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By John A. Mavrogenes

Reflected light microscopy and electron microprobe techniques were used to determine the mineralogy, phase percentages, grain sizes, and textures of Co-Ni-rich mattes. The mattes were produced by submerged bath smelting at the University of Missouri-Rolla Pyrometallurgical Center of a flotation concentrate with 4.S% Co and 5.1% Ni that was prepared at the United States Bureau of Mines Rolla Research Center by flotation up-grading of the cobalt and nickel content of a copper concentrate from the Magmont mine, Viburnum Trend, Southeast Missouri. Nine distinct phases were distinguished in the matte samples, and three of these contain cobalt and nickel. The phases that were free from cobalt and nickel are bornite, chalcocite, pyrrhotite, magnetite, metallic copper, and galena. Submerged bath smelting serves to segregate the cobalt and nickel into phases that can subsequently be recovered by flotation. These phases are: shandite (Ni3PbZSZ)' cobaltpentlandite ((Co,Ni,Fe)9SS)' and Co-bearing Fe-rich sphalerite ((Zn,Fe,Co)S). Most of the cobalt occurs in cobaltpentlandite, but some is present in sphalerite. High total air conditions during smelting favor the development and segregation of cobalt into cobaltpentlandite. Nickel occurs in cobaltpentlandite and shandite. Shandite contains lead, a deleterious constituent in the smelting of cobalt and nickel.

Jan 1, 1989

By Taner Kavas

The refractory bricks of a rotary cement furnace containing of alumina and magnesium chromite were studied in order to determine whether they could be used in the concrete production as aggregates. Three mortars were prepared by mixing 1 part cement, 3 part aggregate materials, 0.5 part water by weight and mechanical, chemical, thermomechanical and microstructural characteristics were evaluated. The compressive and bending strength of samples were determined after 2 and 28 days curing. Resistance to chemicals were established by calculating the weight gain of mortars stored in 2 % HCl solution for 1 h and 24 h. Thermomechanical characteristics were determined by measuring the compressive strength of heat treated specimens at temperatures of 400 °C, 600 °C and 800 °C. Consequently, magnesium chromite containing waste brick aggregates have given the best results.

Jan 1, 2006

By Daowu Yang, Zhuo Ren, Hui Liu

"In this paper, the photochemical catalysis degradation effect of photocatalyst obtained by charcoal-supported nano TiO2 (nano TiO2 / charcoal) on the formaldehyde in the air was studied. The influences of the nano-TiO2 loading and the photoreactor structure on the efficiency of photochemical catalysis degradation of formaldehyde was reviewed.The nano - TiO2 / bamboo charcoal adsorption of formaldehyde, as well as the influences of a certain amount of formaldehyde after adsorption on its photochemical catalysis effect were discussed. The sol preparation process of Ce-doped nano-TiO2 was described. Experimental results indicated that: the surface of bamboo Charcoal still has a strong formaldehyde adsorption capacity after Supported by Nano TiO2.After adsorbing formaldehyde, the photochemical catalysis degradation efficiency of formaldehyde of the catalyst at a steady state is basically the same with new prepared catalysts’. When the thickness of the catalyst layer of the multi-ladder-type structure photoreactor is 2mm, the interval is 20mm, the absorption efficiency of formaldehyde of Nano- TiO2 / bamboo charcoal is the best . Nano-TiO2 undoped Ce responded with no degradation of formaldehyde after 2 hours, while the degradation rate of formaldehyde of the Ce-doped nano- TiO2 reached 15% 2 hours late, and the formaldehyde decontamination of the equipment reached 94%.IntroductionEmerging out of home decoration in the distribution of formaldehyde, benzene, ammonia and other indoor pollutants have been proved to be very harmful to the human body. Photocatalysis can eliminate air pollutants, in particular, can effectively degrade the air volatile organic compounds, it is a new method of air purification developed in recent years. the biggest advantage of photochemical catalysis degradation is green, this method can be available at normal temperature and pressure to degrade formaldehyde and other organic matter into carbon dioxide and water without secondary pollution.Nano-TiO2 have become the most studied photocatalyst due to its stable, non-toxic harmless, superior photochemical catalysis properties [1]. Initially nano-TiO2 powder was used as a photocatalyst, but it’s difficult to recover and easy to wear and tear [2,3]. Later, the TiO2 was used in the form of film loaded on some carriers, such as glass beads [4]. As the photochemical catalysis reaction occurred on the catalyst surface, only the organic matter adsorbed on the catalyst surface can be degraded, so the catalyst was requested that must have a strong adsorption. Combined the adsorption properties of bamboo charcoal and the photochemical catalysis activity of nano-TiO2 together. Made the photocatalyst by loading the nano-TiO2 on bamboo charcoal to degrade organic matter in the air. Nano-TiO2 semiconductor photocatalyst has a strong catalytic oxidation due to the photo generated hole of the surface [5,6],and has a potential application. Some studies have shown that nano-TiO2 photocatalysis activity can be increased by doping certain metal ions [7,8].The aim of our work in this study was to use bamboo charcoal load Ce-doped nano-TiO2 photochemical catalysis oxidation to degrade formaldehyde,and design a multi-ladder structure photoreactor, also prove the availability of the device from the theoretical and experimental."

Jan 1, 2011

By P. F. Stratton, M Huggahalli, N Saxena

"Several studies have been carried out to determine how the optimum atmosphere conditions in the heat treatment of metals can be established for a given product by using different gas injectors and varying atmosphere flow rate and composition. The most common approach taken to gain insight into furnace atmospheres has been to use commercial computational fluid dynamics codes and examples of their use are shown. However, the complexity of these codes, the difficulty in establishing boundary conditions, their cost and computational demands limit their usability in solving day-to-day production problems.A simplified, web-based model of a furnace atmosphere is described where the conservation equations are solved to determine the composition profiles of the atmosphere in the furnace. Although the model is restricted in scope to certain types of furnace, it is shown to give better results than CFD when boundary conditions are uncertain. The application of the model to the understanding of existing furnace conditions and to determining ways of optimising the use of gases are discussed. IntroductionThe important role of protective atmospheres during heat treatment of metals, furnace brazing of assemblies and soldering of printed circuit boards is well established. The atmosphere in the furnace prevents air ingress and oxidation of the parts, helps flush away any flux or binder from braze and solder pastes and provides an important mode of heat transfer [1]. In a batch furnace having typically one or two gas injectors, the gas utilisation and process can be optimised by minimising air leaks and mantaining atmosphere homogeneity with fans or other atmosphere circulation techniques. In a continuous furnace, however, atmosphere optimisation is more difficult as furnace inlets and exits can also let in air. The atmosphere requirements of different stages of heat treatment, brazing or soldering vary [2]. Achieving these atmospheres in different sections of the open-ended furnace is a relatively complex task. Methods such as atmosphere zoning and the use of physical curtains and gas injectors have evolved with time, though it is hard to predict how effective these techniques will be for a given furnace and process. Experts in the field tend to rely on experience and rules-of-thumb rather than scientific method to achieve the required results."

Jan 1, 2001

By Nourreddine Menad

Plastic materials have been associated with electric and electronic applications since the early days of the electrical industry. Plastics can amount to 30 percents of the scrap mass. Generally, they are treated with flame retardants such as halogenated ones and they can result in different toxic chemical compounds. These plastics can be used as combustibles in the recovery of copper and precious metals. However, during their combustion, halogenated flame retardants can produce dibenzo-p-dioxins and dibenzo-furans. The estimated thermodynamic data of several organic compounds resulting from combustion of electric and electronic scrap, have been used in conjunction with the program HSC to calculate the conditions for dioxin and furan formation. The results show that the formation of the dioxins is dependent on the quantities of carbon, hydrogen, chlorine and oxygen reacting in a given system, as well as on parameters such as temperature and pressure.

Jan 1, 1998

By Dale W. Collins

The disposal of arsenic from copper operations possess various health, environmental and processing problems. There are basically two areas of concern. The first being the disposal or treatment of smelter flue dusts and the second the removal of arsenic from refinery electrolytes. A number of treatment options have been proposed including the addition of soluble arsenic wastes to copper heap and dump leaching solutions. This approach will allow arsenic to be reintroduced to the ore via Solvent Extraction (SX) raffinate associated with hydrometallurgical operations. Knowledge of the attenuation behavior and mechanism during leaching is important in determining the long term stability of arsenic and the success of this approach. Parameters, such as uptake capacity, pH, particle size and solution chemistry have been investigated. Arsenic attenuation has been examined using column leaching with experiments employing both continuous flow and pulsed additions of As(V). In the initial stages of leaching, the attenuation of arsenic appears to depend on the pH and iron concentration in the effluent. Arsenic stability in the copper oxide ore has been examined with rinses of progressively lower pH.

Jan 1, 1994

"Depletion of known ore reserves and increased demand for precious metals have caused a revolution in biohydrometallurgical processing technology for gold recovery. Known ore deposits and future discoveries are most likely to be lower grade sulfide ores that can be difficult to recover with current leaching technology. Future metal recovery operations will increasingly use bio-oxidation techniques.Bacteria are an integral part of mineral cycling and mineral transformation in nature. Although biological processes are recognized as part of the mineralization and oxidation reactions in some ore deposits, they have only recently been applied to enhancing metal recovery in hydrometallurgical procedures. This paper explores the traditional metallurgical application of biological leaching and oxidation reactions and reviews the complete range of bacteria available for metal recovery systems. Pre-treatment of ores with bacteria improves metal recoveries in tank leaching systems and shows promise for heap leaching methods.IntroductionThere is no longer any question that bacteria playa natural role in the on-going transformation of some ore deposits (1,2). As applied to sulfide ores, a few strains have been specifically identified that exhibit a natural leaching potential (3). These bacteria can be isolated from waters and soils in old mining districts where they contribute to continuing leaching and pollution problems in acid drainage and heavy metal solubilization. Sulfur and iron bacteria as well as many heterotrophic strains have also been found in ore deposits and sedimentary rocks at depths up to 2000 meters (4). Their presence in both ore deposits and processed ores shows the microbial association with natural leaching and the potential role that bacteria can play in the development of new leaching technology."

Jan 1, 1988

By Guolin Zheng, Jian Pan, Deqing Zhu, Xianlin Zhou

"In ferronickel production, nickel oxide and part of the iron oxide are reduced to metal by agglomeration and smelting in blast furnace. Due to the physical and chemical properties of the laterite ores, a large fraction of fines is generated during the pre-treatment stages and the strength of agglomeration is weakened, which results in low productivity and bad quality. In this paper, the process of pelletization of nickel laterite was developed, and some parameters to strengthen the pelletization of nickel laterite have been optimized. The results show that the compressive strength of fired nickel laterite pellet can reach over 2000 Newton per pellet while firing at the temperature of 1220 °C~1250 °C in 12 min. The product pellet can be used as high-quality burden for blast furnace to manufacture ferronickel.IntroductionIn recent years, the global stainless steel market was developed exuberantly, which greatly promoted the needs of the basic raw material of stainless steel smelting - metal nickel. Currently nickel sulfide ores are only 40% of global nickel reserves, but offer 60% of all the nickel production. However, with the deficit of resources, the nickel sulfide ore (high grade ore) is depleting, so there is an increasing focus on the utilization of low-grade nickel laterite. Recent research has focused on the wet treatment process to utilize nickel laterite, and less on the use of other technologies [1-8]. The economical and efficient technology relies on the reduction of nickel oxide and part of the iron oxide metal by agglomeration and smelting in blast furnace in China. Some domestic steel companies have adopted this process [9, 10]. Unfortunately a large fraction of fines is generated during the pre-treatment stages and the strength of agglomeration is weakened, which results in low productivity and bad quality of fired pellets. In this study, the process of pelletization of nickel laterite was developed firstly, and some parameters to strengthen the pelletization of nickel laterite have been optimized, and the product pellet can be used to produce stainless steel and ferronickel alloy by blast furnace."

Jan 1, 2011

By Bernd-Arno Behrens, Klaus-Georg Kosch

"In times of increasing energy costs automotive lightweight construction is gaining in importance. This paper deals with the production of hybrid steel-aluminum compounds by forging. The compound forging process is a promising method to successfully manufacture functional parts by applying resource-saving process steps. Nevertheless, challenges resulting from different material properties must be solved.The heating of hybrid material work pieces made of steel and aluminum is a great challenge. Steel is forged at a temperature of at least TSt =900 °C, while aluminum should not exceed a temperature of TA1= 500 °C. For achieving the required temperature gradient extensive experimental investigations have been carried out. Intermetallic phases form during the manufacturing process and can influence the bonding and the global part quality. In addition, methods for the characterization of the joining zone between the materials steel and aluminum are analyzed and the factors influencing the formation of intermetallic phases are determined experimentally.IntroductionIn times of increasing energy costs and stricter conditions relating to environmental protection, automotive lightweight construction is gaining in importance. The production of hybrid compounds by forging is a promising method to manufacture functional parts by applying resource-saving process steps. In compound forging a hybrid raw part consisting of a solid core, which is enclosed by a hollow casing, is joint in the forming process. This results in a graded material structure in the part in which the mechanical properties can be specifically adapted to the requirements. Compound forging is the form joining and/or firmly bonded joining of at least two different materials while plastic shape forming occurs (Figure 1)."

Jan 1, 2012

By A. K. Kyllo, N. B. Gray, B. N. McCurry

"Dynamic control of the formation of a solidified layer between a pipe wall and a flowing melt enables the flow rate to be adjusted in real time. This solidified layer can be generated by using a coolant on the outside of the pipe wall to remove the required heat. The coolant, and hence the solidified layer, can be controlled remotely. The dynamic behaviour of the solidified layer was investigated by both physical experiments and mathematical modelling. The mathematical model has been developed using a finite difference technique to describe conduction through the pipe wall and solidified layer. Results from the model were consistent with previous steadystate experimental results using molten lead. Experiments are currently being carried out using molten tin in a recirculating circuit with a cooling system that is instrumented for accurate computer control to validate the model. The circuit is designed for flowrates of up to 24 kg/s (86 tph) of molten tin. Steady-state and dynamic predictions were made for the current rig.Industrial SignificanceThe current method of choice for tapping slags, metals and mattes from many metallurgical furnaces is using an oxygen lance to open the taphole and using a clay plug to close it. There are, however, some significant drawbacks in this method. The heat generated by the oxygen lance erodes the refractory lining of the taphole, as well as the clay plug, and the furnace products themselves corrode the taphole. Using an oxygen lance is also a significant safety hazard to the operators as they must work in close proximity to the furnace and be subjected to a shower of sparks while opening the taphole. Also, the flowrate of material through the taphole cannot be controlled online as the diameter of the opening cannot be varied easily. This feature means that the level of product in a furnace cannot be kept constant."

Jan 1, 1999

By Olexandr Gydin

The evolution of grain and dislocation structures during cold deformation of the new steel LH800 of Salzgitter AG is investigated in the frame of this work. The main feature of this material is its ability to air-harden by carbon content of about 0.1%. The initial ferrite structure of the metal provides high plasticity at cold deformation and subsequent heat treatment increases tensile strength approximately two times. Described are results of in-situ tensile tests in the SEM. SEM and TEM analysis of grain and dislocation structures evolution in samples, which have been uniaxially deformed to certain strains, are carried out. After statistical evaluation of results the grain elongation against strain is determined. A microstructure of a deep drawn cup is analyzed by means of SEM. A quantitative evaluation of grain elongation on the different cup zones and comparison of these data with prediction results based on tensile tests are carried out.

Jan 1, 2009

By Bart Blanpain, Muxing Guo, Zhuangzhuang Liu

In order to stabilize free lime in the basic oxygen furnace (BOF) slag to achieve high value products, quartz sand and other additives are injected into slag. However, the current hot stage slag stabilization does not work in case of slag (before treatment) with a liquid fraction lower than 90%, where the slag containing solid particles is too viscous. Therefore, it is essential to understand how solid phases affect the viscosity of the slag system. In this study, the industrial BOF slags were investigated with respect to the correlation between volume fraction of solid phases and its viscosity. Slag viscosity was measured with a rotating type viscometer at temperatures below the liquidus. The volume fraction of solid phases was quantitatively calculated with FactSage. The Einstein-Roscoe equation was employed to predict the viscosity of BOF slag.

Jan 1, 2016

By A. V. Tarasov

Investigations of thermodynamic properties of Cu-Ni and Cu-Ni-S systems and mattes have been conducted with the aid of a MC-1301 mass-spectrometer designed for studies-of processes of vapor formation of hardly volatile substances. The instrument comprised a combination of an evaporator of Knudsen chamber type with a mass-spectrometer for analysis of the vapor phase, In the process of studies of molten Cu-Ni-S systems and commercial-grade mattes within a temperature interval of 1400-1800 K the partial pressure of sulfur was measured by means of complete isothermal evaporation and the partial pressure of copper and nickel by comparison of ionic currents. The partial pressure values of the components above the molten Cu-Ni-S were used for calculation of activities of the respective components in the melt. The copper and nickel activity data obtained was used for assessing the amount of dissolved losses of these metals in autogenous smelting slags.

Jan 1, 2003

By A. Martins, L. Goulart, E. Araujo, R. Batista, A. Costa e Silva

Steel cleanness is of great importance to the performance of almost all steel products. From very clean steel for bearings to long products used in civil construction, processing variables – in special those in steelmaking operations- must be properly balanced to achieve adequate cleanness for the desired performance. With the present complexity of steels as alloy systems, it is not efficient nor appropriate to develop these processes on empirical basis alone. Computational thermodynamics can greatly improve process development to achieve the desired cleanness level at reasonable costs. In this work, examples of these calculations and their applications to real steel processing are presented and discussed. The advantages, limitations and areas in which improvement in these calculations is desired are highlighted and discussed.

Jan 1, 2015

By W. D. Cho

The slag chemistry in steel processing plays an important role in terms of the removal of impurities including alumina particles. In the present study, the dissolution of solid aluimina particles in CaO-based fluxes at the temperatures between 1450 and 1550 °C has been investigated to determine dissolution kinetics and mechanism. Alumina particles were added directly in the slags and the size of alumina particles was measured as a function of time using optical and scanning electron microscopes. The dissolution rate has also been obtained as a function of Si02, CaF2, MgO and MnO contents in the slags. The diffusion boundary layer between alumina and bulk slag phase has been observed and analyzed using SEM and EDX. In addition, some experiments have been performed for the dissolution of alumina in BaO-based fluxes.

Jan 1, 2003

By Louis J. Cabri

The ion microprobe (dynamic SIMS technique) is a very sensitive instrument for the quantitative determination of trace concentrations of precious metals (often at the ppb level) occurring in common sulfide minerals, either chemically-bound or as discrete particles too small for resolution by SEM. The technique involves sputtering a 250 x 250 Jim area of the grains to a depth of about one ILm and analysing the secondary ions emitted from a circular central region in the sputter crater with a 62.5 I'm diameter. The combination of quantitative mineral-specific sub-ppm analyses together with depth-profiling and the ability to produce secondary ion maps of trace precious metals makes this a very powerful technique in quantifying the precious metal distribution in refractory and other sulfide ores and process products. The technique is particularly well-established for analysis of gold-and platinum-bearing ores and process products.

Jan 1, 1996

By B. Erik Ydstie, Tor Lindstad, Vianey Garcia-Osorio

"As a result of the high temperatures present in a Carbothermic Aluminum Process the content of aluminum and aluminum sub-oxide in the gases leaving this process is high. These gases as well as energy must be recovered. In a Vapor Recovery Unit were the aluminum compounds react in a series of Heterogeneous Non-catalytic Reactions forming solid, liquid and gas products. The different product phases depend on the temperature present in the system. In this work we present dynamic model of the Vapor Recovery Unit of a conceptual Carbothermic Aluminum Process. Because of the complexity of the system several models are developed and coupled to capture the essential physics of the multiphase reaction problem. A Shrinking Core Model describes the reaction mechanisms. Then material and energy balances are coupled with the thermodynamics properties from the FACT database of thermodynamic properties, resulting in a system of nonlinear Partial Differential Equations. In the paper we describe the model development and governing equations for the reaction mechanisms and fluid flow. Finally we review the numerical schemes created for the solution of the model system. The model can be used for control and design purposes.IntroductionThe Carbothennic Processes for producing Aluminum can be divided into two groups (Motzfeldt et al. (1989)) In the first approach pure alumina is produced and reduced to pure aluminum. In the second approach an alloy (e.g. aluminum and silicon) is made and then aluminum is produced from the alloy. The history of both processes has been described by Ginsberg et al. (1965). At least three aluminum producers began largescale testing of this process in the 60's Alcan, Pechey-Ugine and Reynolds. Alcoa did some smaller scale experiments.Alcoa was one of the first companies to produce aluminum by Carbothennic Reduction (Foster et al. (1956)) and US Patent 2,829,961 April 8, 1958. In this process a carbon containing molten aluminum phase was a floated on top of an oxy-carbide melt. During the cooling the dissolved carbon deposited as aluminum carbide. The carbide was then separated from the molten aluminum by a fluxing agent. This process was successful but economic unfeasible."

Jan 1, 2001

By Ali P. Gordon, James Williams

Joints gasketed with viscoelastic seals often receive an application of a secondary torque, i.e., retorque, in order to ensure joint tightness and proper sealing. The motivation of this study is to characterize and analytically model the load and deflection re-torque response of a single 25% glass-fiber reinforced polytetrafluorethylene (PTFE) gasket-bolted joint with serrated flange detail. The Burger-type viscoelastic modeling constants of the material are obtained through isolating the gasket from the bolt by performing a gasket creep test via a MTS electromechanical test frame. The re-load creep response is also investigated by re-loading the gasket after a period of initial creep to observe the response. The modeling constants obtained from the creep tests are used with a Burger-type viscoelastic model to predict the re-torque response of a single boltgasket test fixture in order to validate the ability of the model to simulate the re-torque response under various loading conditions and flange detail.

Jan 1, 2015

By Ramasamy Santhanam

"India’s present annual marine fish catch is 2.9 million tonnes and its low value fishes such as sardines, sciaenids, goat fishes and leiognathids amount to 60%. The fish meal obtained from these resources is mainly used presently as an ingredient in live stock and aquaculture feeds. These fishes offer vast scope in the production of pet foods. Pet foods prepared with leiognathid fish meal (60%), maize flour (10%), wheat flour (5%), vitamin and mineral mixture (5%) and water (20%) and experimented with 50 cats and 50 dogs were found to be ideal. Depending on protein level, feeds are being formulated for experimenting with more number of pet animals. Training programmes are also planned for unemployed people to popularize pet foods for commercial purposes.IntroductionIndia’s present annual marine fish catch is 2.9 million tonnes and low-value fishes sucha s sardines (Sardinella albella, s. gibbosa, S. fimbriata and S. melanura); sciaenids (Otolithus spp. and Jhonius dussumieri); engraulids (Stolephorus indicus); and leiognathids Leiognathus bindus, L. equilus and Gazza achlamys) constitute 60% (Figure 1)[1]. The fish meal obtained from these resources is now mainly used as an ingredient in livestock, poultry and aquaculture feeds. Considering the rich nutritional status of these low-value fishes, it is felt that these resources could be converted into value-added products viz. pet foods."

Jan 1, 2008

By Nagahiro Saito, Takahiro Ishizaki, Mituhito Hirota, Akio Fuwa

"Owing to their extremely high toxicity in the environment, the dioxins have been attracting social, technical and scientific attention in recent years. The authors theoretically had predicted the thermodynamic properties of all the dioxins via quantum chemistry and statistical thermodynamics and elucidated the generation-decomposition behavior of dioxins in the equilibrium calculation· of C-H-0-Cl system. In actual combustion processes, it is said that metallic compounds have much influences on the dioxins behavior. The aim of this study is to reveal the roles of metallic compounds the generation-decomposition behavior of dioxins is revealed from the viewpoints of quantum chemistry. Especially, the catalytic effect of copper has been investigated for the reaction, 2HCl(g)--H2(g}+Cl2(g) and for the etherification reaction from precursors, which is Phenol(g) here, to dioxins. The catalytic role of Cu is shown to have much influence on the generation -decomposition of dioxins.1. IntroductionIt is well known that dioxins are very harmful not only for our health but also for that of our children and grandchildren because they are very stable substance and their reaction rates of decomposition are considerably low. On the other hands, it is not well know how dioxins are generated and decomposed; the generation-decomposition conditions and paths as well as the catalysts to decompose them'1l. The authors believe that the thermodynamic and kinetic study of dioxins is useful to find a solution to these issuers. The authors have been investigating the following problems to reveal the generation-decomposition behavior of dioxins; (a) the prediction of the thermodynamic parameters of dioxins (2), (3), (b) the generation -decomposition behavior of non-chlorinated dioxins by the thermodynamic equilibrium calculations in C-H-O system(4) and (c) the generation-decomposition behavior of dioxins by the thermodynamic equilibrium calculations in C-H-O-CI system(5). Summaries of these thermodynamic researches are as follows.(I) The thermodynamic parameters for dioxins, which had been unknown and/or inaccurate'6 l, could be predicted and are available within the scientific accuracy."

Jan 1, 2000