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By H. C. Gunning

The Privateer is the major mine of the Zeballos mining camp; with a total production from May 1937 through the first half of 1946 of $5; 610; 423 from 139; 254 tons of ore. This includes a small production from the connected Prident mine. The entire operation was closed from October 1943 to November 1945.

Jan 1, 1954

By M. E. Hurst

SINCE 1934 there has been a marked revival of interest in the Porcupine district, especially in the eastern portion of the area, where exploration on the property of Pamour Gold Mines has indicated the presence of extensive gold-bearing deposits. Owing to the prevalence of overburden and the limited amount of exploratory work that has been done, little information is available as yet concerning the distribution and structural relationships of the rocks in the area to the east of Porcupine lake. In order to throw some light on the structural conditions in this section, a brief discussion of the sequence and character of the formations in the better known, producing section of the camp has been included. It should be emphasized that this paper is a preliminary study and that, consequently, the conclusions expressed should not be regarded as final. The writer wishes to acknowledge his indebtedness to P. C. Benedict, whose study of the geological relationships on the Foley-O'Brien property has made possible a fuller understanding of the structure in the central portion of the area. The writer also wishes to express his appreciation of the information and facilities placed at his disposal by R. M. Macaulay and C. D. Stevenson, of Pamour Gold Mines, and by A. Bell, of Noranda Mines, Limited.

Jan 1, 1936

By P. M. Huck, R. John

"The National Uranium Tailings Program was established in 1982 to develop, in part, a mathematical predictive model which would allow the assessment of the impact of uranium mill tailings on the environment and particularly on humans. . To achieve this , various studies were undertaken to establish the role played by key constituents of the tailings. This paper summarizes the findings of a study carried out under that program, to examine the leachability of barium-radium sulphate sludges produced in the treatment of uranium mill tailings decants. The investigators performed detailed chemical an alysis of the sludge, applied geochemical computer models to investigate sludge leaching behaviour, and conducted experiments to assess the impact of bacteria on leaching. The modelling showed that the redox state o f the sludge-leachant system was the most important factor. Substantial bacterially-mediated dissolutio n of the sludge and release of radium was demonstrated experimentally under suitable reducing conditions . INTRODUCTIONIn September 1981, Phillip A. Lapp presented the final report of the National Technical Planning Group on uranium tailings research to the federal government (Lapp, 1981). Lapp' s group had performed an in-depth survey of the status of uranium tailings research in Canada and, as a result, recommended that a national program be funded in the amount of $18 .6 million. Half of this fund ing was to come from the federal government, with the two producing provinces , Ontario and Saskatchewan, providing the balance. However , the provinces declined to support the program and the federal government decided to inaugurate a reduced program with $8.5 million o f funds .In late 1982, the formation of the National Uranium Tailings Program (NUTP) was announced by the minister of state for mines. A primary objective of this program was to develop a mathematical predictive model that would permit the assessment of the impact of uranium mill tailings on the environment, a nd particularly on humans. The program was to use existing information to the greatest possible extent, and then fund research to fill in gaps or substantiate data where necessary .The NUTP was established to administer this program of contract research over a five-year sunset life. By the end of the 1986-87 fiscal year the NUTP had completed about 100 contracts. One of those projects was to study the effect of placing barium-radium sludge ba ck within the tailings matrix. Th is paper gives the results of that study."

Jan 1, 1989

By F. Simon, A. Roth, M. F. Zaeh

Applying Friction Stir Welding in an industrial environment requires knowledge about the robustness of the welding process against imperfections in the joint line resulting from production deviations of the parts to be joined or from improper clamping devices. In this work the influence of gaps on the weld quality of friction stir welded butt joints of the aluminum alloy EN AW-5083-H111 is investigated in detail using the method Design of Experiments. As independent input variables, the rotation speed, the feed rate, the tilt angle, the lateral tool offset and the gap width were chosen. Tensile strength was selected as a measure for the joint quality. Moreover, the fundamental response variables of the FSW process, such as weld temperature, axial force and spindle torque, were recorded and integrated in the empirical process model derived by regression analysis. It was found that each response variable decreases with increasing gap width, whereas the largest impact was identified for the axial force and the temperature at the weld surface. In order to improve the joint strength for a given gap width, increasing the rotation speed and the tilt angle or lowering the feed rate, respectively, proved to be a suitable approach. However, interactions between the tilt angle and the rotation speed have to be considered.

Jan 1, 2014

By C. J. Coulson, G. A. McKay, A. M. Cormie

"The Leitch mine, in the Beardmore area, Thunder Bay district, Ontario, is a part of the Leitch estate. It includes a group of patented claims, staked by P. A. Leitch of Port Arthur early in the century, along bands of jasper, hematite, iron-bearing slates, carbonatized schists, and greywacke, commonly known as 'iron formation'. The folding and shearing in these variably interstratified beds is a striking structural feature. The vein pattern is very definitely related to these structures.ROCKSThe rocks in the area are typical Keewatin lavas-greenstone-overlain by a series of Timiskaming sediments consisting of arkosic greywacke, iron formation, slate, greywacke, conglomerate, and greywacke, in this order from the contact. The sedimentary beds are generally conformable with the older rock contact except on local folds.Small intrusions of diorite occur as nearly vertical dykes and are believed to be of Algoman age. To the northwest of the mine there are larger intrusions of granodiorite belonging to the same period.Several dykes of quartz diabase up to 100 feet in width, striking generally north and south, with a vertical dip, cross the property. These have been classified by W. C. Laird as pre-Keweenawan in age. One of these dykes in particular is of importance for it cuts through the No. 2 vein and serves as a pillar when stoping. It is approximately 6 feet wide.The youngest rock type represented is a sheet of olivine diabase that extends over an area of thousands of square miles in and around lake Nipigon. It underlies most of this area and its outcrops form some of the most interesting topographical features, with fault scarps rising hundreds of feet. In the vicinity of the mine shaft the sheet is about 600 feet thick and extends from a depth of 1,871 feet to approximately 2,470 feet. It has a dense, hard, chilled margin and a sharp, tight contact. It intruded the sediments with very little lateral disturbance. The chief effect was baking, which darkened and hardened the greywacke near the contact. The sheet dips flatly to the cast."

Jan 1, 1954

By John B. Riddell

"AN EXCELLENT review of the status of applied geochemistry was given by Warren (1959) at last year's General Meeting of the C.I.M. The purpose of this paper is to present recent developments and trends. Several important books were announced during 1958: Ginzburg, I. I. Principles of geo-chemical prospecting. (In process of translation from the Russian by V. Sokoloff).Vinogradov, A. P. The geochemistry of rare and zvidely scattered chemical elements in soils. Consultants Bureau, N.Y. Korzhinskii, D. S. Physicochemical basis of the analysis of the paragenesis of minerals. Consultants Bureau, N.Y.In addition to these translations Mason's Geochemistry' has been revised, and Hawkes and Webb (personal communication) are publishing a book on geochemical exploration. A Symposium on Geochemistry was head in Paris in July, 1957, in conjunction with the XVIth International Congress of Pure and Al-lied Geochemistry. The abstracts of the papers presented at this Symposium were published in Geochimica et Cosmocl1imica Acta, 1958, Vol. 14, pp. 150-167."

Jan 1, 1960

By Daniel Hodouin, Mélanie Proulx, Claude Bazin

"Collector and frother are commonly used to induce the floatability of valuable minerals in flotation plants. These reagents are usually distributed down a flotation bank or sometimes added in a single location at the top of the bank. A review of the literature and some experimental results obtained from laboratory and full scale trials indicate that the way flotation reagents are distributed down a flotation bank may influence the flotation response of coarse particles. The paper summarizes these observations which show that the distribution of reagents is a potential tuning variable for process optimization.IntroductionFlotation is in many cases the only way to concentrate sulphide and some oxide minerals. Flotation is a concentration process that uses particle surface composition to induce the selectivity by mean of hydrophobic reagents. The influence of particle size on flotation was firstly analyzed in the 50's1·2 and intensively investigated in the 70's, early 80's and 90's3-18. Most of the observed results show the existence of an optimum flotation size range9 whose recovery is not significantly influenced by a reduction of collector dosage""18. This result brought the idea of using a small portion of the total collector dosage at the top of a rougher bank and to distribute the remaining through the end of the bank to ensure sufficient collection of the coarse particles that need more hydrophobic coverage to attach to air bubbles and be lifted to the surface.This paper discusses the idea of using the distribution of reagents down a flotation bank to tune the operation of the process. Unlike the literature on the effect of reagents (collectors, frother...) dosage that is dense, little attention has been put on the distribution of reagents in a flotation bank. Although research on this subject has not been pushed very far, some operators have recognized the potential of a strategic addition of reagents down a flotation bank19. Except for a few exceptions, the proportions of the reagents to be distributed down a flotation bank are decided according to operator's experience instead of process analysis in relationships with particle size. This paper recalls observations made by different researchers that lead to the idea of using the distribution of reagents as a tuning variable for the flotation process. The paper does not present a detailed analysis or optimization scheme for tuning the distribution of reagents, but analyzes some plant and laboratory results with a view toward the development of a testing methodology and ultimately a validation or rejection of the idea."

Jan 1, 1998

By Jerry Danni

In order to remain viable today, corporations must view the environment as a strategic issue, and integrate environmental management throughout the organization. Corporate programs that used to be based primarily on regulatory compliance now must emphasize strategic environmental management systems, and must integrate these environmental systems with basic business functions. The mining industry today is global, and must have an organizational structure that can embrace different cultures, physical settings, and regulatory regimes. Sound environmental management practices are not different from good management principles. An effective environmental management system should be a complementary system to an organization?s overall management framework, integrated and aligned with the existing management structure. Integrating environmental management into core business functions is just good business. An effective environmental management system is a critical component of a company?s commitment to environmental, social and economic accountability. This paper presents the elements of the Kinross Gold Corporation strategic environmental management system and discusses the integration of the environmental management system into the core business functions throughout the Company

May 1, 2003

By James F. A. Hatley

Northern Saskatchewan comprises an area of about 350 000 km2 and boasts some of the world's largest known high-grade uranium deposits. The successful mining of these deposits, however, can not be accomplished without overcoming technical challenges. Not only is the high grade of the uranium ore challenging, but mining methods need to be developed to deal with groundwater at very high pressures, and ground conditions that vary substantially from excellent to wholly unconsolidated clays and sand. This paper discusses the various mechanisms of inflows at the three of the Cameco Corporation Mines in Northern Saskatchewan. The risk of inflows is quantified in terms of unique challenges from hydrogeologic conditions, rockmass integrity, and uncertainty in geologic conditions. Mitigation strategies in case of an inflow are also briefly described. The paper concludes by addressing the impact of institutional rules (corporate standards) on minimizing, monitoring, and controlling the probability and/or impact of unexpected inflows.

Aug 1, 2010

By Lynn C. Fister

"Coal is rapidly becoming a major alternative to oil. According to the World Coal Study Final Report, total world coal trade could approach one billion tons annually by the year 2000. To facilitate the increased production and export market potential of the coal producing countries, advancements must be made to improve the transportation systems. Coal slurry pipeline systems could play a significant role in achieving these market forecasts.There are three major components to a coal slurry system the preparation plant, the pipeline and the dewatering plant. The experience and expertise gained from the Consolidation Coal Company system in Ohio, the Black Mesa system in Arizona and ETSI's Coal Evaluation Plant demonstrate that slurry pipeline technology is proven and available to meet the coal transport challenge.The costs of transporting coal by slurry pipeline can offer significant savings, as about 70 per cent of its costs are fixed. The reverse is true for railroads, where 75 to 80 per cent of the costs vary with inflation. All forms of transport-rail, barge and pipeline-will be required to move the massive volumes of coal. Coal slurry systems can provide a viable transport alternative.IntroductionThe importance of coal as a major alternative to oil is now well known and accepted throughout the world. Increasing oil prices over the last eight years have had a serious effect on national economics, particularly in those countries that are heavily dependent on oil. Coal can replace oil as the principal fuel source which could support world economic growth over the next two decades. This is the main conclusion of the World Coal Study (WOCOL) Final Report, published in May 1980.The product of that report was a result of considerable deliberation by key industry leader s and energy experts. The underlying message of the World Coal Study is that our energy and economic problems can be faced with confidence if coal use doubles by the early 1990s and triples by 2000, and if steam coal trade expand s considerably."

Jan 1, 1982

By R. S. James, D. C. Peck, P. T. Chubb

"The East Bull Lake gabbro-anorthosite intrusion is one of several Early Proterozoic layered mafic intrusions occurring along the Southern Province - Superior Province boundary in the Elliot Lake - Sudbury region, Ontario. The base of the East Bull Lake intrusion comprises abundant plagioclase cumulates (Leucogabbronorite Zone) hosting two distinct styles of sulfide mineralization: (1) disseminated magmatic sulfides, and (2) disseminated to massive, structurally controlled sulfides. Both types of mineralization are enriched in Pd, Pt, Au, Cu and Ni. The host rocks to the sulfide mineralization display a range of interesting features including nodular textures, dendriticpegmatitic mafic pods, inclusion-rich zones (pyroxenite, anorthosite and granitic inclusions) and magmatic breccias. Disseminated chalcopyrite, pyrrhotite and pentlandite occur in concentrations of up to 100/0 within erratically distributed gossan pods near the base of the intrusion. The sulfides were originally precipitated from intercumulus liquids, but were subsequently recrystallized and locally remobilized along fractures during the major period of metamorphism and deformation that affected the East Bull Lake intrusion. The base- and precious-metal tenor of the structurally controlled sulfides can be explained by extensive remobilization and reconcentration of the pre-existing magmatic sulfides in the vicinity of a major shear zone. Both styles of sulfide mineralization locally contain ppm abundances of POE + Au and are generally Pd- and Cu-rich, although both display large variations in Pd:Pt and Cu:Ni ratios. The magmatic sulfides are more strongly enriched in POE and contain up to 1470 ppm Pd in 100% sulfide. Several factors, including source characteristics, magmatic processes (crustal assimilation, fractional crystallization) and post-magmatic interaction with hydrous fluid, have influenced the present distribution of POE, Cu and Ni in the East Bull Lake intrusion.The magmatic sulfide occurrences from the East Bull Lake intrusion compare favorably with marginal-type deposits from rift-related intrusions (Noril'sk-Talnakh region, Siberia; Duluth Complex, U.S.A.) in terms of their distribution, but are most similar to reef-type POE deposits with respect to their base- and precious-metal geochemistry. The combination of high POE tenors and large tonnages that is observed for the POE-Cu-Ni mineralization from the East Bull Lake intrusion suggests that a good potential exists for the presence of economic concentrations of Pd, Pt, Au, Cu and Ni in the intrusion. On a global scale, the East Bull Lake intrusion is part of a suite of Early Proterozoic plutons, many of which contain significant volumes of stratiform and/or marginaltype POE-Cu-Ni mineralization. The East Bull Lake intrusion is also one of the oldest mineralized intrusions derived from a sub-Superior Province mantle source region that has given rise to several significant magmatic POE-Cu-Ni deposits during the period 2.5 Ga to 1.1 Ga."

Jan 1, 1993

By Z. Zhong, Y. J. Hu, D. Elsworth

"A standard triaxial apparatus was set up to perform sliding tests. Slide-hold-slide (SHS) tests, with hold times from 10 to 3000s and at invariant effective confining pressures of 1MPa, incremented to 3MPa and then 5MPa, were conducted on both dry and wet split limestone samples to study the evolution of fracture friction under holding and sliding processes. Limestone fracture shows time-dependent behaviors in SHS tests, friction drops (creep) gradually during hold periods, and recovers (healing) after re-slide. Frictional healing and creep increment are proportional with hold times, while are inversely proportional with effective confining pressures. Moreover, the wet sample displays heavier healing than the dry one, whereas creep increment of the wet sample is lighter than the dry one. We conclude that the evolution of limestone fracture friction is significantly controlled by mechanisms of fluid-rock interactions.INTRODUCTIONThe evolution of the mechanical properties of fractures and faults exerts a critical influence on the behavior of fault zones and on the earthquake cycle. In addition to natural processes, this behavior has broad implications in induced seismicity and influences oil and gas production, the sequestration of carbon dioxide and the disposal of nuclear wastes.Fault friction is typically measured by slide-hold-slide experiments, where fault gouge is deformed at low velocities (<0.1 mms-1) and over small shear offsets (<30 mm) (Dieterich, 1979, 1981; Mair et al., 1999; Marone, 1998, 2004) or alternatively with rotary-shear devices, that enable higher slip velocities over very large shear offsets (Hirose & Shimamoto, 2005; Mizoguchi et al., 2006). Typical experiments (Dieterich, 1972; Marone, 1998; Olsen et al., 1998; Bos & Spiers, 2002; Tenthorey et al., 2003) show significant creep during the holding period and frictional healing (strength gain) upon reloading. Fault creep and healing are often time-dependent with longer hold times typically resulting in greater magnitudes of creep and in strength gains (Tenthorey et al., 2003; Yasuhara et al., 2005; Carpenter et al., 2012). Frictional healing may arise from growth of grain contacts (potentially induced by pressure solution) (Rabinowicz, 1951; Dieterich & Kilgore, 1994; Yasuhara et al., 2005), strengthening of the contacts (correlates with cementation) (Hickman & Evans, 1992; Beeler et al., 1994; Karner et al., 1997; Olsen et al., 1998; Muhuri et al., 2003; Tenthorey et al., 2003; Li et al., 2011) or via other changes in state including changes in porosity and rearrangement of force chains. Experimental evidence (Dieterich, 1979, 1981; Johnson, 1981; Marone & Scholz, 1988; Marone, 1998; Saffer & Marone, 2003; Moore & Lockner, 2007; Ikari et al., 2007; Ikari et al., 2011; Carpenter et al., 2012) quantifies both the mode and magnitude of second-order changes in the velocity-dependent (including velocity- strengthening and weakening) evolution of frictional strength."

Jan 1, 2015

By John Oxenford

There are currently two operators producing oil from the surface-mineable portions of Alberta?s oil sands (Syncrude Canada Ltd. and Suncor Inc.) and two other companies are proposing to enter the industry (Albian Sands in 2002 and True North in 2004). Tailings from the two current oil sands plants contain approximately 220 000 tonnes per year of recoverable TiO2 and approximately 80 000 tonnes per year of recoverable zircon. This represents approximately 6% of the world?s TiO 2 consumption and approximately 9% of the world?s zircon production. With the commissioning of plants by Albian Sands and True North, and the announced expansion of plants by Syncrude and Suncor, it is expected that these tonnages could quadruple in the next ten years. All of these operators have at least 50 years of reserves even at these expanded production rates. The occurrence of heavy minerals in Alberta?s oil sands has long been known and is well documented in the literature. There have been a number of attempts to produce market-grade products from this resource and the results of this work have been quite mixed. Typically, researchers have used the normal mineral dressing techniques of the industry and have found the mineral assemblage does not respond to these techniques all that well. This has led to the widelyheld suspicion that there must be some difficult metallurgical problems associated with this resource. There are three main problem areas that have created difficulties for previous researchers: 1) The bitumen coating on the sand grains; 2) Secondary mineralization such as pyrite, siderite and calcite 3) A high proportion of aluminosilicates (approximately 25%) that have the same gravity, electrostatic and magnetic properties as other minerals in the heavy mineral suite. Recent work by Lakefield Research shows that these problems can be largely overcome with some novel approaches. The bitumen can be removed by washing with a solvent in the presence of a demulsifier. The pyrite can be removed by flotation. And the titanium and zircon minerals can be separated by selective flotation followed by conventional electrostatic and magnetic separation.

May 1, 2001

By Wei Ye, Lei Li, Xianjian Guo, Feng He

The purpose of the paper is to study the smelting process of copper concentrate with high Cu/S ratio produced in Africa or other areas around the world and theoretically analyze the influence of slag type on the smelting process. The paper has compared the processes used successfully in smelters, including CAPEX and OPEX and other factors, to provide reference for the industry to select the best process under specific conditions. INTRODUCTION At present, a great amount of copper concentrates with high Cu/S ratio, with chalcocite being the major source of copper, have been produced or are about to be produced in the Copperbelt in Africa and other countries in the world. The copper concentrate is usually high in copper (~30–55wt.%) and low in sulfur (~10–15wt.%). The conventional processes of smelting-converting and roasting-leaching-electro-winning for treating this type of concentrate is high energy and materials consumption such as electric power\fuels\flux et al. The direct-to-blister (one-step) smelting process can be considered favorable due to a reduction in processing steps. Up to now, there are four copper smelters in the world operating with the direct-to-blister smelting process. There certainly are problems in the process such as high copper content in the slag, strict operation requirement of slag cleaning electric furnace, etc. Except technical issues, the impact of factors on economical aspect such as power and material cost needs to be considered comprehensively in process selection. In this paper the technical issues of direct-to-blister smelting process, including slag treatment process, were analyzed and the comparison to the conventional processes and economic analysis of direct- to-blister smelting process to treat high Cu/S ratio concentrate were done.

Jan 1, 2019

By Suping Yao, Chuanyu Jiang

In the last decade, the copper industry in China has witnessed a significant change. The capacity and production of refined copper has grown remarkably from 1.5 million tons in 2002 up to 5.88 million tons in 2012. And now, China has become the biggest copper producer in the world, counting about 30% of the global refined copper production. This paper summarized modern copper smelting and converting technologies employed in China copper industry, such as OT flash technology, TSL (ISA/Ausmelt), SKS bottom blowing, Jinfeng side blowing, etc…This paper also presents some key development and improvement of these technologies up to date from their practical application in China, what will contribute as great value to any new / or renovation copper smelting projects down the road. As an engineering company in China, NERIN has been involved in many of these projects in the past decade, played an important role in the engineering works and accumulated intensive experiences. NERIN is one of the best choices for the world clients in the copper industry, providing quick engineering service, delivering cost effective projects.

Jan 1, 2014

By W. H. Zieman

NORMAN WEISS, Milling Engineer, American Smelting• and Refining Company: The subject of the Forum on Rod and Ball Mill Liners is very fascinating, and there is no end of discussion when operators get together on grinding. However, the hypotheses and suppositions easily outrun the facts, especially when we •consider the inaccuracy of many reported observations. Still surprisingly small is the number of concentrators even reasonably well equipped to measure power consumption of each grinding mill, together with running time, so that data on this tangible factor, at least, can be obtained with precision. While the more elaborate devices of this nature, producing for each 24-hour period the total power consumption, average kilowatt hours per hour, short-term demand chart, instantaneous demand, and print-out, may cost in the neighbourhood of $2,500 per mill and may be difficult to justify, the combination of an ammeter, watthour meter, and running-time meter will cost only a few hundred dollars, so there appears to be little reason not to in-stall them in view of their numerous advantages.

Jan 1, 1959

By E. W. O'Brien

Personnel protection involves effective grounding and positive clearance of faults. This paper deals, in a general sense, with various schemes to achieve fool-proof personnel protection and reduce, to a minimum, the effects of human error and equipment failure.

Jan 1, 1966

By M. Leroux, C. J. Martin, S. R. Rao, J. A. Finch

"The effect of nitrogen on the flotation separation of sulphides from complex ores from Brunswick Mining and Smelting (New Brunswick) and Mattabi Mines (Ontario) was investigated. The most significant finding was enhanced pyrite floatability after as little as 3 minutes nitrogen conditioning. This was used in a novel sphalerite/pyrite separation process developed on the Brunswick ore. After aeration and Cu/Pb bulk flotation in air using xanthate the slurry was nitrogen conditioned, xanthate added and the pyrite floated in nitrogen. As an example up to 70% pyrite recovery with about 20% sphalerite recovery was achieved. Sphalerite was recovered from the pyrite tailings and the pyrite concentrate by copper-activation, raising the pH to 10 and floating in air. About 65-70% recovery at 35-40% Zn grade was achieved compared to 25% Zn grade by the conventional route. The process offers a promising alternative to current practice which seeks to depress pyrite at all stages. A possible mechanism of the effect of nitrogen is presented. INTRODUCTIONUse of gases other than air in froth flotation has been reported from time to time. [Podobnik and Shirley, 1982; Lin and Metzer, 1975]. Of all the gases, nitrogen would appear to hold the greatest practical promise because of its easy availability and chemical inertness. It is used in froth flotation in chalcopyrite-molybdenite separation [Redfearn, 1983]. The use of nitrogen in polysulphide chalcopyrite. this case is mainly to reduce the oxidation of a compound (Nokes reagent) used as a depressant for There is no reported use of nitrogen in the flotation of other sulphide minerals."

Jan 1, 1988

By S. Afshar, E. Dajoux, C. Allaire

For various reasons, molten salts, mainly chlorides and fluorides, are used in the aluminum industry. In the holding and melting furnaces, these salts may have different roles such as protecting the metal from oxidation, reducing the metal content of the skim or removing inclusions or impurities from the metal bath. However, the use of these salts may also have some undesirable effects such as easy attack of the furnace lining refractory materials by molten aluminum. The aim of the present investigation was to clarify and to compare the effects of chloride versus fluoride salts, on the corrosion process of the aluminosilicate based refractory materials. A laboratory test and procedure, simulating the conditions at the metal line in the aluminum treatment furnaces, was used. Different aluminum alloys (A1-5wt.%Mg, A1-5.5wt.%Zn and 7075 alloy) and chloride or fluoride salts (MgC12, KC1, CaCl2, NaC1, MgF2, CaF2, NaF and cryolite) were used as well as several aluminosilicate materials. Thermogravimetric measurements were also carried out in order to analyze the effect of the salts on the oxidation of molten aluminum alloys. The experimental results showed that fluoride salts are more aggressive than chlorides against the tested refractory products. It is postulated that the fluorides prevent the formation of a protective oxide layer on the metal surface, favoring at the same time the corrosion of refractories. Moreover, it was found that the presence of Na in fluoride salts increases significantly the aggressiveness of the aluminum alloy towards the refractory samples.

Jan 1, 2004

By A. Yousefpour, M. Hojjati, G. Chouinard

In recent years, high performance thermoplastic composites such as PEEK and PEKK have been developed for aerospace applications. These materials offer, among the other properties, high toughness and damage tolerances. These are semi-crystalline materials and their processing can lead to different crystallinity that in turn have some impact on the final properties. The effect of cooling rate on degree of crystallinity of PEEK is studied to identify the processing window for manufacturing. Samples were heated at the constant heating rate of 20°C/min up to 375°C (above melting point) and held for 10 minute. The enthalpy of the crystallization was measured at different constant cooling rates of 0.5, 1, 2, 5, 10, 20, 30, and 40°C/min. After cooling, the samples were heated at constant heating rate of 2°C/min using modulated DSC. At temperature between 90°C to 375°C, two endotherm peaks were observed. Results suggest that endotherm peaks are related to a melting and recrystallization phenomenon of one crystal morphology. However, the second endotherm peak could be associated with another crystal structure or morphology.

Jan 1, 2006