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By Zhiye Zhao, Jianping Sun, Zhipeng Xu

"The subsea rock cavern project is an underground storage facility. For cost-effective and safe excavation, the risk caused by the groundwater seepage into the rock cavern must be addressed. As one of the essential steps of the assessment work, the hydraulic conductivities of the fractured rock masses should be reliably determined based on the limited measured data and geological information from the few boreholes. On the basis of site investigation data and monitored water flow and water pressure data during excavation, this paper presents an estimation method for hydraulic conductivities of the rock masses containing water bearing zones.INTRODUCTIONIn the development of underground rock caverns/tunnels, the uncertainty of hydro-geological conditions plays a critical role in terms of construction cost and construction safety. Excessive groundwater seepage has been identified as one of the key safety factors which always lead to vast loss, such as the Seikan Tunnel in Japan which encountered sudden water inflow and then catastrophic face collapsing, tunnel flood during excavation (Xu et al., 2013). As a key factor in the risk management associated with the groundwater leakage into rock cavern, the hydraulic conductivity determination is very important for cost estimation, reliable water control and construction management.The case presented in this paper is an underground project consisted of a cluster of rock caverns/tunnels for storage of hydrocarbon products. These caverns are located in heterogeneous sedimentary bedrock, at a depth of 130 m beneath a basin, and the crowns of caverns are located at about 100 m below the sea bottom. The caverns/tunnels are designed at two levels, the water curtain tunnels are at the upper level, and oil storage caverns are at the lower level, as shown in Figure 1. A number of horizontal and vertical water injection holes drilled from the upper water curtain gallery tunnel will establish continuous horizontal and vertical water curtains for providing a stable pressure distribution around the caverns, to keep oil/gas inside the lower storage caverns. As the hydrostatic pressure of groundwater around the storage caverns is higher than the pressure of stored oil and gas, the stored oil and gas will not leak out of the cavern (Lu, 2010; Xu et al., 2015). Groundwater pressure gauges are installed in the water curtain gallery tunnels, and water from the operational and access tunnels is injected continuously into the curtains to maintain the pressure. Some monitoring data are recorded at different construction stages. This paper proposes suitable methods to predict the hydraulic conductivity in rock mass and to determine the hydraulic conductivity in the water bearing zones."

Jan 1, 2015

By A. K. Alzo?ubi

Block toppling in natural rock slopes has been under investigation since the 1970?s. De Freitas and Watters (1973) introduced the term ?toppling? to describe the movements of rock slopes by rotation in steeply dipping beds. The Lornex pit case history from British Columbia (Canada) was chosen to study the effect of mining on the stability of toppling rock slopes. A discrete element approach that allows fracturing of intact material was applied successfully to model the composite rock slide-rock topple movement. Three main movement modes were observed in the field and the numerical model; the sliding of the top of the slope exposed normal scarps, the toppling at the middle part of the slope exposed obsequent scarps facing opposite to the slope face, and dilation of the rock caused by fracturing at the toe formed loose material. The development of the rupture surface at the toe of the slope was traced and did not evolve into a continuous rupture surface throughout the slope both in the field and the numerical simulation. Good agreement was achieved between the deformations recorded in the field and the numerical simulation.

Jun 1, 2012

By Dale Verran, Jared Orynik, Chad Sorba, David Bronkhorst

Denison Mines Corp. (“Denison”) has a 90% interest in the Wheeler River Uranium Project (“Wheeler River”) located along the eastern edge of the Athabasca Basin in northern Saskatchewan between the Key Lake mill and the McArthur River uranium mine. The project is host to the high-grade Phoenix and Gryphon uranium deposits, discovered by Denison in 2008 and 2014 respectively, which include combined Indicated Mineral Resources of 132.1 million pounds U3O8 (1,809,000 tonnes at an average grade of 3.3% U3O8). The Pre-Feasibility Study (“PFS”), completed in accordance with NI 43-101 in September 2018, is highlighted by the selection of the In-Situ Recovery (“ISR”) mining method for the development of the Phoenix deposit, with an estimated average operating cost of $4.33 (US$3.33) per pound U3O8. Phoenix is the highest-grade undeveloped uranium deposit known globally, including Indicated Mineral Resources of 166,000 tonnes at 19.1% U3O8 for 70.2 million pounds U3O8. The paper aims to provide a summary of Wheeler River and an overview of the proposed development of the Phoenix and Gryphon deposits according to the PFS completed for the Project. Further details regarding the PFS, including additional scientific and technical information are described in greater detail in the NI 43-101 Technical Report titled "Pre-Feasibility Study for the Wheeler River Uranium Project, Saskatchewan, Canada" dated October 30, 2018 with an effective date of September 24, 2018. A copy of this report is available on Denison's website and under its profile on SEDAR at www.sedar.com and on EDGAR at www.sec.gov/edgar.shtml.

Jan 1, 2020

By P. R. La Pointe, J. Clark

"Studies have shown that the roof in coal mines is nearly twice as likely to fail at intersections as at entries due to enlarged roof spans, stress redistribution and other factors. However, the relative stability of intersections in a mine varies, and an improved understanding of what factors impact roof instability can lead to efficient, proactive mining practices that both enhance stability and mining efficiency.A study was undertaken at an underground longwall coal mine to develop a model to predict the stability at the intersections of entries and cross-cuts. The statistical analyses relied upon observational and measured data regarding the development of tension cracks, seepage, intersection geometry, mining practices, geological attributes and geomechanical factors at 783 intersections. Each intersection was given a NIOSH roof. Common data mining techniques, such as multivariate linear regression, multinomial logistic regression, decision trees and probabilistic neural nets, were considered and evaluated to establish correlations and associations between stability and the other variables. Two of the more successful techniques were Decision Trees and Multinomial Logistic Regression. The analyses showed that a number of factors impacted stability:• Overburden thickness (impact on stress concentration magnitudes)• Initial opening area (impact on stress concentration magnitudes)• Sulfur content (depositional environment & impact of mechanical properties, leaching effects)• Intersection type (impact on stress concentrations)• Gob distance (impact on stress concentrations)• Presence or proximity of a particular sandstone (impact on mechanical properties)• Roof bolt type and diameter (impact on reinforcement)Some factors showed no statistically significant relation to stability. These included:• Total area• Supported areaSeepage was a more problematic variable in assess. Seepage is associated with instability, but it is not clear whether seepage occurs as a consequence of instability, for example, through the creation of tension cracks, or whether the intersection has been excavated where water already exists and has degraded the rock prior to excavation, leading to greater instability.Seepage appears related to the geology of the roof rock mudstones, not the sandstones. Tension cracks in the intersections occur preferentially where the Sulfur content is below 0.9%. The Sulfur may relate to mechanical differences in the roof rock, and where the Sulfur is low, the roof is less stable, there are more tension cracks, and seepage is greater. This suggests that the weaker mudstones may be more prone the development of tension cracks, not because these rocks are more brittle, but possibly weaker.2-way and 3-way intersections appear to have less seepage than 4-way, although very few intersections overall have any seepage. This is similar to the roof stability, in which the 2-way and 3-way are more stable. 2-way and 3-way intersections have fewer-than-expected tension cracks, while 4-way have more than expected. These results suggest that four-way intersections are weaker and more prone to tension crack development, also suggesting that increased seepage results from weaker roof conditions, rather than the converse. Thus seepage appears to be mostly a consequence of instability rather than a cause and is higher where there are 4-way intersections, mudstone geology and external loading factors like depth of cover and proximity to gob that promotes crack development. The study also indicated that a better understanding of the mudrock facies could reduce uncertainty."

Jan 1, 2015

By K. Östcrdahl

We are developing a cost-saving and environmentally friendly process with low energy consumption to recover the metal content and recycle the acid from spent pickle baths. The metals are precipitated as metal fluorides, which can be turned into metal oxides and hydrofluoric acid by thermal hydrolysis. In the proposed process the solution is concentrated by nanofiltration and the metals are precipitated in a subsequent crystallization step. Different nanofiltration membranes have been evaluated in experimental batch tests. The membrane MPF-34 from Koch Membrane Systems offered both good flux and acceptable metal retention even after long periods of acid storage. The solubility of B-FeF3.3H20 has been measured at varying acid concentrations and at different temperatures. The solubility decreases with increasing hydrofluoric acid and nitric acid concentrations. This suggests that the crystallization process should be operated at high acid concentrations. The crystal growth rate of B-FeF3.3H2O is found to be quite low but increases significantly with temperature. This suggests that the crystallization process should be operated at higher temperatures (40 - 60°C). Within the project a pilot plant has been constructed where the spent pickle bath solution is concentrated by nanofiltration to the desired metal fluoride supersaturation, and B-FeF3.3H2O is crystallized in a 10 L continuous crystallizer.

Jan 1, 2006

By Neil Campbell

"The Pine Point area is on the south shore of Great Slave Lake, 510 air miles north of Edmonton and J JO miles south of Yellowknife, N.W.T. The occurrence there of lead and zinc was reported in J 899 by R. Bell (5) of the Geological Survey of Canada, and in the following years several claims were staked and some prospecting was done. In 1928 Atlas Exploration Co. took over the property containing the discovery occurrences. In 1929 The Consolidated Mining and Smelting Company of Canada Ltd. (""Cominco"") and Ventures Ltd. participated with Atlas in forming the Northern Lead-Zinc Co., which, under the direction of J. M. Bell, carried out 24,499 feet of drilling in the discovery and surrounding areas. Two shafts and many surface pits were also sunk. This work showed that the discovery deposits contain about 500,000 tons of lead-zinc ore, but no new orebody was found.In 1936 D. F. Kidd (11) drew attention to the highly significant space relations between the base-metal discoveries at Pine Point and the projections of certain major Precambrian faults mapped earlier by C. H. Stockwell. Geological work by Cominco in 1940 and subsequent years suggested the presence of mineable deposits within a belt of land including part of the area of earlier field work and extending far beyond it. Between 1946 and 1954 exploration financed by Cominco and Ventures Ltd. included 182,950 feet of diamond drilling, 383 feet of sinking, and 240 feet of drifting, raising, and crosscutting. This work was successful in finding substantial quantities of new ore in places where bedrock is completely concealed.The topography is one of low relief, characterized in many places by swampy muskeg and shallow, marl-bottomed ponds. The area where ore has been found is generally higher ground which, though not well drained, is comparatively dry. It is also marked by raised beaches and a few sand dunes overgrown by small spruce and pine. Bedrock is generally overlain by a variable thickness of hard, glacial boulder clay. This in turn is covered by silt, sand, and gravel, probably deposited from the waters of Great Slave Lake, which formerly extended many miles beyond its present southern shore."

Jan 1, 1949

By W. Dietzel

Fracture mechanics based techniques are used to gain insight into the phenomenon of stress corrosion cracking (SCC) and to develop guidance for avoiding or controlling SCC. From constant extension rate experiments under rising load or rising displacement conditions the susceptibility of high strength steels, aluminum, magnesium and titanium alloys to SCC and hydrogen embrittlement can be assessed. Such tests on pre-cracked specimens are also well suited for studying the mechanisms leading to SCC by employing appropriate models for the degradation of metallic materials which take into account the uptake of atomic hydrogen from the corrosive environment. Measurements of crack growth resistance curves using the crack tip opening displacement as fracture parameter can be compared with simulated R-curves obtained from modeling of the mechanism of hydrogen embrittlement. The materials investigated are a high strength steel and a magnesium alloy both exposed to environmental conditions which fostered the uptake of hydrogen.

Jan 1, 2010

By Matthew S. Hall

Gold/iron oxide catalysts have been prepared and their catalytic performance evaluated for low temperature CO oxidation. The method and temperature used to dry the sample has a significant effect on their catalytic activity. Analysis by TEM revealed the catalysts contained Au particles, although catalysts with high and low activity did not always differ in their microstructure as evidenced by TEM. Catalysts were characterised using XPS and the difference between the Au(4d) and C(1s) binding energies measured; in general the greater the difference, the higher the catalytic activity of the material.

Oct 1, 2003

By L. Jones, S. R. Lawrence, A. R. Holloway

Whilst dense medium separation is best known for its ability to concentrate diamond and coal deposits, the process is now being employed in southern Africa as a pre-concentration step to improve the economics of platinum group metal and nickel ores. DMS plants built for these industries (such as the 1600tph unit at Tati Nickel, Botswana), are spearheading an expansion in this area by reducing mine and process operating costs yet maintaining economic metal recoveries. This paper provides an overview of DMS technology and examines the economic benefits available to North American operators and projects, with recent case studies as reference.

Jan 1, 2009

By Timothy W. Ellis, Abbas H. Mirza, R. David Prengaman

Recycled lead, i.e. material produced by the recycling of lead-acid batteries, has become the primary source of lead in much of the world. This has been important to the recycled lead industry as other uses have dwindled, e.g. lead based pigments, chemicals, fuel additives, solders and CRT glasses. Presently, battery manufacturing accounts for greater than 85% of lead consumption worldwide while recycled lead accounts for approximately the same market share of lead supply. Battery manufacturing and production of recycled lead are intimately coupled. In 2007, of all the industrial base metals, lead from lead-acid batteries had the highest recycling rate in North America at greater than 95%. In this paper we will review some of the processes and technologies used in a modern lead acid battery recycling facility, and how recycled lead has become the material of choice for battery construction through the development of a recovery and refining process that exceeds the industry requirements. We will also briefly review an advanced air emissions treatment system in a modern lead recycling plant that demonstrates the feasibility of a new maximum available control technology (MACT) for secondary lead smelters.

Jan 1, 2011

By F. J. Guevara

A two-dimensional mathematical model for fluid flow and heat transfer in a sixin- line electric smelting furnace was developed to study the effects of temperature on slag viscosity in both the liquid and mushy zones. The model focused on the fluid dynamics of the molten slag and the effects on the formation of a slag freeze layer on the hot face of the furnace wall. Previous experimental and mathematical work, carried out under Ra number of 109 and using a fluid with Pr number of 65, showed that it is possible to mathematically describe the freeze layer formation over a vertical wall using a fixed-grid model. The chemical composition of the slag was taken into account through its effect on the viscous activation energy as well the solidus and liquidus temperatures. The results show that the flow pattern is strongly modified in areas of high viscosity, in front of the cooling system and at the slag-matte and slag-calcine interfaces. The results are discussed in terms of heat flux over the refractories and their effects on cooling system design.

Jan 1, 2007

By Unknown

With the present-day trend of rising labour costs and a lowering of production efficiency of workmen, it has become imperative that every effort be made to use manpower to the greatest advantage and to mechanize mining as much as possible. During the past few years this trend has gained much prominence in the Porcupine camp. In view of this, the executive of the Porcupine Branch considered that the Mechanical Movement of Muck would be a very timely subject for a Symposium. Accordingly a Committee was formed, with A. K. Douglass, Mine Superintendent for Delnite Mines, Ltd., as Chairman, and the Symposium was held in the Auditorium of the McIntyre Community Building, Schumacher, on March 25th last. Papers dealing with shovel loader and mechanical scraper operation at six of the larger mines of the camp were presented and discussed, and a tabulation was prepared giving data on the machines in operation at a total of eleven mines. The papers and tabulation, reproduced below, will doubtless be of considerable interest to operators of mines in all parts of Canada.

Jan 1, 1948

By C. Dodds, R. S. Ferrari-John, The University of Nottingham, G. Dimitrakis, J. Katrib, A. R. Batchelor

"Sorting technologies have the potential to reduce energy use in comminution by rejecting uneconomic ore before feed material enters the mill. However, a major challenge for sorting porphyry copper ores is providing a basis of discrimination between valuable and non-valuable fragments, due to their complex mineralogies and textural features. Microwave heating in combination with infra-red detection (MW-IR) has been shown to provide upgraded feedstock for certain ores at bench scale. Selective heating of copper sulphide minerals compared to the gangue leads to an increased thermal response for valuable fragments, providing the basis for sorting.Rapid scale up of MW-IR from bench scale to a 100 t/h continuous pilot plant facility has been facilitated by the design of microwave choking structures to allow continuous operation at industrially meaningful throughputs, whilst meeting health and safety and electromagnetic compliance standards, and the integration of materials handling with electromagnetic systems.Laboratory batch testing on a pilot scale microwave system has been undertaken to investigate the thermal response of copper ores under industrial conditions, at microwave energy inputs up to 1 kWh/t. These results provided the operating window and recommended test conditions for the continuous pilot plant. Sortability curves predicted in the laboratory are in good agreement with separations achieved during continuous pilot plant operations. The potential microwave sortability of a number of ores has been studied, allowing informed decisions to be made about potential ore candidates based on mineralogy. Future development of the technology will be underpinned by the creation and validation of scale up concepts for 1000 t/h operations. Understanding the value proposition for individual sites/applications will be central to unlocking the potential economic and environmental benefits of microwave sorting."

Jan 1, 2016

By N. J. Shackleton, N. A. Chapman, V. Malysiak, C. T. O’Connor

In this study, the effect of using conventional crushing and high-pressure grinding rolls (HPGR) in combination with dry or wet milling was investigated using a base-metal sulphide (BMS) sphalerite and a platinum group mineral (PGM) ore to determine how these processes affect the flotation performance. In sphalerite, irrespective of the crushing procedure (HPGR or conventional), dry milling resulted in the highest grades and recoveries of zinc, whereas in PGMs, similar treatment produced the poorest results. The results were investigated further by the effect of factors such as percentage liberation and particle size on the flotation results.

Jan 1, 2012

By John R. Hayes, Kebbi A. Hughes, John Rowson, Peter E. R. Blanchard, Jeremiah C. Beam, Andrew P. Grosvenor, Arthur Situm

Uranium ore bodies contain elements within mineral phases that need to be disposed of responsibly. Solid waste can be placed in a tailings management facility (TMF) to contain the waste elements and limit interactions with the environment. It is important to understand how the chemistry of the tailings evolves throughout the lifetime of the operations that feed the TMF and after the site has been decommissioned. The objective of our collaboration with Orano Canada was to study how the tailings from the TMF located at McClean Lake, Saskatchewan change over time. This manuscript discusses our use of X-ray absorption spectroscopy (XAS) and X-ray microprobe to study the fate of Mo and Ca in the tailings. Mo is considered an element of concern (EOC) and it is necessary to determine if a stable solid Mo-bearing species forms. Thermodynamic modeling suggested that aqueous Mo would precipitate over time as powellite (CaMoO4). Comparing Mo K-edge XAS spectra from the solid tailings to the aqueous Mo concentration in the pore water showed that powellite did form and that this did result in a decrease in the aqueous Mo concentration over time. Further, it has been proposed that Ca2+(aq) can react with bicarbonate ions in the pore water and precipitate as calcium carbonate (e.g., CaCO3). This reaction would limit the aqueous bicarbonate present in the tailings that could react with uranyl ions to form soluble uranyl-carbonate complexes. We have identified several trace Ca-bearing species, including carbonates, in the tailings using XAS and X-ray microprobe.

Jan 1, 2020

By D. Satish Kumar, D. Mazumdar

"95% bulk mixing times in three different size water model ladles of a 140 T cylindrical shaped , dual plug ( located diametrically opposite at mid bath radius position) stirred, industrial ladle were determined experimentally with and without an upper buoyant phase. Based on dimensional analysis and a regression of the experimental data and, it was shown that in the inertial and gravitational force dominated flow regimes, 95% bulk mixing times for a slag-less situation can be described via:[equation]Parallel to this, a large number of experiments were also carried out in one of the water models (D=0.30m) to quantify the influence of an upper buoyant phase on mixing. These indicated that mixing time, operating variables and thermo-physical properties of the upper phase liquid can be correlated via a dimensionless relationship of the type:[equation]in which, Q is the ambient gas flow rate, L is the depth of liquid , (AL) is the slag layer thickness and 6 and t are respectively the surface tension and viscosity of the upper phase fluid The dimensional analysis, regression of experimental data as well as the adequacy of the proposed correlations are discussed in the text."

Jan 1, 2004

By A. D. Pittuck

Refractory minerals .containing uranium and columbium have been successfully treated at Queen's University, Kingston, to produce high-grade concentrates. Recoveries of over 90 per cent of the uranium and columbium have been obtained when treating concentrates containing euxenite, fergusonite, betafite, and pyrochlore. The processes ?consisted -of leaching the columbium with hydrofluoric acid, and the uranium with nitric acid, sulphuric acid, or sodium carbonate solutions. The leach liquors were extracted with organic solvents from which the values were stripped and precipitated, producing final products assaying 45 to 55 per cent Ob2O5 and 60 to 70 per cent U3Os.

Jan 1, 1958

By H. C. Gunnings, C. O. Swanson

"The Sullivan mine; at Kimberley in southeastern British Columbia; is the largest silver-lead-zinc mine in the Empire and one of the largest in the world.The original discovery was made in 1892 by four prospectors. Until 1899, when the branch line of the Canadian Pacific railway from Cranbrook to Kimberley was completed, little work was done on the property. In 1900, systematic development was started, and during the next 3 years 5,000 tons of ore was shipped to the smelters at Nelson and Trail. By 1903, some 300,000 tons of ore was developed, and a smelter was started at Marysville, about 5 miles from the mine. However, this smelter closed down in 1907 because of metallurgical difficulties after treating 75,000 tons, and the property came under the control of the American Smelting and Refining Company. An option on the property was taken in 1909 by the Consolidated Mining and Smelting Company of Canada, who exercised their option in the following year. During the next 5 years by selective mining and sorting 188,000 tons of high-grade ore was produced and shipped to Trail. This tonnage came from the upper levels, about 4,600 to 4,800 feet in elevation. At the same time, deep drilling down to the 3,900-foot level showed the presence of an immense body of complex ore. In 1915, the main adit-the 3,900-foot level-was started, and by 1919 this had been driven a distance of 2 miles to develop the ore above this level. Meanwhile, progress was being made in overcoming the milling problems. An interesting account of this work was written by the staff ( 4). In 1923, the first unit of the present concentrator was erected, with a capacity of 2,500 tons a day, and thereafter the rate of production increased rapidly. In 1934 it was around 8,000 tons a day, and to date a total of about 30,000,000 tons of ore has been sent to the mill. In recent years, a considerable part of the production has come from levels between the 3,900-and 3,350-foot, which were opened by an internal incline shaft started in, 1930. In 1942, tin was added to the products separated at the concentrator."

Jan 1, 1954

By T. J. Wells

THE blast furnace is the base of the steel industry, since there is no commercially practical way of converting iron ore directly into steel. In three hundred years, the blast furnace has developed from a small unit using charcoal as fuel and producing about one ton of iron in twenty-four hours to a furnace making upwards of 1,500 tons a day. The principle of the blast furnace is briefly this: A descending column of stock, consisting of ore, fuel, and flux, is met by an ascending stream of gases, consisting in part of gases formed by the combustion of the fuel and in part of pre-heated air which is blown into the lower part of the furnace. The flux combines with the impurities in the ore and the ash in the fuel to form slag, which is drawn off as liquid.

Jan 1, 1943

By A. Azizi, P. Blatter, A. Bouajila

ABSTRACT In-situ monitoring of gold dissolution by means of a rotating electrochemical quartzcrystal microbalance unveiled dramatic decreases in gold leaching from sulphide-rich ore after 360 minutes in an actual cyanidation circuit. Pre-oxidation was effective in enhancing gold extraction by preventing a passive film from forming on gold surfaces. This work aims to highlight efforts undertaken to determine (1) how gold cyanidation is limited by passivation, (2) what reactions and mechanisms are involved during sulphide-rich ore cyanidation, and (3) how peroxidation efficiency of an industrial sulphide ore is controlled by galvanic associations between its sulphide constituents.

Jan 1, 2013