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By J. A. Kost

Contract H0242013 was originally to evaluate through underground tests, water spray systems for controlling respirable dust at the face of a longwall plow. A number of difficulties were encountered which made such an evaluation impractical. The contract was modified to evaluate, in the BCR dust tunnel facility, the live factors believed to affect respirable dust levels. A 60-foot long; plow face mock-up was constructed in the dust tunnel, a facility with controlled airflow and dust concentration. Six types of nozzles were tested with the following parameters: two nozzle orientations, two levels of water pressure, two levels of airflow, and with and without simulated airflow through the gob. Of these factors, the most significant in reducing respirable dust levels was nozzle orientation, where the nozzle directed 45 degrees downstream resulted in 27 percent lower dust levels than those directed 45 degrees upstream (against the airflow). Following in order of effectiveness were the higher water pressure and the lower airflow. All nozzles tested resulted in similar dust reduction, i.e., the type of nozzle was the least significant factor.

Jan 1, 1979

By K. O. Bennington

The thermodynamic properties of synthetic acmite, NaFe3+Si206, were determined by the Bureau of Mines. The enthalpy of formation was determined by hydrofluoric acid solution calorimetry. The values of the standard enthalpy of formation at 298.15 K, ?Hf°298.15, from the elements and from the oxides, ?H°298.15, are ?Hf°298.15 = -615.87 ±0.71 kcal/mole, ?H°298.15 (from oxides) = -32.08 ±0.53 kcal/mole. Various experimental data were combined with other data from the literature to calculate all the related thermodynamic properties in the range of 298 to 1,263 K. The standard Gibbs energy of formation is ?Gf°298.15 = -575.8 kcal/mole.

Jan 1, 1981

By D. B. Dow

The presence of sulphur compounds in petroleum and its products is, generally speaking, undesirable, and the problems involved in removing such compounds are of great importance to the petroleum refiner and to the manufacturer of gasoline. There are several types of these compounds which are dissimilar in physical and chemical characteristics, as evidenced by different objectionable features which they exhibit, and special treatments have been developed to meet conditions existing in various products. This paper deals with the treatment of natural-gas gasoline for the removal of certain sulphur compounds which, if not removed, impart on objectionable odor and in addition badly discolor the product. The presence of this particular type of sulphur compounds is detected by the "doctor" test.* In some instances natural-gas gasoline is purchased on "doctor" test specifications, and the ordinary purchaser, while not buying on "doctor" specifications, is insistent in his demand for a water white product. Gasoline which fails to meet the "doctor" test, if not received by the buyer within a few weeks after time Of manufacture, may be "off color" enough to warrant a deduction from the market price.

Jan 1, 1923

By David L. Veith

This report summarizes a Bureau of Mines review of selected literature on the effects of subsidence due to high-extraction underground coal mining on farmland areas. The data are presented for consideration in evaluating the subsidence effects due to similar mining techniques on the prime farmland areas of Illinois. In Illinois the ground water level in the glacial drift is only 2 to 15 ft below the nearly flat to gently rolling ground surface. The main subsidence concern is flooding, as caused by the lowering of the ground surface, and the subsequent effects on crop production. Positive drainage must be maintained in the farmlands, and the need exists for extensive regional planning by the mining and agricultural industries to maximize short- and long-term production from both efforts. The Bureau is cooperating with the State of Illinois to develop basic information necessary for such planning.

Jan 1, 1987

By J. E. Tiffany

"The new permissible blasting device, Cardox, utilizes as a blasting agent liquid carbon dioxide which is discharged.as a gas from a steel container or shell. The loaded shell is placed in a borehole, stemmed, and tamped in a manner similar to that employed with explosives, and is fired by electricity.The Bureau of Mines' approval for use of the device in coal mines was granted as Approval No. 1 under date of October 3, 1928; as the result of tests made under the conditions and requirements of Schedule 20. There have been three subsequent extensions whereby minor modifications in the original design were granted.The permissibility of the device is subject to the following conditions; (1) It shall be in all respects similar to the sample submitted for tests; (2) certain thicknesses of disc and. weights of heater ingredient and of carbon dioxide, all of which are set forth in Table 2 under the provisions governing permissibility, must be used: (3) the rear cap must always be in place after the shell has been charged, to prevent accidental firing; and (4) firing must be done by means of a permissible-type blasting unit.The permissibility of Cardox was established by gallery tests similar to those used in testing explosives for permissibility. In these tests the shell was discharged into gallery 1 without causing any ignition of gas and air or of gas, dust, and air mixtures there. The conditions of charging the shell, such as weight of the ingredients of the heater element, the carbon dioxide charge, and thicknesses of the disc, were varied according to the conditions under which it would be likely to be used in blasting. The tests made in gallery 1 are here described in detail, as are also the tests which have been made for determining the propulsive strength of the device and the quantities of poisonous gases given off when a shell is discharged."

Mar 1, 1929

By G. R. Hopkins, A. B. Coons

A survey of the petroleum pipe lines by the Bureau of Mines as of May 1, 1923, shows that on that date there was a total of slightly more than 90,000 miles of pipe lines in the United States, having a capacity of approximately 15,750,000 barrels, which is equivalent to one-fourth of the nation's average production for one month. These lines varied in diameter from 2 to 16 inches, the weighted average being 6 inches. The total pipe-line milenge was about equally divided between trunk lines and gathering lines, though the capacity of the former was about four times that of the latter. This was due, of course, to the difference in average diameter, that for the former being 7.4 inches as compared with 3.7 inches for the latter. The common size for trunk lines was 8 inches, and for gathering lines 2 inches. Oklahora, with 19,180 miles of pipe lines, is the leading State in total mileage, with Texas second and Pennsylvania third. From point of trunk lines alone Texas is considerably ahead of any of the other States, a position which it owes to its size and to the growth in the rovement to its Gulf ports. Cali- fornia, though the leading State from point of production, ranks only seventh in pipe-line mileage. This is due to the fortunate location of the Los Angeles Basin fields, some of which are within sight of the refineries to which their oil is delivered or of the port of San Pedro through which their oil is shipped. The last survey of this nature, made in the spring of 1924 by the U. S. Geological Survey, recorded a total mileage of nearly 83,000 with a capacity of approximately 14,450,000 barrels. This indicates an increase of 9 per cent in both mileage and capacity during the two years.

Jan 1, 1927

By Will H. Coghill, G. Dale Cole

"INTRODUCTION This paper describes a method for the rational sorting of particles by means of a laboratory batch jig. Its purpose is to show that a material can be reliably appraised for gravity concentration without the drudgery of sink-float fractionations.Development of the batch- jig method of testing was incidental to a study of the Birmingham, Ala., red-iron ores now being conducted by the Bureau of Mines in cooperation with the University of Alabama and the ore-producing companies.APPLICATIONOres and coal are commonly tested for their gravity-concentration characteristics by specific-gravity dissections in heavy liquids. The heavy liquid most commonly used for coal is zinc chloride and for ores they are benzene, carbon tetrachloride, acetylene tetrabromide, methylene iodide, and thallium malonate formate. The last is poisonous and corrosive to the skin but is essential for separations in the 3.3 to 4.4 specific gravity range. The last two of these liquids are expensive, and several of them are hard to obtain now.Although it is not suggested that heavy-liquid dissections be eliminated entirely, sometimes a more reliable evaluation of coal and ore can be obtained by other and more simple means. For example, sink-float data were unsatisfactory as a guide to commercial gravity concentration of a red-iron ore because they did not take into account the difference in particle shape of the hematite and gangue and the differences in true and apparent specific gravity of the hematite grains, some of which were porous. For this ore, the batch-jig method of testing herein discussed proved advantageous. Not Only did the batch-jig data give a truer picture of the concentration problem, but only about one-tenth the time of the conventional sink-float tests was required."

Jul 1, 1944

By E. C. Tarpley, H. M. Cooper, R. F. Abernethy

The standard method of employing preliminary air-drying to determine the moisture in coal has been criticized with respect to the loss of heating value from excessive air-drying. By this method, the coal is air-dried at approximately 10-15° above room temperature with the loss in weight being less than 0.1 percent per hour, and then the residual moisture at 105°C is determined. The total moisture is calculated from these two values.

Feb 1, 1948

By C. Melvin Lepper

High-resolution shallow seismic reflection methods are being used by the Bureau of Mines to map underground geologic features in coal mines. These features include faults, channel sand, washouts, rolls, and steep dips. The seismic method is proving useful for locating all of these at reasonable cost and with better definition than available with drill programs alone. This report provides a capsule description of the techniques and their application to mine planning.

Jan 1, 1976

By M. H. Stanczyk

The Bureau of Mines made bench-scale laboratory tests on a sample of typical Florida phosphate slime to determine alumina and phosphate extractions obtainable by agitation leaching, by baking and curing, and by a leach-electrolysis scheme. Recovery of mineral values from leached slime pulps by resin-in-pulp ion exchange contact and the reaction of the leached pulps to filtration, flocculation, and settling were also investigated. The best extractions of alumina and phosphate were obtained by (l) agitation leaching with sulfuric, hydrochloric, or nitric acid at an elevated temperature or (2) curing or baking the slime with sulfuric acid. Alumina extractions ranged from 80.8 to 90.0 percent and phosphate extractions ranged from 93.3 to 98.4 percent when the slime was leached at 90° C with sulfuric, hydrochloric, or nitric acids. Baking the slime with sulfuric acid at 200° C for 4 hours yielded an alumina extraction of 92.3 percent and a phosphate extraction of 97.0 percent, whereas curing with sulfuric acid at 100° C for 24 hours gave slightly higher alumina and phosphate extractions. Flocculation and settling properties of the slime were virtually unaffected in all cases. Filter area requirements, although somewhat improved as compared to untreated slime, remained relatively high. The lowest filter area requirement obtained was 44 square feet per ton of dry solids treated per day. Contacting leached slime pulps with ion exchange resins depleted the leach pulps of solubilized values; however, the filtration and settling properties of the barren pulps were unaffected. A leach-electrolysis scheme resulted in some concentration of solubilized phosphorus, but the method showed little promise of being commercially feasible.

Jan 1, 1966

By E. G. Davis

The flash reduction of fine iron ore in a dilute-phase system was investigated at 500° to 900° C within a heated stainless steel tubular coil. Alabama brown iron ore and Mesabi semitaconite ore were fed into the coil concurrently with reducing gases of hydrogen and reformed natural gas, so that the velocity of the gas at the reaction temperature was sufficient to entrain and pneumatically transport the solids through the coil. Reduction is very rapid with retention time of the ore in the coil varying from 4 to 15 seconds. Variables affecting reduction are temperature, ore feed rate, and gas flow or velocity. Results of the studies show that a partially reduced product (10-to 25-percent reduction) can be made which, on subsequent magnetic concentration, yields a concentrate containing 64 to 70 percent iron with a 90-to 94-percent iron recovery. Maximum reduction of 77 percent was obtained when hydrogen was used in a four-stage reduction test to yield a product containing 61 percent metallic iron.

Jan 1, 1972

By T. T. Campbell

Although secondary recovery of lead and lead-tin alloys has been common practice in the United States during recent years, there is little published in-formation concerning recovery techniques. Available information does not cover metal recovery from wet dross skimmings. This investigation by the Bureau of Mines was undertaken to develop techniques that would allow lead-tin alloys to be recovered from wet dross skimmings containing large amounts of zinc chloride. A process was developed, on a laboratory scale, for recovering lead-tin alloys from wet solder dross skimmings. Straight water leaching, either with or without a second leaching operation carried out with a Na2C03 addition for removing chloride, produced a dross that could be smelted without further treatment. Overall recoveries averaging 92 percent of the metal values in the dross were obtained in the form of lead-tin alloys, which had an average tin content of 16 percent and lead content of 84 percent. The recovered alloy contained less than 0.02 percent zinc, as determined by both chemical and spectrographic analyses.

Jan 1, 1956

By T. J. Ballard, Austin B. Clayton

"The Union Copper mine is in the Gold Hill district, Rowan and Cabarrus Counties, N. C.The mine was discovered in 1799 and first worked as a gold mine; but copper was encountered at depth, and the property became an important producer of copper. It is estimated that the mine produced 5,000,000 pounds of copper before operations were discontinued in 1907.As part of the strategic minerals program, the Bureau of Mines conducted a development project on the property from July 1943 to November 1943. Eight diamond-drill holes, totaling 2,500 linear feet, were drilled to delineate the ore body. Analyses of 205 core samples were made.Tabulations of sample analyses and drill-hole logs are presented in this report.The project work embodied in this report was under the immediate supervision of Austin B. Clayton, project engineer, and the general supervision of H. B. Ewoldt, district engineer for North Carolina and Tennessee. The preliminary report, written by Austin B. Clayton, was revised and the various figures redrawn for publication by T. J. Ballard under the general supervision of M. H. Kline, chief, Raleigh Branch, Mining Division.Acknowledgment is due the Metallurgical Branch for analytical determinations of the samples.The mine property is 1.5 miles southwest of the village of Gold. Hill, N. C. (fig. 1). Gold Hill is on U. S. Highway 52 between Salisbury and Albemarle and on a branch line of the Southern Railway. The latitude is 350 30' and longitude 80° 21 The tract consists of 553-1/2 acres in Cabarrus and Rowan Counties.A tentative list of the surface-rights ownership is as follows: William Hoy Barringer - 16 acres, A. W. Tucker - 1 acre, Frank Wagoner - 4 acres, and George Barringer - 3-1/2 acres, in Cabarrus County; A. W. Tucker - 2 acres, H. N. Hedrick - 54 acres, and William Atkins - 473 acres, in, Rowan County, N. C.The mineral rights are owned by Alfred Rossiter, Alice R. Hesslein? and the estate of the late Bella Rosenblatt. The attorneys for the owners are Neidle & Taylor, 6 East 45th Street, New York City.The Union Copper mine is in the Cold Hill mining district of North Carolina where gold was first discovered in 1799. The upper parts of the veins in the district were first worked for gold; however, the increase in the sulfide content of the veins with depth rendered the amalgamation process for gold recovery ineffective, and the mines were closed.The period of greatest activity at the Union Copper mine was from 1899 to 1906. At an earlier period the oxidized and leached part of the lode near the surface was mined from a working known as the ""big cut,"" the reported yield of which was $300,000 in gold.3/ The mine has not been operated since 1907.J. T. Pardee3/ lists the probable value of the production of the Union Copper mine as $1,050,000, of which about $675,000 was the value of some 5,000,000 pounds of copper produced."

Oct 1, 1948

By John P. Capp

Addition of sintered fly-ash/bottom-ash mixtures to rubber formulations failed to increase the skid resistance of the resulting products. Wear, tensile and hot-tear strengths, and resilience of the ash-rubber material, as determined in laboratory tests, were significantly less than that of comparable rubber. The material appeared unsatisfactory for automobile and truck tire manufacture, but might prove suitable as a filler in other rubber goods. Raw fly ash could not be satisfactorily compounded with rubber.

Jan 1, 1972

By David J. Kusler

This report describes a rapid, reliable, and relatively simple method developed by the Bureau of Mines Pyrometallurgy Laboratory at Bruceton, Pa., for determining lime (calcium oxide) and magnesia (magnesium oxide) in various materials containing these constituents in greater than trace amounts. Optionally, titania (titanium dioxide) may be determined for the same sample. The accuracy of the method, suitable for most purposes, is shown by comparing the Bureau results with those obtained by accepted procedures. The method has been applied satisfactorily to the routine analysis of blast-furnace slags, for which purpose it was primarily developed, and to other calcareous compositions. In the Pyrometallurgy Laboratory it has replaced the standard methods previously used to determine lime and magnesia, and has been in general use by that laboratory for the past several years. The analysis time, generally under 3 hours, is considerably less than required by standard methods.

Jan 1, 1960

By T. C. Higgins, J. S. Malesky, J. A. O'Connor

"INTRODUCTION This circular contains the story of a stubborn mine fire of electrical origin that started on the main haulage road of No. 59 mine of the Peabody Coal Co. and illustrates that sometimes serious fires can be fought by direct attack. The story also points out that the cost of such procedure can be extremely high, and it is better, therefore, to minimize the possibility of a fire of electrical origin by suitable over-current and line-fault protection. The lives of 163 men were saved by utilizing a recently sunk air shaft near active workings as an escapeway. These men could not have reached the older openings. Also described are the rescue of 75 additional men through another air shaft, sealing of the fire, attempted extin¬guishment with carbon dioxide, and the difficulties of fighting the fire and recovering the mine.A fire occurred shortly before 12 o'clock noon, August 15, 1949, in the No. 59 mine, Peabody Coal Co., Springfield, Ill. All 257 men underground escaped to the surface. One group of 75 men was delayed from escaping for several hours after the alarm was given because smoke and fire gases were circulating in a main return airway, which intervened between their working section and one air shaft, and also in the stairway compartment of the shaft. After being supplied with universal-type gas masks, or self-rescuers, these men were conducted from the mine by members of a State mine-rescue team and other mine employees. Six nine officials were hospitalized because of exposure to carbon monoxide during fire-fighting activities; all were discharged a few days afterward. Later, while doing work incident to fighting the fire, two men were killed, and several were injured by falls of roof and rib.The fire broke out after a collision of a loaded trip with four empty mine cars on the main east haulage entry. The mine cars were jammed against the trolley wire causing a sustained electric arc that ignited the wooden mine cars and the fire spread to the timbers and coal."

Apr 1, 1950

By V. A. Nieberlein

This paper presents the results of research undertaken to recover titanium and columbium by low-temperature chlorination of low-grade columbium-bearing ilmenite concentrates, and to simultaneously remove chlorinated impurities from the volatile chlorides without resort to distillation. Coke-reduced ilmenite was chlorinated at 400° to 500° C., and the resulting TiC14 was free of most impurities before condensation. A heated purification column was used wherein various packing materials reacted chemically or physically with the impurities which passed through them in the vapor phase. A nearly water-white TiC14 product was obtained directly. The principal impurities in the titanium tetrachloride were: 0.02 percent Fe, 0.01 percent V, 0.05 percent A1, 0.04 percent Si, and 0.07 percent Cb. This is a less pure product than commercial TiC14. Most of the columbium was recovered as crude CbC15, requiring further refining.

Jan 1, 1960

By John E. Rourke, O&apos

A survey of existing and developing field permeability test methods was conducted in order to identify and specify capable methods to be used in feasibility investigations or performance monitoring for in situ leaching of ore deposits. Geologic settings of leachable deposits are discussed, as well as representative techniques used for the in situ leaching operation. Subsurface investigation techniques including drilling, core recovery, and down-hole inspection methods relevant to field permeability investigations are discussed. Field experience is examined and capable field permeability test methods are identified. Specifications for test borehole preparation, test performance. and methods of analysis are given. The test methods are comparatively rated in a matrix with respect to costs ease of use, and data effectiveness' for a broad range of conditions. Well Pump and Packer test methods receive high ratings. Recommendations are made for needed developments in field permeability test methods and a comprehensive bibliography is given.

Jan 1, 1977

By Spencer P. Howell, J. F. Xrawshaw

"A recent premature explosion in a quarry that resulted in the death of nine men and the injury of several others, was directly traceable to a spark from a steam-shovel working under the face directly in front of the hole being loaded. This accident and similar accidents on record in the Bureau of Mines indicates the necessity for pointing out the dangers in quarries of explosives being ignited by sparks emitted from steam shovels and locomotives, and making recommendations for greater safety.Many premature explosions of which the following are examples, have resulted from sparks, both from steam shovels and passing locomotives. (A) The premature explosion occurred during August, 1920 at a limestone quarry, in a 100-foot drill hole, loaded with 1000 pounds of high-grade nitroglycerin and gelatin dynamites. This hole had been loaded with 500 pounds of 75 per cent strength gelatin dynamite, 300 pounds of 60 per cent straight nitroglycerin dynamite, and 200 pounds of 50 per cent straight nitro¬glycerin dynamite; but no steaming had been placed in the hole. The powderman loading the hole saw the spark enter the hole and was able to run a short distance before the explosion took place, thus escaping serious injury. The explosion of this first hole was transmitted to nearby hole similarly charged. The fall of rocks from these two holes buried the steam shovel and some of the gang of men working around it.(B) In September, 1909, in the Canal Zone, a steam shovel uncovered a misfired charge of dynamite. While the dynamite was being picked up the steam shovel continued working nearby. A spark from the shovel set fire to some loose dynamite spilled on the ground from the troken cartridges. This fire was transmitted to a hole which was being loaded close by and caused a premature explosion. One man was injured."

Nov 1, 1920

By E. D. Eastman

"The factors that determine the efficiency of reduction of iron oxides by gaseous reducing agents may be considered in two classes; those which effect the equilibrium between the reacting substances end their products, and those which affect the rete of reaction. Both sets are of prectical importance, the former as influencing the maximum possible efficiency and the latter as determining what fraction of the maximum yield may be readily or profitably obtained. In addition, the thermal changes attending the reduction greatly affect the chance of successful industrial application of any such process, and knowledge of them is necessary for the intelligent design of apparatus and control of the reaction. Some aspects of each of these three divisions of the problem are discussed below.I. The Maximum Reducing Power of Fuel Gases on the Oxides of IronsThe gases that heve been considered specifically in this work are coal gas, water gas and producer gas, typical analyses” of which are given in Table 1 Of the various hydrocarbons represented in Table 1, (several being grouped or averaged as C2R4), methane is the only gas assumed to be capable of existence at appreciable pressures under the conditions of interest here. The equilibria in the several systems which may ensue when one of the above gases is allowed to react with the iron oxides, may therefore be represented in the most general case by equations of the type of the following arbitrarily chosen ones:"

Jun 1, 1923