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By Stuart Simpson

The biggest environmental challenge in mining is the management of mine tailings. Deep----sea tailings placement (DTSP) is practiced where the environmental impacts are predicted to be less than the impacts of tailings storage facilities on land. However, DSTP is often highly controversial owing to the challenges in assessing the impacts in deep water environments and potential long----term impacts beyond the proposed tailings footprint. It is well recognized that total contaminant concentrations are often poor predictors of the risk posed by contaminants in sediments. Metals within tailings are mostly present in highly mineralised forms that are typically much less bioavailable to organisms when compared to other common anthropogenic metals. Thus while metal concentrations in tailings can often appear alarmingly high, when compared to sediment quality guidelines (SQGs) used for assessing common urban and industrial impacts, the bioavailability is typically low. Although now well----embedded within risk----based sediment quality assessment frameworks, contaminant bioavailability is still often overlooked in the management of contaminated sediments. In this presentation, we assess and demonstrate the low bioavailability and chronic ecotoxicology of mineral----rich tailings to two benthic invertebrates, recognized for their sensitivity to metals: impairment of reproduction of the amphipod, Melita plumulosa, and the harpacticoid copepod, Nitocra spinipes. We demonstrate that the metal exposure from mine tailings is low when total concentrations are considered, and that the dose to the organism and toxic response observed is highly dependent on contaminant bioavailability. We discuss a range of approaches for the effective incorporation of metal bioavailability when applying SQGs or setting site-specific management limits for mine tailings in marine environments. While proposed DSTP operations require a high level of environmental scrutiny and monitoring during operation and post-closure, environmentally sustainable operations may be achieved when the bioavailable forms of metals within tailings remain below suitable management limits.

Jan 1, 2014

By Érica Linhares, Anderson Silveira Lopes, Aline Costa

In the production units of ferromanganese alloys wastewater are generated. They mainly arise from gutters of drainage water from warehouse of raw material (manganese ore, reducing agents and other), product and slag. This wastewater, in general, may contain particles that will suffer difficulty to naturally decant, giving the water turbidity and color characteristics. Thus, this study aims to characterize the effluent, the treated water and the sludge from the sedimentation tank from the one main Brazilian plant. The investigated characteristics were: turbidity, total solids (TS), suspended solids (SS), dissolved solids (DS), pH, Eh, COD (chemical oxygen demand), residue classification and chemical analysis by ICP - OES. The turbidity before treatment was 417 NTU and after passing through the tank, 44 NTU, a figure slightly higher than the emission standards for Class 1 regulated by the Brazilian environmental legislation in force. The values for TS, SS and DS of the effluent were 225, 114.3 and 110 mg/L, respectively. For the treated water the values were 93, 48.3 and 45 mg/L for TS, SS and DS, respectively. The sedimentation process was able to reduce by 21 % of the COD. In the test of loss on ignition (LOI) from the tank bottom sludge were observed losses of 29.35 %, while the volatile analysis found 20.70 % of volatiles in the sample. It was determined that the concentrations of Al, Fe, Mn and S are, respectively, 0.1875 mg.L-1, 0.3071 mg.L-1, 0,789 mg l-1 and 0.00828 mg.L-1, values above the maximum allowed by law. Based on the analysis of X-ray diffraction, the identified minerals in the sludge were quartz, muscovite, kaolinite, calcite and albite.

Jan 1, 2014

By Brian Hart, Stamen Dimov

"In refractory ores, a substantial part of the gold content may be present as a sub-microscopic component within the mineral matrix of the various carriers. This type of gold may be present as finely disseminated colloidal size gold particles (<0.5µm) or as a solid solution within the sulphide mineral matrix. Such ores are not amenable to gold recovery by direct cyanidation. In order to liberate the sub-microscopic gold, the ore has to be oxidized before being subjected to gold cyanidation and extraction. Autoclave pressure oxidation (AC POX) of the sulphide ore and subsequent cyanidation is a common technology used to liberate the gold in such refractory ores. The additional presence of active carbonaceous matter in such ores (double refractory ores) represents another major obstacle for efficient gold recovery during the process of pressure oxidation and cyanidation. This carbonaceous matter (c-matter) can adversely affect the gold recovery due to its ability to adsorb, or pre-grob gold from the cyanide solution. Advanced micro-beam analytical techniques such as Dynamic Secondary Ion Mass Spectrometry (D-SIMS) and Time-of-Flight Secondary Ion Mass Spectrometry (TOF-SIMS) have become powerful tools for characterization of different forms and carriers of gold for the needs of the mineral processing industry. Major advantages of these techniques are related to their ability to analyze individual mineral particles and provide quantitative analysis with detection limits in the low ppm/ppb concentration range. This paper describes various micro-beam techniques and procedures implemented at Surface Science Western (SSW) for quantification and characterization of the sub-microscopic gold and the preg-robbed surface gold as part of full gold deportment studies in feeds and process stream products."

Jan 1, 2014

By Willis Forsling, Prabhakar Swarna, Hanumantha Rao Kota

"The solubility of wollastonite and its Hallimond flotation behavior as a function of dodecylamine concentration and pH are examined. The flotation response is characterized by adsorption and surface energy in the presence of amine. The methods of UV-Visible and FT-IR spectroscopy for adsorption and sessile-drop contact angle for surface energy estimation are employed.The results of wollastonite dissolution clearly showed its non uniform dissolution. The surfaces are depleted with calcium ions and became rich in silicon within 10 min of flotation time. Maximum flotation of wollastonite corresponds to a half monolayer coverage of amine, which is substantiated by the surface energy parameters as shown in figure 1."

Jan 1, 2003

By M. Wright, A. H. Mwale

This paper examines the combination of unit technologies in a minerals beneficiation train, and explores the inter-relationship between energy input and water consumption for a given mineralogy and product recovery, as these are two critical environmental issues which affect the overall viability of many minerals plants. In particular, we review constitutive relationships for each of the sub-processes of comminution, flotation, and tailings dewatering, and suggest how these might be integrated into a unified hybrid model, with particle size distribution as the key design variable. Such a model can then be used to explore the trade-offs between different performance objectives (be these technical, economic or environmental) as part of a multiple-objectives optimisation exercise. In this way, it may become practical to envision situations in which concentrate grade and recovery are sacrificed, marginally, in order to reduce energy demand in comminution, and improve overall water recovery. This becomes more relevant as the industry commits to advancing the sustainable development agenda in the face of the increasing life -cycle costs and impacts of minerals processing operations, coupled to declining ore body grades, and the desire to maximise recovery of minor and trace elements. Some specific observations for copper are offered.

Jan 1, 2003

By V. Avzian Belozersky reg 453524, Vasily V. Lodeischikov, Adolf F. Panchenko, Til E. Vidusov, Olga D. Khmelnitskaya, Vladimir E. Dementyev

"Presently, there is a number of gold deposits which cannot be developed using the conventional technologies with acceptable economic indices due to low gold content, high depth of ore occurence and other conditions. For such ores, an innovation technology of underground gold leaching in the place of their occurrence is of special interest. The technology excludes ore mining and hoisting to the surface. This enables the production cost of 1 g of gold to be considerably reduced in comparison with conventional methods of gold recovery.The Maminskoye deposit oxidized ores were chosen as the subject of underground leaching because they are ideally suited for this purpose due to their composition and hydrological parameters. The ore reserves within the underground leaching block are 90, 000 t with 0.7 g/t average gold grade.An experimental system for underground leaching with a throughput of 15 cubic m solutions per hour was developed. A combined filtration-and-infiltration system of the ore massif development by holedrillingwhere pregnant solutions are air-lifted was worked out.The underground leaching flowsheet includes Au dissolution by chlorine-containing solutions, Au adsorption from solution onto active carbon, carbon concentrate ashing and calcine melting to produce Dore metal."

Jan 1, 2003

By Prasad Kopparthi, Narasimha Mangadoddy, Balraju Vadlakonda, A. K. Mukhurjee

"Column flotation (CF) is widely using equipment in mineral processing since many years. ERT technique facilitates non-invasive and nonintrusive visualization of different parameters in a column flotation. The hydrodynamic investigation of two-phase and three-phase are studied using electrical resistance tomography (ERT) coupled with pressure transducers in laboratory column flotation. Bubble size distribution, bubble rise velocity and gas and solids hold-up hydrodynamic parameters are extensively used for column flotation design and performance evaluation. The effect of superficial gas velocity, feed flow rate and slurry height in the column on mean gas holdup and its radial distribution has been analyzed for both two-phase and three phase flows. Influence of solid particles on gas hold-up and its complete elucidation of dispersion in the column are assessed. Experimental results show ERT coupled with PT is suitable as an online monitoring tool to provide useful information on the hydrodynamic parameters of the column flotation. The tomography images, which were generated using a modified sensitivity back projection algorithm, were employed to explore the parameter study in two phase flow in column flotation.Furthermore, the results also indicate that ERT is a very powerful tool for diagnosing the `inside' flow behaviour of gas-liquid two-phase and gas–liquid–solid three-phase flow in columns operating for a wide range of flow regimes.INTRODUCTIONColumn flotation is being widely used in mineral processing industries in last few decades. There has been a lot of attention in understanding the various mechanisms that take place during operation. Due to many reasons column flotation has been found to yield better performance than conventional flotation cells, particularly with fine particles (Honaker and Mohanty, 1996). Due to complex flow behavior in nature, the performance of column flotation influenced by on flow characteristics of the process, (Jena et al., 2008). Previously basic research is carried out to evaluate the effect of the hydrodynamic parameters on the performance of column flotation (Finch and Dobby, 1991)."

Jan 1, 2018

By Felix M. Zhuravlev, Vitalij P. Lyalyuk

"While there is a large industry based on recovering platinum group metals (PGM) from complex sulphide ores containing Cu and Ni, there is little information on the thermodynamics of the matte phase formed on smelting the ore and in particular the behaviour of Pt in the matte.The equilibrium between metallic platinum and industrial mattes was studied in a series of experiments where a small quantity of matte (5g) and platinum foil of 150 µm thickness (0.5 g) were equilibrated in magnesia crucibles at 1400°C under conditions where the oxygen and sulphur partial pressures were controlled.The chemistries of the phases were determined from EDS analysis using a scanning electron microscope. Line scans were initially used to confirm that the foils had attained a uniform composition across their thickness. The composition of the matte was determined from analysis of an area of matte including the small metallic droplets and dendrites.The distribution of Pt in Cu-Fe-Ni mattes (Pt: 1.5 – 3%) and solid Pt alloys (Pt: 54 – 72%) was studied. For a matte of base composition 45%Fe, 11%Ni, 8% Cu, at a base temperature 1400°C, the following behaviour was observed for the Pt distribution ratio:Under the range of sulphur and oxygen pressure of this study (log pO2 from -15 to –12.2, log pS2 from – 4.6 to –2.2), the distribution ratio of Pt between matte and alloy was independent of the sulphur and oxygen pressure, having a value of 0.04.The Pt distribution ratio increased from 0.02 to 0.08 with temperature from 1340 to 1450 oC.For mattes where the proportions of Cu and Ni were kept constant, a slight decreasing trend was shown for the distribution ratio of Pt versus the iron content (37 to 53%) in the matte but was not confirmed because of experimental uncertainty."

Jan 1, 2003

By Steven Wright, Sharif Jahanshahi, Shouyi Sun

"While there is a large industry based on recovering platinum group metals (PGM) from complex sulphide ores containing Cu and Ni, there is little information on the thermodynamics of the matte phase formed on smelting the ore and in particular the behaviour of Pt in the matte.The equilibrium between metallic platinum and industrial mattes was studied in a series of experiments where a small quantity of matte (5g) and platinum foil of 150 µm thickness (0.5 g) were equilibrated in magnesia crucibles at 1400°C under conditions where the oxygen and sulphur partial pressures were controlled.The chemistries of the phases were determined from EDS analysis using a scanning electron microscope. Line scans were initially used to confirm that the foils had attained a uniform composition across their thickness. The composition of the matte was determined from analysis of an area of matte including the small metallic droplets and dendrites.The distribution of Pt in Cu-Fe-Ni mattes (Pt: 1.5 – 3%) and solid Pt alloys (Pt: 54 – 72%) was studied. For a matte of base composition 45%Fe, 11%Ni, 8% Cu, at a base temperature 1400°C, the following behaviour was observed for the Pt distribution ratio:Under the range of sulphur and oxygen pressure of this study (log pO2 from -15 to –12.2, log pS2 from – 4.6 to –2.2), the distribution ratio of Pt between matte and alloy was independent of the sulphur and oxygen pressure, having a value of 0.04.The Pt distribution ratio increased from 0.02 to 0.08 with temperature from 1340 to 1450 oC.For mattes where the proportions of Cu and Ni were kept constant, a slight decreasing trend was shown for the distribution ratio of Pt versus the iron content (37 to 53%) in the matte but was not confirmed because of experimental uncertainty."

Jan 1, 2003

By Katsunori Okaya, Toshio Inoue

"Movement of mill charge in the centrifugal mill is essentially dissimilar from that in the vibration mill with circular path despite the apparently similar mode in the motion of mill body. This dissimilarity is the reason for the substantial advantage regarding the comminution intensity of the centrifugal mill over the conventional vibration mill accounting approximately to one order of magnitude.Bradley et al. (1983) developed a math model regarding the mill charge as a lump. This model is presented in a simple equation with which motion of the mill charge can be predicted in terms of the parameters describing the specification and the operation of the centrifugal mill. This equation can be used to explain the power draft of the mill as well as the stability of mill operation. More recently, on the other hand, a numerical simulation technology called discrete element method (DEM) has become a vital vehicle for estimating the motion of the grinding media in the mill. The authors developed a mill simulator called ‘Mill Solver’. Mill Solver is designed to simulate various types of mills including centrifugal and vibration mills. The principle of this simulator is to calculate individual kinetic events of interaction of balls in the mill in a minute time interval, hence the mill performance can be constructed for estimation."

Jan 1, 2003

By Hakan Gürsoy, Kemal Bilir, Bahri Öteyaka, Ali Uçar, Oktay Sahbaz

"Jet diffuser flotation column (JDFC) is a flotation device resembles Jameson flotation cell (JFC) in terms of operational principles, but it has significant difference structural points of view. This difference is an essential change in the downcomer to provide an increase of performance of the cell for the coarse particles. By using the hydrodynamic and fluid mechanics principles (Sahbaz et al., 2013) downcomer was changed as a diffuser, therefore turbulence at the end of the downcomer was reduced to provide better aggregate stability and homogeneous dissipation of the bubbles in the separation tank. According to experimental results carried out in pilot scale JDFC, not only higher flotation performance comparing with Jameson cell was obtained specifically for coarse talc particles in a certain condition, but also quiescent froth layer was acquired. In these tests, vertical pipe of JDFC having inlet diameter of 6 cm and outlet diameter of 11.5 cm was used with separation tank having the diameter of 39 cm. By using the data, pilot scale JDFC having 410 cm vertical pipe integrated with separation tank was produced and flotation tests were carried out by using the naturally hydrophobic mineral (talc). Finally, the talc recovery obtained as 94% by the use of JDFC, while Jameson cell has the recovery of 77% for the particle size of 250 µm."

Jan 1, 2014

By P. Somasundaran, Tarun Bhambhani, D. R. Nagaraj, P. Patra

"Certain non-sulfide gangue minerals are known to have a detrimental impact on flotation performance. When present in large amounts, they can negatively affect recoveries, grades and throughput at current operations, and dictate the viability and economics of a greenfield project. While the problem has been investigated for a long period of time, a scientific understanding of the mechanisms by which these minerals affect performance has not been obtained, and no acceptable solutions have been developed. This study focused on the role of physical aspects (e.g. shape, size and morphology) of these minerals as the underlying factors for poor performance. Flotation tests were conducted using model mineral systems to understand the impact of one phyllosilicate mineral (muscovite) on flotation kinetics, recoveries and grades. The study reveals that there is minimal impact on flotation kinetics, no impact on recoveries, but a very strong detrimental impact on concentrate grade. The traditional mechanisms of transport such as true flotation and entrainment are not sufficient in describing the extent of transport. The transport is attributed to the unique platy morphology of muscovite, which allows for action of buoyancy forces. Data also shows that the muscovite transport to the froth phase depends on particle size; coarser sized muscovite (100-150@) report to the froth phase in much larger amounts than medium sized muscovite (50-100@). At finer size fractions (<50@) the transport is also increased, and this is likely due to entrainment."

Jan 1, 2014

By Rogerio C. Guimarães, Antonio E. C. Peres

The production of phosphate concentrates (phosphate rock) from slimes represents a challenge to the phosphate industry worldwide. In Brazil, this challenge is particularly relevant due to the consistently low P2O5 grades and the igneous origin. The first industrial experiences of producing phosphate rock from slimes (-44µm or -325#) fraction started at Arafertil, currently Bunge Fertilizantes SA, in Araxá, in the 1980.s. This production corresponds, nowadays, to 35% of the total production of concentrates in the company (830,000t/year) in a circuit consisting of desliming in 40mm microcyclones and concentration in flotation columns, corn starch and fatty acids being utilised as reagents. The performance of slimes flotation and the process control, at Bunge´s concentrator, were improved after the introduction of column flotation technology, in the first half of the nineties. The column flotation technology for slimes recovery was expanded to other Brazilian concentrators still in the nineties: Ultrafértil (Catalão - GO), Bunge (Cajati - SP), Fosfértil (Tapira - MG) and Copebrás (Catalão - GO). At present the Brazilian production of phosphate rock is approximately 4.5Mt/year, with a strong trend for a market increase. Genuinely Brazilian technology is utilised for the processing of slimes, the concentrates representing 11 to 13% of the overall production. The production of apatite concentrates from slimes was relevant to increase phosphate recovery and reduce costs, contributing to the growth of the fertilisers industry.

Jan 1, 2003

By Takashi Furuyama, Sukeyuki Mori, Tetsuo Ikejiri, Abel Bissombolo, Yoshitsugu Koga, Masamichi Hata

In Japan, the increasing number of automobiles newly put into circulation is followed by a larger amount of end-of-life vehicles from which valuable metals are being recovered in shredder and related plants. Nevertheless, the processing of these scrapped automobiles which has reach a recycling rate of about 75%, generates a huge volume of waste, locally known as .shredder dust., which is commonly dumped on landfills. The saturation and depletion of valuable disposal sites in the near future, as well as the social and environmental problems related to the accumulation of these residues disposals are a major challenge for the automobile shredding industry. To promote an alternative way for the management of these disposals, the authors have initiated and developed a system for their processing, on the basis that more than 90% of these residues are combustible materials that could be used as refuses derived fuel. The developed processing system points out the mechanical/physical separation of shredded automobiles residues into two streams by means of an ascending airflow passing through a vertical zigzag separator and, the compaction of the light-density fraction of materials (that is about 60% of auto shredder residue recovered as float products and mainly composed of cotton, sponges and light plastics) to form a refuse derived fuel (RDF), the density, calorific value and ignition loss of which are 1.19 g/cm3, 4470 kcal/kg and 60.7%, respectively.

Jan 1, 2003

By Rod Hocking, Nenad Djordjevic, Randolph A. Pax

"Semi Autogenous (SAG) mills exhibit complex interactions between the competing processes occurring inside them. Traditional practice is to measure the operation of the SAG mill at an operating point in terms of its load, power draw, steel load, ore throughput rate, water addition rate and more recently the feed size distribution. However significant departures from standard operating conditions can occur due to changes, for example, in ore hardness, the quest for higher throughputs and mill internal geometry.Fundamental to SAG mill operation are the internal processes that ensure that a given ore throughput and discharge grind size are obtained and maintained. These processes can be measured using non-contact acoustic emissions from the SAG mills which utilise the information rich noise that is generated by the grinding, flow and charge movement inside a mill. Non-contact acoustic in-mill measurements can be used for the validation of discrete element modelling (DEM). The approach being reported in this paper is to model the individual physical processes and then to simulate the assemblage of a physical mill.By modelling the assemblage of steel balls in a 1 m pilot mill and duplicating the experimental arrangement exactly with the PFC3D model, it was possible to replicate the pattern of falling balls in the experimental mill. Furthermore, the key features of the acoustic emission spectrum that was calculated compared favourably to the measured spectrum at low frequencies. The experimental spectrum is shown in Figure 1."

Jan 1, 2003

By M. Pelser, Lorenzen L.

"The presence of calcium and magnesium in the hydrometallurgical processing of base metals, results in a number of process difficulties. These problems range from the contamination of the final product (where the final product is a precipitate) to high energy consumptions and large bleed streams during electrowinning. Calcium poses an additional problem in sulphate solutions owing to the low solubility of its sulphate salts. This can easily lead to a process stream that is supersaturated with calcium sulphate, resulting in unwanted solids formation within the process equipment.A review of literature has proven that there is no conventional method for the control of calcium and or magnesium, although a number of potential processes have been identified. The technologies investigated included precipitation, ion exchange and solvent extraction, for which at least one method was found under each. To make the reader aware of these processes a short description was provided of each within the text.Of these processes, fluoride precipitation was selected for experimental investigation based on the low solubility of calcium and magnesium compared to the base metals. This process involves the addition of a soluble fluoride to precipitate CaF2 and MgF2. The experiments were designed to investigate the equilibrium of the system at varying parameters of which the level of fluoride addition, the ratio of calcium to magnesium, and the identity of the soluble fluoride was reported. In all of the instances the process showed high selectivity towards calcium and magnesium over the base metals. The experiments proofed the process to have a higher affinity towards the removal of magnesium at compositions where the molar ratio of calcium to magnesium was higher than 1:3. It is often the case that the calcium to magnesium ratio is in the region of 1: 10. From this it follows that the fluoride addition has to be stoichiometric or greater for calcium and magnesium combined, if the calcium is to be precipitated. This was demonstrated as well. On the identity of the soluble fluoride hydrogen fluoride was compared to ammonium fluoride, of which the latter was found to be preferred."

Jan 1, 2003

By Markus A. Reuter, Bernardete Castro, Antoinette van Schaik, Han Remmerswaal

"INTRODUCTIONThis paper describes the inseparable relation between product design, liberation, and metallurgical recovery in the optimisation of the recycling of passenger vehicles. This is illustrated by the use of an optimisation model that uses among others a material combination matrix based on metallurgical process data, which depicts the consequences of the quality of intermediate recycling products on the metallurgical material recovery and final alloy metal quality. Various simulations will illustrate the effect of changes in product design and hence liberation on the recycling of end-of-life vehicles. Although this paper focuses on cars, the discussion is equally valid for any end-of-life product. Calibration of the model will be discussed with reference to experiments carried out in order to study the optimal recovery of aluminium applications used in passenger vehicles.OPTIMISATION MODEL FOR LINKING DESIGN TO RECYCLINGImproving the efficiency of the material cycle of the car is essential to ensure a sustainable development of our society as well as e.g. to comply with the recycling targets imposed by EU legislation. In the design of the car various materials are combined and connected in many different ways, making up the complex 'mineralogy' of the car and its components, which is changing rapidly and continuously over time. The liberation of materials during shredding plays an important role in the composition (and quality) of the intermediate recycling streams. In order to include the influence of product design (mineralogy), liberation, and particle composition (quality of the intermediate recycling streams) in the optimisation of the recycling of end-of-life vehicles, a systems engineering tool for optimisation of the recycling of end-of-life vehicles was developed, including a liberation model. The optimisation model predicts the recovery rate as a function of product design (in this case a car), liberation, efficiency of the different process steps, economy and legislation based on a developed recycling flow sheet for end-of-life vehicles. Optimisation can only be achieved through the combination of the knowledge areas of product design, shredding, mechanical separation technology linked to pyro- and hydrometallurgy, composing a complex interconnected network of unit operations."

Jan 1, 2003

By Tatyana A. Ivanova, Tamara N. Matveyeva, Anatoliy A. Fedorov, Tatyana V. Nedosekina, Valentin A. Chanturiya

"As native gold resources are depleted, gold-sulfide ores consisting essentially of pyrite, arsenopyrite, chalcopyrite and pyrrhotite become one of the major precious metal sources, being presently estimated to account for more than 40 % of total world gold reserves.The prime objective of flotation of gold-bearing sulfide minerals is to increase precious metal recovery and to reduce the product cost through achieving maximum selectivity of the separation process. Separation of Fe and As sulfides in selective flotation of gold-bearing ore products helps reduce the amount of ore mass being sent to hydrometallurgical processing, and permits of recovering gold from As-free gold-containing pyrite concentrate by using a lower-cost pyrometallurgical procedure.An ingenious methodology purposively developed by the authors for comprehensive assessment of flotation properties, electrophysical characteristics and crystal chemistry features of natural gold-bearing sulfide minerals of different origin has been used in this study.Comparison of the elemental composition, non-stoichiometry and flotation activity of different monomineralic pyrite varieties revealed that samples with negligible impurity content are nearly stoichiometric, and show similar flotation properties. Samples with high Cu, As and Au contents are highly non-stoichiometric and readily floatable, even in a highly alkaline environment. Samples with high surface sulfur content and the most defective crystal lattices, with iron atoms substituting for sulfide vacancies, are most sensitive to depressive action of the alkali.A correlation between the type of conductivity, impurity content and amount of xanthate compounds on the surface and in the liquid phase of monomineralic pyrite and arsenopyrite suspensions detected by the extractive spectrophotometric analysis has been identified and analyzed. Experiments showed that the proportion of cuprous xanthate in sorptive collector layers on sample surfaces increases with increasing Cu content of the samples. In general, pH for pH, overall xanthate sorption on pyrite is greater than on arsenopyrite, with the difference increasing in passing from an acid environment to an alkaline one. A significant decrease in xanthate sorption on arsenopyrite is observed at pH greater than 9, whereas sorption on pyrite markedly decreases at pH greater than 11."

Jan 1, 2003

By F. L. Mentg

The utilization of acid leaching tailings was studied. It is obvious that the Fe in acid leaching tailings can be leached into solutions as Fe2+. In this paper, the influence of conditions, including the concentration of ferrous sulfate, pH, temperature and velocity of air flow was investigated. The optimum conditions for preparing seed crystal are as follows: the concentration of ferrous sulfate is 20 g/L; pH is 9.5~10; reaction temperature is 10~20?; velocity of air flow is 0.4m3/h. The optimum conditions for preparing iron oxide red are as follows: the concentration of ferrous sulfate is 5 g/L; reaction temperature is 80~85?; velocity of air flow is 0.13m3/h. At last, the product of iron oxide red could be prepared by ammonia method.

Jan 1, 2014

By Peter Rubie, John Russell

"For many years, optimizing the relining of hard rock grinding mills has been complicated by the large number of variables, the low frequency of relines (resulting in a slow relining experience assessment and review cycle), and the potential economic risk associated with some changes to relining equipment or work practices. A technology that has its roots in the automotive manufacturing industry is being utilized to construct a statistically accurate, configurable, and dynamic simulation of the mill relining process. The detailed effects of various mechanization and process changes can be rapidly modeled and compared. Application of this discrete event analysis technology in the mineral processing industry delivers a range of benefits to many industry stakeholders. For example, mill maintenance managers and contract relining companies can embrace the opportunity to benchmark current performance against world’s best practice. Concentrator plant designers and mill manufacturers, informed by this technology’s scientifically defensible data set, can accurately plan for maximum plant efficiency when designing an infrastructure and equipment combination that truly maximizes annual plant availability. Time-motion studies of grinding mill reline data at mills of varying dimensions, liner configurations, mill relining equipment, operator and tool variables, have been integral to the development of this dynamic simulation tool and its associated data set. Access to mill relining simulation technology will enable mineral processing industry professionals to take advantage of an increased capacity to develop mineral concentrator performance optimisation initiatives within the given financial, physical and technological constraints of the individual concentrator plant."

Jan 1, 2014