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By Dong Joon Min, Joo Hyun Park, Mi Sun Choi, Jae Hong Shin

Sublimation of ZrCl4 is important for the production of nuclear grade metallic Zr in Kroll’s process. The sublimation kinetics of ZrCl4 was investigated by TGA under both isothermal and non-isothermal conditions. The sublimation rate of ZrCl4 increased with increasing temperature under isothermal conditions. ZrCl4 sublimation was confirmed to be a zero-order process under isothermal conditions, whereas it was first-order kinetics under non-isothermal conditions. The activation energy of ZrCl4 sublimation under isothermal conditions was 21.7 kJ/mol. The activation energy for non-isothermal sublimation was 101.4 kJ/mol and 108.1 kJ/mol with the Kissinger method and Flynn- Wall-Ozawa method, respectively. These non-isothermal activation energies were very close to the heat of sublimation (103.3 kJ/mol). Sublimation occurs by two elementary steps: surface reaction and desorption. Therefore, the overall activation energy of ZrCl4 sublimation is 104.8(±3.4) kJ/mol. The activation energy of the surface reaction and desorption steps are proposed to be 83.1 kJ/mol and 21.7 kJ/mol, respectively.

Jan 1, 2014

Sm-Co alloy is a kind of magnetic material with high power and has been applied in modern industry widely. In this study, the wet chemical co-precipitation was developed for synthesis of the Sm-Co alloy oxide precursor. The thermodynamic analysis of the studied system was done to clarify the solution behavior theoretically based on the thermodynamic equilibrium and simultaneous equilibrium. Then, the experiments were done to address the various effects on the wet chemical process, including solution pH, reactant concentration, dispersant, reaction temperature and time, etc. It is found that by precise control of the process, the Sm-Co alloy oxide precursor was synthesized with fine crystallization and special size & size distribution.

Jan 1, 2005

By Ji-He Wei

Keywords: stainless steel, AOD refining, side and top combined blowing, mixing characteristics, water modeling The fluid mixing characteristics in the bath during the side and top combined blowing AOD (argon-oxygen decarburization) refining process of stainless steel have preliminarily been studied on a water model unit of a 120 t AOD converter. The geometric similarity ratio between the model and its prototype (including the side tuyeres and the top lances) was 1:4. On the basis of the theoretical calculations for the parameters of the gas streams in the side tuyeres and the top lances, the gas blowing rates used for the model have more reasonably been determined. The influence of the tuyere number and position arrangement, and the gas flow rates for side and top blowing on the characteristics has been examined. The results demonstrated that the liquid in the bath underwent vigorous circulatory motion during gas blowing, without obvious dead zone in the bath, resulting in a well mixing effectiveness. The gas flow rate of the main tuyere had a governing role on the characteristics, a suitable increase in the gas flow rate of the subtuyere could improve mixing efficiency, and the gas jet from top lance could make the mixing time prolong. Corresponding to the oxygen top blowing rate specified by the technology, a roughly equivalent and good mixing effectiveness could be reached by using six side tuyeres with an angle of 27° between each tuyere, and five side tuyeres with an angular separation of 22.5° or 27° between each tuyere. The relationships of the mixing time with the gas blowing rates of main-tuyeres and sub-tuyeres and top lance, the angle between each tuyere, and the tuyere number have been obtained.

Jan 1, 2005

By Yanjie Liang

Elemental sulfur and volatilization kiln slag(VKS)containing heavy-metal produced by smelter factories were used to produce sulfured building material. The effects of heating mode, material proportion (MSulfur:MVKS), size of waste particles and ratio of aggregate to filler(A/F) on the mechanical properties and leaching toxicities of solidified stuff were investigated. The optimal conditions for the solidification are stepped heating mode, 3:7 ratio of MSulfur to MVKS, particle size less than 150µm and 3/17 ratio of A/F. Under the above optimal conditions, the compressive strength of solidified stuff rises to 35 MPa, and water absorption is down to 4%-6%.Furthermore, when NaOH is applied as an additive in the process of solidification, the 2+concentrations of most heavy metals except Pb have reached the national leaching toxicity standard. The results of X-ray diffraction reveal that sulfured solidification is caused by the physical encapsulation rather than chemical transformation.

Jan 1, 2010

By Carl W. Lam

The increased obsolescence rate of electronic products has made it evermore pertinent to understand the potential environmental impact of materials choices to help guide electronic waste (e-waste) management and promote awareness of high burden materials. Methods for screening for the performance of materials and their potential burden on human health and the environment can be used to comparatively select constituents of present and prospective electronic products. These methods should be able to yield more robust information when linked to other decision-making strategies where integrated data on consumer preferences, production quantities, and regulatory initiatives are sparse or unavailable. A framework is presented here for generating metrics of ecological toxicity, human health toxicity (cancer and non-cancer categories) and global resource consumption for evaluating environmental impact of materials (specifically metals) in electronic products. The time-dependent impact trends of United States? printed wiring board (PWB) metals usage, principally derive

Jan 1, 2010

By Dirk van Zyl

As part of the North American regional activities during the Mining, Minerals and Sustainable Development Project (MMSD) one project focused on the development of sustainability evaluations at the operations level. Engagement was identified as one of the seven important questions to be addressed. Engineers and scientists employed in the mining, minerals and materials production arenas must understand the importance of stakeholder engagement, both within and outside the operations as it is essential in the ongoing activities required to contribute to sustainable development. After developing the awareness that a social license can only be contemplated if engagement is in place, they also have to develop skills in engagement processes. This presentation will present the business case for engagement as well as an approach to motivate undergraduate mining engineers to embrace it. The presentation will also review some recent and ongoing research to improve the engagement process.

Jan 1, 2010

By A. J. Rigby

Refractory linings in converters or anode furnaces used to over-oxidize the blister copper will suffer rapid deterioration, due to prolonged contact with copper oxide-rich slag. Nitrogen stirring with COP KIN porous plugs and use of SEMTECH OPC in converters and anode refining vessels can considerably reduce both refractory wear and processing times. In addition, careful control of the vessel atmosphere and the use of real-time optical process control minimize both slag volume and contact time with the vessel refractory.

Jan 1, 2005

By Zeljka Pokrajcic

Crushing and grinding, or comminution, circuits are the most energy intensive process of a mineral processing plant. Comminution involves the physical size reduction of an orebody to a particle size sufficient for recovery of the mineral values. However, the comminution process remains inherently inefficient. The inefficiency is a result of the operating nature of comminution devices such as grinding mills, where transfer of energy between grinding media and particles in unconstrained and completely random. New comminution circuit design strategies are presented in this paper. The aim of the new strategies is to improve the overall efficiency of the comminution process and reduce the total energy consumption of a comminution circuit. The energy efficient strategies include the: ? rejection of coarse size liberated gangue from the comminution circuit and further downstream size reduction ? use of more efficient grinding and crushing equipment ? the selection of coarser particle product sizes to alleviate the increased energy intensity required to achieve finer product sizes Singularly and when combined, these energy efficient strategies can significantly decrease the overall energy consumption of a comminution circuit. This paper also explores the financial impact of certain energy efficient strategies using an analysis tool called EcoNomics?. It shows that substantial financial gains can be made by including more efficient technologies and methods in comminution circuit design.

Jan 1, 2010

The purpose of this study was to investigate the immobilization as a host for metallic pollutants (Cr, Cu, Pb, and Zn) by ettringite phase. Ettringite phase is produced through hydration reaction of calcium aluminate with gypsum. From the XRD patterns, it is known that the distance between spaces in 010 planes in ettringite crystal increase with an increase of ionic radius of heavy metal except Pb; no big difference is shown. For this reason, the d-value of 010 planes in ettringite crystal increased with the substitution of Cr, Cu and Zn having a big Al ironic radius. But in case of Pb, because the substitution occurred at calcium site, it does not influence to increase d-value of 010 planes.

Jan 1, 2006

By Gabrielle Gaustad

For aluminum, substitution of primary with secondary resources decreases energy consumption; this energy advantage creates a strong economic incentive to recycle. Several authors have raised concerns that the current sinks for secondary materials may soon be saturated, impeding subsequent expansion of recycling. This work combines dynamic material flow analysis with optimal batch planning models to quantify the significance and drivers of these pending limits under several scenarios, and thereby explore potential opportunities to increase recycling. An aluminum recycling system case was developed that includes containers and packaging, automotive, and construction products and scraps. The impacts on aggregate scrap utilization and materials cost are explored in the context of changing alloy demand and lifetime. Insights drawn from this specific case study could be applied to multi-stakeholder, systemic models.

Jan 1, 2010

By Theo Lehner

Turning matte into anodes continues to be an area to watch: for visitors to see pyrometallurgy in action; for metallurgists to keep up with modern smelting furnaces and ever increasing production rates; for management to remain profitable using more tools than taught in school; and for environmentalists to detect the last small clouds from the ever cleaner smelter. Current converting practices have been screened and analyzed, and today, converting and casting is a modern industry. An impressive, though typical learning curve of converter productivity may be detected. Local conditions such as availability and type of raw materials, products extracted, cost factors, etc., have stimulated the development of add-ons or even alternatives to the still dominant method of converting by Peirce-Smith technology. Turning blister copper into anodes follows a similar path, namely increased productivity and improved quality. We dare to predict that development will continue.

Jan 1, 2005

By Yunnen Chen

In the present study, waste materials like pine sawdust and spent grains were investigated to assess their potential for removal of cobalt ion from water by the process of biosorption. The effects of solution pH, reaction time and initial concentration were studied in batch experiments. The removal efficiency of Co(? ) by spent grains was higher than that of pine sawdust. The initial removal was rapid and equilibrium was established in less than 90 min. Equilibrium data all agreed well with both Langmuir and Freundlich isotherm models for the two metal-biomass sorption processes. Good correlation coefficients were obtained for the pseudo second-order kinetic model. Pine sawdust and spent grains were shown to be promising biosorbents for Co(? ) removal from aqueous solutions.

Jan 1, 2010

By Hong Yong Sohn

Keywords: Barium sulfate, Barium sulfide, Environment, Kinetics, Pollutants, Sulfur dioxide conversion, Thermodynamics Nonferrous smelters and coal gasification processes generate sulfur dioxide streams, most of which are treated to produce sulfuric acid with the accompanying problems of market shortage and transportation difficulties. While the conversion of sulfur dioxide to elemental sulfur has many environmental advantages, no processes exist that are environmentally acceptable and economically viable. A method for converting sulfur dioxide to elemental sulfur by a cyclic process involving calcium or barium sulfide and calcium or barium sulfate without generating solid wastes has been developed. In this process, the sulfate, as the starting raw material, is reduced by a suitable reducing agent such as hydrogen to produce the sulfide, which is used to reduce sulfur dioxide producing elemental sulfur vapor and regenerating the sulfate. The latter is then reduced to reproduce the sulfide. This paper describes work on the BaS/BaSO4 system. Thermodynamic analysis and experimental results indicated that the BaS-SO2 reaction produces mainly sulfur vapor and solid barium sulfate and that the gaseous product from the BaSO4-H2 reaction is mainly water vapor. The rates of the two reactions are reasonably rapid in the temperature range 700-1050°C.

Jan 1, 2005

By Emmanuel N. Zevgolis Ismene-Polyxeni Kostika

Keywords: reduction, kinetics, laterites, rotary kiln, dust In this work, the reduction kinetics of dust from nickeliferous Greek laterites is investigated. The dust is a by-product from laterite treatment in rotary kilns and it comes from washing towers, electrostatic filters and polycyclones. Laboratory made pellets from this dust were also examined. Reducibility was studied in the temperature range of 700°C to 850°C in a laboratory tube furnace. Kinetic analysis of the results showed that at lower temperature values the mixed kinetic model verifies the experimental results of dust and pellet samples. At higher temperatures (800° and 850°C) diffusion becomes the rate controlling mechanism. The calculated activation energy values verify also the above mentioned results.

Jan 1, 2005

By Christophe Thiébaut

Keywords: Pyrochemistry, Salts Treatment, Distillation The pyrochemical purification of metal generates spent salts. When this metal is an actinide such as plutonium, the slags cannot be discarded and are thus disposed in nuclear facility. In order to handle with these slags, the decision has been taken to reduce stored quantities. The development of a pyrochemical treatment is in progress in the CEA Valduc centre. The feed salt, typically composed of various Pu and Am species contained into monovalent or divalent chloride matrix, is first oxidized to convert the actinides into oxides. Then the chlorides are separated from the actinide oxides by vacuum distillation. Temperatures higher than 750°C for monochloride salts mixture NaCl/KCl and higher than 1100°C for divalent CaCl2 base salts, are required to produce an industrial flow of vaporization. Inactive qualification of the process for NaCl/KCl base salt has been carried out with lanthanide surrogates. Then, a pilot equipment, called distillator has been designed and built for production-scale distillation of NaCl/KCl and CaCl2 oxidized plutonium salts. Industrial flows of vaporization have been obtained with this pilot equipment : about 4 g/cm²/h for NaCl/KCl at 800?900°C and 1 Pa, and more than 1,5 g/cm²/h for CaCl2 base salts between 1000?1200°C at 0.1 Pa. The last step, now in progress, is the integration of the distillator into a glove box.

Jan 1, 2005

By Haotian Xue

A new process to extracted antimony directly from stibnite concentrate by reductive sulfur-fixation smelting in sodium molten salt has been presented. The influences of sodium salt content and composition, ferric oxide addition, temperature and time was investigated, respectively. The optimum conditions was determined as follows: W????: ??concentrate=40%, W??alt: ????concentrate =88.75%, WFe2O3 :Wconcentrate =55.13%, W??aCl: ????alt=40%, 1123K, 1h. Under above-mentioned optimum conditions, the average direct recovery ratio of antimony can reach 91.48%, and the main chemical composition of obtained crude antimony is Sb 94.31%, Fe 4.436%, Pb 0.502%, Au 0.0236%. In comparison to traditional antimony pyrometallurgical process, the smelting temperature of present process is reduced from 1423~1473K to 1123~1173K. During the smelting operation, SO2 emision can be avoided completely due to sulfur-fixation as FeS. Furthermore , S0 can be obtained when the molten slag is handled by water leaching with conditions of 323K, L/S=5/1, 2h.

Jan 1, 2014

By Hans Korfmacher

Product take-back regulations implemented in Europe have presented significant challenges to the consumer electronic product and battery industries. Initially companies established single compliance organizations within individual Member States. These programs met business needs but were inefficient and costly. They were protected from pressures of marketplace competition and could not leverage economies of scale. In order to address these problems P&G, Hewlett Packard, Sony and Electrolux conceived a pan-European compliance organization to collect waste electronic equipment Europe-wide. This organization, called the European Recycling Platform (ERP), operates in competition with existing national compliance systems. Since 2005 ERP has collected 800,000+ tons of waste electronic products and delivered millions of dollars in cost savings. This presentation reviews the steps needed to establish successful competitive collection organizations that provide sustainable recycling at the lowest cost.

Jan 1, 2010

By C. M. F. Vieira

In the county of Campos dos Goytacazes, north of the State of Rio de Janeiro, Brazil, there is a large production of red ceramic, mainly perforated bricks. A percentage of these bricks are damaged during the firing processing and become a red ceramic waste. This work investigates a possible solution to this environmental problem through the mixture of fired brick wastes, up to 20 wt.%, with clay bodies to produce red ceramics. Cylindrical pressed bodies were fired at temperatures varying from 500 to 1100ºC. After firing, samples were then tested for linear shrinkage, water absorption and mechanical strength. The results showed that brick waste addition did not changed the workability of the clay and that up to 5 wt.% of waste no detrimental effect occurred on the fired properties at all temperatures.

Jan 1, 2010

By Seong- Rin Lim

Light-emitting diodes (LEDs) are regarded as environmentally friendly light sources due to their high energy efficiency and lack of mercury content. LEDs are used for a variety of domestic and commercial lighting systems, where they are replacing incandescent and fluorescent lamps at a rapid rate. Incandescent lamps inefficiently consume energy because electricity is mostly converted to heat rather than light. This causes unnecessary environmental impacts and energy consumption associated with power generation and transmission from a life cycle perspective. Although fluorescent lamps are more energy-efficient than incandescent lamps, their disposal at end-of-life presents special challenges because of the presence of toxic mercury. Despite the seemingly apparent advantages of LED, very few studies have rigorously addressed potential environmental consequences of their disposal. Specifically, LEDs are designed with III-V semiconductors that presumably consist of toxic and rare materials, including arsenic, gallium, and indium. We hypothesize that, depending on their concentrations and leachability, these constituents may also contribute to render LEDs as hazardous waste at the end of their useful life.

Jan 1, 2010

By Elaine Araújo

Since the ancient times, clays were used as decolorant material for various types of oils. These clays were called ?decolorant clay?. They have the property to decolor dye materials present in mineral oils, plants and animals. Biofuel is a fuel derived from biomass of live organisms. As biodiesel is produced from renewable sources, the generation of employment due to industrial scale production may cause a reduction in the dependence on foreign diesel importing, as well as the reduction of air pollution by the addition of biodiesel to diesel. This study aimed to develop a technological process to decolor post- consumption oil to be applied as biofuel. The results were characterized by techniques of XRD (X-ray diffraction), X-ray fluorescence and FTIR (Fourier Transform Infrared). It was observed that the post-consumption oils presented a higher decoloration result after treatment with the Brazilian clay.

Jan 1, 2009