The use of fundamental numerical models to provide insight for the development of practically useful models, and • Decision support delivered through remote operations centres. JKMRC and CRC-ORE are collaborating to develop a next-generation simulation-based decision support system that assists in addressing these challenges. The Integrated Extraction Simulator (IES) combines many years of pragmatic and successful work integrated with modern technology trends - in particular the rapid move to cloud-based computing."

Jan 1, 2014

By D. Renda

With thise Process of obtaining a solid fuel which is both ecological clean and has a high calorific value by a two-stage method of enriching preferably type lignitic coals to remove a high content of all sulphurs, incuding organic sulphur, which method comprises converting the coal to a semi-coke from followed by magnetic separation. In the Experiments given the best results the washed lignite coal in the West-Turkey, Tavsanli- Region, size -3.35 mm on dry basis. In the microscopic studies of the brigh-thin cross-section taken from the samples of sulfur min-erals pyrite in the dimension of 2~50 micrometers and melnicovite 10 micrometers particles. An thermal treatment an semi-coking themperature between 370°C to 650°C give the best Result of 480 °C. The oxidation and decomposition of sulphur minerals pyrite and melnicovite in lignite coal proceed the iron oxides Fe2O3 and pyrrhotite FeS on the surface layer. The Magnetic Seperator (Rare Earth Magnetic Separator, REMS) is capable this two form of sulphur, including organic and inorganic sulphur, in semi-coke and resulted in the magnetic-fraction in REMS. The non-magnetic-fraction remove total sulphur by 68 %, ash by 44 % and increase the upper calorific value in 15 %. The clean lignitic coal can be utilized in human or energy power stations.

Jan 1, 2014

"The Circular Economy (CE) will play an important role in shaping a resource-efficient society. Enabling this transformation from a linear to a CE requires precise quantification of resource efficiency and thus the economic viability of the system. Based on the development of simulation tools of classical minerals processing and process metallurgy, the Outotec (2018) HSC simulation platform could be further developed (gleaning from many academically published works of the author listed below), permitting the simulation of the CE system and to subsequently calculate its resource efficiency. It enables the estimation of a simulation-based Recycling Index (RI) from a product’s Bill of Material (BoM) and Full Material Declaration (FMD). It is a unique methodology for Design for Recycling (DfR) based on minerals engineering linked to a deep understanding of minerals and metallurgical process engineering. A key to this simulation is a detailed understanding of the mineralogy (both geological and designed) of the CE system and its many products, materials and systems, both in a geological mineral and a product-designer-mineral sense. In addition, a detailed understanding and quantification of the thermodynamic properties of the system (both energy and exergy/entropy) is key to understanding its economics and its limitations. With this approach, the actual losses of the CE system are shown and thus highlights the limits of the CE as defined by minerals and metallurgical process engineering principles. INTRODUCTION From the dawn of the industrial era up to today, many of our products have been created according to the principles of a linear economy: we find resources, make a product, and then dispose of it when we are done using it. But in recent years, there has been a growing awareness of the need to move to a Circular Economy (CE), an approach that aims to maximize the usefulness of products, components and materials across the entire lifecycle. In terms of recycling, this means achieving maximum recovery of materials once products reach the end of their usable life while also maximizing resource efficiency. Of importance is therefore also not only the recovery of critical technology elements that make the CE system run, but also the criticality of the metallurgical infrastructure that must be present to recover these elements economically. Ellen Macarthur (2017) defines the CE as “Looking beyond the current ""take, make and dispose” extractive industrial model, the circular economy is restorative and regenerative by design. Relying on system-wide innovation, it aims to redefine products and services to design waste out, while minimising negative impacts. Underpinned by a transition to renewable energy sources, the circular model builds economic, natural and social capital.” However, when translating this significant message to images, it is striking that the key extractive industry is not depicted in the Ellen Macarthur as well as EU depiction of a CE (EU 2015). Other CE discussions are also wanting in their fundamental detail and description e.g. Accenture (2015) and Beaulieu et al. (2016)."

Jan 1, 2018

By C. V. G. K. Murty

Sillimanite, chemically named Aluminum silicate, 3Al2O3SiO2 is one of the three forms of alumino silicate polymorphs and commonly encountered in aluminous metamorphic, plutonic, and volcanic rocks and their weathering products. Most of the sillimanite deposits are granular and are of high grade available in coastal areas as associated mineral along with Titanium bearing minerals namely ilmenite, rutile etc. Sillimanite is one of the widely accepted raw materials for the manufacture of high alumina refractories (55-60 % alumina) or bricks. Sillimanite based refractory bricks are used for the lining of Blast furnaces, Arc furnaces, Soaking pits, Reheating furnaces of iron and steel, rotary kilns for cement manufacturing and general kilns for lime production. Considering the vast potential of unexploited sillimanite reserves in India, M/s Trimex Sands Pvt. Ltd., (TSPL)has set up a Mineral Sand Processing plant in 2010 at Andhra Pradesh with a capacity to produce about 50,000 tons of sillimanite per annum besides the production of various heavy minerals such as ilmenite, rutile, zircon and garnet. Traditionally in India, sillimanite is upgraded by froth flotation technique using Oleic acid as a collector cum frother, sodium silicate as depressant and soda ash as pH regulator. At TSPL, Conventional mechanical float cells are installed to float sillimanite. In addition to the usual problems associated with conventional cells, poor flow ability of the sillimanite concentrate is experienced in dry circuit due to the presence of sodium oleate. Fine garnet in the sillimanite concentrate contributes to high iron content in the final product, making sillimanite separation a nightmare for operators (lower recoveries coupled with inferior grades). Various efforts were made to improve the performance of the circuit such as introduction of additional frother like MIBC, optimizing the operating parameters such as pulp density, collector dosage, depressant dosage, air flow rate, pH etc., use of collector aids, stage wise addition of reagents etc. The challenges faced to produce a sillimanite product with stringent quality norms and the efforts made to improve the grade and recovery are described in this paper. Keywords: sillimanite, froth flotation, conventional mechanical cell

Sep 1, 2012

By Shounak Banerjee, Suresh Babu Dasari, Dharmendr Kumar, Shashank Pardhikar, Beena Rai, Venugopal Tammishetti

Recent increase in steel demand has led to the increased usage of high grade iron ores. During the mining, crushing and washing of ore, huge quantities of fines and slimes (<150 µm) are generated, majority of which is dumped into tailing ponds owing to their high alumina contents (~10-15%). Due to rapid depletion of high grade iron ore, it is the need of the hour to utilize low grade iron ore fines and slimes. These fines and slimes contain high iron values assaying 45-60% Fe. Dumping these valuable resources in ponds locks enormous land space and causes environmental hazards. The constituent minerals present in Indian iron ores comprise of hematite, goethite, gibbsite, kaolinite and quartz. Our research is focused on beneficiation of iron ore slimes through selective flocculation. We use density functional theory simulations to screen the reagents and perform experiments with screened reagents to determine the experimental conditions for effective performance of the reagents. Our studies revealed that reagents like starch, guar gum and carboxymethyl cellulose exhibit excellent selectivity in high alkaline pH range. However, the higher cost of alkali makes the process economically less attractive. In the present study, a commercial reagent from NALCO Water (Hi-Tex 83570) has been explored as selective flocculant for beneficiation of iron ore slimes in wide pH range (4-11). However, the reagent was also found to be the most selective in alkaline pH range only. Full factorial design of experiments was done considering three parameters namely, pulp density, flocculant dosage and settling time. Regression models were developed for yield, iron grade, alumina grade and iron recovery in the concentrate, using experimental results. Further parameter optimization was done to achieve high Fe recoveries and low alumina recoveries. The optimal parameters thus arrived at were validated with the experiments. We were able to achieve a concentrate grade of 60.0% Fe and 5.1% Al2O3 with 68.8% Fe recovery from a feed containing of 53.1% Fe and 8.9% Al2O3. The performance of flocculant Hi-Tex 83570 was also compared with reagents starch and guar gum.

Jan 1, 2018

Systemic process mineralogy study on Baerbulawu refractory hematite ore in Kazakhstan has been carried out. The ore contains Fe 41.34%, and 87.26 % of which exists in hematite. Most hema-tite occurs as fine or ultrafine grains and its average size is only 0.015mm. The gangue is mainly composed of quartz, mica, chlorite, kaolinite and other clay minerals. The liberation of hematite is only 66% when the ore is grinded to 75% ?0.074mm, while part of gangue is already liberated from hematite under this grinding condition, so these gangue can be cast away by magnetic separation in advance. Hematite will not liberate completely from gangue untill grinding fineness reaches 86% ?0.038mm, at the same time, free particles of ultrafine hematite tend to coagulate randomly with quartz and clay minerals, so appropriate dispersant is necessary to pre-vent hematite and clay minerals from coagulation. Based on the process mineralogy research, final technology flowsheet is high-intensity magnetic separation by coarse grinding?rough magnetic concentrate regrinding?inverse flotation, and an ideal index is achieved. The yield of final iron concentrate is 43.46%, and its grade and recovery are 66.76% and 70.55% respectively. The research result is also useful to other similar iron ores.

Jan 1, 2014

By Duong Huu Hoang, Nathalie Kupka, Urs A. Peuker, Martin Rudolph

"The froth ability, froth stability and the froth structure are strong influences in flotation process i.e. on water recovery, bubble size, entrainment of gangue particle, flotation rate constants, grade and recovery. The labscale flotation of rich apatite ore with a high mass pull leads to significant changes in pulp and froth properties over time. The froth stability decreases with increasing the flotation time. These changes can be related to different solid contents, reagent concentration, froth heights and bubble size distributions. This study presents the results from froth studies and discussions on the particle size of fully liberated silicates and degree of entrainment based on automated mineralogy size-by-size analysis. The change of entrainment in a rich apatite ore batch flotation with time will describe more precisely by measuring froth properties using a Dynamic Foam Analyzer. It is concluded that the degree of entrainment is not only dependent on particle size but also the pulp density due to its effect on particle settling and also froth properties in varying resistance to particle drainage. Furthermore, entrainment models are applied to predict the effect of size, flotation time on entrainmentINTRODUCTIONFroth flotation belongs to the group of heterocoagulation separation techniques. Froth flotation is classically divided into two active zones, the pulp zone (where particle collection occurs) and the froth zone. A schematics drawing of the interaction between both zones is plotted in Figure 18 (Yianatos and Contreras, 2010). In froth flotation, the collision probability in the collection zone is governed by the physics of the process or hydrodynamics (Wills and Finch, 2016). The true flotation event in the pulp occurs when the hydrophobic valuable mineral particles collide with bubbles and formation of a stable particle-bubble aggregates moving upwards against gravity to the froth phase (Yianatos et al., 2009)."

Jan 1, 2018

By T. V. Chnyrenkova, J. Troncoso, V. A. Luganov, G. P. Kluev

"Arsenic-gold bearing ores are used as flux in smelting or are leached to extract gold. The main aim is to decrease the arsenic content in processed materials and to break up the ore lattice, thus liberating the gold. Some regulations were established by authorities for sulfidizing of arsenic bearing compounds in a presence of pyrite and for oxidation of ores and concentrates in the presence of soda.This article analyses the results of laboratory and pilot plant testing of dissociating and oxidizing roasting of gold-arsenic bearing concentrates. During the dissociation roasting under vacuum, arsenic is sublimated into elemental and sulfide forms. This process allows for the minimization of the negative influence on the environment, but requires costly engineering solutions. Roasting in a limited quantity of oxygen in the gaseous phase makes it possible to sublimate arsenic in the form of oxides and sulfides and it may be carried out in fluid bed furnaces.Oxidizing roasting of the concentrates in the presence of soda results in formation of water-soluble compounds and forces practically all arsenic and sulfur to remain in the cinder."

Jan 1, 2003

By Auhin Kumar Maparu

Metal oxide nano-particles are used as additives in various industrial applications such as pigments in paints, additives in adhesives, plastics, cosmetics, functional coatings, personal care and health care products, for antibacterial applications and more recently in heat transfer applications. In most of these applications, usually dry nano-particle powders are added to the formulations. However, often it becomes difficult to achieve a uniform and stable dispersion of nano-particles in the given formulation. Thus, a scalable and commercially viable process for in-situ production of stable nano-particles suspensions in the desired medium will certainly be more beneficial. Ultra-fine grinding in high energy mills (planetary mill, stirred media mill) has been used to produce fine particles (sub-micron size). However, in order to obtain nano-particles (particle size <100 nm), the choice of appropriate dispersant and solvent is crucial, since freshly generated nano-particles tend to agglomerate due to their high surface reactivity. We have employed molecular modeling (MM) based selection methodology to arrive at the most suitable solvent?dispersant combination for preparation of the given metal oxide nano-particles. Molecular modeling techniques are employed to compute the interaction energy of a given dispersant with surface of the metal oxide particles in the presence of the dispersion medium. The interaction energy helps identify a dispersant that has strong affinity for the metal oxide surfaces allowing for strong dispersant adsorption and hence a more stable dispersion. For example, in case of aqueous nano-titania suspensions, poly-carboxylic acids like citric acid provide better dispersion than mono-carboxylic acids like lauric acid, mysristic acid, and oleic acid. While in non-aqueous medium like ethanol, p-hydroxybenzoic acid and glycerol trioleate perform better. The suspension is produced in-situ by ultra-fine grinding of the metal oxide powder in the presence of the selected dispersant and dispersion medium in a planetary ball mill. By careful selection of various process parameters such as percent loading of powder, jar filling, grinding media to powder ratio, time and amount of dispersant addition, both aqueous and non-aqueous suspensions of metal oxide nano-particles with average particle size less than 100 nm are produced. The aqueous suspensions of alumina and titania produced in presence of citric acid dispersant exhibit median particle size of 83 and 62 nm, respectively. These suspensions have been found to be stable for nearly 3 years. The nano-particles thus produced are used in the preparation of nano-fluids?advance heat transfer liquids, which show enhanced heat transfer capabilities and unaltered stability and performance even after several heating-cooling cycles. The nano-particles are also utilized for making efficient photo catalysts, which are found to be highly effective under sunlight. Keywords: stability, nano-fluid, milling, grinding, thermal conductivity, nanocoolant, photocatalyst

Sep 1, 2012

By G. K. Nimal Subasinghe

The performance of Knelson Concentrators (KC) used in gravity gold circuits often rely on manufacturers recommendations for selecting operating parameters such as, fluidising water flow rate and cycle time. These parameters are not only dependent on the machine parameters but also on the feed characteristics such as, size distribution of the gold and gangue particles and the composition of its constituent minerals. Particles entering a KC experience a centrifugal acceleration due to the high bowl rotational speeds. The required centripetal force to maintain a circular orbit is provided by the fluid drag force created by inwardly moving fluidising water and the Bagnold?s force arising from the particle/particle collisions. When the fluidising water flow rate is low particles move towards the outer rim of the bowl forming a packed bed within the grooves. On the other hand, if the fluidizing water flowrate is high the bed expands and some particles would move towards the centre of the bowl and gets carried to the tailings stream, thereby reducing the amount of material retained within the grooves of the bowl. Based on a force balance on a particle captured within the KC, a criterion which can be used to predict the amount of material recovered in the bowl has been derived and validated by experimental data. It has been shown that this criterion may be used to demarcate the transition of the bed from a packed-bed state to a fluidised state depending on the fluidizing water flowrate. By identifying the conditions for the optimal expansion of the bed comprising different constituent mineral particles, it is possible to estimate the optimal fluidising water flow rate that would maximise gold recovery while minimising gangue recovery. It was also observed that the accumulation of valuable mineral in the bowl takes place by the displacement of the gangue particles in the bed by the incoming heavy mineral particles. The kinetics of this segregation process was also studied using synthetic mineral mixtures. The experimental data suggests that this process follows first order kinetics and that the build up of heavy mineral reaches a maximum which could be used to identify the optimal cycle time. In this work, the suitability of the above model in optimizing the performance of a KC have been reviewed. Also the necessity and merits of testing an unaltered feed samples in a larger KC as op-posed to the commonly adopted GRG test has been discussed.

Jan 1, 2014

By B. K. Gorain

Mining of low grade deposits along with the necessity to design and operate flotation plants with high throughput presents unique metallurgical and environmental challenges that need to be addressed to reduce project risks, improve project economics and to sustain the profitability of operations over the life of a mine. Some of the key challenges include poor recovery of valuables and concentrate quality issues due to complex mineralogy, the need to use poor quality water such as brackish or sea water, reduce environmental impact from the process, integrate flotation with hydrometallurgy to maximize precious metals recovery, escalation of capital and operating costs, use of unproven technology and constant use of larger equipment, high ore variability, worldwide constraints on resource availability and an ever increasing need for reliable metallurgical input to financial models to evaluate economic viability of projects. The need to develop effective solutions to these problems in a short time frame is becoming a key to the success of any new project and for sustaining the profitability of a mining operation. An integrated multi-disciplinary approach to problem solving is crucial with the need for a more lateral thinking along with strategic partnerships and collaboration involving the right players. This paper presents some of the key findings based on experiences from a large number of challenging projects and operations focused on solving complex flotation problems Keywords: mineral processing, flotation, flotation problem solving, flotation optimization, plant design, innovation

Sep 1, 2012

By Ingvar Ymén, Anders Sandc, Jan Rosenkranzc, Lisa Malma, Ann-Sofi Kindstedt Danielssonb

The understanding of particle surface properties is essential for the study and evaluation of froth flotation phenomena, particularly in the investigation of various chemical or reagent effects. Dynamic Vapor Sorption (DVS) is a method used for the analysis of surface properties of powders for instance in the pharmaceutical industry. To the knowledge of the authors, it has however not been used before in applications related to mineral processing. The DVS technique involves measurement of the water uptake of a relatively small amount of sample as a function of the relative humidity (% RH) in a temperature-controlled environment. The purpose of this work was to evaluate the method and investigate how it can complement existing techniques for surface characterization in mineral processing. Four samples (feed, CuPb concentrate, Cu concentrate and Pb concentrate) from the Cu – Pb flotation process in the Garpenberg concentrator, Sweden, were analyzed by DVS and the traditional capillary absorption technique (Washburn capillary rise). This enabled comparison between the two methods and evaluation of their respective advantages and disadvantages. Both methods give the expected ranking of the hydrophobicity for CuPb concentrate, Cu concentrate and Pb concentrate, but a discrepancy was observed for the feed. Washburn gave a value for the contact angle which was in the same range as for the CuPb concentrate, whereas DVS gave a value for the moisture uptake which was much higher than for the CuPb concentrate. Thus, DVS ranks all samples correctly, but with an unexpectedly high value for the feed whereas Washburn gives good ranking for three samples out of four. Potential reasons for the discrepancies are discussed.

Jan 1, 2018

By M. Surracco, M. C. Tilocca

"Mineral comminution is often a costly process which also requires high level of energy. In the course of the studies carried out by the researchers of the Department of Civil-Environmental Engineering and Architecture at the University of Cagliari, aiming at the optimization of the reduction processes, it has been experimented, among of others, the effects of high-speed water jets on minerals grinding. As far as coal is concerned, some of the solutions initially adopted are presented in this paper, which essentially relied on the water jet power only, with secondary use of mechanical actions, to reach the most modern solutions that envisage the use of mechanical energy, normally used in traditional grinding machines, in synergy with hydraulic energy transferred by water jet.INTRODUCTION Mineral comminution can be rather expensive and demand a high-energy consumption, especially for fine sizes (Austin, 1979). Further interesting perspectives in this area may be offered by comminution means aided by high pressure water jets (Ciccu 2007), whose crushing potential is currently used for several operations such as cutting different materials, rock digging and industrial cleaning. The crushing action of water jets may induce a traction stress in materials where substances of a mineral nature, especially if characterised by permeable porosity, oppose a minor resistance (Griffith, 1920). The first solutions to this purpose essentially relied on the sole energy of water jets, with a secondary use of mechanical actions (Ciccu, 1993). Results were encouraging, despite the high values of specific energy for the low capacity of treatment. However, due to the difficulty in making the techniques mainly based on hydraulic energy practically applicable to solids comminution a solution was experimented, with some interesting results, consisting in the combination of mechanical energy, normally used in traditional grinding devices, with hydraulic energy transferred through water jets, in a synergic relationship (Ciccu, 1998; Tilocca, 2016)."

Jan 1, 2018

By A. K. Suri

India plans to increase the nuclear power share in overall energy-mix to about 30% by 2032 using both indigenous and imported reactor technologies. In the immediate time-frame, it is envisaged to generate 10000 MW electricity by PHWR technology by 2020 using indigenous uranium resources. This necessitates setting-up of new uranium mills and augmenting the existing resource, mining and milling capacities. This paper describes the current status and future R & D needs towards achieving the targeted demand of yellow-cake. Keywords: uranium, hydrometallurgy, leaching, yellow cake

Sep 1, 2012

By T. Wallmach, S. B. Blancher, A. Delaporte, P. Goncalves

"Fe-Ti oxides concentrates produced from heavy mineral sand deposits are widely used for the production of titanium dioxide pigments that are critical components of white paint, plastics and paper. According to mining industry, the Fe-Ti concentrates mostly consists of three phases: ilmenite, leucoxene and rutile. However, a few mineralogical studies have shown that the variety of Fe-Ti oxides found in sand deposits is far more complex, mostly due to alteration processes. The aim of this contribution is to characterize in detail by means of Qemscan analyses the mineralogy of the three main concentrates (ilmenite, leucoxene and rutile) produced by the Grande Côte Operation (GCO) mineralurgical plant in Senegal. The ultimate goal is to characterize the different products and textures formed during the natural ilmenite alteration processes, to localize the phases carrying the main impurities (Cr and P), and finally to determine the physical properties of each mineral component to improve metal recoveries. Along alteration processes, Ti content increase. Ilmenite (FeTiO3) is progressively transformed into pseudorutile (Fe2Ti3O9) particles which could also be altered and transformed into hydroxylian pseudorutile [FeTi6O12(OH)3.3H2O] or complex blends of anatase microcrystals (TiO2). These transformations are accompanied by significant changes in particle textures. Microporosity and fractures appear and the impurity content also increases. Anatase rich microcrystal assemblages, so far described as Leucoxene, could be identified to consist of grains with higher porosities, water contents and higher intrapore impurities. These particles are the main carriers of chromium and phosphorus. The observed mineral transition textures have a significant impact on the ore dressing processes. During these transformations, the physical properties of these phases change, the magnetic susceptibility as well as densities decreases, due to the increase in porosity. The separation of particles, especially those with high porosity will help improving the GCO mineralurgical plant performance and to reduce the impurity contents in finals products."

Jan 1, 2018