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By J. Etcheverry, E. Seguel, R. Díaz, F. Parada, R. Parra, E. Balladares

A thermodynamic and kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite during partial roasting of enargite-containing copper concentrates. The proposed mechanism involves solid-solid-gas and solid-gas reactions between chalcocite, pyrrhotite, gaseous sulfur and oxygen. The formation of bornite could be explained by a two-step reaction: the first one involving the formation of chalcopyrite by a reaction between Cu2S, FeS and gaseous sulfur, followed by a second step in which the newly formed chalcopyrite reacts with additional chalcocite to form bornite. Although thermodynamically the direct formation of bornite is more favorable than that of chalcopyrite, the lower diffusion kinetics of bornite formation could explain the preferential formation of chalcopyrite. If the reaction occurs with stoichiometric chalcocite and pyrrhotite in the presence of gaseous sulfur to form chalcopyrite, no bornite is formed, while for the stoichiometric reaction between chalcopyrite and chalcocite in the absence of sulfur, only bornite is formed. For the formation of magnetite and chalcopyrite the mechanism could involve the partial reaction of chalcocite and pyrrhotite in the presence of oxygen. The proposed model is thermodynamically consistent with the experimental results obtained in laboratory and pilot plant. INTRODUCTION The processing of high-arsenic copper concentrates with over 0.7 wt.-% arsenic by conventional smelting-converting normally require an additional arsenic removal step to reduce arsenic content to levels below 0.2–0.3%. One of these high-arsenic copper concentrates is the one produced by the Ministro Hales Division (DMH) of CODELCO, which has the typical chemical composition shown in Table 1. Enargite (Cu3AsS4), chalcocite (Cu2S) and pyrite (FeS2) are the main mineralogical species present in these concentrates, with over 75 wt.-%, as shown in Table 2. Partial or “neutral” roasting of these concentrates under controlled temperature and partial oxygen pressure conditions at 923–993K (650–720ºC) can remove up to 95% of the arsenic as As2S3 (As4S6), which has a high vapor pressure under these conditions, leaving a calcine with low residual arsenic. In copper concentrates, arsenic is present generally as enargite and arsenopyrite. This compounds as well as others such as pyrite and covelite, decompose readily above 770 K (500ºC), releasing, in addition to gaseous arsenic trisulfide, gaseous sulfur which by oxidizing to SO2 generates most of the heat required by the process.

Jan 1, 2019

By A J. Kyle

After a brief description of the shaft and surface facilities, this paper describes the planning for the mining operation, the selection of equipment the general method of mining and the sequence of operation. All of the major items of equipment are described, including the components of the power system. The detailed planning is reviewed -from the shaft sinking to the three-shift mining operation. Excavation and equipment changes, as well as long-range planning, are al o di cussed. Introduction THE successful completion of the Yarbo No. 1 shaft of International Minerals & Chemical Corporation (Canada) Limited in July, 1962, added a new type of mine to Canada&apos;s many producing operations. IMC Esterhazy is a unique mining operation in Canada; in fact, it is unique to potash mining in general. Not only is thi&apos;3 a trackless operation utilizing shuttle cars and belt conveyors in its material handling systems, but it excavates all of the ore with continuous boring machine<:;.

Jan 1, 1964

By G E. Craig, W. M. Williams

A simple, easily constructed apparatus suitable for the zone refining of iron and other reactive materials is described. After eight passes at one inch per hour, the iron produced showed a marked drop in hardness to 49 Brinell. In addition, an arbitrarily -defined recrystallization temperature was lowered by about 35°C and the rate of grain growth greatly increased. CERTAIN materials, of which iron is one, are so reactive that they cannot be zone refined in any known container without becoming contaminated. For such substances, the floating zone method ( 1) may be used. In this method, the specimen is supported vertically in an inert atmosphere and the molten zone supports itself by its own sur-face tension. The method was first applied to silicon (2) and has since been used for other reactive metals such as zirconium and titanium. Smith and Rutherford (3) have previously reported on the floating zone refining of iron; the efficiency of the method for reducing the car-bon content was demonstrated on

Jan 1, 1962

By Denis Yaychuk, Gary Billingsley

The economic eva luation of a mineral property or mining venture should include the quantification of ri k as part of the analy is. The re ults of such an analysis provide the decision-makers not only with the most likely financial outcome and the probability of achieving that or any other outcome. but al o with a ranki ng of the relative impact of all the ri sk factors. These type of resu lts offer more complete information for investment and technical deci ions than the traditional cash flow/ ensitivity analysis. In addi tion. by attempting to quantify ri sk. the personnel providing the va ri able input are forced to take a much clo e r look at the data involved, and are fo rced to work together. the reby increa ing substantially the awa reness of the impact their work and others· work has on th e outcome of the analysis.

Jan 1, 1986

By K. D. Genn, A. Mucha

This paper deals with Hilton Mines' approach to the maintenance of wear items such as truck boxes, shovel buckets, tractor pads, crawler sprocket idlers and the drop-ball. Each will be given a brief. description as to application, design, kind of materials involved and type of wear. The maintenance procedure is then outlined in terms of materials used, preliminary preparation, and welding and machining practices. The service history of new and re-paired items and the relative economics of repair vs replacement will then be presented.

Jan 1, 1969

By Stewart W. Daniel

"Increasing labour costs, the trend to larger mills, the processing of lower grade ores and a diminishing sup-ply of well-trained and experienced mill operators contribute to the necessity of automating a grinding circuit. With sophisticated process control techniques, supervision of the mill line is reduced to an occasional inspection by the shift supervisor. Process operating decisions and/or adjustments are quickly and accurately performed by the electronic devices to be described. When the variables in the grinding circuit are stabilized using the sensors and controllers as discussed, the over-all grinding circuit is maintained at its optimum grinding load level, with ample protection against under-and overloading."

Jan 1, 1967

By M. A. Upham

"MINING is Canada's second largest basic industry, producing material with a gross value of 2.5 billion dollars, led only by agriculture with 2.9 billion dollars. It pro-vides employment, directly and in-directly, for three quarters of a million people. Since the Second War, the value of mineral production in Canada has tripled. Economists forecast that over the next 15 years its value will triple again. Canada is a basic and leading supplier of nickel, iron, copper, zinc, lead and uranium. It is also a major oil producer, leads the world in the production of asbestos and in five years will be the leading producer of potash, a basic constituent of fertilizer.It can be seen that Canada's wealth and economic progress lies in being a primary producer of economic minerals and in building secondary industries to manufacture finished products from these raw materials. Canada's future in the field of mineral production looks bright, with our resources just starting to be tapped. Outside of the large expanse of Soviet Russia, we are by far the world's most fertile mineral exploration area."

Jan 1, 1967

By W. A. Toohey

Introduction From the earliest times it has been an inherent trait of man to build or create something for his own use or convenience. The need of some form of shelter other than that of the caves led him to bind together stones and other materials to form walls for his abode. Moistened clay which hardened upon drying was no doubt first employed. The Assyrians and Babylonians appear to have employed it or the bitumen found in their country. The early Egyptians and Greeks used some form of lime in their construction work. In addition to these shelters, other structures received attention, and, long before the Roman Empire was established, the Carthaginians made use of a natural cement as binding material. Portions of an aqueduct, seventy miles long, in Northern Africa, built in those early days, are still in use. The Etruscans were the first people in Italy to employ a mortar in their buildings. The Romans, learning the art from the Etruscans, improved the mortar by using a mixture of lime and volcanic ash, called &apos;puzzolan&apos;, and built not only roads but those famous structures, the ruins of many of which exist to this day. The Pantheon at Rome, built by Hadrian about 120 A.D., is perhaps the finest example of the early use of cement in building construction. With the decline of the Roman Empire, the art of making cement seems to have been lost, and for centuries the builders of Europe used only lime mortar. Pure limestones were selected for making the lime and great care was taken in the preparation of the mortar, the supply for one year being made the previous season and left to thoroughly slake or &apos;ripen&apos; in pits covered with earth. The mortar thus produced gave excellent service above ground or where it was exposed to the hardening action of the air, but would not harden under water.

Jan 1, 1927

By J. J. Jonas, G. R. Stewart, N. Pokutylowicz, S. Yue, R. Varano, A. Elwazri

Differing thermal histories in and around a weld can lead to differences in grain size, phase composition and morphology of precipitates; mechanical properties will vary accordingly. Hardness testing gives limited information and the machining and testing of tensile and/or impact specimens that would reveal these variations (which may occur over very small distances) is not practical. Therefore, in this investigation, shear punch testing was applied to measure the variation in the room temperature mechanical properties of a welded pipeline steel.

Jan 1, 2005

? Élaboration de la Directive 019 (1982) ? Objectifs: ? Protection de l ?environnement ? Procédure administrative pour analyse et évaluation environnementale ? Officialisée en 1989 ? pas eu de modifications depuis ce temps Contenu de la Directive 019 ? Requête d ?autorisation ? Gestion des eaux ? Traitement des effluents ? Gestion des déchets et des résidus miniers ? Suivi environnemental Directive 019 Exigences environnementales ? Effluents miniers ? As, Cu, Ni, Pb, Zn, Fe, CN, MES, pH, toxicité aiguë ? Suivi environnemental annuel ? Effluent ? Réseau hydrographique ? Restauration

May 1, 2001

By T. G. Joseph, M. Welz

ABSTRACT: Joseph (2002) introduced passive seismic monitoring to measure mining equipment performance. This paper evaluates the potential of passive seismic monitoring to correlate mining equipment operation with oil sands surface response, with a mining hauler as the seismic source. When applied to moving haulers, this action–reaction approach is complex. Vibrations from on-board equipment, such as pumps and tires, dirty the signal with noise. To facilitate any correlation, the signal must be cleaned up. Existing geophysical analytical techniques were manipulated to evaluate the noise problem and to filter sufficiently to permit an evaluation of whether a mining equipment action–ground response relationshipis in fact discernable.

Jan 1, 2011

By M. Cousineau, S. Gariepy

"Current business and corporate environments push for improving metal accounting practices in smelters. The ensuing projects commonly proceed along a bottom-up approach. As such, efforts are first put on reviewing the measurement system and then on remedying the identified weaknesses. The focus is thus moved to mass/metal balance only after the measurements upgrade process has been completed. However, practice has shown that assessing the high variances related to suboptimal measurement processes is complicated without the help of statistical data reconciliation. This bottom-up approach leads to a to-do list that can not only exceed available resources but also lack prioritization in view of achieving the targeted end use. This paper describes an upgrade project done differently where all the three dimensions of the metal accounting system: hardware, software, and people were instead involved at the onset. Personnel was thus trained on data reconciliation software at the beginning of the project to make the reconciled mass balance benefits available earlier in the upgrading project. This has pinpointed the most critical measurements where accuracy and reproducibility should be improved. Overall, not only the instrumentation retrofitting process has been streamlined, but the global risk for the whole upgrading project has been significantly lowered.INTRODUCTION Mining companies are pressured to improve their production accounting practices in response to the strengthening of corporate requirements for timely and accurate production reporting (Gaylard, Randolph, & Wortley, 2014). Smelters are not spared from these changes. However, their unique situation in the mining value chain set them as strategic targets for upgrading projects. They usually have a longer lifespan than concentrators thereby offering an extended lifecycle to justify investments. Furthermore, numerous smelters have toll agreements with third parties. Accurate cost and production accounting is, therefore, a vital piece of information to fix acceptable contract conditions. Mining companies are ultimately aiming at a clearer view of the operating performance of each business unit to improve their business decisions in a competitive environment. This sought for increase in visibility through plant performance can only be achieved through an upgrade of the metal accounting system. Figure 1 shows the different components of a state of the art system (Gaylard, Morrison, Randolph, Wortley, & Beck, 2009)."

Jan 1, 2017

By M. M. Papic

"This paper describes the Sasol coal liquefaction process, as used in South Africa. It covers coal supply, coal gasification, gas purification, Fischer-Tropsch synthesis, the major utility systems involved and the economics of the process.IntroductionThe Sasol coal liquefaction process is based on Fischer-Tropsch synthesis of liquid fuels from carbon monoxide and hydrogen, which are in turn obtained by gasification of coal with steam and oxygen. The process is shown schematically in Figure I.The first step in the process is coal preparation, in which the coal is crushed and screened to a 3-50 mm size for gasification on one side and to -3 mm size for steam and power production on the other. Oxygen needed for coal gasificatoin is produced in the air separation plant.Coal is gasified under pressure by steam and oxygen in the Lurgi gasification plant, where raw, impure gas is produced . The raw gas is first washed in a scrubber with a circulating gas liquor, heat is then recovered from it in a waste heat recovery boiler and the gas is further cooled for purification. Water-insoluble materials (tar oils) in the gas liquor are separated from aqueous solution and sent to tar refining for the recovery of tar products. The aqueous portion of the gas liquor goes to a Phenosolvan solvent extraction process, where phenols and ammonia are recovered. Water then proceeds to the effluent treatment plant.The scrubbed and cooled raw gas goes to a Rectisol gas purification plant, where all components other than hydrogen, carbon monoxide and methane are removed as completely as possible by absorption in refrigerated methanol. The acid gases (CO2, H2S) stripped from the methanol in the Rectisol unit are processed in a Stretford plant for recovery of sulphur. Regenerated methanol is returned to the process. The purified synthesis gas is passed to the fluidized-bed Synthol reactors, where Fischer-Tropsch synthesis reactions take place.The synthesis products are recovered in a product recovery unit as separate streams of decant oil containing higher-molecular- weight hydrocarbons, light oil comprised of lower-molecular- weight species, the aqueous stream containing water solubles, a C3/C4 stream, a C2 stream , a methane stream and a hydrogen-rich stream. Most of the hydrogen is recycled to the Synthol reactors; a major portion of the methane is reformed to hydrogen and carbon monoxide for recycle; the C2 fraction goes to an ethylene plant; and liquid streams proceed to the product refinery.The product refinery is used to upgrade and purify the Synthol products to specification fuels and chemicals.Sasol l, the first coal liquefaction plant in South Africa , was built in 1955. It is still operating and has a product output of about half a million tonnes per year. The Sasol II plant is in a commissioning stage and will be in full operation in 1981. It is about five times the size of Sasoll. It uses over 12 million tonnes of coal and produces more than 2 million tonnes of saleable products annually (1,2,3). The Sasol llI plant, which is a mirror image of Sasol II, is under construction and scheduled for completion in 1983."

Jan 1, 1981

By P. R. Stephenson

Mining projects depend on the amount and quality of the mineral reserves, which in turn depend on the amount and quality of the mineral resources. Only Measured and Indicated Resources may be converted to mineral reserves and Inferred Resources may not, with certain exceptions, be used in economic studies. Responsibility for the estimation of mineral resources rests with the Qualified Person (QP) and there is a wealth of literature, text books and case studies to guide the QP. Responsibility for the classification of the mineral resources also rests with the QP. While there is some industry guidance and common practice on approaches to resource classification on which the QP can draw, the process is (or should be) heavily dependent on the exercise of judgement by the QP. However, this inevitably leads to situations where, for example, one QP?s Inferred Resource is another QP?s Indicated Resource. If the QP?s judgement is poorly reasoned or illogical (as is sometimes the case), it can have a major impact on the project, often with substantial cost or value implications. Project managers and company executives should not unquestioningly accept QP?s classification decisions and should apply the same intensity of due diligence that they apply to other critical elements of the project.

May 1, 2011

By W. L. Ott, C. L. Lewis

"AbstractA technique is described for preparation of palladium sponge and for spectrochemical analysis of the metal in this form. The precision and accuracy of the method are discussed. Analyses are compared with previous spectrochemical analyses of palladium in the black form. Good agreement was found in the two sets •of results and it is concluded that they are more reliable than wet chemical .analyses of the same material.IntroductionFOR SEVERAL YEARS the problem of platinum metal analysis by spectrochemical methods has been under investigation at the Spedtrographic Laboratory, Department of Geological Sciences, Queen's University. The problem, briefly -stated, is as follows: Samples of platinum, palladium,-rhodium, ruthenium, and iridium are received as fine metal powders, called sponge. Direct spectrographic analysis of this material has not been found satisfactory due to its heterogeneity •as regards contaminant metals, which may be present up to a total of one per •cent or more. Further-more, spectrographic standards are difficult to obtain and difficult to prepare accurately by adding weighed portions of contaminant metals to the sponge. The fact that •contaminant metals in original samples are probably alloyed with the major constituent is a further difficulty since complete fusion of these refractory metals proved impractical in the present case as a means of standard preparation. It •has, therefore, been found most satisfactory to dissolve the metals, prepare standards by addition of solutions of contaminant metals, and to reduce both standards and samples to a homogeneous form. A previous paper, by Hawley, Wark, Lewis and Ott (2) dealt with a method for spectrochemical analysis of platinum and palladium in their black form. Since completion of research on the black technique, the possibility of analyzing palladium accurately in its sponge form has• been investigated."

Jan 1, 1953

By W. O. Karvinen

"In the Timmins area, a close spatial and chronological association exists between gold deposits and two major stratabound carbonate-rich members and related quartz-feldspar porphyries. Synvo/canic and metamorphogenic are the two main types of mineralization recognized. Synvolcanic ores include the stratiform quartz-ankerite ""veins"", pyritic carbonates and chert-carbonate-tuff sedimentary rocks and epigenetic ventrelated breccias and stringer zones. Metamorphogenic ores consist of quartz-carbonate fracture fillings in dilatant zones developed during various phases of regional deformation and metamorphism. They are classically epigenetic in character.The evidence suggests a primary syngenetic enrichment of gold on the ocean floor and in vent areas during submarine felsic volcanism and related exhalative-hydrothermal activity followed by further enrichment into quartz-carbonate stockworks during regional deformation and greenschist metamorphism.Although normally thin (a few hundred metres), carbonate members in Archean volcanic terrain represent intense hydrothermal activity which could have transported and enriched gold. They should be used to locate fossil vents and structurally favourable zones where economic concentrations of gold may be found."

Jan 1, 1982

By E. Vesely, A. Saxena

"SAG mill liners are designed for protecting the mill shell and providing lifting power for ore charge and grinding media. Due to the impacts from the charge and the grinding media, the liner experiences dimple, plastic deformation, strain hardening, fatigue, peening and final failure. Because of the collisional environment directly measuring such dynamical loads is extremely difficult if not impossible. In this study we tried to evaluate the liner failure risk by simulating the collisions of solid particles with mill liner using Discrete Element Method (DEM). DEM simulation has been proved to be a very useful tool in evaluation of granular flow and its impacts on the solid structure. But there are certain limits in DEM coherently, such as the number of solid elements, the computer runtime, etc. Here we first present the general feature of the particle-liner collision in terms of impact force and collision energy. Then the effects of parameter selection is discussed. Our simulations show the fatal collisional event of huge impact force is very rare and the collisional events of low impact is much more frequent. The fatal event may contribute most to the liner failure. The rarity of the fatal events may be missed in a short runtime simulation. This technical challenge combined with lacking of criterion to evaluate varying impact loads in fatigue problems may further complicate the evaluation. Should we use the largest impact force alone or we should use the more frequent events is an open question and requires more effort. In order to evaluate the quality of liner design, we proposed a relative comparison method. In the end we show the implication and application of this method in liner optimization by a work example. In particular, the effects of the charge level of grinding balls and their size on the operation performance is presented.INTRODUCTION Grinding is one of the most important and expensive steps of mineral processing. A variety of grinding mills such as rod mills, ball mills, semi-autogenous (SAG) mills and autogenous (AG) mills are being utilized for comminution of mineral ores (Gupta & Yan, 2016). Up to today, SAG mills and AG mills have been widely used to reduce operation costs and increase throughput. In an AG mill, a rotating drum throws larger rocks of ore in a cascading motion which causes impact breakage of larger rocks and compressive grinding of finer particles. Unlike AG mills, SAG mills use steel grinding balls to break ores of size quite small such that they cannot be easily broken in AG mill. SAG mill liners are designed for protecting the mill shell and providing lifting power for ore charge and grinding media. Due to the impacts from the charge and the grinding media, the liner experiences dimple, plastic deformation, strain hardening, fatigue, peening and final failure. Quality and performance of SAG mill liners play a fundamental role to enhance efficiency of grinding mills, because failure of liners is the major cause for unexpected breakdown (Banisi, Hadizadeh, Mahmoudabadi, & Eilkhany, 2006)."

Jan 1, 2019

By G. W. H. Norman

INTEREST in the mineral possibilities (gold, copper) of northern Quebec, north of the Quebec-Cochrane branch of the Canadian National railway, has centred for many years in the Chibougamau district (see Figure 1). Since 1934, however, promising gold discoveries in the Rose Lake-Florence River section, 115 miles southwest of Chibougamau lake, have widened the interest, and prospectors have examined other parts of the country between Chibougamau lake and Bell river and the surrounding districts. The object of this paper is to !resent an outline of the geology, and to describe the mineral deposits, o part of this region, or, more specifically, of the part embraced by the Opawica-Chibougamau and Waswanipi map-areas(l), which include the districts about Chibougamau lake and Rose lake-Florence river, where mineral deposits are now in course of development either by surface or underground work. Early discoveries, developments, and explorations in the Chibougamau district are well summarized in the report of the Chibougamau Commission, published in 1911(2). The Commission discredited previous optimistic accounts of mineral discoveries in the area, made initially in 1903, but at the same time they expressed the opinion that, from a geological standpoint, the district promised a reward to diligent and intelligent prospecting. Their general conclusion-that prospecting in the area was not then (1911) commercially advisable in view of its inaccessibility and other handicaps shifted interest from the district until, some years later, valuable discoveries were made in the Rouyn area, and aircraft widened the field of successful exploration. During the past ten years or so, considerable energy has been spent in promoting the development of the district. The net result has been the discovery of a number of prospects, the majority of which have been explored only by trenching and, in most cases, diamond drilling.

Jan 1, 1936

By J. Budac, R. Kofluk, S. Mankasingh

Stainless steels such as 316L or 304 are normally relatively resistant to attack by nitric acid. However research at Sherritt International’s Fort Saskatchewan Operation reveals that when the stainless steel is immersed in an aqueous system in which nitric acid is used to dissolve metals such as cobalt or nickel, the steel can be seriously corroded. Sherritt is patenting a simple process for arresting the corrosion via the use of copper. This process is expected to substantially eliminate corrosion in processes where nitric acid is used to dissolve metals attached to a stainless steel substrate.

Jan 1, 2014

By R. J. Fruehan

Oxygen steelmaking (OSM) is not only the dominant steelmaking process but defines the structure of the industry. There are a number of myths regarding the future of OSM, which are false. These myths include that the EAF will become the dominant process in the near future, it is less costly to produce steel in an EAF and OSM is a mature technology and no new developments are occurring. These myths are shown to be false. Selected new developments are discussed such as post combustion, recycling of waste oxides, slag splashing and sensors.

Jan 1, 2004