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By G. Pouskouleli, T. A. Wheat

"The role and benefits of using statistical methodology in the development and optimization of materials and processes is examined. It is shown that considerable benefits accrue from the use of an appropriate design in which a number of factors (process parameters) are varied simultaneously while the system response such as percent recovery, degree of separation, purity, etc. is monitored and ultimately optimized.Compared with the commonly encountered one-factor-at-a time approach, this schema exploits reduced experimentation (thereby requiring reduced resources [staff, time, dollars, etc.]) yet yields quantitative information on the significance of each factor and their combinations on the measured response."

Jan 1, 1992

By W. A. Haley

This paper discusses how a large wheel loader should be equipped, with particular attention paid to tires and tread life, and describes the several steps that can be taken to provide favorable working conditions and reduce over-all costs. A comparison is then made of wheel loader production and costs vs those of power shovels, and the present and possible future applications of the wheel loader are outlined.

Jan 1, 1969

By Jolanta Olkowska-Oetzel

Reactions of gold?phosphino complexes [(AuX)(PR3)] (X= Cl, Br, I; R = organic rest) with Se(SiMe3)2 lead to the formation of gold complexes with chalcogenide bridges. The reaction of the complex Ph3PAuCl and tBuSe(SiMe3) gives the cluster [Au5Se2(PPh3)4]Cl 1. The in situ preparation of the complex [(AuCl)2dpph] (dpph = Ph2P(CH2)6PPh2) by reaction of dpph with Me2SAuCl, and subsequent reaction with Se(SiMe3)2 leads to the formation of [(Au3Se)2(dpph)3]Cl2 2. Reactions of the gold(I) complex [(AuCl)2dpppe], (dpppe = Ph2P(CH2)5PPh2) with Se(SiMe3)2 and InCl3 in different molar ratios lead to the formation of [Au10Se4(dpppe)4]InCl5 3 and [Au4(SeInCl3)2(dpppe)2] 4. The reaction of [(AuCl)2dpph] with Te(SiMe3)2 and GaCl3 produces the isostructural cluster compound [Au4(TeGaCl3)2(dpph)2] 5. From the reaction of Se(SiMe3)2 with [(AuCl)2dppe] (dppe = Ph2P(CH2)2PPh2) and InCl3 [Au8Se4In(dppe)4](InCl4)3 6 can be isolated. The structures of 1 - 6 were determined by X?ray diffraction.

Oct 1, 2003

By E. L. C. Martins, M. J. Nicol, D. Majuste, A. D. Souza

The effects of organic compounds on the current efficiency (CE), morphology, crystal structure and mechanical properties of the metal deposited during the electrowinning of zinc are described. A flotation collector and lubricating oil were selected based on observations made during the industrial production of zinc from silicate ores, in Brazil. The analysis by Fourier transform infrared spectroscopy of these compounds, which may be present in minor amounts in the electrolyte solution, indicated the presence of a polar amine group in the collector, while the lubricating oil is a non-polar compound. The average CE value obtained from organic-free industrial solution was 91.15 ± 0.26 %. The CE dropped to 54.35 ± 0.73 % in the presence of 100 mg·L-1 of collector in the solution, and a negative effect was also observed in the presence of similar amounts of oil (88.84 ± 0.61 %). The characterization of the deposits by scanning electron microscopy and X-ray diffraction revealed the formation of pores in deposits obtained from solutions containing the oil, while a different growth pattern (perpendicular zinc platelets) was identified when the flotation collector was added to the industrial solution. In the presence of these contaminants in the solution, guided-bend tests revealed that the deposits have a higher resistance to deformation, but lower ductility, properties that may affect the performance of the stripping stage. As a result of this work, simple control and optimization actions were applied in the industrial plant, which resulted in important improvements in the electrowinning process.

Jan 1, 2014

By R. V. Tomkins

Introduction In the past fifteen years, bentonite production in the United States has increased very rapidly. From l50,000 tons in l934, it rose to 400,000 tons in l 942 and to a record 920,000 tons in 1948. Occurrences of bentonite ?in western Canada were described in the early part of the century by Ries and Keele (3), Ells (2), Spence (4). and other officer of the Dominion Department of Mines, and, in Saskatchewan, Professor W. G. Worcester (6), of the University of Saskatchewan has explored and carried out tests on deposits of the material at various times during the past thirty years. Nevertheless, Canadian developments have not kept pace with those in the United States. Exact figures for total Canadian production are not released, but it is probably under l0,000 tons annually. There are a great number of uses for bentonite, but in the United States three alone account for 90 per cent of the consumption. These are for drilling gel, foundry sand bond, and oil decolorizer. The tremendous oil exploration programme on the Canadian prairies has increased the possibility of an adequate domestic market for drilling gel. Therefore, in Saskatchewan, our efforts have been directed mainly to the production of a good drilling gel, with a minor part of the project devoted to activation of bentonites for oil decolorizing.

Jan 1, 1952

By D. W. Boydell

The response of reclaimed gold tailings to acid leaching was investigated in the laboratory, followed by a pilot-plant program in which the operations of CCD, CIX and SX were tested with plant feed material. These results formed the basis for the design of the extension to the existing uranium plant at Blyvooruitzicht Gold Mine, commissioned in July 1977. This circuit consists of slimes-dam reclamation by bucket-wheel excavator at a rate of 100,000 t solids per month, acid leaching in pachucas, a five-stage CCD washing section, two parallel C1X absorption columns and two elution columns, SX and an ADU precipitation section. Barren solution is recycled to the CCD section as wash and to the repulper at the slimes dam. The performance of the plant during the first year of operation is compared with the predictions on which the plant design was based. Rated capacity was achieved within three weeks of start-up at a nominal dissolved uranium recovery in the ion-exchange section of around 98%. Owing to recycle, the over-all recovery in the ion-exchange and solvent extraction sections is somewhat higher than this figure.

Jan 1, 1979

By Engineering Staff

"This paper briefly describes the surface mining operations at Smoky River Coal Limited (formerly McIntyre Mines Limited, Coal Division) near Grande Cache, Alberta. Geology, mining methods, equipment, manpower and reclamation and environment topics are discussed. Introduction Smoky River Coal Limited, a wholly-owned subsidiary of McIntyre Mines Limited of Calgary, Alberta, produces a high quality, low sulphur, low volatile bituminous coking coal from its minesite located at west central Alberta, approximately 20 km from the town of Grande Cache and 360 km west of Edmonton (Fig. I). Most of the coal property is contained within a 30 km long by 20 km wide block lying in a northwest-southeast direction in mountainous terrain. Elevations vary from 920 m above sea level ·at the plant·site on the Smoky River to 1,600 mat the upper levels of current and proposed mining operations. A total of 11 coal seams have been identified. Only two seams, No. 4 Seam and No. 10 Seam are currently considered of major commercial value. These seams are recovered by both surface and underground mining. Approximately 650Jo of the plant feed coal is obtained from a conventional shovel/truck surface mine; the balance is mined underground by room-andpillar methods. Background In 1921, McIntyre Mines Limited acquired some 26,300 hectares of coal leases at Smoky River. Since then the leases were explored intermittently by different companies including McIntyre. In the mid-l 960s exploration activities increased and several feasibility studies were completed. Development of the area was undertaken by McIntyre in 1968 and, in August of the same year, a long-term contract was signed with a consortium of Japanese steel mills for delivery of 2 x 106 t of clean coking coal for 15 years commencing in 1970. Production was focussed on underground mining, using longwall methods."

Jan 1, 1985

By H. O. Lien

Among the known iron deposits in Canada, many are of low grade and require beneficiation to produce an acceptable blast-furnace feed. Some of the deposits have never been considered for commercial exploitation due to the lack of a suitable concentrating process. A number of deposits of this type are located in Northern Ontario. The problem in upgrading these deposits is three fold. Firstly, the iron occurs as a mixture of magnetite and hematite. Secondly, the grain size of the material can be fine to very fine. Thirdly, the complex mixture of gangue minerals, which consists invariably of silica, flaky silicates and carbonates, slimes excessively on fine grinding. Algoma's efforts to concentrate these iron-bearing materials culminated in the development of a "Selective Flocculation and Desliming Process" employing slimes removal as the sole beneficiation technique. The process was applied successfully in the laboratory using two stages of grinding and a total of seven deslimings. Prior to the removal of slimes, the iron-bearing fines were selectively flocculated from a thoroughly dispersed pulp using a modified starch as flocculant, Sodium silicate was employed as dispersant. An attempt was made to optimize some of the process variables using material from one specific iron formation near the town of Geraldton in Northern Ontario. The preparation of the starch proved most critical. This matter, and the method used to evaluate the degree of breakdown of the starch molecule, are therefore discussed in some detail.

Jan 1, 1978

By V. G. Papangelakis, A. Dani

"Alkaline pressure oxidation, particularly in the presence of trona as additive, can be used to oxidize high carbonate refractory gold ores as it prevents the formation of CO2 in the autoclave. However, the presence of silica in the ore can lead to the encapsulation of pyrite due to the solubility of silica in alkaline solutions and its subsequent reprecipitation on the reacting pyrite surface, leading to the formation of a passive layer. This fundamental study investigates the chemical composition and thickness of the passive layer on a rotating pyrite disk using XPS and SEM, as a function of process conditions at 230°C, in an aqueous slurry containing silica sand, sodium carbonate and calcium carbonate under 100 psi of oxygen overpressure.INTRODUCTIONAlkaline pressure oxidation (POX) has been used successfully to treat high carbonate refractory gold ores, which contain carbonates in addition to sulphides, most notably at Mercur and Goldstrike mines operated by Barrick Gold. There are several advantages to using alkaline POX over its acid counterpart, especially due to high carbonate content. First, it eliminates the production of CO2 in the autoclave without resorting to pre-acidification, which allows for high oxygen utilization. Second, alkaline POX suppresses the formation of elemental sulphur and intermediate sulphur oxyanions (such as thiosulphates and dithionates), which reduce gold recovery. Third, the use of sodium hydroxide or salts prevents the formation of anhydrite scale by forming soluble sodium sulphate. Other advantages are the use of cheaper materials of construction and the formation of non-acidic residue that do not require further treatment prior to cyanidation (Thomas, 2005).Sodium carbonate in particular is a promising reagent for alkaline POX because it was shown to significantly accelerate the kinetics of pyrite oxidation by molecular oxygen, when compared to other reagents such as sodium hydroxide, sodium borate and calcium hydroxide. This has been attributed to the following factors: a) the faster oxidation kinetics of Fe2+-CO3 complexes compared to Fe2+ oxidation, b) the buffering effect of carbonate ions on the acidic pyrite surface, and c) the increased solubility of oxidizing Fe(III) species due to carbonate complexation (Caldeira, 2010)."

Jan 1, 2012

By Qingxia Liu, Mingbo Zhang, Hongbo Zeng

The shortage of freshwater has been a major challenge for mineral flotation in arid areas. When using high salinity water, certain electrolytes are detrimental to flotation while others can improve the flotability of minerals. In this paper, the flotation behaviors and contact angles of pyrite in both Milli-Q water and high salinity water were investigated using different collectors at various pH levels. Results show that the thionocarbamate has a less affinity to pyrite in different solutions under mildly alkaline conditions as compared with potassium amyl xanthate (PAX) and N-isopropoxypropyl-N’-ethoxycarbonyl thiourea (iPOPECTU). At high pH levels, the slime coating on pyrite surfaces, which is caused by colloidal precipitates of magnesium and calcium ions in seawater, was confirmed by SEM, EDX and in-situ zeta potential measurement. The slime coating of colloidal precipitates on mineral surfaces led to low recovery of pyrite at high pH levels. The study of flotation behavior of pyrite in high salinity water improves our fundamental understanding of mineral flotation in seawater.

Jan 1, 2015

By M. Venkatraman

The limit of Hall - Petch relationship in ultra fine grained steels has been examined based on dislocation pile-up mechanism. When the grain size becomes small the dislocation multiplicity ceases resulting in very low work hardening rate in these materials. An approximate analysis of the theories of hardening indicates that H-P relation is obeyed up to 100nm. It appears that grain refinement is not the suggested approach to improve toughness as well as strength below a critical size.

Jan 1, 2004

By L. S. Beck

"IntroductionThe Beaverlodge District is an important mineralogenic province of pitchblende and occupies about 1300 square kilometres centred on Beaverlodge Lake near the north shore of Lake Athabasca in northwest Saskatchewan (Fig. 1). Uranium City is the main settlement of the area and is serviced by scheduled aircraft from Edmonton, some 700 km to the southwest, and from Prince Albert which lies a similar distance to the south.During the summer, boats and barges supply the area from the railhead to Fort McMurray via the Athabasca River and Lake Athabasca, a distance of about 550 km. For the past few years a winter road has been maintained across Lake Athabasca to Cluff Lake to connect with Highway 155.The topography of the area is typical of the Precambrian Shield with generally low relief and a disorganized drainage of numerous lakes separated by hummocky rock ridges, muskeg and drift-covered areas. Local topography in the area is, however, extremely rugged, particularly south and east of Beaverlodge Lake, where resistant rocks form prominent hills and ridges extending as much as 180 m above lake level. Rock exposures are abundant and form over 50 per cent of the land area.History of Exploration and DevelopmentEconomic interest was first aroused by Tyrrell (1896) who described an occurrence of iron formation at Fish Hook Bay; however, subsequent evaluation of the deposit indicated it to be uneconomic."

Jan 1, 1986

By J. Cui, Z. Meng, W. Zhao

"The decomposition of rare earth concentrates containing bastnasite and monazite by alkali solutions has been investigated. A slurry of the rare earth concentrate and the alkali solutions was calcined at different temperatures. The impacts of calcination temperature on the decomposition of rare earth minerals, the oxidation of cerium, the deportment of fluorine and phosphorous, and the adaptability of the method to the different grades of rare earth concentrate were all studied. A possible technique for comprehensive recovery is proposed in which the chemical elements such as rare earth, fluorine, phosphorus, calcium, iron and thorium could be recycled or recovered. INTRODUCTIONThe liquid alkali decomposition method is an important technique for the decomposition of mixed rare earth concentrates. The technique is relatively clean compared with the sulfuric acid roasting method. However, its operation is intermittent rather than continuous. The two-step solid-liquid reaction and the subsequent water washing make it not very suitable for mass production and application. An important reason for the disadvantage is that an additional process of ""calcium removal by acid leaching"" is needed for the technique. The content of calcium in Baotou rare earth concentrates is usually 6-12%. The requirement of the current technique is that the content of calcium should be reduced to about 0.2% after the calcium removal process. Otherwise, the decomposition and leaching of rare earth will be affected. Therefore, calcium removal by acid leaching is a necessity before the alkali decomposition process is carried out. Research on different alkali decomposition techniques has been conducted with prior calcium removal by acid leaching (Xu, 1995; Yu, 1993; Han, Li, Chang, Liu & Xu, 1985). There have been some investigations of direct decomposition of the bastnasite (Feng, Pan & Li, 1998; Zhao, Zhang, Yang & Liu, 2002)and monazite (Sun, Li, Li, Su, Zhao & Liu, 1998; Zhou, 2005) by alkali-liquid, however, all studies were carried out in solid-liquid reaction system, and continuous calcination studies have not been reported.This paper investigates the process of direct decomposition of Baotou rare earth concentrates by continuous calcination with concentrated alkali. Using the rotary tubular electric furnace, the mixture of rare earth concentrate and concentrated alkali solution were decomposed continuously. Satisfactory decomposition results were achieved. A method for clean processing and comprehensive resource recovery from Baotou rare earth concentrates is proposed."

Jan 1, 2012

By A. R. Naji Meidani, A. Cameron, A. Richardson, M. Isac, R. I. L. Guthrie

The supersonic core of shrouded jets remain coherent over longer distances vs conventional supersonic jets. This phenomenon should allow for greater penetration of oxygen into slag/steel reactor systems. As such, they hold the promise for faster slag/metal mixing in BOF type metallurgical reactor systems, possibly creating greater surface area/volume ratios of reacting phases, and thereby faster kinetics, as compared to conventional supersonic jet systems. In order to assess the potential of shrouded supersonic jets versus their conventional counterparts, an experimental investigation of impinging shrouded supersonic jets into a water model of a simplified BOF system was carried out in the MMPC's water modelling laboratory. The experimental results for three different designs of a shrouded supersonic jet nozzle have been compared in terms of greater penetration depths and reduced mixing times. Based on a novel dimensional analysis, the depth of penetration of a gas jet into a liquid bath is shown to depend on the nozzle-bath distance, the liquid's Froude, Reynolds and Weber numbers, reflecting the ratios of gravity, viscous and surface tension forces to the jet's inertial, or momentum, forces. Good agreement between the mathematical model and experiment was obtained in terms of predicted and observed depths of penetration. Further efforts have been made to study jet penetration into liquid metals. The effects of mean liquid density of slag/metal mixtures and a wide range of gas flow rates on the penetration depth were investigated theoretically. The results show that the penetration depth can be increased with increasing gas flow rate and decreased bath density.

Jan 1, 2004

"These guidelines set out information on timely disclosure of news releases which are intended to provide, existing shareholders and potential investors, factual information on which a reasoned investment decision can be made.Consider the problems and concerns raised by the following hypothetical news releases:Natural Resource Company""The Company has recently optioned a large and exciting gold property near the ""XXX"" gold discovery area. In describing the property, the Company's independent consultant has said: ""The favourable location of, and some of the results of prior work done on the property give the Company a worthwhile mineral exploration opportunity .... "". The Company proposes to expeditiously conduct a sizeable exploration program on the property as soon as the appropriate financing has been arranged.""Non-Resource Company""Based on discussions with several European countries, the Company anticipates that it will have orders to ship over 200,000 crates of widgets to those European countries over the next two years. These orders, which considerably exceed the Company's forecasts for the first year, represent a projected profit to the Company in excess of $1,000,000 over the next five year period.""GuidelinesTimely disclosure news releases are intended to provide, to both existing shareholders and potential investors, factual information on which a reasoned investment decision can be made. National Instrument 43-101 Standards of Disclosure for Mineral Projects provides requirements for disclosure of a scientific or technical nature for a mineral resource company.The examples do not provide sufficient detail and are misleading because material information is omitted. The following guidelines should be observed when preparing a news release:"

Jan 1, 2003

By The Staff

"THE Wabana iron ore mines, owned and operated by the Dominion Steel and Coal Corporation, Limited, .are on Bell Island in Conception bay, on the east coast of Newfoundland. Mining began on surface in 1895 and, although open-pit work is still done on a small scale, the entire output may be considered to•be derived from extensive submarine workings. In 1958 the average daily production of hematite ore was close to 12,000 tons, almost all of which was concentrated in a heavy-media plant. SUMMARYThe character, occurrence, and extent of the submarine bedded deposits enabled early operators to meet prevailing market demands with the minimum attention paid to exploration. Mechanization of the mine and the pressure for sustained high tonnages since 1955 have emphasized the importance of an expanded exploration and development programme.A serious handicap has been the impossibility of utilizing normal diamond drilling methods to explore ore conditions in advance of mining faces. Drilling between tl1e bedded zones has been done but the major difficulty has been to delineate ore reserves in the lower bed, which has the greatest ore potential of the three mineable seams."

Jan 1, 1960

By Charles B. Newmarch

Abstract In the course of coal studies undertaken by the B.C. Department of Mines in southeastern British Columbia, special attention was directed to problems of coal seam correlation. Methods that had been used successfully in other coalfields were found, in the Crowsnest area, to have a restricted use or furnished only additional evidence that might prove helpful when used in conjunction with other criteria. A correlation technique involving semi-quantitative spectrographic analyses of coal ashes was developed. Elements detected in the ash include Si, B, P, Fe, Mg, Mn, Pb, Ti, Cr, Ga, Ca, Al, Ge, Ba, Mo, V, Ag, ?y;b, Na, Zn, Zr, Ni, Sr, Cu, K. Of these, the elements found to be most useful in correlation were Na, Ba, Si, V, and Mg. The element Na was invariably detected in the ash from one of the seams but was not found in samples taken from any of the others. In all of the four seams sampled statistically, significant differences in the amount of certain trace elements were noted. When the values obtained for these trace elements were portrayed in the form of histograms, the resulting diagrams had a characteristic shape for each seam. The diagrams provided a basis for seam identification within the limited area (8,000 feet by 4,000 feet) that was investigated. Introduction During the field seasons of 1946, 1947, and 1948 the British Columbia Department of Mines undertook a geological investigation of the coal measures of southeastern B.C. As field work progressed in the Crowsnest area it was found that, within the Kootenay formation, which contains all the commercial seams of the region, the coal beds are the most persistent stratigraphic units. Because of relatively rapid changes in ?both the thickness of the seams and the interval between seams, difficulty has invariably been experienced in attempts at correlation. Even short-range correlati0ns by able geologists who have worked in the Crowsnest coal basin have been questioned by the operating companies. It was apparent, therefore, that a more dependable correlation technique was needed so that stratigraphic and structural studies could be of greatest value. This paper presents, firstly, a summary of the results obtained in attempted correlations using methods that have been found effective in other coalfields. Secondly, a method based on semi-quantitative spectrographic analysis of coal ash is described and the apparently promising results are discussed.

Jan 1, 1950

By Kyeong Woo Chung, Ho-Sung Yoon, Jyothi Rajesh Kumar, Chul-Joo Kim, Sung-Don Kim

The aim of the present study is to investigate the extraction, separation and recovery of the indivisible metals of dysprosium and neodymium from permanent magnets scrap leach liquor solutions with meaningful recovery. The present experimental development focused on dysprosium separation from neodymium and recovery by suitable mineral acids. Fundamental studies of the effect of time, pH and extractant concentration on the metal separation were conducted followed by proposal of a mechanism for extraction. Process development included generation of McCabe-Thiele diagrams and counter current extraction (CCE) studies. After loaded organic generation from the CCE process, this was followed by scrubbing studies as well final recovery of dysprosium.

Jan 1, 2014

Mine Safety in Chile ?Since the year 2000 fatality rate averages 34 per year ?1% of world mining labour force but 8% of world?s mining fatalities San Jose Mine Safety ?From 1998 to 2010 eight fatalities ?In 2003 mine inspectors recognized no second means of egress and a raise system was developed ?In 2006 182 workers were injured, 56 of them seriously ?In January 2007, there was a fatality after a rock burst, and the government ordered the mine closed ?Less than a year later the mine was back in operations. It had not complied with some of the basic safety measures ordered. One of those measures was to complete the escape way ladder.

May 1, 2011

By G. W. Poling

Sedimentation behaviour of siliceous mill tailings derived from a magnetite-chalcopyrite ore in fresh water, fresh water - sea water mixtures and full-salinity sea waters are compared. Results of batch settling tests are presented in the form of settling curves and solids flux curves. The addition of a few per cent of sea water markedly enhanced the zone sedimentation rate due to particle agglomeration caused by a reduction in zeta potential of the suspended solids. The presence of a small amount of residual, previously magnetized magnetite in the tailings also enhanced agglomeration and sedimentation. The significance of these results to submarine disposal of mill tailings is discussed.

Jan 1, 1973