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By Luis de la Pe[n]a Porth

The present process refers to a method for efficiently obtaining high purity metallic copper from copper ammonium sulfite. Essentially, this process consists of submitting the copper ammonium sulfite to the action of heat and pressure with the object of obtaining by the decomposition of it, metallic copper, ammonium sulfate, sulfur dioxide, and sulfuric acid.

Jan 1, 1974

By F. Habashi

The Republic of South Africa is a heterogeneous mixture of Black Africans, Afrikaans, British, Indians, Malayans, French Huguenots, and many others from Europe and Asia. A decisive date in its recent history is the collapse of the Apartheid Regime in 1994. For a metallurgist, South Africa is the country of diamonds, gold, platinum, and many other metals. In 1887 Cecil Rhodes (1853-1902) was able to take control of the De Beers Mining Company after the discovery of diamonds at Kimberly in 1866. It was there where the so-called School of Mines was inaugurated in 1896.

Jan 1, 2010

By R. K. Mensah-Biney, M. T. Hepworth, K. J. Reid

The loading characteristics of gold-bromide species onto activated carbon were evaluated using a batch system. The overall loading of gold onto activated carbon was rapid for the first few hours, but it continued without cessation as a result of the reduction of gold. Therefore, conventional equilibrium considerations were not applicable. Although loading continued slowly after several days, an abnormally high, loading capacity value of 10-12 meq/g carbon (650-800 kg Au/t) could be attained in 72 hours. The loading of gold-bromo species by activated carbon was by the mass transfer of (AuBr4)- species to the external surface to be reduced to metallic gold by carbon. Elution of gold from loaded carbon was feasible provided the carbon had not been loaded to high capacity values. If loading is carried to high levels, complete elution becomes impractical, and the gold may be recovered by ashing the carbon. For the high loading capacities observed, this option would appear to be cost effective. The effect of several variables on the loading capacity of the activated carbon for gold-bromo species is discussed.

Jan 1, 1994

By Jurgen H. Kleinau

This paper details Keeler/ Dorr-Oliver's experience with the application of fluid bed combustion technology to the burning of coal-mining waste. The designs of two stage fluid bed combustors/dryers are demonstrated as useful in the drying of coal, slag and coke, using coal and coal refuse (gob) as fuel. Anthracite mining refuse (culm) is more than abundant in Northeastern Pennsylvania. After demonstration at Shamokin, Pennsylvania, a full commercial-sized fluid bed boiler using culm is used for district heating in Wilkes-Barre, Pennsylvania. Limited research work has shown the utility of using fine coal as filter aid in sludge in¬cineration. With the rising avenues of the suitability of coal as auxiliary fuel in fluid bed sludge incineration, an expansion of these concepts combines the use of coal or coal refuse as filter aid and auxiliary fuel. Lime¬stone addition controls SO2 emission.

Jan 1, 1985

By L. J. Hoover

The objective of this study was to assess the health and environmental impacts of fluidized-bed combustion (FBC) of coal, specifically as applied to baseload generation of electrical energy by utilities. The study* was a short-term effort that based its analyses on information derived from the experience of the group or quickly obtained from the literature. The approach was to compare Atmospheric Fluidized-Bed Combustion (AFBC) and Pressurized Fluidized-Bed Combustion (PFBC) with two current technologies: low-sulfur coal combustion (LSC) and flue gas desulfurization (FGD) used with high-sulfur coals. A wet-limestone process was selected as the FGD technology. The impacts compared involved not only health and environment but also sociology, resource use, and dollar cost. Conditions for comparison were centered around a nominal date of 1988, when initial operation of commercial AFBC plants may occur. The PFBC has a later introductory date, a nominal 1995 (its impacts relative to other competitive technologies now in the R&D stages were not compared.)

Jan 1, 1978

By S. J. Schatzel, R. B. Krog, H. Dougherty

Longwall face ventilation is an important component of the overall coal mine ventilation system. Increased production rates due to higher-capacity mining equipment tend to also increase methane emission rates from the coal face, which must be diluted by the face ventilation. Increases in panel length, with some mines exceeding 6,100 m (20,000 ft), and panel width provide additional challenges to face ventilation designs. To assess the effectiveness of current face ventilation practices at a study site, a face monitoring study with continuous monitoring of methane concentrations and automated recording of longwall shearer activity was combined with a tracer gas test on a longwall face. The study was conducted at a U.S. longwall mine operating in a thick, bituminous coal seam and using a U-type, bleederless ventilation system. Multiple gob gas ventholes were located near the longwall face. These boreholes had some unusual design concepts, including a system of manifolds to modify borehole vacuum and flow and completion depths close to the horizon of the mined coalbed that enabled direct communication with the mine atmosphere. The mine operator also had the capacity to inject nitrogen into the longwall gob, which occurred during the monitoring study. The results show that emission rates on the longwall face showed a very limited increase in methane concentrations from headgate to tailgate despite the occurrence of methane delays during monitoring. Average face air velocities were 3.03 m/s (596 fpm) at shield 57 and 2.20 m/s (433 fpm) at shield 165. The time required for the sulfur hexafluoride (SF6 ) peak to occur at each monitoring location has been interpreted as being representative of the movement of the tracer slug. The rate of movement of the slug was much slower in reaching the first monitoring location at shield 57 compared with the other face locations. This lower rate of movement, compared with the main face ventilation, is thought to be the product of a flow path within and behind the shields that is moving in the general direction of the headgate to the tailgate. Barometric pressure variations were pronounced over the course of the study and varied on a diurnal basis.

Jan 1, 2018

By S. J. Schatzel, R. B. Krog, H. Dougherty

Longwall face ventilation is an important component of the overall coal mine ventilation system. Increased production rates due to higher-capacity mining equipment tend to also increase methane emission rates from the coal face, which must be diluted by the face ventilation. Increases in panel length, with some mines exceeding 6,100 m (20,000 ft), and panel width provide additional challenges to face ventilation designs. To assess the effectiveness of current face ventilation practices at a study site, a face monitoring study with continuous monitoring of methane concentrations and automated recording of longwall shearer activity was combined with a tracer gas test on a longwall face. The study was conducted at a U.S. longwall mine operating in a thick, bituminous coal seam and using a U-type, bleederless ventilation system. Multiple gob gas ventholes were located near the longwall face. These boreholes had some unusual design concepts, including a system of manifolds to modify borehole vacuum and flow and completion depths close to the horizon of the mined coalbed that enabled direct communication with the mine atmosphere. The mine operator also had the capacity to inject nitrogen into the longwall gob, which occurred during the monitoring study. The results show that emission rates on the longwall face showed a very limited increase in methane concentrations from headgate to tailgate despite the occurrence of methane delays during monitoring. Average face air velocities were 3.03 m/s (596 fpm) at shield 57 and 2.20 m/s (433 fpm) at shield 165. The time required for the sulfur hexafluoride (SF6 ) peak to occur at each monitoring location has been interpreted as being representative of the movement of the tracer slug. The rate of movement of the slug was much slower in reaching the first monitoring location at shield 57 compared with the other face locations. This lower rate of movement, compared with the main face ventilation, is thought to be the product of a flow path within and behind the shields that is moving in the general direction of the headgate to the tailgate. Barometric pressure variations were pronounced over the course of the study and varied on a diurnal basis.

Jan 1, 2017

By J. Weinstein

New erosion, corrosion resistant metal, ceramic, and polymer composite technologies are being developed and marketed by Alanx Products L.P. for use in hydrocyclones, pumps, valves, and other applications in mining and minerals processing. This paper will present an overview of the ceramic/metal composite material system and properties developed, which include excellent erosion/ corrosion resistance. Wear data will be shown from a variety of laboratory tests in dry and wet conditions, in aqueous neutral and corrosive environments. Comparisons will be made with a variety of competitive materials currently used in the industries sited. Data will also be presented on field tests with pumps and hydrocyclones in hard rock mining and other abrasive/corrosive environments. Field data from North and South America, as well as Australian mining applications will be highlighted.

Jan 1, 1992

By Sandy Worden

Coal mining companies in Australia are managing the high-consequence risks across their operations more effectively by using an interactive online risk management system known as Riskgate Developed by the Minerals Industry Safety and Health Centre (MISHC) at the University of Queensland, Australia, Riskgate contains detailed information about 11 high-consequence risk areas (called topics in the system) for opencut and underground coal mines (Table 1). The existing topics are: fires; strata control for underground mining; ground control for opencut mining; tires; isolation; collisions; explosions and explosives; manual tasks; and trips, slips and falls. Every Riskgate topic is focused on coal industry activities (mining, processing, transport and storage). The scope includes mine sites, lease areas and mine infrastructure (mobile, fixed plant, field equipment, buildings, road and rail transport), and all aspects of the mine life cycle from design through to decommissioning. The topics uniformly recognize that a loss of control can result in injury or fatality, equipment damage, production loss, reputation loss and environmental damage. However, the priority focus for Riskgate is the safety of mine personnel.

Jul 1, 2013

By Howard J. Haselhuhn

"The effectiveness of reagent adsorption onto hematite ore particle surfaces is critical during beneficiation to promote effective selective flocculation and dispersion and increase iron oxide recovery. The relationship between aqueous calcium in the process water and the effectiveness of common iron ore dispersants has never before been studied. The nature of common dispersants was studied in the presence and absence of calcium in the process water. The settling behavior of hematite-rich iron ore at pH 11 was assessed in the presence of calcium and inorganic dispersants: sodium silicate, sodium tripolyphosphate (STPP), sodium hexametaphosphate (SHMP) and organic dispersant ethylenediamenetetraacetic acid (EDTA). It was found that inorganic dispersants are ineffective at a pH of 11 without activating the surface sites of the ore particles with calcium. Organic dispersants, however, were found to be effective with and without surface site activation.IntroductionThe United States produced 54 million metric tons of concentrated iron ore in 2011 (Jorgenson, 2013). Over 8 Mt were produced using a process known as selective flocculation and dispersion (CCI, 2011). The grade of this ore is slowly depleting, making it imperative that processing efficiency improves. To increase processing efficiency, a complete understanding of the effects of chemical reagents in the process must be acquired. This process relies heavily on dispersants to disperse iron oxides from gangue minerals in settling processes. The mechanism that these dispersants use to disperse the ore and its relationship to calcium in the process water has never been studied. The following extended abstract summarizes the relationship between aqueous calcium in process water and the effectiveness of common iron ore dispersants at dispersing hydrated hematite ore. These tests were carried out at a pH of 11, as this is a typical pH used to ensure dispersion in selective flocculation and dispersion processes."

Jan 1, 2015

By Mike Harrington, Tung Vu

The Regional Connector Transit Project is a 1.9-mile-long underground light rail system that will connect LA Metro’s A (Blue), E (Expo), and L (Gold) Lines in downtown Los Angeles. This $1.75-billion design-build project is scheduled for revenue service in Spring 2023. The project consists of 21-foot diameter twin-bored tunnels, a 300-footlong crossover SEM cavern, three new underground stations (at 1st Street/Central Avenue, 2nd Street/ Broadway Avenue, and 2nd/Hope Streets), and cut-and-cover tunnels along South Flower, Alameda, and 1st Streets. This paper, which is the continuation of our previous paper presented in RETC 2019—LA Metro Regional Connector Transit Project: Successful Halfway-Through Completion, will provide insight regarding the construction of major components, and the system integration and testing work undertaken for this complex transit project.

Jun 13, 2023

By M. M. Veras, C. H. Sampaio, A. S. Young, D. Neto, C. O. Petter

"Due to new technological developments, automatic sensor based sorting has made progress within industrial minerals, precious metals, diamond, and coal mining in recent years (Lessard et. al. 2016). In order to re-introduce the technology to other mining sectors, this research discusses its application to iron, manganese, and zinc ores through test works performed by the authors. These test works were performed using Dual Energy X-ray Transmission (DE-XRT) sensor technology. In each case, pre-concentrations of the ore were created demonstrating the possibility to reduce waste material, energy costs, and water consumption while improving product quality of the ores. INTRODUCTION Sorting of mining ores is as old as mining itself (Salter, 1991). Sensor based sorting applications in coal mining began as early as the late 19th century (Louis 1928). New sensor technologies were developed and implemented sequentially for uranium, nickel, coal, and gold mining (Refining, 1949, Rose et al, 1950, Bloomfield et al, 1966, Clayton et al, 1987, Robben and Mosser, 2014). While these sensor technologies were developed decades ago, computational capacity to keep pace with the vast amount of information required utilizing the sensor technology did not arrive until recently (Lessard et. al., 2016). The sensor based sorting (SBS) process was effectively described by Salter and Wyatt in Minerals Engineering in 1991, and Wotruba and Harbeck in 2010 in the Ullmann’s Encyclopedia of Industrial Chemistry under Sensor Based Sorting. Both descriptions include the following key steps: 1. Presentation of the material or particles. 2. Examination or detection of the material or particles. 3. Processing or analysis of the data generated. 4. Physical separation of the material or particles by external means. Effective presentation of the material or particles is achieved when the sensor is capable of identifying each particle individually. This step requires that each fragment of the material be isolated, and it often involves acceleration of the material fragments by chute or mechanical means, as well as the spreading of particles by vibratory feeders (Salter and Wyatt, 1991, and Wotruba and Harbeck, 2010). The isolated particles typically are conveyed into an area wherein they are subjected to electromagnetic irradiation (except in cases of some radioactive ores), either in the form of x-ray, visible light, infrared, or other energies. A wide range of applications for sensor based sorting exists in the literature. The majority of applications fall into one of two camps, (1) pre-concentration of mineral ores, or (2) characterization of the material during processing (Buxton and Benndorf 2013). While there is much to be gained from in-line material characterization and the resulting control both of quality and processing, this article focuses primarily on the camp of pre-concentration of mineral ores."

Jan 1, 2017

By K. E. Robinson

During operation of tailings impoundments, water is lost through decanting, evaporation and seepage. Techniques have been developed to regulate or control each of these components. Collectively implemented, these techniques form the basis of tailings impoundment management. Regulation of the rate and level of decanting influences the size of a free water pond, and, thereby, the amount of evaporation and seepage, which are both area-dependent. Conversely, the encouragement of seepage and/or evaporation could also be used to reduce decanting requirements. Management of one of the components of a tailings impoundment's water balance is reflected in changes in the other components. The seepage component has the greatest potential impact on the environment, and consequently requires the closest scrutiny. Water percolating through tailings backfill transports heavy metals and other dissolved solids from the impoundment into the local groundwater regime. Depending on the seepage volume and concentration of contaminants, seepage from impoundments could exceed environmentally tolerable limits. Once mobilized, seepage-borne pollution is much more difficult to treat, mainly because of the problems in collecting the diffusive transportation medium. Pollution abatement measures relative to tailings impoundment seepage depend on seepage prevention or reduction. Seepage control measures include constructing barriers to flow, pump-back systems of interception and restricting the supply of water available for seepage.

Jan 1, 1987

By James C. Conti

A surface charge sensor has been developed that responds to changes in the double layer properties of colloidal silica during the cationic flotation of silica from taconite ores. Sensor design allows for the measurement of two aspects of the electrical double layer surrounding all solids immersed in ionic solutions. One aspect responds to a flow induced change in the double layer properties of a solid. The other is a function of the chemical composition of the aqueous phase. Evaluation of sensor performance during froth flotation experiments has been encouraging. Process monitoring capabilities are indicated.

Jan 1, 1981

By W. W. Harvey

The work to be described was part of an exploratory research program directed toward identifying potentially useful but little known reactions in extractive metallurgy. In particular, the major copper sulfide minerals, as a group, have long been considered insoluble in nonoxidizing acids (e.g. Forward and Barren, 1J60; Parsons and Ingraham, 1970; Peters et al. 1972). This generalization was considered to include nonoxidizing conditions in warm aqueous MC1 solutions (Ingraham et al. 1972) and, indeed, was consistent with our own chemical and mineralogical experience. On the other hand, under hydrothermal conditions, copper and sulfide species are carried in solution and deposited as sulfides in mineralized veins. The question that poses itself is: what are the mildest conditions of temperature and fluid composition under which commercially important copper sulfide minerals can be solubilized in the absence of an oxidizing agent? A reference to H2S formation during oxygen-sulfuric acid pressure leaching (Warren, 1958) of chalcopyrite, when the oxygen partial pressure was allowed to fall, provided a clue. In the present study, experimentation with chalcopyrite concentrate in dilute hydrochloric acid, under re flux conditions (in Pyrex flasks) and with an inert purge gas, revealed substantial amounts of H2S production and iron solubilization, cite negligible copper solubilization, after 2 ½ -4 days. Under comparable conditions the extent of reaction with dilute sulfuric, acetic and phosphoric acids was markedly less.

Jan 1, 1976

By Mark C. Williams, Shunsuke Managi, Noriko Hikosaka Behling

Particle processing is a key to using solid particles in fuel cell applications. Selectivity with regard to reactivity, impurities, etc. is an important feature and the treatment of particle surfaces could greatly impact the performance of direct carbon fuel cells. Solid fuel particles will become increasingly important in the future. Present energy conversion systems for solid fuels are too inefficient. New energy conversion systems for solid fuels with higher energy conversion efficiencies are possible. Fuel cell technology is a key technology in these new conversion systems. The direct carbon fuel cell (DCFC) operates on carbon particles obtained from a variety of solid fuel feedstocks. The DCFC is the only fuel cell designed to directly oxidize carbon particles in a special anode chamber. The particles are generally graphite structure with high purity. The electrolyte used is the high temperature solid oxide, molten carbonate, or hydroxide electrolyte. Since a pure stream of CO2 is produced, the stream can easily be sequestered and disposed. Pure carbon dioxide produced as a by-product would also have a market in many industries. A well-defined technology roadmap identifying key research and development (R&D) issues is necessary to provide a framework for the development of these systems and to prevent entrenchment in inherently inefficient technologies. This review paper describes the direct carbon fuel cell and its system, how it works, the developmental status, the characteristics of the carbon particles needed, and the research and development issues for the technology

By Leonardo Rosas Sánchez, Darío Ángel Bulla

"The two track road sector between Cisneros-Loboguerrero (having a length of 14 km and 11 short unidirectional tunnels) is a new highway still on construction located along the existing Highway Buga – Buenaventura (Colombia). Due to the steep topography, difficult geological/geotechnical conditions, the traditional portal construction approach was impossible to be implemented in eleven (11) of the twenty two (22) portals. In this specific project, the skewed portal approach was developed as the optimal and more effective solution. The construction time and costs of portals were reduced in 21 months and 75%, respectively. At the same time, the natural equilibrium of the slopes was maintained, thus, facilitating adequate safety factors along the useful life of the project. This document pretends to show a detailed design experience (and the construction of the entry portal of tunnel 11 (left)). INTRODUCTION The Cisneros-Loboguerrero project is a 14 km length dual lane highway, connecting productive zones with the Pacific Ocean along the current Bogota-Buenaventura highway as shown in Figure 1. The project is located at the northern side of the Dagua River Valley. The preliminary design suggested constructing portals under challenging topographical conditions, i.e., slope cuts having heights between 50 to 100 m (some having slopes > 100%) requiring complex developments and having very high risks.The entry portal of tunnel 11 (left) was the first portal successfully built by implementing the skewed portal approach. Later, this approach was used as a model for the construction of the other ten (10) portal having similar topographic and geotechnical conditions. The development of this new alternative provided a considerable reduction on the construction time of portals, thus relieving a critical path in this project."

Jan 1, 2016

By H. D. Dahl

In January, 1969, the Central Research Division of Continental Oil Company initiated a research program on roof control. The purpose of the research was to improve roof stability. Toward this end, it was necessary to determine which of the many geological and geometrical variables have a significant effect on roof stability. The isolation of these significant variables would allow research effort to be concentrated where it would be most effective in improving roof control. The research effort was directed toward two major objectives. One was to de-fine the geological and/or geometrical parameters that affect the severity of roof conditions in any particular area of the mine. This study was concerned with roof fall intensity. The second was to define why roof falls in Humphrey No. mine (and in northern West Virginia-south-western Pennsylvania coal mining areas) are oriented so that they occur primarily in north-south rooms or entries. This study was concerned with roof fall orientation. To provide a reference framework for further discussion, a geological description of the area is presented in Part II. In Parts III and IV, the procedures, methods, and 'results of the research applied toward the afore-mentioned major objectives are presented. Part V contains the conclusions and recommendations for-warded by this study.

Jan 1, 1971

By Kevin Sharman, Peri Mehling

A detailed assessment of acid rock drainage (ARD) potential was conducted at the Quintette Coal Mine site in northeastern British Columbia The site is unusual in that the coal seams contain low sulphur levels as compared to eastern coals (typically less than 0.5%), and the non-coal wastes generally do not to have the potential to generate acid on the basis of static ABA tests. The presence of small iron-stained seeps on the pit walls indicate localized sulphide oxidation, while the overall mine site drainage has remained of excellent quality with extremely low levels of metals after approximately 15 years of mining. Thus the site provides an excellent comparison to more problematic coal mine sites. For the Quintette assessment, static acid-base accounting (ABA) analyses of individual samples were compared to criteria for potentially acid generating materials developed for the U.S. Appalachian coal, as well as criteria developed in British Columbia for hard rock mines. Geologic units were characterized by the percentage of samples, or weighted thickness, that was deemed potentially acid generating (PAG). Links were then made to actual seepage and water quality emanating from geologic units around the site. Seeps at the site demonstrate a large range in pH (2.32 to 8.18). The few acidic seeps (pH < 4.0) were found to contain elevated levels of sulphates, dissolved iron, manganese and aluminum, consistent with the metals typically of concern in Appalachian coal mines. Other heavy metals that were detected in acidic seeps at Quintette included copper, zinc, nickel and cadmium. The use of simple ABA tests, and comparison of individual sample results with the Appalachian and British Columbia criteria, was found to be useful in predicting the probable sources of the small localized acidic seeps.

Jan 1, 2000

By V. F. Swanson

A petrographic study was made of the type and sources of mineral contamination occurring on phosphate rock products from Florida. Emphasis was placed on contaminants in the screened rock (+1 mm) since this portion of the product undergoes no physical beneficiation except for scrubbing to remove slimes. Since iron and aluminum con- tent of the finished product affect the salability, special emphasis was placed on identifying types and sources of these contaminants and relating chemical composition to visual characteristics. Wavellite derived from the overburden was the major aluminum contaminant with some aluminum being included as secondary clayballs. Iron occurred as phosphates in the overburden, and as colloidal oxides included in the phosphate pebbles. Chert and limestone contamination were derived from the Hawthorne formation underlying the phosphate matrix.

Jan 1, 1969