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By Zhang Zhonghan

A domestic tungsten-tin ore presents very complex property. How to effectively recover the scheelite, wolframite and cassiterite in the ore has long been a difficult problem to be solved urgently. On the basis of process mineralogy study, a main flow-sheet for effective recovery of tungsten-tin minerals has been developed, which including ?fine grinding of feed?bulk flotation of all sulfides followed by their selective separation?iron recovery by LIMS?tungsten-tin minerals bulk flotation using new technique developed by our institute?tungsten-tin recovery by gravity from above tungsten-tin bulk flotation tailings?. As for the treatment of tungsten-tin bulk rougher concentrate, several flow-sheets of tungsten-tin separation by direct hydrometallurgy or a flow-sheet consisting of scheelite cleaning at elevated temperature followed by the gravity separation of scheelite cleaner tailing?separation of wolframite from cassiterite by dry HIMS or by direct hydrometallurgy are developed. For a low grade head ore, all valuable sulfide, magnetite, scheelite, wolframite and cassiterite are recovered with satisfactory in lab scale test. Keywords: micro-fine cassiterite, tungsten-tin bulk flotation, gravity separation-flotation-dry HIMS combined flow-sheet, hydrometallurgy

Sep 1, 2012

By S. Banisi, A. Haji-Zadeh, H. Asadi, M. Maleki-Moghaddam

One area in AG/SAG milling field which has received a great attention is the optimization of liner design for any application to increase the availability of mills. The Gol-E-Gohar iron ore concentration plant uses three 9m × 2.05m autogenous mills (AG) in parallel in a dry operation. The AG mill shell is lined with three series (57 cm each) of 36-row liners. Due to large variations in feed characteristics and inadequate blending, the performance of AG mills has been lower than the target value. Therefore, to improve the comminution efficiency, the optimization of the design of AG mill shell liners was applied in this plant. By simulation it was found that increasing the liner lifter face angle from 7 to 30° while maintaining the original lifter height (i.e., 22.5 cm) could provide an appropriate charge trajectory. Measurement of the wear profiles of shell liners indicated that the wear along the liner length was not uniform and the highest wear occurred between 0.5 m and 1.2 m of the mill length. A new liner design was proposed by redistributing the metal from parts with a lower wear rate to the parts with a higher wear rate to arrive at a uniform wear profile along the liner length at the liner removal time. The non-uniform shell liner was constructed and installed in one of the three parallel dry AG mills. It was found that the first and second liner designs increased the mill throughput by 2.6 and 7.5%, respectively. After conversion to SAG milling on the account of liner change, 18% (from 413 to 489 t/h) increase in throughput was realized. It was predicted that the non-uniform liner designs will increase the liner life time by 10% and will reduce the scrap metal from the current value of 59% to 50%.

Jan 1, 2014

By B. Tora

The new method of evaluation of grindability of hard coal and its blend is shown. Standard Hardgrove test is used as a base to work out this method. The essence of this method consists of simulation of milling process in close circuit (mill-classifier) and determination of energy consumption and quantity of product under the constant feed flow. The research equipment designed specially for this project is described New method of grindability measuring completes standard Hardgrove method withdrawing its faults: ? bigger (c.a. 10 times) and more representative sample is used; ? the milling process is carried out in close circuit (similarly to the industrial condition); ? energy consumption of the milling process is determined for three samples, which differs in grain size. The new method of evaluation of grindability of hard coal and its blend is shown. Standard Hardgrove test is used as a base to work out this method. This method allows us to determine energy consumption of the milling process. The essence of this method consist of simulation of milling process in close circuit (mill-classifier) and determination of energy consumption and quantity of product under the constant feed flow. Our results will complete the Hardgrove method and will help us to better characterise coal. At the same time investigations in industrial scale are carried out. These investigations will verify this new method. Also a new mathematical model of the milling process is being elaborated. It will be used to predict behaviour of coals in industrial conditions.

Jan 1, 2014

By Z. Pokrajcic

The traditional comminution circuit is a major consumer of energy ? both as electrical energy and through consumption of media and wear resistant liners. Up to 40% of electrical energy con-sumed at a mine site is attributed to comminution however only a few percent of this energy is used in the generation of new surfaces from size reduction. This paper describes the evaluation of modifications using simulation models based on two operating comminution circuits. The aim of these modifications is to decrease both the amount of electrical energy consumed in the size reduction process, known as direct energy, as well as to decrease the consumption of grinding consumables such as steel grinding media and mill liners, designated as indirect energy. The approach is two-fold: ??Employ, where possible, autogenous grinding techniques to eliminate the need for grinding media and reduce mill liner wear. ??Optimise the use of the grinding energy distribution in the comminution circuit by using more energy efficient grinding devices to target typically problematic features of a comminution circuit such as critical size material from the primary mill and overgrinding in the secondary mill. The investigations show that significant total energy savings, as high as 50% in some cases, can be achieved by employing the techniques described while maintaining circuit throughput and product size. Investigations also show potential benefits in downstream flotation processes as the product size distribution generated from the eco-efficient circuit is generally ?narrower? in shape for improved flotation performance and containing less material in the coarse fraction for overall better liberation.

Jan 1, 2014

The molybdenum ores currently utilized in China are mostly molybdenum sulfide ores whereas oxidized molybdenum ores, being finely disseminated and difficult to process, have not been exploited and utilized effectively. In this article the beneficiation process of a molybdenum ore occurred in an oxidized ore zone was investigated in order to provide a new way for the development and utilization of the oxidized molybdenum ores in China. The molybdenum mineral in the ore was mainly wulfenite and the associated minerals included barite, limonite, quartz and small amount of cerusite. Limonite in the ore occurred in a crust and honeycomb-like colloidal state and composed the framework for the formation of the other minerals in the ore, which filled the pores in the framework. Wulfenite was mainly fine-grained and occurred in the fine porous crust and honeycomb-like framework. The finely disseminated ore structure made the separation and recovery of the molybdenum mineral in the ore very difficult. On the basis of the mineralogical study of the ore, experiments were conducted to compare the various mineral processing methods for the beneficiation of the ore, including single gravity concentration, single magnetic separation, single flotation, and a combination of high intensity magnetic separation and gravity concentration. The results indicated that with single gravity concentration a molybdenum concentrate containing 5.85 % Mo with a yield of 11.76 % and a Mo recovery of 43.5 % was produced. With single high intensity magnetic separation it was very hard to obtain a molybdenum concentrate product. With single flotation process a molybdenum concentrate containing 7.06 % Mo with a yield of 15.14 % and a Mo recovery of 62.63 % was produced. With a combination of high intensity magnetic separation and gravity concentration a molybdenum concentrate containing 6.46 % Mo with a yield of 11.81 % and a Mo recovery of 42.11 % was produced. In conclusion, compared to the other methods the flotation process can produce more reasonable technological and economical results and is the best process for the exploitation and utilization of the finely disseminated oxidized molybdenum ore.

Jan 1, 2014

By W. H. Yong

The molybdenum ores currently utilized in China are mostly molybdenum sulfide ores, whereas oxidized molybdenum ores have not been exploited and utilized efficiently. The aim of this article is to study the applied mineralogy of an intergrown iron-molybdenum oxidized ore in order to provide a mineralogical basis for the ore beneficiation research. The ore occurred in a surface oxidized zone seam and contained 23.65% Fe2O3 and 1.58% Mo. Various characterization techniques were employed to study the chemical composition and mineral composition of the ore, the particle size distribution of the minerals in the ore, and the tex-ture and structure of the ore. The results showed that the iron-molybdenum ore occurred in a wet, soft and earthy state. The ore was composed mainly of several oxidized minerals and colloidal min-erals, including wulfenite, barite, limonite and quartz. Wulfenite was one of the major and stable components in the ore and occurred as a separate mineral. Wulfenite, barite and quartz were granu-lar minerals with particle size ranging from fine to coarse but mainly in the fine particle range. Li-monite showed a crust and honeycomb-like colloidal state and composed the framework in the ore for the formation of the other minerals. They filled the pores in the framework and the size of the pores affected the size of the minerals formed in the pores and hence the recovery of wulfenite in ore beneficiation. According to the applied mineralogical properties of the oxidized molybdenum ore, a promising ore beneficiation process was proposed as follow Magnetic separation should be carried out first to separate the magnetic iron minerals and then the molybdenum mineral will be recovered by gravity concentration or a combination process of gravity concentration and flotation, depending on the distribution of the molybdenum mineral in the product of the magnetic separation.

Jan 1, 2014

By Dee Bradshaw

"Process mineralogy’ is a form of applied mineralogy which focuses on addressing problems associated with the processing of ores. ‘Mineralogy’ is the scientific study of minerals and ‘mineral processing’ is the production of concentrates from ores. ‘Process mineralogy,’ however can be defined as the practical study of minerals associated with the processing of ores, concentrates and smelter products for the development and optimisation of metallurgical flowsheets, including the waste and environmental management considerations. This hybrid discipline consists of teams that include geologists, mineralogists, samplers, mineral processors and often others, working together. The degree of cross-training, communication and trust dictates the potential capacity of the team and where an appropriate work dynamic is fostered, in which relationships flourish as much as does the ethic of technical excellence, it is possible to develop technical capabilities that surpass those of conventional teams. The world’s demand for metals is ever increasing and ore deposits available for extraction and processing are lower grade and more complex, often containing deleterious elements that require tailored treatment. Generally, in the past, the technical challenges only needed to be overcome and assessed economically to make an ore deposit viable; increasingly and in the future, a more sustainable approach including environmental and societal considerations is needed. Process mineralogical assessment is increasingly providing the critical information that stands between failure or collapse and survival or success of some mining operations. In this paper, selected case studies are used to demonstrate the valuable role of the process mineralogy tools being used to provide the platform for innovative technology development. Their common attributes are discussed and distilled, thus providing some insights and potential guidance for addressing some of the likely future challenges of the mining industry."

Jan 1, 2014

By Arkady Senchenko, Yevgeny Zhagun, Yury Kulikov, John Starkey

"The paper contains description of a new project in Russia - gold-processing plant at Aleksandrovskoye deposit (start up in September, 2013). The paper includes a brief description of plant flowsheet, data for material composition and technological properties of ore, as well as information about the achieved parameters of ore processing over the first months of plant operation. The project is interesting because a new semiautogenous mill and a ball mill were purchased on the basis of SAGDesign Consulting Group recommendations after the testing of ore samples characterizing the deposit according to specific years of operation. The plant has relatively small design capacity - 750 000 tpa, but nevertheless is the biggest gold-processing plant in the territory of Zabaikalsky region. Major valuable component in the ore is gold, silver is recovered as a by-product. The ores are very hard to grind. The design grinding flowsheet includes a semiautogenous mill operating in closed circuit with a screen, and a ball mill operating in a closed circuit with hydrocyclones (SAB). Process technology includes gravity processing and flotation with subsequent cyanide leaching of concentrates. Mill operation analysis and conclusions about the compliance of the achieved values to target ones are shown, as well as the accuracy of SAGDesign method when applied to very hard ores of Aleksandrovkoye deposit are presented in this paper. Basic directions of technological flowsheet optimization are also given."

Jan 1, 2014

Hydrofluoric acid (HF) is traditionally used in plant operation to separate feldspars from quartz. It acts during the conditioning step as a pH regulator and an activating agent providing an excellent selectivity. However, a corrosive chemical environment and the ecological impacts from the potential fluoride ion contamination are limiting factors to use this chemical agent at an industrial scale. Investigations of the amine-feldspar interactions in the absence and presence of non-linear long-chain alcohols were carried out on two ore samples. The presence of alcohol molecules led to form a closed packed layer only on the surface of feldspars. The highest order and packing at the feldspar surface were observed with a particular alkyl chain structure as Guerbert alcohols. A new flotation process was developed and tested at both lab and pilot scales on different feldspar ores. The Guerbert alcohols allow to perform a feldspar concentrate with very low content in quartz (2.3-3.5 %) and feldspars recovery from 78 to 81 % while the aliphatic isoalcohols show a more higher recovery level (88-89 %). New HF-free process is strongly dependent on the pH range (1.7-2.5) and sulphuric acid consumption during conditioning steps. Optimal amine/alcohol weight ratio is ranged between 0.8 and 1.0. The values below 0.8 decrease strongly the flotation selectivity and the quartz recovery within the feldspar concentrates is higher than that occurs with HF.

Sep 1, 2012

By U. Ulusoy

Surface roughness and acuteness are known as the two of the main properties of the particle morphology affecting the behavior of the powders in the process. Since the techniques used for the morphological characterization of powders by 2-dimensional microscopic measurement from the polished sections that have some disadvantages, the 3-dimensional analysis has often relied on measurements of particle morphology. A review of literature data was presented for high-grade barite and pyrite particles ground by ball and autogenous mills to determine the morphological properties using a new 3-D approach based on BET nitrogen gas adsorption and Permaran methods. Micromeritics Flowsorb II 2300 instrument which employs BET nitrogen adsorption technique was used for the specific surface area measurements and the roughness of the particles. Permaran (manufactured by Outokumpu Oy) was used for the measurements of airflow resistance of powder samples for the acuteness. Spherical glass beads were used as reference sample for the acuteness measurements. The obtained parameters, which are surface roughness and acuteness, were corre-lated with the floatability performance of those mineral particles. The flotation performances of those particles ground in different mills (ball and autogenous) were also evaluated by a Hallimond tube. The results showed that lower roughness and acuteness values caused higher flotation recoveries for both barite and pyrite particles that were tested independently in different type of the mills. In other words; particles with smooth surfaces resulted in better floatability for barite and pyrite minerals studied.

Jan 1, 2014

By A. V. Yevdokimov, Ye. V. Bogorodsky

The paper presents the results of the research on the development of gravity concentrates processing technology (gold grade is from 50 g/t to 1 kg/t and over) using intensive cyanidation with gold recovery to pregnant solutions followed by precipitation of metals from them using various methods. Test work and pilot plant results confirm that a new developed hydrodynamic regime provides an efficient treatment of gravity concentrates of polydisperse composition without their grinding and preliminary desliming. The resulting pregnant and washing solutions are amenable to metals recovery using electrowinning, cementation onto zinc dust and CIS. Cone plants with a lower ball valve for cyanidation of unground gravity concentrates developed by IRGIREDMET JSC have been successfully tested at a number of Russian operations. Currently, a modular plant equipped with gold electric precipitation from pregnant solution unit is successfully operated at a Russian gold processing plant. Cyanidation of the resulting high-grade gravity concentrate is carried out at the concentration of 8-10 g/L NaCN and 10 g/L NaOH. Gold recovery to the solution is 97-98%. Electrowinning is carried out in flow cell GNC-40M. In this case, the residual gold concentration yield is 0.3-0.5 mg/L. Also, a modular plant for relatively low-grade middlings (50-100 g/t Au) of gravity concentration has been introduced. The concentration of NaCN and NaOH is 2-3 g/L and 1.5-2 g/L, respectively, during leaching. This plant is equipped with a unit for gold cementation from pregnant solution with zinc dust. This cementation unit is of original design. It is made in the form of a filtering device and is composed of several layers of carbon fiber which contacts with zinc powder. The residual gold concentration yield from a cementation unit is less than 0.1 mg/L. Gold recovery is 93-97%. In 2017-2018, the introduction of intensive cyanidation modular plants to gravity concentrates will be planned at new projects of Russia and the CIS.

Jan 1, 2018

By F. Ngoroma

Concentrators processing PGM bearing ores make use of polysaccharide depressants to reduce the recovery of the undesired naturally floatable gangue minerals, mainly silicates, present in the ore. Recent work has shown that high depressant dosages can completely depress naturally floatable gangue and thus prevent it from reporting to the concentrate. These high depressant dosages can, however, have a negative effect on the recovery of valuable minerals present in the ore by reducing the stability of the froth. In order to counterbalance the effects of depressant addition, frothers are added. It is, however, preferable to maintain independent control over bubble size and froth stability which is difficult to achieve with only one frother. An alternative strategy is, to use a blend of frothers, e.g. a weaker frother in combination with a stronger frother. Such a system allows an additional degree of freedom: changing the ratio of the two frothers, that would provide more independent control of bubble size and froth stability. This study demonstrates, through the use of batch flotation tests, how blending low molecular weight alcohols with commercially available frothers impact the solids and water recovery, as well as the valuable mineral recovery and concentrate grade in different PGM ores. Higher water and solids recoveries together with higher valuable mineral recoveries (>90% copper and >70% nickel) were obtained from tests using frother blends.

Sep 1, 2012

By X. Xu

This paper presents the research on comprehensive recovery of copper, gold, silver and iron from tailings from high-intensity magnetic separation in Tonglushan Mine. By comparison of experimental results of three flowsheets?regrinding of tailings-conventional sulphidizing flotation, water heating enhanced sulphidizing flotation and acid leaching-sulphidizing precipitation flotation, it is concluded that regrinding of tailings-conventional sulphidizing flotation flowsheet has the best economical and technical performance and practicability. Regrinding and using the mixture of sodium hydroxamate and sodium xanthate are two of the notable technical characteristics of this best flowsheet. The system for comprehensive recovery of tailings has been put into production. It not only can recover the valuable minerals from tailings in Tonglushan Mine, but also can reduce the environmental pollution, resulting great economic and social benefit.

Jan 1, 2014

Taknar polymetal (Cu-Zn-Au-Ag-Pb) deposit and concentration flotation plant are located in the northeast of Iran. The flotation feed contains Chalcopyrite, sphalerite and pyrite with 4, 4 and 8 percent respectively. Cu and Zn contents are 1.26 and 3.5 present. Pyrite decreases the quality of base metal concentrates and increases the amount of sulfur compounds produced in the base metal extraction processes. Therefore, depression of pyrite is essential in the concentration of base metal sulfides by flotation. For flotation tests, 4 mixed collector systems, MIBC (20g/t), lime and tow depression systems (sodium cyanide (60g/t)-zinc sulphate and dextrin (300g/t)-zinc sulphate) were used as collector, frother, pH regulator and pyrite-sphalerite depressants in the chalcopyrite flotation stage, respectively, and SIPX, MIBC, lime and copper sulphate (as activator) were used in sphalerite flotation from first stage tailings. The results have shown that, sodium cyanide is a suitable depressant for pyrite and sphalerite in the first stage of flotation. Compared to dextrin as depressant, chalcopyrite recovery was decreased approximately 1.83%. In addition, when sodium cyanide was used as pyrite depressant, copper sulphate consumption raised approximately 90 g/t for activation of sphalerite. From Environment and HSE points of view, dextrin is natural, biodegradable, and non-toxic while cyanide is very high toxic. Keywords: sequential flotation, Cu-Zn massive sulphide, pyrite depressant, dextrin, cyanide

Sep 1, 2012

By Francisco Cubillos, Jorge Menacho, Cesar Gomez, Juan Rodríguez

Mineral flotation is the most used process to selectively separate particles of one or more minerals of interest. The process uses natural or induced hydrophobicity to collect particles on the surface of rising bubbles through collisions and formation of bubble-particle aggregates. Flotation machines must keep particles in suspension and well distributed, while at the same time, disperse a mass of air into a population of small bubbles. The efficiency of the separation depends primarily on the characteristics of the bubble population generated in the machine and its distribution and flow throughout its volume. The formation and separation of bubble-particle aggregates create two zones, with strong interactions between them, and with markedly different hydrodynamics conditions. A model describing two-phase hydrodynamics of the continuous and dispersed phases (frother solutions and bubbles, respectively), moving along the whole unit, is proposed. Bubble populations are characterized at the formation stage including the effect of the presence of frothers. Flow through the aggregates formation zone, where bubbles move freely and are closely spherical, is modeled using drift-flux analysis. In the aggregates separation zone, bubbles initially pack maintaining a water layer thick enough to prevent capillary forces to affect their shape. As water drainage proceeds, bubbles deform, capillary channels form, and a network of channels with a diameter size distribution develops; channels become narrower (permeability is reduced) as the distance from the interface increases. Froth hydrodynamics is characterized using models originally developed to describe unsaturated flow through porous solid particle beds. Effects of hydrostatic pressure are considered.

Jan 1, 2014

By Z. G. Guan

The tungsten ore in Xingluokeng belongs to a symbiotic deposit containing granite and fine vein-type wolframite and scheelite. The tungsten (WO3wolframite) accounts for only 0.233% of the raw ore, 49.60% of the , 49.60% of the scheelite and 0.8% of the tungstite. The dissemination size of the tungsten ore is extremely uneven, with 0.02~1.28 mm for scheelite and 0.01~1.28 mm for wolframite. The dissemination size of scheelite is coarser than that of wolframite. The size of 83% of scheelite and 60% of wolframite is greater than 0.04 mm. The composition of minerals in the ore is quite complex. The major metallic minerals include wolframite, scheelite and pyrite, which are followed by molybdenite, chalcopyrite, arsenopyrite, limonite, magnetite, hematite and siderite. The major gangue minerals include quartz, feldspar, muscovite, biotite and sericite, which are followed by chlorite, fluorite, apatite, dolomite, etc. According to the dissemination features and liberation degree of the tungsten minerals, the technology flowsheet of gravity concentration for coarse particles and flotation for fine particles to re-cover the low-grade and fine vein-type tungsten minerals is adopted, and -0.7 mm is selected as the processing size. The closed-circuit grinding procedure, with the combination of the rod mill and high-frequency vibration screen, is adopted. The grinding product is classified into three products of -0.7 +0.2 mm, -0.2 +0.04 mm and -0.04 mm. The gravity separation is adopted for the former two to recover tungsten minerals and the flotation is adopted for the last one. Under the condition that the raw ore contains 0.23% WO3, some technology indexes of beneficiation have been achieved. The gravity tungsten concentrate contains 63.54% WO3 with the recovery 70.11%. The slime flotation tungsten concentrate contains 35.22% WO3 with the recovery 10.48%. The composite tungsten concentrate contains 57.53% WO3 with the recovery 80.59%. Thus, the tungsten minerals are re-covered effectively.

Jan 1, 2014

The objective of the paper is to develop a material balance calculation procedure for a production unit involving two plants separated by a pipeline. The case study is taken from the oil sands industry. The raw sands are first mixed with water in a conditioning plant, then transported through a pipeline to an oil extraction plant. The combination of pipeline dimensions and nominal throughput creates a significant variable time lag between the two plants. As usual, mass balance calculations required for the evaluation of plant performance indicators, such as bitumen recovery, are inaccurate due to measurement errors. In addition, in the present case study, the time lag of the pipe creates an additional source of uncertainty, which may lead to misinterpretations and wrong decisions. Raw data are usually reconciled through steady-state mass balancing, to correct for measurement errors. However, because of the significant pipeline dynamic lag, standard steady-state daily mass balance may fail at giving an appropriate picture of the operations. The proposed solution to the data reconciliation problem includes the use of a pipeline plug-flow model in the mass balance calculation. To fulfil the industrial constraint that current data reconciliation must not modify past reconciled values, while still satisfying dynamic constraints, a daily one-step method, i.e. a unitary filter-ing horizon, is recommended. The method is illustrated with simulation data, and the results com-pared to those of standard data reconciliation methods.

Jan 1, 2014

By P. Ying

An auxiliary system connected with SEM-EDX for rapid identification of mineral and rock sample has been developed. With the aid of a synthetic spectrum library created, using the compare and match techniques provided by INCA software in EDX the mineral or rock sample names for refer-ence can be given at the same time analyzed.

Jan 1, 2014

By X. Q. Chen

According to the different characters of the middle-low grade bauxite, based on the normal flotation & reverse flotation technology, the author innovates the new technology which is named bi-flotation, it integrates the advantages of normal flotation & reverse flotation, while avoids their disadvantages. Take Henan middle-low grade bauxite as research object, according to the pilot experiment of bi-flotation technology, the concentrate A/S is 9.37 and the recovery of alumina is 80.18% by flotation separate the raw ore which A/S is only 4.19.

Jan 1, 2014

Datun Concentrator currently processes complex sulfide ores in Gejiu Municipality, Yunnan Province, China. The ore contains much higher arsenic than other ores. The run of mine ore is fed to the concentrator to recover copper and tin by bulk flotation and gravity concentration, and then the other sulphides, such as pyrite, arsenopyrite, etc. didn?t get utilized and are discarded as tailings due to the high arsenic content. In order to utilize the pyrites in the tailings, a series of tests have been conducted for finding the solution of arsenic removal from high arsenic-bearing pyrite concentrates through simple flotation process. By means of orthogonal experimental design, the optimized levels and main factors have been found out for the roughing stage. Through selection of the effective in-organic depressants for the arsenic-bearing minerals, the arsenic in the pyrite concentrate can be removed to meet the requirement of sulfuric acid plant (As%=0.5%) by the open flotation process, i.e., one-time roughing and two-time cleaning.

Jan 1, 2014