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By C. D. Winkler

Vanadium-based sulphuric acid catalyst has been utilized to oxidize SO2 to SO3 since the early 1900s. This versatile product displaced the expensive and easily poisoned platinum-based catalyst in nearly all applications by the 1930s. MECS has been manufacturing the vanadium-based catalyst since 1925 and today is the leading supplier in the world of sulphuric acid catalysts in a variety of forms. Currently, MECS has worldwide customer/technical support for the catalyst as well as a dedicated catalyst manufacturing plant in Martinez, California. MECS also has a strong technical and research and development programme dedicated to creating new and improved products and services. This paper will describe some of the technical details of vanadium-based sulphuric acid catalysts as well as offering a unique look into how caesium-promoted MECS catalysts can be used in single and double absorption acid plants, and off-gas plants running on irregular gas feeds, to reduce emissions and preheater run times. An update on MECS technical services extended for use in characterizing converter performance is also presented.

Jan 1, 2009

By J. E. Chilton

No regular monitoring of methane is required in areas of gassy coal mines outby the mining face. Methane ignitions that have occurred in mine outby areas indicate the need to provide better protection to workers. Handheld methane monitors are now used by some miners to make periodic measurements of methane at the working face. The IYONI II gas detector which is incorporated into a miner’s cap lamp and worn on a miner’s helmet can continuously provide an alarm signal whenever methane levels exceed a set level. Tests were conducted to evaluate the performance characteristics of this methane detector by measuring response times with methane gas supplied through a calibration fixture or adaptor. Other response time tests were performed with the detector in an environmental test box. Performance was also evaluated in a full scale test gallery where face methane emission and underground ventilation were simulated. Procedures for calibration by response time measurement of the IYONI II detector have been developed. In limited testing, the IYONI II detector was found to reliably detect the presence of 1 percent by volume methane.

Jan 1, 2003

Toxic gases, mostly carbon monoxide (CO) and nitrous oxides (NOx), are invariably generated by commercial explosives under practical conditions of usage because of oxygen unbalance and non-ideal chemical reaction. Permitted explosives are statutorily required to meet the criteria stipulated by regulatory authority for their toxic fume quality for their safe use in underground coalmines. Solid blasting using P5 explosives contribute around 60% production from Indian underground coal mines. Low pull and yield per blast in solid blasting has been identified as a reason for low production and productivity of Indian underground coal mines. In an effort to improve performance of solid blasting, it was envisaged to apply air decking between suitable P5 explosives using high density polyethylene (HDPE) spacers under a Ministry of Coal, Government of India funded project. A non-deflagrating slurry explosive composition having high air gap sensitivity was specially developed for this purpose, so that air decked cartridges get detonated sympathetically with single priming. However, statutory authority in India apprehended that the use of oxygen negative HDPE spacers can influence the generation of toxic gases. The effect of using HDPE spacers on the generation of toxic gases was studied under simulated laboratory conditions with newly developed as well as with three commercial P5 explosives. The results of studies presented in this paper revealed that the level of carbon monoxide increases linearly and there is no significant effect on the level of oxides of nitrogen due to the use of HDPE spacers with selected explosives. Studies also revealed that this newly developed slurry explosive can be used for air decking up to 15 cm using HDPE spacers of weight not more than 21 g without exceeding the permissible limits for toxic gases.

Jan 1, 2008

By R. T. Tshikhudo

Nanotechnology can provide solutions to many of the world?s socio-economic challenges. The application of nanomaterials for water treatment and analysis, point-of-care diagnostics and targeted drug delivery systems or devices could improve the quality of life for people in developing countries. Gold colloids have a long history (dating back to the 4th century AD) and are particularly well known for their aesthetic appeal and their therapeutic properties. Since Faraday published a report on the synthesis and properties of colloidal gold in 1857, a reasonable insight into the nature of gold sols (nucleation, growth and kinetics of coagulation) has been developed. Considerable attention has been drawn during the past few decades to the development and optimization of methods for the preparation of gold nanoparticles. In nanoscience and nanotechnology today, gold nanomaterials appear to be the most widely used material by both academics and industrialists. This is due to the extraordinary properties of gold nanoparticles (e.g. optical, catalytic, and magnetic?they are also known to act as strong Raman enhancers and may also amplify fluorescence under certain circumstances). Mintek, through Project AuTEK and the DST/Mintek Nanotechnology Innovation Centre (NIC), has been at the forefront of the development of new industrial uses for gold. Mintek?s gold nanotechnology programme focuses on the development of gold-based nanostructured materials and their applications in health, water and other related areas. While few projects use gold nanoparticles for water treatment and analysis, Mintek?s gold nanoparticles are widely used in the health sector. For example, gold nanoparticles are engineered and produced in large quantities as systems for targeted drug delivery. They are also used as tools for advanced rapid diagnostic tests. Both optical and electrochemical rapid diagnostic methods are developed for the human and animal health sectors for point-of-care testing. This paper gives a brief introduction and overview of gold nanotechnology, and desrcibes the development of some of Mintek?s gold nanoparticle targeted drug delivery systems and lateral flow point of care prototype devices.

Jan 1, 2009

By O. S. Tinkler, K. C. Sole

"Although the first large-scale application of copper recovery by solvent extraction took place in Zambia in the early 1970s, it is only in the last decade that this technology has become widely employed in this part of the world and is now a mainstay unit operation in copper hydrometallurgical flow sheets. The mineralogy of the ores of the African Copperbelt, and hence the characteristics of African leach liquors, differs significantly from those in Chile and the southwestern USA, where copper solvent extraction has had a long and successful history. These differences provide operators, metallurgists, reagent vendors, and engineers with many challenges: new approaches are needed to adapt solvent-extraction technology for successful implementation in this region. This paper examines typical operating practice in the African Copperbelt, discusses differences compared with other parts of the world, and looks at some of the challenges and opportunities presented by these flow sheets. IntroductionFollowing the success of the Rancher’s Bluebird and Bagdad solvent extraction and electrowinning (SX–EW) operations in Arizona in the late 1960s, the Tailings Leach Plant at Chingola, Zambia, became the first large-scale copper SX plant in the world, commissioned in 1974. Despite the equipment design now being outdated, this plant still continues to operate successfully, indicating the versatility and adaptability of this technology. Today, there are some 75 copper SX operations worldwide with cathode production above 10 kt/a. The top ten producers currently account for about 40% of the global 4.3 Mt/a SX–EW copper production. South America (predominantly Chile and Peru) is the largest copper cathodeproducing region, with annual production of some 2 Mt. The Central African Copperbelt (Zambia and the Democratic Republic of Congo (DRC)) is second, with cathode production of 1.2 Mt/a, and North America (USA and Mexico) third, producing close to 0.8 Mt/a Cu (Solvay Cytec data, 2014). The remaining 0.35 Mt/a comes from all other regions combined (referred to as ‘Rest-of-World’)."

Jan 1, 2016

By M. Gericke

Over the past few decades the commercial application of heap bioleaching technology for the extraction of base metals has become increasingly important, due mainly to the depletion of high-grade ore reserves. Heap bioleaching is widely used for the extraction of copper from secondary copper sulphide ores. The design and engineering aspects of the process have received considerable attention, but issues related to the microbiology of the process have been subjected to less rigorous scrutiny. The major role of micro-organisms in bioleaching processes is to catalyse the regeneration of ferric iron and protons, from ferrous iron and by sulphur oxidation respectively. It is accepted that even the most carefully engineered heaps are heterogeneous in terms of temperature, pH, the presence of anaerobic pockets, irrigation efficiency, and dissolved solutes. Since interactions between solution chemistry, mineralogy, and microbial populations exist in heaps, a better understanding of the correlation between microbial numbers and types with changes in these chemical and physical profiles with time would be beneficial during process design and operation of heaps, and could result in faster start-up times and higher metal recoveries. This paper reviews the role of microbiology in heap bioleaching processes. Aspects such as microbial diversity, identification and monitoring of cultures, inoculation strategies, colonization behaviour, and tolerance to metals and salts are discussed, and the potential contribution of the knowledge to the improvement of the operation and design of heap bioleach processes assessed. Conclusions are drawn with respect to the role of genetic engineering, heap inoculation practises, and remaining areas for future heap bioleaching research and development.

Jan 1, 2012

By M. Timucin

High-temperature phase relations and thermodynamics of the condensed phase region of the Pb-S-O system at 1473 K were analysed by use of the available information. The sub-regular solution models on Pb-PbS and PbO-PbSO4 continuous melts were used in conjunction to generate a consistent set of thermodynamic and phase equilibrium conditions for the Pb-S-O system. The directions and distributions of conjugation lines between melts of this system were derived with relevant activity and composition data. The calculations permitted the thermodynamic analysis of direct lead smelting and the construction of isothermal reaction diagrams for the system in terms of oxygen and sulphur partial pressures at 1473 K.

Jan 1, 1989

By R. Mumbi, M. Peart, E. Arinaitwe, B. Mbao, J. Zulu

Since 1925, xanthates have been widely used in sulfide flotation due to their low cost, ease of manufacture, and ability to float most value species. However, the industry's increasing need for safer and more selective alternatives, driven by low head grades, poor-quality, difficult-to-process ore with complex mineralogy, and stricter environmental regulations, has led to the development of Solvay's AERO® XR series of collectors. These custom-formulated products are based on greener chemistries and offer metallurgical benefits that are similar to or better than those of xanthates, without the safety concerns. Developed through Solvay's Flotation Matrix (FM) 100 approach, the XR series collectors are suitable for a wide range of applications, including the processing of Cu, Zn, and Cu-Ni, as well as the flotation of precious metals. This paper will highlight the differences between xanthates and XR series collectors, and present case studies of their successful commercial application at various global operations.

Jan 1, 2023

1. Book review Steels- microstructure and properties, by R. W. K. Honeycombe. London, Edward Arnold, 1981. 244 pp. Rl9,90. (Reviewer: P. T. Wedepohl) 2. New books Decision making in continuous steel casting, by Mark A. Vonderembse. New York, Bowker Publishing Co., 1981. U8 pp. Handbook on continuous casting, by E. Herrmann' Diisseldorf, Aluminium-Verlag GmbH, 1980. 742 pp. Cloth DM 1250, leather DM 1500. Pore structure analysis from a nitrogen adsorption study of porous materials using a volumetric method. User's guide to the FORTRAN programs: PORESl and PORES2, by E. G. K. Woods. Pretoria, CERGCSIR (P.O. Box 395, Pretoria 0001), May 1981. Oil and gas from coal, by Dick Olliver. London, Financial Times (10 Cannon Street, London EC4P 4BY), 1980. £120. The seventies: a review, the eighties, a preview, by W. Hibbard (editor). Oxford, Pergamon, 1981. 120 pp. £12.50. Computers in materials technology, by T. Ericsson editor). Oxford, Pergamon, 1981. 230 pp. £14.50.

Jan 1, 1981

Colloquium and General Meeting A General Meeting and Colloquium was held on 'New Advances in Non-ferrous Pyrometallurgy' in Kelvin House, Johannesburg, on Wednesday, 17th March, 1976. The President, Dr R E. Robinson, opened the proceedings at 1OhOO,by welcoming the authors and delegates, who numbered approximately one hundred and twenty. Tinplate Conference The Tin Research Institute is organizing the 1st International Tinplate Conference, which is to be held in London from 5th to 8th October, 1976.

Jan 6, 1976

By J. Manchisi

Laboratory investigations were conducted to establish the feasibility of bioleaching a mixed copper oxide/sulphide rougher concentrate from Nchanga Mine on the Zambian Copperbelt. The objective was to determine the kinetics and extent of copper extraction for this material. Batch experiments were conducted under different solution conditions in stirred tank bioreactors. The progress of (bio)leaching was monitored through measurements of soluble ferrous and ferric iron, copper, pH, and redox potentials, while bacterial activity was monitored online through 02 and C02 gas utilization rates. About 20 per cent copper was solubilized within 2 hours in all cases of non-oxidative (abiotic), oxidative (abiotic), and bioleaching experiments. This was attributed to the dissolution of mainly copper oxides. Subsequently, bioleaching experiments resulted in an overall copper extraction of 93 per cent, with up to 8 g.L-1 copper after six leaching days, compared to 58 per cent copper extraction in the abiotic oxidative acid leaching experiments. However, there was little effect of time (i.e. poor dissolution kinetics) on copper recovery for abiotic non-oxidative acid leaching of the material. Hence, the rate of sulphide leaching increased due to the activity of bacteria. Thus, the material is potentially bioleachable under mesophilic conditions. However, more exhaustive test work needs to be conducted to establish the effect of bioleaching variables and heat requirement.

Jan 1, 2012

By B. M. Kunar

It is well known that job-related hazards and individual factors influence occupational injuries. However, research involving coalminers has been limited. This case-control study assessed the relationships of job-related hazards and individual/life style factors with injuries among underground coal miners. It compared 245 cases with at least one injury during the previous two-year period with 245 matched controls with no injury. The data were gathered via personal interview and analysed using the conditional logistic model. The significant risk factors were materials handling (adjusted OR 5.15), poor environmental/working conditions (2.63), geological/strata control-related hazards (2.35), lack of formal education (3.00), sleep disorders (1.86), alcohol consumption (2.32), disease (2.23), having a large family (5.40), and risk-taking behaviour (9.40). Machine-related hazards, sleep disorders and alcohol consumption primarily affected workers aged less than 45 years; whereas, environment/working condition-related hazards, presence of disease, smoking, risk-taking behaviour and large family size were more likely among workers aged 45 or over. Keywords: Occupational injuries, sleep disorders, job hazards, alcohol, coal miners

Jan 1, 2010

By W. D. Grimsley, R. P. King, J. B. See

Samples (15 to 20 g) of pre-calcined Mamatwan manganese ore or pure Mn 304 smaller than 48 mesh were reacted at temperatures in the range 1000 to 1300°C with samples of spectrographically pure graphite smaller than 325 mesh. Samples (1 g) of ore or pure Mn02 smaller than 48 mesh were reacted at temperatures of 1000 and 1200°C with pure graphite fines in argon, with graphite in carbon, .'1onoxide, and with carbon monoxide alone. In each case, the loss of mass as a function of time was recorded with a hermobalance. The rate and degree of reduction were found to increase with additions of carbon and with increasing temperature up to 1300oC, when they reached their maximum. The shape of the reduction curves, together with the results obtained from examination of the products of reaction by microscopy and X-ray diffraction, were used as the basis for a postulated reduction mechanism. Some details are given of an initial kinetic model that was used to verify the proposed mechanism. It was found that the reduction of Mamatwan ore by graphite at temperatures in the range 1000 to 1300°C occurs in two stages: (i) an initial stage during which the higher oxides of manganese are rapidly reduced to MnO with concurrent formation of CaMn2O4 and (ii) a longer stage during which CaMn2O4 and MnO are reduced to carbides by carbon dissolved in the ferromanganese phase.

Jan 1, 1978

By A. Navarra, A. Quelopana

The mine production scheduling problem (MPSP) has been studied since the 1960s, and remains an active area of computational research. In extending the concepts of the MPSP, the automated mine may now be regarded as a hierarchical intelligent agent in which the bottom layer consists of distributed robotic equipment, while strategic functionality occupies the higher layers. Here we present a disambiguation of artificial intelligence, machine learning, computational optimization, and automation within the mining context. Specifically, the Q-learning algorithm has been adapted to generate the initial solutions for a high-performing strategic mine planning algorithm, originally developed by Lamghari, Dimitrakopoulos and Ferland, based on the variable neighbourhood descent (VND) metaheuristic. The hierarchical intelligent agent is presented as an integrative conceptual platform, defining the interaction between our new Q-learning adaptation and Lamghari’s VND, and potentially other hierarchically controlled components of an artificially intelligent mine, having various degrees of automation. Sample computations involving Q-learning and VND are presented.

Dec 1, 2021

By J H. Sullivan

Contents Background information Locality of Kumba?s Iron Ore Mines Sishen?s Product Specifications Geological Description of boreholes Sample Preperation Block delineations Production Geology Process Laboratory information Turnover times reached Inter Laboratory Comparisons Quality control activities in lab Purpose of laboratory Results attained Standard samples Monitoring of processes with QA/QC standards Mean paired difference of duplicates Duplicate samples Conclusion

Jan 1, 2005

By N. J. Roodt

Mine dumps created in terms of the pre-MPRDA regime (old order mine dumps) are currently not regulated by the MPRDA, and the common law owners of such dumps are free to process them without the need to obtain the relevant rights. The MPRDA Amendment Act purports to change this position. However, the wording of the Amendment Act raises a number of problems which render the post-amendment position at best unclear and at worst absurd and unworkable. The primary concern with the Amendment Act is that, on one interpretation, material placed on the same dump at different times may be treated differently at law. Thus, parts of a dump may be subject to one person?s right while others may be subject to another?s right. Moreover, case law has generally regarded mine dumps as movable property and, by extending the MPRDA to apply to all mine dumps, the Legislature is extending the ambit of the Act to cover movable property, a scenario not contemplated by the wording of the Act (even after its amendment) in relation to applications for rights. The better interpretation of the amendments, which are not yet in force, is that they will not apply retrospectively to old order mine dumps.

Jan 1, 2010

By J. H. French, O. E. Lissner

S. J. Venning (Member): The authors should be congratulated on producing such concise data from the plethora of experimental report results. Their observations on the cost of liners calls for some comment however, as the really unique feature about liners in South Africa is that they can be obtained so cheaply. Attention has been focussed on the 1961 cost of white iron at R50 per ton for chill cast block liners while manganese steel liners are reported as costing as much as R250 per ton. The former are however, a relatively heavy, simple casting with a low labour content and reasonably high percentage productivity, made from metal melted in a cupola. The capital investment to produce this type of casting is low compared with that required to produce manganese or other alloy steels. The chill cast liner block is always a production item and is cast in a permanent mould. Almost all manganese mill liners, except perhaps small aperture screens, are sold for considerably less than the R250 per ton quoted by the authors. Where a price of this nature is asked it would be because the design of the casting demanded is complicated or leaves little metal to carry the labour and other costs of production. As reference has also been made in the paper to liner costs in America, prices for similar types of liners obtained during a visit to Canada and the U.S.A. in 1961, could be of interest: Material Price per Location short ton Ni-hard R250 Elliot Lake Body liners block type Ni-Hard R300-310 FAS New York Mn Steel R280-290 FAS New York Screens (grids) slotted Cr.Mo. Steel R600 FAS New York hole Ni-Hard R320 Elliot Lake At this time the price of comparable manganese steel block type liners on the Witwatersrand was between R145/R155 per short ton. White iron in Canada was then quoted at about R150 per ton, but as Ni-Hard gave a life of at least two to twoand-a-half times that of white iron, it was a much more attractive proposition particularly when relining and down time costs were taken into consideration. There is little doubt that most foundries would welcome clear and complete specifications of the customers requirements and systematic checks to ensure that these specifications are being met. B.S.S. or other accepted standards should form the basis of these, and periodic inspections should be undertaken to ensure that only those foundries capable of complying should be included as suppliers. The authors have referred to new designs, but can the industry really call the grid and plate new when the patents were taken out during the second world war and the sawtooth block has been used for at least 35 years. Unfortunately, far too little thought and consideration are normally given to the ultimate mill liner design while the mills themselves are on the drawing boards. The position and size of the door opening, which is the key to the ultimate shell liner configuration, the drilling of the

Jan 9, 1968

By E. F. W. Buermann

This paper, which is meant to be read in conjunction with the other papers on the Grootegeluk Coal Project in this Issue (J. S. Afr. Inst. Mm. Metal/., vol. 82, no. 12. Dec. 1982) deals with the extent to which civil-engineering infrastructure had to be provided for that project, near Ellisras in the Transvaal.

Jan 1, 1982

By R. P. King

The University of the Witwatersrand (Wits) and the minerals industry of South Africa have grown with the city of Johannesburg. The former has provided teaching and research in mining and metallurgy, while the latter has been responsible for the practical training of metallurgists and for the testing and implementation of innovative ideas proposed by the academics. This interplay between inventiveness and industrial application is illustrated by three examples: the establishment of the iron and steel industry as a result of the persistent experimentation undertaken by Professor G. H. Stanley, the first Professor of Metallurgy and Assaying at the South African School of Mines, which later became Wits; the establishment of the research organization that eventually became the Council for Mineral Technology (Mintek) - again through Professor Stanley's faith in the role of research; and the establishment at Wits of physical metallurgy as a discipline in its own right, as first suggested by Professor C. E. Mavrocordatos of Wits against the opinion of his colleagues in the industry. The Department of Metallurgy at Wits has been well supported by the minerals industry. Not only does the industry provide grants for the financial support of students, but it supplements the salaries of personnel in the Department, making possible the recruitment of top-class academic staff. At present the greatest problem is the lack of interest shown by matriculants in the metallurgical industry as a career. However, an enormous effort is being made by the Chamber of Mines, The South African Institute of Mining and Metallurgy, and the Wits Department of Metallurgy to ensure that matriculants receive appropriate information about the career prospects in the minerals industry.

Jan 1, 1983

By O. K. H. Sheff

An editorial in the April 1990 edition of Mining Magazine is worth a wider audience in South Africa, particularly as the SAIMM enters its own centenary decade and the process of change in the minerals industry world-wide makes increasing demands on the professionalism of its leaders. The editorial considers the changing status of engineers, who up to the 1880s had been held in high regard by society. Alumina and bauxite Economists forecast a slower economic growth rate in 1990, but expect continued increase in demand for aluminum at a 3 per cent annual rate during the decade. Structural and numerical analysis Struceng & Femcad (structural analysis and finiteelement method) is a conference and exhibition that is to be held in Grenoble (France) on 17th and 18th October, 1990. It is sponsored by the Institute for Industrial Technology Transfer (ITT-International).

Jan 1, 1990