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By Qingming Feng, Dongbo An, Jinhong Zhang

The application of the geopolymerization of mine tailings as construction materials is hindered by the fact that conventional geopolymerization of mine tailings usually involves a large consumption of alkali, i.e., sodium hydroxide (NaOH), and a long curing time, because of the relatively low reactivity and the high Si/Al ratio of mine tailings when compared to other active resources such as fly ash and clay minerals. The present study is focused on efficiently activating mine tailings, reducing alkali consumption, decreasing curing time and improving compressive strength. We firstly investigate the temperature effect on the alkali activation of mine tailings during geopolymerization. Secondly, the impact of additives, i.e., calcium hydroxide and aluminium oxide, on the compressive strength of samples is studied. Thirdly, different forming pressures have been applied to remove excessive alkali and its impact on samples' strength has been investigated. The results show that a 40 MPa unconfined compressive strength (UCS) can be achieved with the geopolymerization samples after mine tailings are activated by sodium hydroxide at 170°C for 1 hour with the addition of calcium hydroxide and alkali dissolved aluminium oxide, further compressed with a 10 MPa forming pressure and finally cured at 90°C for 3 days. The findings of the present work provide a novel method for the geopolymerization of mine tailings as construction materials.

Jan 1, 2014

By B. A. Kutlin, S. A. Ropeyko, N. A. Yurlova

"The aim of NPO RIVS research and practice activities is to minimize impact of the mineral processing plants (MPP) on environment by using new concentration methods, high-technology equipment, implementation of engineering solutions directed to reduce emission of polluting substances (PS) into atmosphere, application of low-waste technologies, decrease of water withdrawal from a surface water or groundwater source for process needs. In our studies environmental safety of mineral flotation is provided through technologies using highly selective chemicals, that leads not only to reducing reagent consumption, and production of saleable products of high content of extracted minerals, but also to reducing pollutant emissions, decreasing supply of surfactants (SAA) in natural geosystems, primarily, in ground and surface waters. Decrease of water withdrawal from a surface water or groundwater sources for process needs can be achieved by using closed circuits and waste water treatment for further use in process operations, recycled water conditioning to obtain optimum quality parameters for process operations of concentration. Concentration in water (wet processing), tailings dewatering and semidry and dry (filtration cake) stockpiling in tailing ponds, efficient dust-collecting systems contribute to pollutant emission reduction. Use of mineral wastes – concentration tailings as a source of valued components, facilitates efficient use of natural resources and reduces wastes and its impact on natural ecosystems due to smaller areas of damaged lands during waste products disposal. Process and engineering solutions of NPO RIVS that allow diminishing impact of MPP on natural environment (NE) have been implemented in mining and processing complexes of Russia, Kazakhstan, Ukraine, Kirghizia and Mongolia. Compliance with environmental safety requirements contributes to enhancement of mineral processing and sustainable mineral development.INTRODUCTION Mining and processing complexes have a significant impact on environment as a result of extraction and recovery of mineral resources, landscape changes, waste disposal and, as a consequence, pollution of soils, surface and underground water sources. Therefore, the aim of the operation of the mineral processing enterprises in its research and practical activities is to reduce impact on environment due to new beneficiation technologies, high-technology equipment, implementation of engineering solutions directed to reduce emissions of polluting substances (PS) into atmosphere, use of low-waste technologies, decrease of water withdrawal from a surface water or groundwater source for process needs. Compliance with the requirements of environmental safety encourages advancement of mineral processing technologies and sustainable mineral development. Concentration in water, tailings dewatering and semidry and dry (filtration cake) stockpiling in tailing ponds, efficient dust-collecting systems contribute to pollutant emission reduction. Use of mineral wastes – concentration tailings as a source of valued components, facilitates efficient use of natural resources and minimizes waste formation and its impact on natural ecosystems due to reduction of damaged land areas during waste disposal."

Jan 1, 2018

By Wantae Kim, Hoon Lee, Kwanho Kim, Sangbae Kim

Mechanochemical activation of starting minerals and their effect on the solid-phase synthesis and properties of ceramics with lower thermal expansion coefficient was examined. The mineral mixture, pyrophyllite-gibbsite-lithium carbonate, was prepared for the synthesis of ?-eucryptite (Li2O•Al2O3•2SiO2). Dry grinding using a planetary ball mill promoted the amorphization of the starting mixtures. XRD and FT-IR results showed that the crystallization of the target materials occurred from the ground mixtures by calcination. The crystallization of them increased with increment of grinding time and calcination temperature. In the synthesis, the trace of undesired phases such as quartz and cristobalite once formed during calcination at the temperature range from 750 to 850 °C almost disappeared and monophase ?-eucryptite was formed in the ground mixture at 950 °C. The lowest liner thermal expansion coefficient (TEC) of ?-eucryptite prepared was -2.5x10-6•°C-1. The thermal expansion behavior characteristics of the calcined

Jan 1, 2014

By Sergio Castro, Janusz Laskowski

In the flotation in highly concentrated electrolyte solutions not only ionic strength but also chemical composition, flotation pH and mineral properties play an important role. As a result an improvement or depression may be observed. A strong improvement in the floatability of hydrophobic bituminous coals and other inherently hydrophobic minerals is characteristic for the "salt flotation process", which is carried out in concentrated electrolyte solutions at natural pH and without addition of any flotation reagents. However, pH is a key factor when saline and hipersaline waters with hydrolyzing metallic ions are used as process water. In the case of flotation of Cu-Mo sulfide ores in seawater, molybdenite is strongly depressed by the Mg2+ hydrolysis products when pH is raised to depress pyrite. Process water with a high content of Mg2+ and Ca2+ ions, and this also includes seawater, have deleterious effect on the anionic flotation of industrial minerals with fatty acids. The flotation of potash ores is carried out in NaCl-KCl saturated brine (6-7 mole/L of NaCl and KCl) with the use of long-chain amines. Such a high electrolyte concentration changes dramatically the amine Krafft point making the collector insoluble in brine; its mode of action entirely differs from that in conventional flotation processes.

Jan 1, 2014

By C. L. Xiao

With reference to the test report carried out by Guangzhou Nonferrous Metal Research Institute in 1983, the mineral process flow sheet of Yichun Tantalum-niobium mine is determined based on the characters of ores and successful experiences in light of the problems in the existing flowsheet: The ore is desilted before crushing; the primary slime is separately treated; the staged grinding process used while the fine slime is collectedly treated with tantalum and niobium as the main recoveries and lepidolite and feldspar powder as the secondary. The flowsheet is featured by comprehensive recovery, low investment and low energy cost.

Jan 1, 2014

By Valentine Chanturiya, Irina Khabarova, Maria Ryazantseva, Igor Bunin

"XPS investigations of the influence of HPEMP - treatment duration on the surface composition for natural chalcopyrite and sphalerite are described. HPEMP is a video pulse with a nanosecond front lasting between 5 and 10 ns. The electrical field component can reach 30 kV, whereas pulses repetition frequency is 100 Hz. In general, the formation of metal-deficient surfaces, polysulphides or elemental sulphur and oxides/hydroxides, were determined during the treatment for both sulphides as well as the essential differences of the way of mineral surface transformation during the treatment. The chalcopyrite surface shows the formation of elemental sulphur under the HPEMP treatment at 103 pulses while appearance of unstable sulphite species was detected at the chalcopyrite surface within 5 seconds (0.5•103 pulses) under the same treatment conditions. The results indicate that the quantity of adsorbed water (at.%) is changed considerably during the HPEM - treatment depending on treatment duration for both minerals. The concentration of water onto the chalcopyrite surface decreased during 30 seconds (3•103 pulses) of the HPEMP - treatment and it rose after the treatment at 5•103 pulses. The inverse dependency was obtained for sphalerite surface. Single mineral flotation tests have shown the significant increasing of the minerals recovery."

Jan 1, 2014

High flotation of iron sulfide minerals at high pH values in copper ores is mainly due to the activation of these minerals by copper species dissolved from copper sulfide minerals during grinding. Several methods have been tested to reduce this copper activation during grinding and therefore to depress iron sulfide flotation. They include grinding the minerals at high pH values or with a less reactive medium such as high chrome, and addition of a thiol collector or copper complexant during grinding. The efficacy of these methods in the flotation of a copper ore was tested against more common methods of depression of iron sulfide flotation. The mechanism of iron sulfide depression in these methods was also investigated.

Jan 1, 2014

By S. Banisi, A. Ghasemi, S. Zare, F. Ghorbani, E. Nematollahi

"Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Working at the maximum operating capacity of comminution equipment plays a significant role in the efficiency of the circuit. Appropriate design of cone crusher feed box could result in the choked crushing which is known as a vital factor in achieving target performance. In this research, the non-uniform cone crusher feeding at the Sarcheshmeh copper complex was studied and appropriate measures were taken to solve the problem. The problem resulted in non-uniform and high wear rate of crusher liners and high fluctuations of power draw. In recent decades, the discrete element method (DEM) has been applied successfully to study the effect of different factors on the behavior of particles flow. In this work, various designs for feed box were tested using an in-house developed DEM software called KMPCDEM©. The best feed box design obtained from the simulations was selected, constructed and installed in of the cone crushers. The new feed box design resulted in more uniform feed distribution on the distributor plate of crusher indicated by a reduction of the standard deviation of power draw measurements from 13 to 3 kWh. The better control of the crusher, 49% increase in the crusher throughput and finer and narrower product size distribution were the main outcomes of the installation of the new feed box. Furthermore, the wear rate on mantle and liners of crusher not only decreased but it also became uniform.INTRODUCTION Comminution is the most energy intensive operation which constitutes the major portion of operating and capital costs of the mineral processing plants. Reaching the maximum operating capacity in comminution equipment is a key sign of approaching the nominal productivity of the process. Due to the effect of crusher efficiency on the downstream circuit performance, optimization of the crushing circuits has received considerable attention (Herbst, & Potapov, 2004; Quist, & Evertsson, 2010; Li, Huiqi, McDowell, Glenn R, Lowndes and Ian, 2014; Cleary, Sinnott, Morrison, Cummins, & Delaney, 2017). Improving the performance of crushing circuits not only decreases the capital and operating costs but also increases the efficiency of downstream grinding circuits (Jacobson, Janssen, & Urbinatti, 2010). In cone crushers particles can be subjected to two different modes of compressive breakage; single particle breakage (free feeding) and inter-particle breakage (choked feeding). The maximum efficiency of the cone crusher directly depends on the type of feeding arrangement (Operation Manual, 1977). An appropriate feeding must lead to choked feeding the cone crusher. If the rate and method of feeding the crushers are correctly be executed, the maximum efficiency of the crushers could be available (Jacobson et al., 2010)."

Jan 1, 2018

By M. Brozek

The particle settling velocity is the argument of separation in such processes as classification and enrichment in jigs. It characterizes material forwarded to the separation process and belongs to the so-called complex arguments because it is the function of particle density and size. i.e. the function of two simple arguments. The affiliation to a given subset is determined by the values of two mag-nitudes and the distribution of such argument in a sample is the function of distributions of particle density and size. The paper will present a method of determining the distribution of settling velocity in the sample of spherical particles for the turbulent particle motion in which the settling velocity is expressed by the Newton formula. Because it depends on density and size of particle which are random variable of certain distributions, the settling velocity is a random variable. Applying theorems of probability, concerning distributions of function of random variables, the authors will present general formula of probability density function of settling velocity for the turbulent motion and particularly calculate probability density function for Weibull?s forms of frequency functions of particle size and density. Distribution of settling velocity will calculate numerically and perform in graphical form.

Jan 1, 2014

By Brian Loveday, Sandile Nkwanyana, Indresan Govender

"Recent batch experiments by the authors in a pilot scale ball mill (Ø = 0.6m) have demonstrated that a partial replacement of the ball charge by pebbles (25 % pebbles; 75 % steel balls) optimally reduces the ball and power consumption without altering the rate of production of fine material (passing 75 microns). At higher pebble volumes, the production rate of fines was reduced progressively. With the 25/75 composite charge a saving of 13 % in power consumption was achieved, and a saving of 25 % in steel ball consumption is implied. A partial replacement of steel balls by pebbles reduces the overall density of the grinding media in the charge. Taking into consideration that the production rate of fines is usually proportional to the bulk density of the charge in the mill, it would be expected that a composite charge (e.g. 25/75) would coarsen the grind and consequently reduce the rate of production of fines. Pebble wear contributes a small proportion of fines and it doesn’t provide a full explanation of why the 25/75 composite charge has no (or minimal) adverse effects on the rate of production of fines. Clearly, the production of fines across the mill is directly related to the shear and compressive power dissipation density. Accordingly, we hypothesise that the spatial power dissipation distribution meeting the minimum requirements for fines production— at the so-called active regions—are equivalent, or minimally comparable, for both the 25/75 composite and 100 % ball charge operating conditions. To test the hypothesis, we performed DEM simulations to analyse power dissipation in the active regions. 1. INTRODUCTION Comminution remains to be the most expensive process in mining operations, particularly because the energy consumed in this process accounts for 30-70 % of the total cost of a mining operation (Nadolski et al, 2014). Optimization of comminution circuits has been focussed on reducing capital and operating costs and maximising throughput capacity. For existing operations, it is often a challenge if the optimization process recommends retrofitting new ‘major’ equipment. The challenge arises from new capital cost and the difficulty of retrofitting in an existing circuit, while maintaining production (Major et al, 2001). Thus, for existing mining operations, optimization of comminution (cost and throughput) is often limited to operating conditions and/or addition of auxiliary equipment (such as pebble crushers, additional screens and high pressure grinding rolls (HPGR)) (McIvor and Greenwood, 1996; Hart et al, 2001; Powell et al, 2015b)."

Jan 1, 2018

By M. Niinae

Electrokinetic soil remediation by electroosmosis and ionic migration is restricted to soluble sub-stances. At a higher pH, the soil particles sorb more heavy metals, such as cadmium, than at a lower pH and the precipitation reactions of heavy metals are promoted. Both mechanisms make heavy metals immobile, rendering clean up more difficult and electrokinetic extraction inefficient. There-fore, the acidification of soils is very important to increase the clean up efficiencies of heavy metals, such as cadmium by electrokinetic method from contaminated soils. In the present study, acidification of soils and cadmium transport are predicted with a numerical method in which electrical flow is coupled with hydraulic flow, and the sorption process in the soils is induced in the model. The effects of some factors such as electrode configuration, electric field strength and electrode spacing for saturated soils are investigated using this numerical model. The results obtained this study are summarized as follows: The two-dimensional electrode configurations containing cathode surrounded by three or more anodes rapidly acidify the soils and remove cadmium from soils compared with one-dimensional electrode configuration. However, two-dimensional electrode configurations develop spots of inactive electric field between cathodes. A larger electrode spacing increases the processing time required, and it was also found that a larger electric field strength reduced the processing time required.

Jan 1, 2014

By Kaustubh Joshi, Pradip, Beena Rai, Venugopal Tammishetti

"Rapid depletion of high grade iron ores coupled with the increasing demand for the blast furnace grade iron ore in recent times has shifted the research focus on the development of appropriate technologies for the utilization of low - grade alumina rich iron ore slimes. These slimes are currently being dumped into tailing ponds owing to their high alumina content. Typical constituent minerals present in the Indian iron ore slimes are hematite, goethite, gibbsite and kaolinite. Considering the fine particle size distribution (<37 microns) in the slimes, selective dispersion-flocculation seems to be one of the most appropriate process which has been explored by us. We present our successful results on a natural iron ore slime sample obtained from one of the mines in India. We have been able to achieve a concentrate assaying >67% Fe, and <3% Al2O3 and 2.8% loss on ignition (LOI) from the slime sample assaying 60.4% Fe, 7.7% Al2O3 and 5.45% LOI with an Fe recovery of 62-69% simply by adjusting the pulp pH. We have scaled up the process to a semi batch scale as a prelude to commercialize it for the beneficiation of low grade iron ore slimes."

Jan 1, 2014

By E. V. Zelinskaya

"Mineral and industrial raw material mining and preparation make a negative impact on the environment. The main types of impact are the land resources gathering, soil and water balance disturbance, surface-water, underground space and atmospheric air pollution, as well as the vast amount of solid and liquid waste production. Considerable attention in recent decades has been given to waste recycling. The task is to maximize the use of both newly formed and accumulated solid and liquid wastes. The mining and mining and smelting enterprises industrial waters are a very promising source of secondary hydromineralic raw materials. They have high concentrations of not only calcium, sodium, but also, for example, lithium, rubidium, heavy non-ferrous metals. In general, unfortunately, we have to state that today there is no wide practice of extracting valuable components from waste enrichment, as well as processing of man-made waters to extract metals from them. The quantity of extracted components from underground, and furthermore passing waters, is insignificant. At the same time there is a tendency to increased demand for rare metals: Sr, B, Br, I. This is explained by their wide use in many industries. For example, the consumption of lithium products is steadily increasing. The obtained results showed that in the liquid phase in connection with high salt content and a significant difference in the macro- and microcomponents contents, conditions are initially created for the microcomponents selective isolation possibility. The identified conditions realization is most possible in such technological processes as cryotechnology, sorption and ion flotation. There is an urgent need to expand research in this direction and to recognize as a publicly important task the mining and industrial waste processing full-scale introduction into the practice of operating mining and processing enterprises and iron and steel companies.INTRODUCTION Mineral and industrial raw material mining and preparation make a negative impact on the environment. The main types of impact are the land resources gathering, soil and water balance disturbance, surface-water, underground space and atmospheric air pollution, as well as the vast amount of solid and liquid waste production."

Jan 1, 2018

By Sarthak Kaushik

Zeta potential measurements show that the isoelectric point of crandallite, in aqueous solution of 10-2 N sodium chloride is at about pH 5.5. Measurements of turbidity confirm the point of zero charge or crandallite. Calcium ions specifically adsorbed on the surface and thus changed the zeta potential and turbidity. From the measured data, it is confirmed that starch acts as a flocculent for crandallite. Oleic acid, which is a collector used in phosphate ore processing is weakly adsorbed on the surface of crandallite. This results in hydrophobic coagulation of particles resulting in a lower turbidity.

Sep 1, 2012

By Mario Gerards, Sergej Podkow, Marco Steinberg

"The JONES® WHIMS technology is based on the magnetic separation process and is widely used for the recovery of magnetically susceptible iron ore particles. The conventional machine design is well-known within the iron ore beneficiation industry for more than 50 years and recognized to be highly reliable, robust and extremely compact with the advantages of high capacity and selectivity. In 1981 Rana Gruber AS, Norway bought 14 JONES® WHIMS DP 317 separators when the magnetic separation plant was built and erected. Today, 11 of these old machines are still operating profitably and efficiently. The former supplier was the coal and minerals division of Klöckner-Humboldt-Deutz (KHD) which is today MBE Coal & Minerals Technology GmbH (MBE). This paper outlines a detailed description of the project of revamping the above mentioned old machines and describes the challenge of incorporating enhanced and newly developed technology into an existing processing plant. Further it gives an overview of the recent developments on the design of the JONES® WHIMS. In order to meet modern product requirements and to increase and secure plant productivity, in 2012 Rana Gruber AS settled a contract covering two new designed JONES® WHIMS DP 317 HFR separators to be implemented into the existing building and the upgrading of all 11 older JONES® WHIMS under the use of as many refurbished items as possible. The two new machines were fully developed by the product specialists of the supplier in cooperation with the operator Rana Gruber AS, thereby taking advantage of their great experience. The design of the new machine is based on the conventional design, i.e. the general operating mode as well as the overall dimensions are identical. Finally this paper gives an overview about the erection and commission phase of the two new machines and gives a detailed comparison between conventional and enhanced WHIMS technology."

Jan 1, 2014

By Masanori Mori, Hajime Miki, Osamu Ichikawa, Tsuyoshi Hirajima, Mitsuru Sawada, Keiko Sasaki

For pretreatment of selective flotation, surface oxidation of chalcopyrite and molybdenite was applied by oxygen plasma then the minerals were washed by solution at pH 9 with oxygen bubbling. Surface characteristics of these minerals were investigated with AFM, XPS, zeta potential and contact angle measurements. Contact angle of chalcopyrite and molybdenite decreased a lot by plasma treatment. When they were washed with pH 9 solution with oxygen bubbling, contact angle of molybdenite increased whereas chalcopyrite one kept low. Adhesion force measurements indicated similar behavior. Result of flotation experiments indicated low recovery of both chalcopyrite and molybdenite after plasma treatment and only molybdenite recovery became higher after washing. Selective flotation of chalcopyrite and molybdenite could be achieved with this process. Possible mechanism of selective flotation was proposed from the results of XPS, AFM, etc.

Jan 1, 2014

By Andrey V. Yevdokimov

The results of the test work on gold leaching using high strength of cyanide solution in the presence of activators are presented. The major physical and chemical relationships of gold leaching were determined. Intensive cyanidation results of gravity concentrates with various material compositions using an activator are given. Process design criteria for intensive cyanidation unit were developed on the base of pilot plant test results. Keywords: gold, activators, intensive cyanidation, gravity concentrates

Sep 1, 2012

By T. Neesse

In many cases, the use of hydrocyclone control is desirable for the stabilization of separation in the setting of changing feed conditions. Control concepts based on exact mathematical models are not satisfactory due to the complexity of the physical process. In this case, fuzzy control is a suitable solution. The data are primarily derived from an optical sensor that monitors the outside view of the free underflow stream. A throttling valve, serving as an actuator, is installed in the overflow pipe that regulates the volume split of the cyclone. Applications in closed circuit grinding and in separation plants for tunnel driving, fine sand dewatering, and classification of kaolin demonstrate the typical use of this development. Additionally, the technological characteristics of the cyclone may be improved by this control, which is mainly caused by the increased discharge capacity of the un-der flow nozzle. A further advantage is the option to operate at an optimal operation point. In many cases, this point is located at the transition spray/rope discharge. The improved operation characteristics present new options for extensive applications of fuzzy cyclone control.

Jan 1, 2014

By Zoran S. Markovic

The extensive laboratory investigations were carried out in order to determinate behavior of sulphide and nonsulphide copper bearing particles during the flotation. The present ore sample were contained 0.55% Cu with 20.1% of nonsulphide copper in it and gangue material with higher contents of alumina about 19.07%. In this paper will be presented some results such as: effect of particle size, pH and applied collectors. The main goal was in application of collectors S-7518, as well as mixture of KEX and Z-96. Z-96 is a product from Chemical Industry Zupa Krusevac which was used as auxiliary collector in mixture with xanthates. The best results were done with this mixture in ratio KEX / Z-96 as 77/23 % in area of oxidized minerals flotation, but the collector S-7518 was achieved better results in sulphide mineral flotation. The S-7518 has better selectivity between copper minerals and pyrite comparing to mixture of KEX/Z-96 in mentioned optimal ratio. Flotation recovery and copper grade in concentrate were studied by flotation kinetics tests.

Sep 1, 2012

By Z. F. Hu

Tourmaline has the characteristics of piezoelectricity, thermoelectricity, spontaneous polarization and far-off infrared radiations. Ultra-fine powders of tourmaline have extensive applications in the fields of electron, chemical and environment protection, as well as health protection. The preparation technology of ultra-fine tourmaline powder is discussed. The key equipment of a pilot plant for producing ultra-fine tourmaline powder with jet mill and stirred ball mill is described. Using this pilot plant facility it is possible to produce tourmaline powder with particle size smaller than 100 nm, and a continuous production process can be realized. The final powder product has many superior performance such as high whiteness and large specific surface area, and it?s a negative ions emission can reach the value of 7190 ions per cubic centimeter.

Jan 1, 2014