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By J. H. E. Jeffes, K. T. Jacob

The activity coefficients of oxygen in liquid Pb-Sn alloys have been measured between 550 and 1100°C by use of solid oxide galvanic cells: Pt, Ni-NiO | Zr02 Solid electrolyte | O (Pb + Sn), Cermet, Pt; and Pt, Fe-FeO | Zr02 Solid electrolyte | 0(Pb + Sn), Cermet, Pt. Alcock and Richardson's quasi-chemical equation, with the coordination number of atoms set to 2, is found to predict successfully the activity coefficients of oxygen in these alloys. The relative partial molar enthalpy and entropy of oxygen at 1 atom per cent in the alloys have been calculated from the variation of the activity coefficient with temperature. The addition of Sn to an unsaturated solution of O in Pb is shown to decrease significantly both the partial molar enthalpy and entropy of O. As the measurements were restricted to a narrow range between 750 and 1100°C in Pb-rich alloys, however, the pronounced variation of the partial molar enthalpy of O with temperature at constant alloy composition predicted by the quasi-chemical model could not be verified.

Dec 1, 1971

By N T. Byrom

This paper is essentially in two parts. It describes how risk assessment fits into the overall framework of the activities required to control risk effectively within an occupational health and safety (OH&S) management system. It then goes on to describe the assessment of an OH&S system by the process of auditing.

Jan 7, 1996

By R. Patel, J. Ephraim

The production of titanium dioxide (TiO2) from its minerals such as ilmenite is challenging, and subsequent isolation of titanium from TiO2 is even more difficult because of the metal-oxygen bond strength. Currently, titanium sponge is mainly produced via the Kroll process, which is energy intensive and generates large quantities of waste. A number of international research groups have come up with technologies for the production of titanium metal. However, none of them have been commercialised, because of engineering or economic issues. The team at Bradford have confirmed that ultra-pure titanium powders can be separated from TiO2 powder through metallothermic reduction and are working to scale up the process.

May 1, 2015

By L. R. Chimimba

"The Trojan nickel deposit occurs within a pile of ultramafic lavas subjected to a lower amphibolite grade of metamorphism. The lavas form part of the Upper Greenstones (Bulawayan Group) of the Mazoe greenstone belt. The nickel mineralization occurs as disseminated, massive and near-massive sulphides. The massive and near-massive ore occurs along the basal contact of the serpentinite units and is overlain by the more abundant disseminated ore, which occurs within the serpentinite. The main sulphide minerals are pyrrhotite. pentlandite and chalcopvrite. Minor amounts of millerite and pvrite are present. The Ni : Cu ratio in all three types of ore averages 15:1.The intercumulus nature of sulphides in the near-massive ore and similar textures occasionally seen in the disseminated ore indicates a magmatic origin of the mineralization. The basal position of the near-massive and massive ore suggests that the sul­ phides settled out under gravity during the emplacement and crystallization of a peridotitic magma. The deposit has been deformed and some of the primary massive ore has been remobilized into veins and breccias. The disseminated mineralization now occurs mainly as blebs of sulphides intergrown with silicate minerals or as stringers of sulphides between foliation planes in the serpentinite."

Jan 1, 1984

By R. W. Ruddle

The advent of new methods of roasting, “flash roasting and fluidisation”, which are now under development, combined with the use of oxygen-enriched air, may markedly increase the SO2 content of roaster smokes. Skogmo suggests that the production of smokes containing as much as 50 per cent SO2 should be feasible. The use of flash smelting processes may well enable a similar increase in the SO2 content of smelter smokes to be made. In this event the recovery of sulphur would be greatly cheapened and the process might well be much more economic, even if allowance is made for the cost of generating the oxygen

Jan 1, 1953

Discussions of the papers with a written contribution on Paper No. 11 and authors' written replies. Also brief obituary of Dr. T. David Jones on p146.

Jan 1, 1947

By A. C. Dunham, Y. D. Drakapoulos, P. W. Scott

The Pt and Pd occur alloyed with copper in small, irregularly-shaped grains, 0.25-5.0 micrometers in maximum dimensions. Grains of unalloyed native copper are also present. The grains are completely surrounded by or marginal to magnetite with inclusions of Ni-Fe-Co sulphides and native Ni-Fe, which is apparently a product of the serpentinisation process. Crystallisation of the Pt-Pd-enriched copper probably occurred at the same time, at low temperature, but the previous form of the Pt and Pd is unknown as no earlier PGE phases have been found. While Pt and Pd minerals are usually important in early-magmatic base-metal sulphides, Pt alloyed with Cu is extremely rare and apparently occurs only very late in the paragenetic sequence. A Cu alloy with Pd dominant over Pt and only minor amounts of other elements appears not to have been reported

Jun 14, 1905

By A. Paulin, A. W. D. Hills

The work has shown that packed-bed behaviour can be predicted from the results of single-particle experiments, total reaction times being predicted somewhat more accurately than gas and solid temperatures and gas compositions. A small laboratory packed-bed reactor was built and used to study the decomposition of beds of specially prepared CaCO3 spheres, steps being taken to minimise the effects exerted by the walls of the bed on processes occurring within the bed. Gas and solid temperatures and gas compositions were measured at various points in the bed and compared with theoretical predictions based on kinetic data determined in previous single-particle experiments. The measured solid temperatures and total reaction times agreed remarkably well with the values predicted theoretically. Gas and solid temperatures measured after the reaction had finished at any point in the bed did not agree with the theory. This was because solid temperatures in the bed rose very rapidly once the reaction was completed and the walls of the bed could not be heated at a sufficient rate for their temperatures to rise as rapidly; thus some loss of heat from the bed to the walls was inevitable, and this could not be accounted for in the theory. In addition, the theory did not allow for the conduction of heat within the bed, and this resulted in some further slight discrepancy between the measured and predicted values, particularly after the reaction was completed. Gas compositions measured in the bed were rather scattered, but, even so, they agreed moderately well with the predictions of the theory.

Dec 1, 1971

By J. P. Ress

In 1903, seventeen years after mining of the Witwatersrand gold-bearing reefs started, the findings erf the Miners' Phthisis Commission (Transvaal) resulted in the initiation of measures with the object of controlling dust production. The substance of these measures was as follows: Removal of persons from places where they would be exposed to blasting fumes; use of water to suppress dust made in drilling and in other operations; supply and control of air to working-places; filtration of dusty air; and determination of the amount of the dust in the air. Broadly speaking, progress in dust control has followed these four lines with increasing success as the nature of the problem has become better known. Complete success has not, however, been achieved, partly because increasing mechanization of mining has intensified the problem and partly because the application of these measures is not infallible, being subject, in many cases, to human control. A brief summary of the development of these measures will lead to a description of present-day practice.

Jan 1, 1947

By V. E. Ross

A comparison was made of three methods for determining the contributions of true flotation and entrainment during batch flotation tests. In the first method size-by-size recoveries are measured in both the presence and the absence of a collector, a frother being present in both tests. In the second method the mass of solids and water recovered after a chosen time of flotation is varied by changing the rate of froth removal and the depth of the froth. The third method uses a transfer factor to describe the classification of solids and water, and hence the changes in the composition of the pulp, during a single flotation test. Batch flotation tests were carried out with artificial mixtures of pyrite and gangue, the amount of floated material recovered being calculated according to each of the three methods. The discrepancies betweeen the calculated amounts are analysed in terms of the assumptions that are made for the various methods and the most suitable conditions for the application of each method are identified

Dec 1, 1991

By A. G. Waters, N. J. Bristow

A comparative study was made of an untreated and a heated haematite ore and a sinter produced from a feed consisting of 100% ore, to study the influence on reduction behaviour of sinter bonding phases such as SFCA (silico-ferrite of calcium and alumina). Under low-temperature reduction conditions the order of increasing reducibility followed that of increasing porosity and surface area but under similar conditions at 900 degrees C the sinter exhibited higher reducibility than the ores even though the total porosity and chemical reducibility of the individual phases were lower. This behaviour can be explained in terms of the higher total porosity of the natural ore at low temperatures and the higher level of fine pores in the sinter at high temperatures due to the presence of SFCA, which acts to support the fine (c.0.1 micrometre) pores created by the reduction process. This leads to the conclusion that the main role of SFCA in sinter during high-temperature reduction is to maintain a high level of fine porosity. Some implications of this work for granule design and sintering practice are discussed

Apr 1, 1991

By Dobson C. L.

The memoir, presented at the North of England Institute of Mining and Mechanical Engineers' general meeting held in Newcastle-upon-Tyne on 3rd June 1916, outlines the career of one of the Institute's oldest members and past-president 1896-1898, including the improvements he introduced at Harton, St. Hilda and Boldon collieries and his activities with the Institute and the Durham Coal Owners' Association

Dec 1, 1916

By D. J. Buchanan

British Coal's mining research programme is directed towards the strategic objectives of reducing production costs, improving product quality and resolving health, safety and environmental issues. The strategy for R&D is described and selected parts of the programme are reviewed. Two major initiatives are directed towards reducing production costs: geotechnics and automation. Integrated exploration techniques are used to delineate geological structures as an aid to mine planning. Rockbolting is being rapidly introduced and the in situ stress field has been found to be of significant influence. Automation is the subject of a major programme. A strategy for coal quality has been devised. The health, safety and environmental programme concentrates on the traditional hazards together with surface environmental problems.

Jan 12, 1992

By A. H. G. Mitchell

Gold-poor and gold-rich porphyry and epithermal gold-silver deposits of Caenozoic and Cretaceous age in the western Pacific and central and eastern Europe are confined to predominantly andesitic continental margins and island arcs. The arc volcanic rocks overlie a complex non-oceanic basement of stacked nappes, the uppermost of which is often ophiolitic. The emplacement of ophiolite triggered a reversal of tectonic polarity, subduction and arc magmatism. Andesitic volcanism and the formation of a strato-volcano were followed by the ascent of magma and porphyry copper mineralisation. Regional propylitic alteration came from convecting, predominantly meteoric fluids. Magmatic degassing caused advanced argillic alteration. This is commonly unmineralised in perched water tables, but may sometimes host high sulphidation gold or enargite gold at deeper levels within the propylitic zone. The onset of extensional stress after the andesitic volcanism allowed meteoric water to circulate to depths of 5 km or more, with consequent cooling of an ascending magma body at depth and the development of low sulphidation epithermal gold mineralisation near and immediately above the sub-volcanic basement surface. All andesitic arcs are mineralised. Regional controls on their ore potential include the level of erosion and geological features in the basement that focus the ascent of fluids. Differences between the mineralisation of the European and the western Pacific arcs may reflect the presence of older, more granitic basements in many of the European arcs.

Jan 12, 1992

By A. Policard

The bodies of mammals possess a very efficient mechanism for ridding themselves of inhaled dust. When the lung is healthy this mechanism works very well, and dust is quickly and completely expelled from the lung either by the respiratory tract or the lymphatics. The mechanism, however, is easily upset, and slight alterations in the condition of the ciliated epithelium or the circulation of lymph are sufficient to interfere with it, therefore the second mechanism comes into play and the dust is fixed and immobilized in some part of the lung. This, however, is not a real cleansing process, since the lung becomes a dust-trap, and may become'pneumokoniotic. The mechanism is protective at first, but later, when the accumulation of dust is considerable, it gives rise to trouble. The lung cannot become, so to speak, a physiological dust-trap, and still retain its normal structure and function; pneumokoniosis begins, which is essentially a disease due to the mechanical presence of large amounts of inert foreign material.

Jan 1, 1947

By L. J. Barnes, R. O. Koch, J. H. Versteegh, P. J. H. Scheeren, F. J. Janssen

Following two years of laboratory research with bench scale reactors, a 9 m3 experimental process demonstration reactor was installed at Budelco's zinc refinery to treat their underlying groundwater. A 600-fold scale-up was successfully achieved. It has demonstrated that this anaerobic microbial process can remove a wide range of heavy metals and sulphate to the required levels. Extended operation of the demonstration unit has shown that the process is robust, can withstand wide variations in feed composition, rapidly recovers from operational upsets and is easy to start up and shut down. The metal sludge produced can be processed in a metal refinery to recover both metals and sulphur.

Jan 12, 1992

By R. Trueman, D. B. Tyler

Numerical modelling was used to determine the magnitude and direction of stresses around drives both adjacent to and distant from open stopes in the South Crofty tin mine. Modelling predicted that drives near the stopes are situated in a stress-relaxed zone. The peripheries of drives that are sited in solid rock away from the influence of stoping are in compression. Key-block modelling was used to determine the typical geometries of critical blocks and distinct element modelling was used to determine block stability. The conclusions derived from modelling fitted the observational data. This indicated that key-block theory is a valid tool for analysing the stability of roadways in the South Crofty mine. The support requirements for drives located next to stoped-out areas were formulated using a risk analysis approach to key-block formation. The results were compared with support guidelines derived using empirical design methods. Good agreement was obtained for the roofs of the drives but not for the sidewalls. The concept of a critical excavation width was formulated: once an excavation is larger than the critical size the length of rockbolts need not be increased as the excavtion dimensions increase. This may be the case in all rock mases.

Jan 4, 1993

By A. D. Read

Selective flocculation was investigated as a possible method of recovering values from mineral slimes which are too finely divided to be treated by conventional mineral processing methods. It has proved possible to flocculate selectively either haematite or a silicate from a stably dispersed mixture by varying the anionic character of the high-molecular-weight, partially hydrolysed polyacrylamide employed. Different separation methods have been developed for hard and soft water media. Electrokinetic and infrared techniques have been employed to elucidate the mechanism whereby selectivity has been attained in the different cases. The following influences on the various selective flocculation parameters have been investigated: (a) the level of the different reagent additions and (b) the shear conditions during and after flocculant addition. A feature of the particular system studied was the high solids content at which it was possible to achieve good selectivity. Probable reasons for this are advanced, and the possibilities and potentialities of the process are discussed.

Dec 1, 1971

By Hickling G.

Discussion at the Manchester Geological and Mining Society's general meeting held in Manchester, February 8th 1916, with Mr. Leonard R. Fletcher, President, in the chair, of papers previously published in Trans. Inst. Min. Engrs.,1915, vol. L, p.322 and p.328. Included are a written contribution by Ollerenshaw W. and oral discussion by the author, Gerrard J., Paton J.D., Smith S.A., Stephenson H., Dixon H.O., Pickup W., Fletcher L.R. and Atherton H.S.

Dec 1, 1916

By D. F. Ball, P. R. Dawson, J. T. Fitton

Report of discussion at December, 1970, IMM general meeting (Chairman: M. J. Cahalan, President) and contributed remarks on the paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, September, 1970, pp. C189-96, plus the authors' replies. Contributors included Cohen E., Hope B., Wasse D.G., Shakespeare A.G., Burwood D.S., Jones H.A., Dartnell J., Carter G.C., Henderson T.A., Relf G. and Clark S.W.

Dec 1, 1971