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By Mathias Woydt

The tribological and mechanical properties of binderless and metal-bonded niobium carbides (8 or 12 vol.-% of Cobalt, 12 vol.-% of Fe3Al) are presented. Rotating disks made of niobium carbide bearing hard metals were mated against alumina (99.7%) under unlubricated (dry) unidirectional sliding tests (0,1 m/s to 12,0 m/s; 22°C and 400°C) as well as in oscillation tests (f= 20 Hz, ?x= 0,2 mm, 2/50/98% rel. humidity, n= 105/106 cycles). Microstructure and phase compositions were determined as well. The tribological data obtained were benchmarked with different ceramics, cermets, hard metals and thermally sprayed coatings, where NbC bonded with 8% and 12% Co presented above 8 m/s the lowest wear rates so far in such a benchmark. Binderless NbC (HP-NbC1) and the metal bonded NbCs exhibited low wear rates under dry sliding associated with high P?V load carrying capacities. NbC-based hard metal bonded with 12 vol.-% of Fe3Al resulted in a higher hardness level than for 12 vol.-% cobalt. The tribological profile established revealed a strong position of NbC bearing materials under tribological considerations and for closed tribosystems against established reference tribo-couples.

Jul 31, 2018

By Alessandro Molinari

In recent times, coke oven machines are acquiring a more prominent role in the coke making process. Apart from the traditional handling of the coal and coke flow, nowadays these machines are also deeply involved in all environmental and process control aspects. Paul Wurth coke oven machines have been developed by Schalke to meet the most recent requirements in terms of emissions control, automation, instrumentation, operability and maintainability. In CSP, Ceará, the new coke making plant represents the status of the art of the technologies applied to the whole coking process; starting from the Coke Oven Batteries and the Gas Treatment Plant developed by Paul Wurth up to the Coke Machines supplied by Schalker Eisenhütte, whose technology is now part of Paul Wurth coke making products portfolio. Present paper describes the plant configuration focusing on Coke Oven Machines and the key factors which are guarantying the success of the project.

Aug 16, 2017

By Rogério Felício dos Santos

Nitriding of metallic materials using electric discharges generated during electric discharge machining (EDM) is a recently developed technique. The aim of this paper was to correlate mechanical properties of a nitrided layer produced in AISI 4140 steel by EDM nitriding with the type and amount of nitrides. A conventional die-sinking EDM equipment and electrolytic copper electrodes were used to generate the electric discharges. The electrolyte was a solution of urea in deionized water. Knoop microhardness profiles assessed the variation of hardness along the nitrided layer, whereas the elastic modulus of this layer was measured using nanoindentation tests. Optical microscopy and X-ray diffraction (XRD) were used to characterize the nitrided surface. The results showed the formation of a nitrided layer containing iron nitrides with average thickness of around 25 µm. The amount of nitrides reduced from the surface towards the centre and these results correlated well with microhardness profiles obtained.

Jul 31, 2018

By Douglas Glenn Stalheim

The uniformity of the final cross sectional microstructure and subsequent final mechanical properties and shape of structural steels is dependent on the type or types of recrystallization behaviors that are created. There are three main recrystallization behaviors that are the foundation of the metallurgy created during production. Alloy design and subsequent processing design strategy drive how much of each recrystallization behavior is created through the cross section of the product. Carbon manganese steels create only one basic behavior while the addition of microalloys, in particular niobium, can add two additional behaviors. The behaviors are intertwined with each other and build upon each other. The three behaviors are Type I, static recrystallization, Type II, no-recrystallization, and Type III, metadynamic/dynamic recrystallization. How much of each behavior is generated through the cross section through the production influences the final transformed microstructure and corresponding mechanical properties and shape performance. This paper will discuss the three behaviors, how they are generated, how to identify which behavior is occurring through modeling or actual mill data. Actual examples from production will be discussed.

Aug 16, 2017

By Boryong Lee, Heedong Sung, Minho Park, Sunyoung Choi

Recently, the demand for ultra-thin steel plate with high hardness and strength has been increasing in various industries. In order to satisfy this requirement, steel company designs the chemistry with low CEQ and obtains the required characteristics through quenching and tempering process. Especially, these steels are accompanied by low temperature tempering as a necessary process. Unlike ordinary high temperature tempering steels, it is impossible to improve the flatness after low temperature tempering. Therefore, shape control in the quenching process is very important for securing the excellent quality flatness. In order to obtain flatness in the quenching process, uniform cooling inside the plate should be accompanied. However, the quenching process has limitations in estimating the temperature behavior during cooling because the plate temperature is lowered to room temperature. In this study, a thermocouple was installed inside the actual quenching plate to measure the temperature behavior during cooling and to establish the manufacturing conditions of the quenching plate to ensure excellent flatness quality.

Oct 1, 2019

By Satish V. Kailas

For product sustainability “closing the cycle” is the first requirement. If the materials used in making the product is not replenished at the rate at which it is being extracted, the cycle is open and the product would not be sustainable. This includes the materials used in generating the energy used to make the product, the transportation, use and disposal. If the materials used in a product, that includes lubricants, is one that cannot be replenished, it has to be recycled for the product to be sustainable. The other basic condition for sustainability is the eco-friendliness of the product. It is argued that the present lubricants do not fall in this category. Using the example of cutting oil emulsions we have shown that it is possible to meet the conditions of sustainability in terms of both the material extraction-replenishment cycle and eco-toxicity. Cutting oil emulsions made from coconut oil and natural additives are shown to have superior cutting properties and are completely eco-friendly. It is concluded that products made using these conditions are possible and is a necessity for man to lead a sustainable life. Closing the cycle, with respect to the energy used in the cycle will make the product completely eco-friendly.

Jul 31, 2018

By Elizaveta Cheremisina

In steelmaking process lime serves as flux. Rapid lime assimilation and slag formation of the desired composition have a significant effect on the refining reactions. It is important to know the rate limiting step of lime dissolution to control and improve the converter process. Kinetics of pure CaO and industrial lime dissolution in model slag has been studied in the range of temperatures 1300 –1600°C. Lime samples were prepared in cylinder form and immersed in the melt for predetermined time. Considering the total mass balance of CaO in the slag and linear dimensions of lime samples, mass transfer coefficients were derived. Diffusion coefficients were calculated under conditions of non-stationary diffusion. The derived activation energy of less than 200 kJ/mol indicates that diffusion is the limiting step in the process of lime-dissolution in slag.

Oct 30, 2017

By Mery-Cecilia Gómez-Marroquín

O presente trabalho trata da formação da ferrita de zinco a partir da mistura e posterior reação solido-solido entre o óxido de zinco e óxido de ferro - Fe2O3 puros em proporções equimolares. A faixa de temperatura onde teve lugar a formação foi entre 1073 e 1373 K. Testes de redução da ferrita de zinco sintética-ZF e pós de aciaria elétrica–EAFD foram realizadas usando misturas de CO e CO2 que variaram entre 50 e 100% CO. Ambos os testes (formação e redução de ZF e EAFD) foram suportados usando técnicas de caracterização física, química, estrutural e microscópica. No caso da redução, foi observado que tanto a temperatura como a percentagem de CO, foram os fatores que, mais afetaram a redução de ferrita de zinco contida no EAFD. A máxima percentagem de redução foi 85%, para 100% CO, 1373 K e 105 min, e 52%, para 50% CO, 1373 K e 105 min. Por outro lado, atingiu o 100% para 100% CO, 1273K, em 80.75 min, 60%, para 50% CO a 1373 K durante 105 min.

Aug 16, 2017

By Mery-Cecilia Gómez-Marroquín

O presente trabalho trata da formação da ferrita de zinco a partir da mistura e posterior reação solido-solido entre o óxido de zinco e óxido de ferro - Fe2O3 puros em proporções equimolares. A faixa de temperatura onde teve lugar a formação foi entre 1073 e 1373 K. Testes de redução da ferrita da zinco sintética-ZF e pós de aciaria elétrica–EAFD foram realizadas usando misturas de CO e CO2 que variaram entre 50 e 100% CO. Ambos os testes (formação e redução de ZF e EAFD) foram suportados usando técnicas de caracterização física, química, estrutural e microscópica. No caso da redução, foi observado que tanto a temperatura como a percentagem de CO, foram os fatores que, mais afetarem a redução de ferrita de zinco contida no EAFD. A máxima percentagem de redução da ZF foi 85%, para 100% CO, 1373K e 105 min, e 52%, para 50% CO, 1373K e 105 min. Por outro lado, atingiu o 100% para 100% CO, 1273K, em 80.75 min, 60%, para 50% CO a 1373K durante 105 min. no caso da redução do EAFD

Aug 17, 2017

By Edmar de Souza Silva, Antonio Augusto Gorni, Emanuelle Garcia Reis, Daniel Bojikian Matsubara

Controlled rolling followed by accelerated cooling, known worldwide as TMCP, aims to increase mechanical properties without toughness deterioration. The process principle is to promote the plate cooling with water jets along the range of the austenite transformation temperatures. The accelerated cooling process is only fully effective when controlled in an integrated manner, as it alone cannot ensure significant improvements in the final properties of steels. Plate surface quality depends on some parameters that must be controlled before the start of the plate accelerated cooling. Good flatness is essential to avoid irregular water accumulations during cooling. After the reheating process, the slab should have uniform temperature, uniform austenitic grain size and easily removable scale. The slab thermal and microstructural heterogeneities are inherited by the rolled plate and tend to increase further during the accelerated cooling. This results in flatness problems, high level of internal stresses and mechanical property variations. The descaling strategy is an extremely important factor and must be determined with great caution. It is important that scale thickness and distribution is uniform to ensure homogeneous cooling over the entire plate surface. Otherwise, there will be an uneven temperature distribution, which can cause serious problems of flatness, surface quality and mechanical properties.

Oct 1, 2019

By Valeria Romina Stricker

Acerbrag es una empresa Argentina siderúrgica de 50 años de trayectoria, desde el año 2007 pertenece al grupo Votorantim de origen Brasilero. Se dedica a la elaboración de aceros largos para la construcción. La planta industrial cuenta con un proceso de acería integrado, horno eléctrico, horno cuchara y máquina de colada continua. La materia prima es 100% chatarra, característica que la diferencia del resto de las acerías del país. Debido a esto el enfoque principal de este proyecto es reducir el costo de fabricación mediante un “empobrecimiento” de la carga metálica a partir de la flexibilización de los límites de especificación. Esto implica un mayor control del desempeño de los procesos a fin de detectar posibles desvíos, para ello fue necesario implementar la utilización de herramientas estadísticas y gráficas para su monitoreo. La modificación en el mix de fabricación no muestra una alteración significativa en la composición química y propiedades mecánicas de los productos terminados, situación favorable para la continuidad del proyecto. Se observa además, de la reducción de costo esperada, una ventaja en la operación del patio de chatarra y el proceso de acería y en la utilización de chatarras con altos niveles de residuales tales como Cr – Ni.

Aug 16, 2017

By Guilherme Guidugli

The hot blast stoves are a regenerative heat exchange system, accounting for 10 to 20% of the total energy requirement in an integrated steel plant, responsible for the supply of about one-third of the blast furnace heat input and responsible for a constant flow of hot air to the blast furnace, according to the required production. Because of their important role in the hot metal production, a stable operation and an appropriate combustion control is necessary. This paper aims to present the results of an investigation and modifications performed as an operating multi-furnace plant, as well as the parameters considered to ensure thermal equilibrium, improving in the stoves heating cycle.

Aug 16, 2017

By Hervé Thomasson

Siemens VAI has made an important Research & Development effort since 10 years on laser welder field. The last step of this program was in 2010, the evolution of its laser welder range by implementing the solid state technology with laser cutting and welding. Since this step, 8 welders were produced by Siemens VAI. Now after more than 1 year of industrial feedback, the results are showing a high level of performances on very demanding processing lines for a large range of products from Silicon steel to High Strength Steel with DP and TRIP grades. This laser welder concept using laser cutting and welding through solid state laser source is also proposed by Siemens VAI for pickling lines and tandem mills with significant advantages compared to standard solution.

Jul 30, 2018

By Luca Tommasi

Danieli complemented its wide range of production plants for the iron and steel industry with a further step upstream into iron ore pelletizing and beneficiation. Danieli has engineered and constructed a state of the art and fully automated pilot plant facility – pot grate and sinter box – at Altos Hornos de Mexico S.A. (AHMSA) Pelletizing Plant, Monclova, Mexico. Installation and commissioning were completed in October 2009. Key features of the pot grate include the avoidance of the need for operator intervention during the test, automatic system preheat, absence of dead time, heat recuperation system with an air/air heat exchanger, oxygen control in preheating and firing with zirconia oxygen analyzer, possibility to test deep beds up to 625 mm. A series of projects have been accomplished by AHMSA availing of the pot grate facility with the aim to enhance pellet plant productivity and to reduce operating costs. The results obtained by use of Danieli pot grate combined with the experience and skill of plant operators has shown significant technical and economical benefits thus fully justifying the initial investment made by AHMSA and confirming the importance of having an in-house testing facility in order to optimize industrial plant operations.

Aug 16, 2017

By Richard Harvey, Robert Paul Mawer

In recent times there has been an increase in the demand from Steel plants for a technology that offers the most economical environmentally sustainable solution. In terms of blast furnace off gas cleaning this has seen a drive towards Cyclone technology replacing the older Dustcatchers. Cyclone technology can achieve dust removal efficiencies as high as 95% increasing the dust yield at the primary stage of gas cleaning. The dry dust (rich in Fe and C) can then be recycled to the Sinter Plant or Blast Furnace. Capture of dust at this stage also has the benefit that sludge generation from the secondary stage is also reduced meaning less waste to landfill and / or recovery of some of the by-products for further use. Primetals Technologies already offer a state of the art Tri-Axial Cyclone installed on many sites world-wide, however, this paper focuses on a hybrid of this technology, the DustClone. The DustClone is a low CAPEX unit that is essentially a Cyclone housed inside the Dustcatcher. This unit is aimed at operators who may be carrying out smaller scaled shutdowns / repairs that normally have a reduced CAPEX. This paper describes the technology that Primetals Technologies have developed.

Oct 1, 2019

By Michel Rodrigo Luiz, Glaudistoni da Silva Félix, Osmar Duarte Junior

This article deals with a project to reduce the preparation time and threading the coils in the input section of a pickling line coupled to the cold strip mill (PLTCM) at ArcelorMittal Vega. The project developed serves for the detection and elimination of bottlenecks in the input section. The project was conceived by the philosophy of the Theory of Constraints (TOC) and Lean Six Sigma (6 sigma), here seen as sequencing serial / parallel in the preparation and threading the coils. In this context, a proposal to modify the automatic sequencing and reduction of interruptions due to failure of the automation / equipment confirmed its effectiveness reducing the total time preparation time and threading the coils in the entry section by 15%. This project was developed without investment costs, bringing gains on the order of US$613,769.00.

Oct 1, 2019

By Jônatas Venancio Barbosa, Dagoberto Brandão Santos, Túlio Magno Füzessy de Melo

In this work, the mechanical and metallurgical behavior of titanium added ultra-low carbon (ULC-Ti) steel under hot and warm working conditions was studied by means of dilatometer compression tests. Double compression schedules were performed at temperatures between 700°C and 1000°C, inter-pass times of 0.5-100 s, and deformations of 0.5 and 0.3 in the first and second stages, respectively, with strain rate of 1 s-1. The analysis of the flow curves obtained allowed the evaluation of the softening characteristics of the steel. The softening and microstructure features indicate different restoration mechanisms depending on the temperature range. Static recrystallization with rapid microstructure restoration is observed at temperatures within the austenitic and intercritical field. Strain induced boundary motion and recovery mechanisms apparently control the restoration process in the ferrite region. In general, flow stress curves showed dynamic recovery behavior. Only the deformation in the intercritical region produced a peak in the flow stress curves. Isothermal holding tests associated with single hit compression indicated the presence of dynamic strain induced transformation, accelerating the softening kinetics at the intercritical region.

Oct 1, 2019

By Leszek Maldzinski

The present concept assumes carrying out the process of controlled nitriding with NH3 alone. This is a simpler process than that using two-component mixes of ammonia diluted with N2 or NH3diss. The regulation of the chemical composition of the atmosphere in the retort, and therefore the regulation of the nitriding potential KN, is obtained through the variation of the inflow rate of NH3 into the retort. What is a completely new things in a relevant process, the inflow of NH3 into the furnace is at times reduced to zero, which widens the range of the gas composition in the retort (and by the same token, of KN). The amount of NH3 introduced into the furnace is regulated (controlled) with the aid of a gas analyzer (for example an infrared analyzer). The gas analyzer opens and closes periodically the NH3 inlet valve with a frequency maintaining a desired gas composition (a desired KN) in the retort. The concept was based on experimental and theoretical investigations in term of thermodynamic and kinetic of gas nitriding. Investigations were carried out in a laboratory furnace with a quartz tube and also in an industrial furnace with a steel retort and a circulating fan. Nitriding was performed using NH3, NH3+H2, NH3+NH3diss. mixtures. In an industrial furnace the supply of NH3 into the retort was periodically closed, though with an operating circulation fan. The studies demonstrated that the growth rate of nitrided layer depends only on the composition of the atmosphere, (or KN), in the retort. It depends neither on a type of atmosphere introduced into furnace (NH3, NH3+NH3diss. or NH3+H2) nor a type of furnace (laboratory with a quartz tube or industrial with steel retort and fan). The results proved also that entirely closing of NH3 supply to the retort does not affect the growth rate of nitrided layer. A detailed analyses of the results was performed in a paper.

Aug 16, 2017

By Jovanir Francisqueto, José Fagundes, Nayara Neves Coutinho, Marco Túlio Costa

The purpose of this project is to increase the visibility of which will be daily produced on the hot strip mill (HSM). The forecast was performed through the implementation of an automated tool for weekly HSM production planning. The project was started with the definition of the weekly planning process, through the determination of the main business objectives, like as: priorities of service (customers and delivery date), definition of HSM’s rules and restrictions of operating resources. Using a sophisticated mathematical model, through the computational simulation is possible the experimentation of various production scenarios, allowing the visualization of volumes by type of sequence, clients / priorities, mix to be produced, cylinder change quantity forecast, better forecasting of the productivity of the HSM, consumption of utilities, within others. Main benefits: sequencing which production orders should be produced, reducing unforeseen stops due lack of material, improving the quality of the stock which allows the reduction of the aging of slabs in the slabyard and the vision of customer services. Computational simulation as a weekly planning tool achieve, with other benefits, to present alternatives for better decision making.

Oct 6, 2019

By Álvaro Lúcio

This paper outlines the DPC process as na economic and environment friendly option for the use of cultivated forest as a source of raw material for metallurgical charcoal.The DPC process was specially developed to bring logistic, environmental, technical, economic and global energy efficiency when compared to termal1 the existing biomass carbonization process. The DPC process utilizes the volatile materials (condensable and non condensable) as a source of the energy required by the carbonization process guarantying its complete combustion. As result the DPC process avoids the burning of termal1 the loaded wood, obtaining a higher charcoal to biomass yield, and avoids the emission to the atmosphere of polluting gases. Gases emitted by the carbonizing wood have na energy termal1e enough to dry the wood soon after its harvesting. By avoiding the storage in the field during na average of 150 days, the resulting economy is quite significant. As a termal1e1 the higher charcoal to biomass yield na termal1e1e economy is obtained through the reduction of the cultivated forest term. This paper emphasizes the economic advantages of the DPC process.

Aug 16, 2017