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By Jon Errey, Aleksandar Petrovic, Karl Haase

"Developing a gold deposit of this magnitude in the Amazonian jungle of Guyana posed many challenges. This paper describes not only the process & logistical challenges arising from the remote mine site location in a tropical environment with a local industry unaccustomed to recent large scale gold mining operations, but also the innovative technical solutions employed to address the unique ore body characteristics. The best examples of this approach were dealing with the initial high clay content saprolite ore from the development phase and primary mining pits whilst ensuring that the design also implemented the right method to deal with the future fresh rock in an environmentally sensitive habitat. In order to do this separate individual crushing flowsheets were generated, focusing on the specific material handling equipment that would be suitable to handle these various types of material and ensure high recoveries were maintained.INTRODUCTIONAurora gold mine is located in forested region of Guyana, 170 km west of capital Georgetown, and 130 km West North-West of Bartica, a settlement at the junction of the Essequibo and Cuyuni Rivers.The Aurora gold project (Aurora) is a 5,000 tonne per day open-pit/underground operation, which will produce a total of 3.29 million oz. gold – averaging 194,000 oz. per year – over an initial 17 year mine life. At the final investment decision in 2014 Aurora had a total resource of 6.54 million ounces in the measured and indicated categories (62.83 million tonnes at 3.24 g/t Au) as well as additional 1.82 million ounces in the inferred category (16.93 million tonnes at 3.34 g/t Au)."

Jan 1, 2016

By H. Y. Sun, Q. Y. Tan, X. P. Niu, L. Li, Y. Jia, R. M. Ruan

During bioleaching processes of sulfide minerals, the sulfide minerals act as the natural habitats for acidophiles, of which, most are autotrophic iron and sulfur oxidizing microbes. These microbes acquire energy by oxidation of sulfide minerals, and play crucial role in bioleaching processes. In the industrial bioleaching heaps, microbial community and their activity are highly related to engineering configurations, while the optimized industrial operation can help to fast dissolution of aim minerals and acid/iron balance under optimized microbial condition. Microbial community succession and activity formation, the function of microbes to mineral dissolution, the mechanisms to promotion and inhibition of sulfide minerals oxidation, and the industrial instances for microbial community regulation were reviewed. For these instances, promoted microbial activity helped to fast pyrite oxidation for sulfuric acid generation, which realized zero sulfur acid addition to the irrigation solution in the initiation of a bioleaching heaps. High microbial activity by optimized operation parameters improved Cu leaching efficiency during the heap bioleaching process. And also by inhibition of microbial activity, especially the iron oxidizing microbes, the excessive pyrite oxidation can be inhibited, which helped to the acid/iron balance during heap bioleaching. INTRODUCTION Around the world, high grade copper ore are exploited, while barely new high-grade deposits are succeeded, the copper grade of ore deposit is constantly decreasing. The increasing copper demands worldwide requests to process these low-grade ore deposits. Processing of low-grade ores are not economical by usual extraction processes. Heap leaching is a cheaper process for recovery of low-grade ores, and has been applied to extract valuable metals from sulfide minerals worldwide, such as copper, gold, uranium and nickel (Gericke et al., 2009). Heap leaching process has greatly decreased the economic grade and expanded the recoverable ore reserve worldwide (Brierley, 2008). It is usually carried out in the open environments, and could process huge amount of ore (usually in millions of tonnes in one reactor) in the heap reactor (Gericke et al., 2009). For copper sulfide, especially the secondary copper sulfides, heap (dump) bioleaching is successfully applied. Heap bioleaching process is cost saving, and sometimes can be achieved without adding chemical into heaps, by microbial fixing of the atmospheric N2 and CO2, and generating oxidant Fe3+ and sulfuric acid in heaps from oxidation of sulfide minerals. Also heap bioleaching is environment friendly by cycling use of the leaching solution, and without exhaust emission.

Jan 1, 2019

By S. Manning, W. Morris

Mineral exploration assessment file information has long been considered a useful resource for developing mineral exploration strategies, and one of the most common data sets fled in assessment reports is ground magnetic surveys. The new Earth Resources and Land Information System database (ERLIS) now provides a method for rapidly accessing all references to a specific area through a series of raster images. The ERLIS provides access to the Assessment File Research Imaging (AFRI) database which comprises geo-science mineral exploration assessment file data, Mineral Deposits Inventory (MDI), together with provincial aeromagnetic data from the Ontario Ministry of Northern Development and Mines(MNDM). Conversion of the raster images of ground geophysical data to vector data files together with the concatenation of grids from adjacent claims provides a method for constructing high resolution magnetic regional images. The value of this resource is demonstrated through the construction of a single composite magnetic image derived from eight assessment file grids for an area south of Kirkland Lake, Ontario, within Pacaud and Catharine Townships. The composite grid of magnetic data provides a map with resolution that is not achieved by currently available Ontario Geological Survey airborne data sets. Details contained within the new high resolution image, permit the differentiation of lithologies and their boundaries, fault orientations and the location of alteration zones with magnetic response.

Jan 1, 1997

By E. O. Reinbold, J. H. Johnson, D. E. Keski-Hynnila

A field laboratory for use in monitoring underground mine air quality has been developed and proven in underground service. The laboratory includes two separate monitoring systems and data analysis computer programs. One is the Mine Air Monitoring Laboratory (MAML). This is an enclosed trailer-mounted laboratory capable of monitoring CO2, CO, NO, NO2 particulate matter, S02, NH3, temperature and air velocity in the mine drift. The MAML can be up to 1000 feet away from the area being monitored. The second system is the vehicle data system, mounted on the load-haul-dump (LHD) vehicle, which monitors engine speed, engine fuel rack position, exhaust gas temperature, ambient temperature, vehicle speed, CO2 concentration near the operators' breathing zone and the mode of operation of the vehicle. The two computer data analysis programs and the two field instrument systems comprise a complete Mine Air Quality Laboratory (MAQL) for underground pollutant studies. Data from the systems have been used for studying vehicle duty cycles, ventilation systems, exhaust after-treatment devices, vehicle exhaust system design and portable instrumentation. Descriptions of the laboratory are presented along with a summary of some of the experiments performed. The capabilities of the lab are discussed, along with future potential uses.

Jan 1, 1981

By W. J. Bennett

WHEN Dr. Horace Fraser, your President, invited me to speak to you today I advised him in confidence that I was leaving my present positions on April 30th. In the circumstances it seemed to me that this audience might prefer to have as its speaker one who wo.uld J1ave a continuing association with the atomic energy programme. Dr. Fraser was kind enough to suggest that my re-marks might he of special interest to you, since I would be able to sum up my views on the atomic energy programme. I hope that I will not disappoint him or you on that score. I am particularly pleased that my last public appearance in my present positions should be at the Annual Convention of the C.I.M. since, as all of you know, a very important part of my work has been in the mining field. As it happens, my first public address on the subject of atomic energy and its raw material -uranium -was made at your Annual Convention in Montreal in April, 1949. It seems fitting that my final address should also be made at this convention -nine years later.

Jan 1, 1958

By H. R. Oliveira, C. R. Aragonez de Vasconcellos

Pipeline operation and maintenance necessarily involves geotechnical studies at points and areas with deflagrated instabilities or still to map and monitor areas prone to geotechnical problems. Landslides, erosions and debris flows are some examples of natural hazards, that not rarely, can bring high consequences to pipelines, sometimes leading them to high stresses levels and ruptures. Bolivia-Brazil Natural Gas Pipeline has 2.593 kilometers since Rio Grande City in Bolivia until Canoas City, in south Brazil. The pipeline crosses a lot of types of geological fields and difficult topography. The south spread of the pipeline has the most prone areas to geotechnical hazards because of its hard topography combined with the variety of geological materials, such as, colluvium deposits and debris flow areas. The aim of this paper is to present the right-of-way geotechnical risks that affect pipelines, presenting some practical remedial works done by TBG at Bolivia-Brazil Natural Gas Pipeline as well as the integrity plan and the adopted actions in way to prevent geotechnical accidents.

Jan 1, 2005

By Azadeh Riahi

The main goal of this paper is to investigate the effects of permeability anisotropy in Large Open Pit (LOP) mines for problems that exhibit homogeneous anisotropic characteristics. The most important effect of the groundwater flow in open pit mines is on the stability of the pit slopes. This study will investigate the effects of having increased permeability in both horizontal and vertical directions on three aspects of LOP behavior, location of phreatic surface, pore pressure distribution and stability of slopes. The hydromechanical coupling is simulated using a one-way coupling approach. The Shear Strength Reduction method (SSR) is applied to assess the stability of slopes. The studies performed in this paper suggest that anisotropy in permeability leads to a significantly different regime of pore pressure dissipation depending on two aspects, ratio of anisotropy and the relative magnitude of permeability to simulated time. As a result, variation in safety factors and the location and depth of the failure surface must be expected.

Jun 1, 2012

By Bahjat Khoshaba, Bern Klein, Haixing Yan, Libin Tong, Andrew Bamber

"When a conductive or magnetic particle was put into an electromagnetic field introduced by an electromagnetic sensor, the particle can influence the electromagnetic field which can be used to characterize this particle. The electromagnetic technology based on eddy current theory was explored to investigate its potential in both the separation of minerals and the pre-concentration of a base metal ore. Samples tested in the study included the minerals obtained from Ward’s Science and the low grade copper ore particles obtained from Mount Polley Mine. The effects of mineral type, sensor frequency, particle size, particle position on the sensor surface, and particle lift-off on the magnitude and phase of the electromagnetic spectra were investigated. The electromagnetic spectra of various minerals show that it is possible to separate chalcopyrite or magnetite from tested minerals, simply based on the magnitude of the spectra. The spectra of the ore particles were determined by the mineral in the particles with the strongest signal. The effect of the pre-concentration of the low grade copper ore is determined by the association of chalcopyrite with magnetite. Direct sorting is the mechanism in the separation of mineral particles, while indirect sorting is the mechanism for low grade ores.INTRODUCTIONSensor-based sorting technologies include radiometric, X-ray transmission, X-ray fluorescence, near infrared, photometric, inductive, microwave heating and so on. Sorting not only discards barren rocks away from the concentrator but also recovers metal bearing that would be lose to the waste dump. The benefits of pre-concentration using sensor-based sorting are achieved on reduced energy consumption for comminution and reduced water usage on a volume per weight of metal basis (Bamber, 2008; Gunson, Klein, Veiga, & Dunbar, 2012; Kleine & Wotruba, 2010; Knapp, Neubert, Schropp, & Wotruba, 2014; Kobzev, 2014; Lessard, de Bakker, & McHugh, 2014; Mazhary & Klein, 2015; Robben, Wotruba, Robben, von Ketelhodt, & Kowalzcyk, 2013). Amongst others, high frequency electromagnetic sensors were developed for ore sorting at MineSense Technologies Ltd. and are subject of this paper. Improving the understanding of ore heterogeneity is the basis for developing a successful semi-bulk or bulk sorting systems by incorporating the sensors in the material handling equipment (MineSense Technologies Ltd., 2016). The present study focuses on the bulk sorting potential and bulk sorting mechanisms of the electromagnetic technology in the pre-concentration of minerals or ores."

Jan 1, 2016

By M. Härting, D. T. Britton, M. Nzikou Mamboukou

"Copper containing different types of nanocomposites have been characterized for nanolabelling and ID. Three types of the rare earth nanoparticles were used for this study, the oxide and the sulphur compound of the Eu and Tb. Characterization techniques uses SEM, and Raman for morphology, chemical composition, and optical characterization respectively. It has been shown that it is possible to include the rare earth particle in a copper matrix without damaging its physical properties. INTRODUCTIONThe development of new materials, often involves the addition of new properties without changing the beneficial properties of the original material (Chen et al., 2009; Khana et al., 2007; Patil et al., 2008). Nanocomposites are nanostructured materials, whose structural elements including clusters, crystallites or molecules, of dimensions ranging between 1 to 100 nm (Moriarty, 2001), or a composite material where one of the phases is a one, two or three dimensionally nanostructured material (Nanotechnology, 2006; Wang, 2001). Nanocomposite materials research is a fast growing area due to the high demand for materials for specialized applications (Edelstein & Cammarata, 1998), such as biolabelling, magnetic storage media, solar energy transformation (Jisen et al., 2004), and resistance welding applications (Bessergenev et al., 1997; Kwon et al.,2006).The properties of the nanocomposite materials depend not only on the properties of their individual parent materials, but also on their morphology and the interfacial characteristics. Thus, significant efforts have been focused on the control of the nanoscale structures via innovative synthesis approaches. Therefore, novel materials of unique properties may be obtained by combining properties from the parent constituents into a single material (Balan, 2006; Garcia et al., 2009). Possible effects of nanocomposites in the original material may include changes in the mechanical properties such as hardness , wear resistance (Rafaja et al., 1987), and electrical properties (Britton et al., 2003). The inclusion process may therefore be used to tailor materials to have particular mechanical, electrical and optical properties (Das et al., 2009). However, to fully understand the nanocomposite, it is necessary to study the fundamental properties of both the host matrix and the inclusions (Li, 2008)."

Jan 1, 2012

By K. Maruyama, T. Nagasaka, R. d. Chairaksa-Fujimoto, T. Miki

Electric arc furnace dust or EAF dust is considered as a hazardous waste but contains a significant amount of economically attractive non-ferrous metals especially zinc as zinc ferrite (ZnFe2O4) and zincite (ZnO). The hydrometallurgical process is one alternative choice because it has the advantage of low energy consumption. The leaching of ZnO from the dust is very easy. However, the complex major zinc compound in EAF dust is ZnFe2O4, which is very stable and insoluble in alkaline or acidic media under delicate conditions, and causes the low zinc recovery yield by hydrometallurgical process. Moreover, halogens and heavy metals in the dust are also problematic. In order to develop a new effective EAF dust treatment process, the authors have proposed "CaO addition process" as pre-dust treatment to transform all of ZnFe2O4 in the EAF dust to ZnO and Ca2Fe2O5. In this study, the selective zinc leaching from the CaO treated EAF dust with NaOH and NH4Cl solutions was carried out. The effect of temperature, reaction time and solute concentration were systematically investigated. All of zinc in CaO treated EAF dust was successfully leached into both solutions.

Jan 1, 2014

By E. G. Leonardon

The question of geophysical prospecting is one that is beginning to occupy a pre-eminent place in the minds of those actively concerned in the discovery and exploitation of ore deposits. This is in marked contrast to the reception accorded such ideas when the Junior author, six and a half years ago, began introducing electrical prospectii1g to the mining fraternity on this continent. Happily, the mention of geophysics no longer evokes the sceptical and pitying smiles that it did in those days. A little reflection will show that modern geophysical methods are merely a logical development from pre-existing technique. In the study of geological problems, is it not logical to use all possible physical properties of matter? The study of crystal form and cleavage, the examination of thin sections of minerals by means of polarized light or ordinary light, in fact, utilize physical properties of minerals for the benefit of the geologist. These are, of course, laboratory methods, and the extension of the study of similar properties into field work was inevitable. This began with the magnetometric surveys, used as early as 1760 in New Jersey to locate iron ores. Eighty-four years later, John Locke's work in the United States resulted in pointing out relationships between the terrestrial magnetic field and main tectonic features of the earth's crust.

Jan 1, 1928

By Alan Bauer, Melvin A. Cook

Measured detonation pressures of "prills and oil" (94/6 ammonium nitrate/fuel oil) and three of the new "slurry" blasting agents are presented and compared with computed, ideal detonation pressures and with detonation pressures expected from the measured detonation velocities. Results seem to show that the peak pressure in the detonation wave in these cases is the Chapman-Jouguet pressure and that no "spike" exists in these detonation waves. The absence of the Zeldovich-von Neumann "spike" is noteworthy in view of the very long reaction zone lengths of these mixtures. The measured detonation pressure of one of the slurry blasting agents (DBA-3") under steel confinement ( 172 kilobars) is shown to be considerably greater than the ideal detonation pressure of 75 per cent gelatin dynamite (p. = 135 kilobars) despite the fact that the detonation was still somewhat non-ideal in "DBA-3," its computed ideal detonation pressure being 180 kb. The popular 94/b AN /FO blasting agent exhibited a detonation pressure of only 13.5 kb in 5" paper tubes, but 37.5 kb in 5"• steel pipe compared with a computed ideal pressure of 40 kb.

Jan 1, 1961

By R. E. Hamilton

"The requirements for effective optimization of a mineral dressing operation are discussed, with specific reference to a flotation system . Also considered are the relation-ships between automatic control and optimization pro-grams. Variables are classified into the following groups, and the significance of the classification is discussed: (a) Directly measurable (b) Directly manipulable (c) Uncontrollable (d) Calculable from measurable variables (e) Affected by changes in manipulable or uncontrol-lable variables. New sensors for measuring variables not normally measured are described."

Jan 1, 1967

By F. J. Hrach, S. A. Gasiorowski, J. D. Bittner

"Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs.. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash. TECHNOLOGY OVERVIEWThe ST separator utilizes electrical charge differences between materials produced by surface contact or triboelectric charging. When two materials are in contact, material with a higher affinity for electrons gains electrons and thus charges negative, while material with lower electron affinity charges positive. This contact exchange of charge is universally observed for all materials, at times causing electrostatic nuisances that are a problem in some industries. Electron affinity is dependent on the chemical composition of the particle surface and will result in substantial differential charging of materials in a mixture of discrete particles of different composition.In the ST separator (Figures 1 and 2), material is fed into the thin gap 0.9 – 1.5 cm (0.35 -0.6 in.) between two parallel planar electrodes. The particles are triboelectrically charged by interparticle contact. For example, in the case of coal combustion fly ash, a mixture of carbon particles and mineral particles, the positively charged carbon and the negatively charged mineral are attracted to opposite electrodes. The particles are then swept up by a continuous moving open-mesh belt and conveyed in opposite directions. The belt moves the particles adjacent to each electrode toward opposite ends of the separator. The electric field need only move the particles a tiny fraction of a centimeter to move a particle from a left-moving to a right-moving stream. The counter current flow of the separating particles and continual triboelectric charging by carbon-mineral collisions provides for a multistage separation and results in excellent purity and recovery in a single-pass unit. The high belt speed also enables very high throughputs, up to 40 tonnes per hour on a single separator. By controlling various process parameters, such as belt speed, feed point, electrode gap and feed rate, the ST process produces low carbon fly ash at carbon contents of 2 % ± 0.5% from feed fly ashes ranging in carbon from 4% to over 30%."

Jan 1, 2012

By D. M. Baird

ABSTRACT A revised stratigraphic section of Carboniferous rocks which occupy about 700 square miles in southwestern Newfoundland is presented. Gypsum, which outcrops at thirty-five different localities, is found to belong to four principal zones in the section. The newly mapped structure of the region makes the otherwise random occurrences of gypsum appear as systematic outcroppings of the four zones which follow the regional structure. Details of several occurrences are given and those most advantageous for exploitation are pointed out. INTRODUCTION ROCKS of Carboniferous age occupy an area of about 700 square miles in southwestern Newfoundland. They occur in a belt, from 5 to 15 miles wide, which extends from the head of St. Georges bay southwestward for 65 miles to the mouth of Little Codroy river (see Figure 1). Several hundred feet of Pennsylvanian rocks overlie rocks of Mississippian age, which are at least 12,000 feet thick. The rocks of the Carboniferous section of Newfoundland are very similar to those of Nova Scotia and represent a northeastward continuation of the same palaeophysiographic conditions. Mississippian measures of Windsor equivalence include thick gypsum deposits which outcrop at many places and which extend under large areas as indicated by sink-holes and by structural considerations.

Jan 1, 1951

"AbstractThe Sedimentary Basin area of Western Canada, which lies between the Precambrian Shield and the Cordilleran mountain area, covers approximately 800,000 square miles. Sediments ranging in age from Cambrian to Tertiary are present and, of these, horizons in the Upper and Lower Cretaceous, Jurassic, Mississippian, and Devonian have yielded commercial oil and gas flows. Producing horizons in the Cretaceous and Jurassic are sandstone, while all those of the Palaeozoic are carbonate rocks such as red limestone or dolomite (bioherms). Shows of oil and gas have been encountered also in the Cambrian and Triassic sediments.The broad structural features of this vast expanse of sedimentary rocks are the Moose Jaw syncline, the Sweet Grass-Battle River arch, the Alberta syncline, the Foothills belt, the Rocky and Mackenzie mountains, the Great Bear-Slave Lake basin, and the Mackenzie Delta Basin area.This contribution outlines the .stratigraphy and structure of the Basin area, and gives examples of present producing oilfield structures and stratigraphic traps.Part 1.-Regional StratigraphyIntroductionThe vast expanse of relatively undisturbed sedimentary rocks of western Canada has long been recognized as prospective territory to search for oil and/ or gas. This search in western Canada dates back before the turn of the century, but, considering the size of area to be explored and tested, the effort an<l money expended upon it, which, before the recent discovery of oil at Leduc, Alberta, appeared large and fruitless, now seems almost ridiculously small. A check-up of effort and money expended prior to and since the Leduc discovery would undoubtedly reveal that more wildcatting and development has taken place during the last two and a half years than during all previous years combined. The figures would astound not only the average citizen, but many within the industry itself."

Jan 1, 1950

By W. G. Dallas

The social and environmental problems presented by the location of a large zinc/ lead ore body within one mile of a thriving town are described. The development problems are social, involving the education of the in habitants , and environmental, requiring the development of a planning strategy and the evolution of a baseline and post -operational monitoring system. The necessity for an environmental-impact assessment and a thorough baseline study is emphasized. The continuing psycho-social consideration of community reaction is advocated.

Jan 1, 1977

By J. F. Wright

INTRODUCTION Eighteen years ago about half a dozen experienced prospectors moved from northern Ontario to northwest Manitoba to prospect &apos;greenstone&apos; areas shown on geological maps of .parts of northern Manitoba prepared by J. B. Tyrrell, D. B. Dowling, and Wm. Mclnnes. Gold-bearing quartz was soon discovered by these men in this new field, and in succeeding years many more prospectors entered the district. A number of the pioneers are still prospecting, and since 1913 mineral deposits have been discovered each year in widely separated areas of the large district extending 150 miles eastward from the 102nd meridian and 60 miles north of latitude 54°30&apos;. The majority of the discoveries, however, have been made near Schist, Elbow, Wekusko, and Kississing lakes. One hundred or more mineral occurrences of some merit are known, the main types being sulphide replacement bodies containing nickel-copper or copper-zinc and gold-bearing quartz veins. Some underground exploration or diamond drilling has been completed on 25 or more of the prospects. Up to the present, three ore-bodies, namely, Flin Flon, Sherritt-Gordon, and Mandy, have been proved. Of these, Flin Flon, the largest, is estimated to contain from 16,000,000 o 19,000,000 tons of copper-zinc ore carrying some gold, silver, and lead. Next in importance in regard to tonnage is Sherritt-Gordon, with a calculated reserve of nearly 5,250,000 tons of copper-zinc ore carrying less than $1.00 combined gold and silver.

Jan 1, 1931

By Michel Ruel

Most plants do not track how their systems perform. Optimization is the easiest way to benefit from your control systems. We suggest an approach in four phases. The first phase is to assess all equipment to determine the performances for instruments, valves, variable speed drives, and other equipment. The second phase is to remediate instrumentation problems, including the ones pertaining to valves, variable speed drives, analyzers, transmitters. When equipment is in order, loops are put back in automatic mode. If a loop oscillates, use standard default values for this type of loop. The third phase consists in validating the control strategies, properly configuring the systems (control system, programs and parameters, HMI, alarms), and then tuning the loops and control strategies. The fourth phase consists in analyzing the process and expected performances in order to optimize the control loops and control strategies. If performance is not sufficient, a decision tree will be presented to determine the right approach: advanced regulatory control, model predictive control, or fuzzy logic control. Once all steps have been completed, control performance monitoring software is used to sustain the results and pinpoint equipment or loops not performing as stated. Alarm management and rationalization could also be performed after auditing the alarm system, if needed. Examples from plants will be used to demonstrate how this step-by-step method is applied and produces results. INTRODUCTION Maximizing what you already have is the best investment to remain competitive. This article aims to show the benefits of a systematic approach using modern tools to improve plant performance. We at BBA suggest dividing the work in four phases, and a subsequent phase can begin when the previous one has progressed: Assess, Remediate, Stabilize, Optimize, or add advanced control. This approach has been successfully applied to several sites. Examples and illustrations from these plants demonstrate how this step-by-step method is applied and produces results. Under the BBA method, there are four questions to answer before proceeding to the next step. For each control strategy, you should ask the following questions: Assessment: Does it work? Remediation: Do you use it? Stabilization: Is it stable? Optimization: Does it perform? Do you need advanced control?

Jan 1, 2019

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012