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By U. Troncoso

Mantoverde is a heap leach-SX-EW operation that was commissioned in December 1995 at a production rate of 42,130 ton of copper per year and 5.4 million ton of ore per year. Copper production has been steadily increased to reach 62,000 ton in 2005. The forecast copper production for 2006 is 60,300 ton for an ore treatment rate of 9.5 million ton. A first dump leach operation was started in 1999 at a production rate of 1,922 ton of copper. A second dump leach operation was started in early 2002 at a production rate of 2,805 ton of copper. Dump leach production will be increased over time to as much as 24,000 ton of copper. Several improvements in the heap leach process have been implemented to cope with the higher ore throughput and copper production. However, the solvent extraction plant has remained unchanged which has resulted in a lower availability of raffinate solution and, as a consequence, in longer leach cycles. Different studies have been undertaken in order to optimize the solution management system at Mantoverde, including column test work aimed to reduce the leach cycle and solvent extraction plant modifications aimed to increase the raffinate solution availability. The test work program and the economical evaluations carried out, as well as the conclusions and recommendations obtained, are discussed in this paper.

Jan 1, 2007

By G. M. Humphrey

It is a great honour and privilege to be here in this distinguished company of the outstanding men in the mining industry and the political life of Canada. I fully recognize that I am so honoured as a symbol of the combination of American and Canadian leaders in industry who are partners in the sponsor-ship of the Quebec-Labrador iron-ore mining development which we are undertaking, and as such I want to express our great appreciation of the co-operation and assistance we have met on every hand in Canada, and the genuine friendliness and never-failing courtesy which we are always accorded. We are quite aware that it springs primarily from the very high regard in which our partner and sponsor, Jules Timmins, and our other Canadian associates are held. Their high standing among you is well known and we quite naturally fall heir to the benefits of the great esteem in which you hold them. Jules Timmins and his long-time associate, John Knox, were the original inspiration for our participation in this venture. It was their enthusiasm and vision which caught our interest and led to our joining with them in the years of exploration and search which have brought us to the threshold of this great development where we stand today. So much has been written of the details of our exploration and plans for future development that it would bore you for me to review them further here, but there is a phase of this development, and an extremely important phase of it, which I think has passed almost unnoticed and which it may be well worth while for me to bring to your attention this evening.

Jan 1, 1951

Post--Crunch Financial Management -An Overview A. The Industry and the Capital Markets B. .The SME -De-risking the Current and New Assets Followed by: C. The Lender?s Perspective on Re-financing?Jeff Stufsky, BNPParibas, NYCD D. .The Agency/Export Credit Lender Perspective?Doug Macaulay, EDC, Ottawa E. The Foreign Political Insurance Perspective?Pierre Vieillescazes, Carrick-Bend, Washington, DC ?Four Fundamental Metal Models No Longer Prevail. ?Mining is in new ?waters?: so be prepared (next page). ?Capital markets are uncertain-so be your own financier first ?If tight capital may remain, prepare to triage based on cash-flow production (not oz, lbs, tonnes, etc) ?Know your banker/financier(and it should know mining) ?In the past, it was ?know your borrower? ?The climbing team can fall if one climber carries too much ?Constantly re-assess the risk matrix (and j/v?s), and ?De-risk/diversify both the asset and the capital base

May 1, 2010

By Z. Xie

Gas diffusion electrodes (GDEs) for high temperature polymer electrolyte fuel cells (PEFCs) have been prepared using ZrP-modified Nafion ionomer. The performances of these GDEs as cathodes and anodes were evaluated and compared with conventional Nafion ionomer GDEs using Nafion 112 as the PEM under elevated temperature and reduced relative humidity. ZrP-modified Nafion ionomer was incorporated into the catalyst layer to enhance water retention and/or increase the protonic conductivity. The fabrication of ZrP-GDEs was implemented by the ion exchange of Nafion solution with zirconyl chloride, followed by the impregnation of GDEs in H3PO4 solution. The composite electrolytes in the catalyst layer possessed a ZrP content of 20% by weight. GDEs were characterized by TGA, SEM, XRD, and CV. Scanning electron microscopy (SEM) indicated evenly distributed elemental Zr and P within the catalyst layer. Cyclic voltammetry shows a reduced electrochemically-active surface area when the ZrP is incorporated into GDEs. Polarization and impedance analyses indicate the cathode with ZrP-modified Nafion ionomer did not show an enhanced or decreased performance, compared with conventional Nafion ionomer GDEs under elevated temperature and decreased humidity. However, when GDEs with ZrP¬Nafion ionomer were used as the anode, an improved performance was observed. Preliminary experiments show that the anode is more sensitive to dehydration than the cathode under elevated temperature and/or low humidity. Improving the anode water retention capability will help to reduce losses at the anode. However, the incorporation of hygroscopic agents in the cathode catalyst layer is not essential because it is self-humidified by electrochemically-produced water even under elevated operating temperature and lower humidity.

Jan 1, 2005

By F. W. Gray

Foreword: It is not my purpose, in this address, to write the history of the Geological Survey of Canada, which has from time to time been reviewed by the officers of the Survey itself, and by men more competent than myself to handle so large a subject, but rather to set out some of the reasons for the regard in which the Survey is held by our Institute, the body best qualified to speak for the mining men of Canada. And, a further purpose is to publish the desire of our Institute that the work of the Survey shall be maintained at the highest pitch of efficiency the resources of our country. will permit, because to scrimp expenses on the Survey is 'to save at the spigot and lose at the bunghole." A historical examination of the grounds on which it may be asserted the Geological Survey has been, and still is, of fundamental economic value to our country, discloses a prescience on the part of the forefathers of Canada, calling for our admiring gratitude, and reveals a unanimity among the real leaders of Canadian thought, on the value of geological knowledge, that is impressive in its continuance dawn to this date. There seems always to have been before our people the realisation that large stretches of Canada are unfitted for agricultural settlement, and that our glaciated areas, the barrens and tundra of the North, and our extensive mountain ranges, had promise of compensating mineral content which the geologist and the prospector, labouring together through the years, would disclose. The Geological Survey is one of Canada's oldest public services, distinguished by an unimpaired tradition of honourable and useful labour. Founded in 1843, under William Edmond Logan, not yet 'Sir William', one year after the Act of Union, it was directed by him until 1869, or into the early years of Confederation, so that the early years .of the Survey were also, politically, the formative years of Canada, as we know her today.

Jan 1, 1932

By Warnett Kennedy

"GENUINE CONCERN for the environment is a built-in attitude of mind. If you do not have it by age 40 you probably never will. Some people speak the jargon of 'environment' and 'ecology' for political reasons, others because it feeds their need and bias toward attitudes of moral indignation or dissent. Others pay lip-service for purely business reasons. Complete reactionaries equate conservationists, ecologists and environmentalists as either 'commies' or 'pinkos'. Their real credo is the old saying, ""Where there's muck there's brass."" Those who have genuine concern for good environment are not only romantics like Thoreau but realists who sense the danger to our planet if human greed is rampant and unchallenged. The cities are in real trouble. Almost 75 per cent of the population already live in and around cities. Even mining men live in cities or bring up their children in the new 'instant' towns. The ecology of cities is the concern of all. Our distinguished guest Stewart Udall, in his book ""The-Quiet Crisis,"" quoted Thoreau in 1859 as having written ""each town should have a miniature wilderness park, a primitive forest of five hundred or a thousand acres where a stick should never be cut for fuel, a common possession forever."" Mr. Udall will be glad to know that this advice was taken in at least one instance known to me. I refer to Stanley Park in Vancouver. It is a primitive forest of 1000 acres right inside our small downtown peninsula. It remains unmanicured. This month we celebrated the completion of a seawall of 4%, miles along its perimeter. The construction of this wonderful walkway started in 1910. We are very, very proud of our park."

Jan 1, 1972

By A. B. Isaeva, A. Yu. Lein, A. A. Karpenko, V. V. Serova, A. P. Lisitzin, V. Yu. Rusakov, V. N. Lukashin

Abstract - The flux of sediment matter was determined using sediment traps near a black smoker ("Saracen’s Head," Broken Spur hydrothermal field) and the mineral and chemical compositions of the settled matter were examined. The metallic minerals are represented by Fe sulfides (pyrite and pyrrhotite), and Cu and Zn sulfides are also found in small and equal quantities. The hydrothermal suspended matter contains abiogenic calcite in amounts comparable to that in Ca sulfates. The content of silica and, specifically, of amorphous Si is unusually low. Such correlations between chemical elements and minerals, together with the isotopic compositions of S and C, are characteristic of a relatively young and active stage in the evolution of a hydrothermal system. Sediment traps within and under neutrally buoyant hydrothermal plumes collected biogenic material in addition to hydrothermal components. Microbial chemosynthetic production of organic carbon near the hydrothermal vent is comparable to primary production in the euphotic layer. Fe, Zn, Ca, Si, Ba and P are enriched in particulate matter in comparison to the background. A vast compound plume containing the discharge of multiple hydrothermal vents was found to the south of the Broken Spur hydrothermal field.

Jan 1, 1999

By A. C. Stevenson

"There are many critical application issues that affect all AC drives, but there are several that are absolutely mandatory for pulse width modulated (PWM) AC drives. If these rules are not followed, the drive system will have insulation, bearing EMI or noise problems. Pulse Width Output VoltageFigure 1 shows the output current of a typical pulse width modulated (PWM) drive. This is, of course, not a clean sine wave thus will have a lot of very significant harmonics. In fact, the harmonic spectrum is directly related to multiples of the carrier switching frequency plus side bands related to the basic output frequency. A typical spectrum for a PWM source bridge switching at 5 kHz is shown in Figure 2. Notice that the spectrum has multiples of the 5 kHz switching frequency and the number of side bands gets larger as the harmonic number increases.IGBT Switching TransientsWhenever we have PWM inverter switching, voltage transients are formed that propagate (usually at about half the speed of light) down the power cables to the motor just like in a radio frequency transmission line. If we do not terminate these transmission lines (motor cables) properly, the voltage pulses will be reflected when they reach the motor end and will be transiently increased up to twice their original amplitude.This transient voltage rise, shown in Figure 3, is important for three reasons:1. Insulation Voltage Stress — Higher voltage stress in the motor connecting cables and motor insulation will lead to a shorter insulation lifetime. If any of the voltage transient peaks exceed the insulation corona discharge level (partial discharge level), the insulation will gradually degrade with each voltage pulse. When it has been sufficiently degraded, it will then fail.Most new “inverter rated” motors have triple layer insulation which has a 1600 to 2000 volt partial discharge level. This will make them suitable to withstand the double voltage peak transient from a 600 volt inverter. It is wise to make sure of this fact, since a “standard” induction motor will only withstand about 1200 volts. Use of a standard motor in this application would shorten its life drastically. This can sometimes be as little as a matter of hours."

Jan 1, 2000

By J. Drelich

We report structural forces measured for 10 nm silica particles deposited on alumina substrate and 5-80 nm alumina particles on mica using atomic force microscopy technique. For nanoparticles forming clusters, oscillation of structural forces was recorded with a periodicity that is close to the size of the nanoparticles used. Additionally, selected force-separation results indicate that the forces involved between the AFM probe and individual nanoparticles can be studied using the nanoparticle-coated substrates.

Jan 1, 2006

By L. Chunpongtong

The Athabasca oil sands mineable resource is located in northeastern Alberta, Canada. In oil sands mining, the ore zone is regulated to have a minimum mining thickness of 3 m and a cutoff grade of 7 wt.%. The current algorithm that is widely used to flag ore zones and waste zones tends to overestimate oil reserves and causes low-grade ore to be processed. This paper presents the development of a more complex algorithm that is more representative of the actual oil found during operations and that can prevent low-grade ore from being sent for processing.

Jan 1, 2014

By D. W. I. Griffiths, J. C. Bélanger

"La Division Matagami de Minéraux Noranda inc. a profité de la construction de sa nouvelle mine (Isle-Dieu) pour continuer sa modernisation.L'utilisation d'automates programmables (PLC) s'est intensifiée pour contrôler et automatiser de plus en plus d'équipement dans ses minessouterraines, au concentrateur, dans les atelierset bureaux.Tous les PLC comrnuniquent entre eux et les IBM PC sont utilisespour exterioriser l'information et faire Ie lien entre Ie personnel et les automates. Le système Central IBM 36 emmagasine les donnees traitees par lesPLC (a travers les PC). Ces donnees sont transmisesau programme d'entretien de chaque equipement et compile les heures, cycles, tonnes, etc., fait imprimer automatiquement les feuilles d'entretien préventif ', etc.Les principales realisations adate et en progrès pour la mine Isle-Dieu sont:• automation complète du système de remblayage du concentrateur ala mine Isle-Dieu situee a2 km de la mine principale;• automation du fonctionnnement des ventilateurs qui comprendra la position des portes de ventilation, Ie chauffage, Ie débit, etc.;• automation des pompes, surveillance des sous stat ions électriques, concentration des gas (CO, SO2) à chaque niveau en tout temps et du propane à l'entree d'air frais;• tonnage et cycles par Ie treuil; et• contrôle d'autres équipernents à differénts niveaux. D'autres travaux furent egalement effectues par les employes, tels que:• la conversion d'un Scooptram ST5A de diesel à électrique;• I'installation complete de systèmes de depoussierage a I'eau (scrubber) pour le concassage secondaire;• I'installation d'un marteau hydraulique avant les concasseurs coniques;• la rénovation des cellules de flottation ; et• l'installation d'un système de gardiennage par caméra. D'autres projets seront effectués ou étudiés:• automation d'un Scooptram"";• automation d'un marteau hydraulique;• récupération de Scooptrarn; téléguidé:• gestion de l'énergie, contrôle de la demande, surveillance et contrôle de l'équipernent de machines fixes(compresseurs, boulloires, pompes à vide, génératrices, débits et pression d'air, eau pour diagnostiquer les problémes, analyser les coûts;• concasseur portatif pour fabriquer de la pierre concassée pour utiliser dans les chemins sous-terre, et• utilisation de micro-ondes pour transmettre les images captées par camera."

Jan 1, 1990

By Franc R. Joubin, Donald H. James

"The Property of Rix Athabasca Uranium Mines Limited is in the Beaverlodge area of northwestern Saskatchewan. The mine is 7 miles by road north from the Lake Athabasca port of Bushell which is 250 miles north by aircraft or boat from railhead at Waterways, Alberta.The Rix property is a portion of the former DD 1 concession, obtained in 1949 from the government of Saskatchewan when private prospecting for uranium became permissible. The concession was prospected in detail during the 1950 and 1951 field seasons and a great many radioactive show-ings were discovered. Development and drilling were concentrated in two and later three of these areas, and by late 1952 enough ore had been indicated in the Leonard series and ""Smitty"" zone to justify underground development by adit-drift and shaft respectively.Four hundred feet of drift development on the Leonard No. 1 vein and the sinking of a two-level vertical shaft with related lateral development on the Smitty zone were completed in 1953. In April 1954 the Smitty section was placed in production at a rate averaging 100 tons per day, thereupon becoming the first privately owned post-war uranium producer in Canada. The ore is shipped for processing 12 miles by truck to the mill of Eldorado Mining and Refining Limited.Until recently all of the Company's production was drawn from the Smitty orebody. In April, 1955, ore production commenced from the faulted west extension of the Smitty structure, known as the Rix 62 zone, and from the Leonard No. 1 vein.The Smitty orebody (see Figure 2) is an intensely brecciated lenticular zone bordering both sides of the Smitty fault. The breccia areas are irregularly mineralized with pitchblende, very sparse galena, and pyrite in a gangue of feldspar, chlorite, calcite, and silica, all thoroughly soaked with fine-grained hematite to produce the locally-called ""red alteration"".Tenor of the ore currently being mined is classified information. The average grade estimated, prior to production, was 0.20 per cent (4.0 lbs.) U308 per ton."

Jan 1, 1949

By The Staff

"SummaryDetermination of uranium in ores may be made by measurement of their radioactivity.The method most commonly used is that of measuring beta radiations with the tray-type beta counter. This will give an accurate uranium determination provided the sample does not contain thurium and that the beta and gamma activities have not been disturbed from their natural state of equilibrium. Such a loss of equilibrium will result from mining the ore or from the weathering of the surface rock.A method is described which eliminates errors due to loss of equilibrium. The beta and gamma activities are measured simultaneously in one simple operation. This method is recommended for assaying samples of products from milling operations and its use is limited only by the presence of thorium in a ratio greater than one part of thorium to twenty parts of uranium.A third method is recommended for the analysis of exploration samples and diamond drill cores, which may be assayed in the uncrushed state.Rapid determinations of a large number of samples is possible with the pressure ionization chamber, which is sensitive to gamma activity."

Jan 1, 1950

By MacDonald W. L. F. C. A.

IN accordance with the usual approach to a participation in a panel discussion, this paper is, in some respects, intentionally controversial. I would suggest, how-ever that there is more than a grain of truth in many of the comments made. Before dealing with a particular problem. It is appropriate to set out a few of the more significant objective of an: accounting system: (1) The provision of historical data <•concerning past events, for the information of shareholders, tax authorities, etc. This data can also be used as a tool to predict the future. (2) The provision of a record to safeguard the company's assets and to form the basis of any claim for insurance or other damages. (3) The provision of an accounting framework in making an economic study of a proposed course of future action such as the development of an orebody or the outlay of a substantial sum for new equipment. ( 4) The

Jan 1, 1962

"In 1989, improved milling and recoveries resulted in a record production of 7 722 200 Ib Nb2P5 at the Niobec Mine. At the beginning of 1990, proven and probable reserves stood at 11 952 000 tons grading 0.65% Nb205. This year, the world steel market has slowed and as a result, niobium consumption is down. Consequently, production at the mine dropped 14% for the second quarter.IntroductionThe Niobec Mine is located approximately nine miles northwest of Chicoutimi, Quebec, (Fig. I). After ten years of production, the Niobec Mine is the only operating niobium mine in North America and the second largest producer of niobium in the world after Brazil.The Niobec Mine is a joint venture held equally by Teck Corporation and Carnbior. Teck Corporation operates the mine while Cambior is responsible for marketing and selling the niobium pentoxide concentrate (Nb2P5).The deposit was discovered in 1964 following an airborne radiometric survey in search of uranium. However, mining of the deposit did not begin until 1976. The initial production capacity of 1500 tons per day was increased several times to the present capacity of 2450 tons . The deposit is considered as an ample source of pyrochlore concentrate for at least 15 years at the present production rate.Niobium, also known as columbium, is a greyish-white metal used primarily as an alloy in various steels and other metals. The use of niobium in alloys heightens tensile strength and improves corrosion resistance while at the same time reducing the weight of the alloy. Niobium is also used in the fabrication of steel for the aerospace, automobile, and oil and gas pipeline industries. Although substitutes for niobium exist, their use often results in diminished performance and net cost increases."

Jan 1, 1990

By R. C. E. Bray, Peter Price

"The property of Pamour Porcupine Mines, Limited, is in the eastern Porcupine area, about 12 miles northeast of Timmins. It covers parts of lots 3-6 (inclusive), cons. 5 and 6, Whitney tp., Cochrane district, Ontario. It is an amalgamation of the old La Palme, Three Nations, and Porcupine Grande properties.The first discovery on the Pamour was made in 1911. During 1911 to 1914 a small shaft was sunk on the Three Nations vein to the 200-foot level and a 100-ton stamp mill was put in operation, but only a small production was achieved. The property remained idle from 1914 to 1923. In 1924 some diamond drilling was done along the Keewatin-Timiskaming contact with some encouraging results, but the gold mineralization encountered was too low in general at the price of gold then prevailing to warrant further · work. The increase in the price of gold revived interest in the area, and the above noted amalgamation was effected in 1934. Options were taken and successively dropped by two large mining companies. Following this, exploration both on the surface and underground was started by Quebec Gold Mining Corporation, Limited. Diamond drilling in the early part of 1933 showed considerable ore in conglomerate and greywacke to the east. In the middle of 1935 Noranda Mines, Limited, assumed control and management. A new shaft was sunk and the property was ·equipped with a mill having an initial capacity of750 tons a day. This was subsequently enlarged to 1,500 tons a day.From the commencement of milling (May 16, 1936) to the end of 1946, 5,025,545 tons of ore having an average grade of 0.1327 oz. a ton ($4.64 at $35 an oz.) have been mined and milled."

Jan 1, 1954

By Jas. E. Thomson

"The Kirkland Lake-Larder Lake gold area is in northeastern Ontario and is a continuation of the ore-bearing belt that extends across northwestern Quebec through the Rouyn, Cadillac, Malartic, and Bourlamaque areas. It is the oldest mining camp along this famous mineral belt. Gold discoveries were first made at Larder Lake and Swastika in 1906, but it was not until 1913 that important developments at Kirkland Lake created a real interest in the country. Total gold production of the camp passed the million dollar a year mark in 1920 and increased in amount yearly until the advent of the second World War when there was a falling off due to labour shortage. The Kirkland-Larder camp ranks as the second largest gold producing area ' in Ontario. To the end of 1944, twenty-two mines in the area had produced bullion valued at $515,631,428 and ten mines had distributed dividends amounting to $205,981,116. The average grade of the ore milled in this period has been $15.17 a ton for the mines in the Kirkland Lake area and $6.49 a ton for the mines at Larder Lake.ROCK FORMATIONS OF THE AREAIn a general way the rocks of the country may be divided into the lithological groups indicated on the accompanying geological sketch map. This map has been compiled largely from recently issued geological sheets of the Geological Branch of the Ontario Department of Minest. Owing to the present difficulty of separating the formations of the Larder Lake country into the twofold age divisions of Keewatin and Timiskaming, the usual custom in the past, a lithological grouping of formations has been adopted. The age terms 'Keewatin and 'Timiskaming' are loosely used in this article to express the often used but not necessarily accurate distinction between the main groups of older strata."

Jan 1, 1954

By J. Petit, P. Girard, A-M. Gilbert, D. Faucher

L&apos;annee 2000 a été une année stratégique et significative pour l&apos; Aluminerie de Bécancour dans la réduction des gaz a effets de serre. L&apos; équipe s&apos; etait donne comme defi un jour d&apos;arriver a l&apos;objectif de zero effet d&apos;anode dans les sa11es de cuve (720 cuves au total). Le cha11enge s&apos;averait tres ambitieux car la fa<;on d&apos;alimenter une cuve d&apos;electrolyse pour obtenir son maximum de rendement faraday est de travailler le plus pres possible de l&apos;effet d&apos;anode pour eviter l&apos;embourbement de ce11es-ci. Ceci signifie que techniquement nous a11ons en moyenne, quotidiennement, 12500 fois pres de l&apos;effet d&apos;anode sur !&apos;ensemble de nos 720 cuves qui produisent aujourd&apos;hui environ 405 000 tonnes d&apos;aluminium liquide annuellement. Des 695 kg equivalent en C02 par tonne d&apos;aluminium produite en moyenne annue11ement, de 1990 a 2000, nous en sommes rendus ace jour a environ 35 kg equivalent en C02 par tonne produite. Nous sommes pres d&apos; atteindre notre objectif mais les demiers gains sont plus difficiles a atteindre. Les strategies d&apos;automatisme et d&apos;informatique, incluant l&apos;aspect de !&apos;implication humaine sur les bonnes pratiques de travail sur les cuves d&apos;electrolyse, sont les cles de ces resultats.

Jan 1, 2006

By Serge Perreault

Le cuivre est un métal fascinant qui joue un rôle essentiel dans le développement des différentes civilisations depuis 7000 ans. Le cuivre est aussi un métal polyvalent et essentiel qui est très présent dans notre vie quotidienne. L’un des premiers métaux utilisés par les humains, il est un élément chimique qui se trouve à l’état natif, ce qui est rare pour les métaux. Il apparaît principalement dans des minéraux, notamment sous forme de sulfures, en raison de son caractère chalcophile (c’est-à-dire son attraction pour l’élément soufre). Le cuivre se trouve dans la croûte terrestre sous forme de minéraux de cuivre, tels que dans les sulfures dont la chalcopyrite, la bornite, la covellite et la chalcocite. Il est également présent sous sa forme native ou dans des minéraux oxydés comme la cuprite et dans des carbonates hydratés, comme la malachite et l’azurite. La formation de gisements de minerai de cuivre implique des processus géologiques complexes, notamment l’activité hydrothermale, les intrusions magmatiques et l’altération des roches. Les gisements de minerai de cuivre se trouvent dans divers types d’environnements géologiques, dont les gisements porphyriques, les gisements de cuivre encaissés dans des roches sédimentaires, les gisements de type skarn, les gisements de sulfures massifs volcanogènes, les gisements magmatiques de type nickel-cuivre, les gisements de cuivre oxydé, et d’autres [1].

May 2, 2024

By M. Nagamori, A. J. Plumpton

"A low-grade concentrate from the Crevier Township, Quebec, containing 1.8% Ta205 and 13.7% Nb205 was reduced with carbon at 1600°C, and niobium and tantalum were selectively absorbed in liquid iron. To slag off the zirconia-rich gangue, some silica and lime were added as flux. Metallic iron was added in such a way that the combined contents of TaC and NbC did not exceed 20% in the ferroalloy . Up to 95% of the niobium, and up to 80% of the tantalum contained in the concentrate were recovered in the metal. The ferroalloy was ground finely and dissolved in 2 wt % sulphuric acid to leach out iron and silicon preferentially. The insoluble residue consisted principally of NbC and TaC, the calcination of which yielded an enriched concentrate comprising 80% Nb2O5 and 8% Ta2O5. The insoluble residue could also be chlorinated to obtain an impure liquid of Nb2Cl5 and TaCl5. Process variables and their effects are discussed in terms of higher metal recoveries in the smelting.IntroductionPresently, about one-third of the world production of tantalum comes from the pyrometallurgical reprocessing of tin slag, a by-product of tin smelting, containing sometimes 2 to 10% Ta205 and about the same amount of Nb205. Upon heating tin slags with carbon at about 1600°C in an electric furnace, tantalum and niobium oxides are converted to TaC and NbC, which are absorbed by the coexisting phase of molten metallic iron(1,2). The Fe-Nb-Ta-C melts cannot be decarburized by oxidation because of the preferential formation of Nb and Ta oxides over CO gas(3). So, the ferroalloys containing tantalum and niobium carbides are commercially treated by acid-leaching and I or chlorination to eliminate iron and thus permitting the eventual recovery of purified tantalum and niobium oxides(2).Absorbing Ta and Nb carbides in molten iron was first proposed and demonstrated by Zimmerley and Back(4) in 1957 in order to recover selectively tantalum and niobium from lowgrade concentrates. The process was successfully applied to the electric furnace smelting of tin slags by Hunter and Fursmant(5) over a period preceding 1965."

Jan 1, 1985