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By V. Barranco, K. Yliniemi, A. Hubin, B. P. Wilson, D. Janas, M. Lundström, P. Hannula

Typical copper electrorefining electrolyte contains tens of grams of copper, some nickel and a wide variety of impurities. Some of these impurities comprise trace amounts of dissolved precious metals like Ag, Pd and Pt that currently are not fully exploited. This study presents an electrochemical method to recover precious metals via a combined electrodeposition-redox replacement (EDRR) process, where energy is used only to deposit copper during the ED-step, while the RR-step relies on the spontaneous replacement of copper by the precious metals (i.e. cementation). In order to conduct the recovery successfully, process parameters such as deposition potential (EDE), deposition time (tDE), redox replacement time (tRR) and the number of cycles (n) was adjusted. Investigations performed in synthetic electrolyte (40 g/L Cu, Ag = 10 ppm) proved the possibility to recover a high purity silver. Short deposition times (tDE) were found to result in small Cu particles that provided a suitably high surface area for silver cementation. In addition, experiments performed in real industrial electrolytes containing 44 g/L Cu and 54 ppb Ag (Boliden Harjavalta, Pori), demonstrated that EDRR could attain Ag recoveries of between 46–67% in an energy efficient, additive-free manner. INTRODUCTION The raw materials used in the state-of-art primary and secondary copper smelters contain mainly base metals, but also notable amounts of Ag, Pt and other precious metals. These valuable metals distribute mostly into the copper matte during the pyrometallurgical treatment (Tirronen et al., 2017) and end up into the cast anodes. During the electrorefining stage, metals more noble than copper such as gold and platinum, are not dissolved but enrich into the anode slimes. In contrast, silver may dissolve slightly and thus, minor chloride addition is used to retain silver in the slime as sparingly soluble AgCl. Moreover, other metals less noble than copper may also dissolve, such as nickel. Therefore the electrolytes used in electrorefining typically contain substantial amounts of copper, nickel and even arsenic as well as minor metals such as antimony and bismuth. In the Boliden electrorefinery these were reported to be in the magnitude of 51.2– 60.4 g/L of Cu, 10.9–15.8 g/L Ni, 7.2–15.9 As, 0.2–0.4 Sb and 0.1–0.4 Bi with an associated sulfuric acid concentration of 139–155 g/L (Lehtiniemi et al., 2018). Copper is the most noble of the dominating base metals in the electrolyte and is thus deposited on the cathode as 99.99% purity LME-A grade. Anode slimes are collected and subjected to precious metals treatment e.g. via pressure leaching—selenium recovery— Doré smelting—Ag refining—Au/Pt/Pd leaching and reduction process (Ludvigsson & Larsson, 2003). The Pori refinery, operating in Finland since 1941, not only produces 133 000 t Cu cathode and 2300 t nickel sulphate annually but also 66 t silver, 4.6 t gold and palladium and platinum (in year 2017).

Jan 1, 2019

By M. Nzotta, L. Teng, S. Seetharaman, A. Chychko

The objective of the present work is to optimize the EAF practice towards Mo alloying with maximum retention of the alloying element in molten steel. During Mo additions, there were significant losses to the dust (ca 7 %) and to the slag phase (ca 2 %), which had serious economic and environmental impacts. The present work was aimed at designing a suitable Mo precursor, an alternative to ferromolybdenum, as the Mo source and a process sequence for optimal retention of Mo in the steel. The design of the Mo source should be in such a way that low cost raw materials such as MoO3 concentrate have to be used, stable during the addition so that the vapour phase losses as MoO3 are kept minimum and the dissolution of the precursor in molten steel is easy without loss to the slag phase. After thermodynamic considerations, three precursor materials were chosen, viz. CaMoO4, MgMoO4 and Fe2MoO4. Synthetic mixtures of the component oxides in each case as well as pure MoO3 were investigated by TGA and high temperature XRD in order to find out the temperature range in which the compounds were formed. Experiments were also conducted separately where the evolved gases were analyzed. All the three precursors were formed easily and the loss of MoO3 to the vapour phase was found to be extremely low. Addition of the oxide mixtures to steel melts were conducted in three different scales, viz. 16 g, 500 g and 3 tons (induction furnacle). Initial experiments showed that MgMoO4 was not suitable since the Mo yield in the steel melt was not very high. Fe2MoO4 was found to perform best, the Mo yield reaching 98 %. Further trials were conducted in the 65 ton Electric Arc Furnace (EAF) at Uddeholms AB in Hagfors. Mixtures of mill scale, MoO3 and carbon in suitable proportions were added in a pre-determined addition sequence. It was found that, in the actual practice, the Mo yield reached 99 %, equaling in performance the addition of ferromolybdenum. The process offers an effective use of cheaper raw materials and very high Mo yield avoiding a pre-treatment step like the production of ferromolybdenum. This is both cost effective and environmentally advantageous. The process has been patented and is being currently implemented at Uddeholms AB, Hagfors, Sweden.

Jan 1, 2011

By C. S. Ha, H. S. Choi, D. Y. Shin

POSCO installed a new 100 ton oxygen bottom-blown converter in 2013 for the development of new steelmaking process named as PS-BOP which is reading POSCO-Saarstahl Basic Oxygen Process. This process was developed by the collaboration research between POSCO and Saarstahl AG in Germany that is based on substantial increase of CO post combustion in a converter by blowing hot air from the top of converter. The collaboration research has been finished successfully in November 2013 with 17% decrease in hot metal ratio (HMR) when hot air was blown from the top of the oxygen bottom-blown converter. After the collaboration research the converter has been tried to be operated as oxygen top and bottom-blown converter to reduce bottom wear and to decrease production cost with increased use of low cost Fe source by the help of increased CO post combustion. The presentation includes experience on the start up of oxygen bottom-blown converter, HMR reduction trials with hot air top blowing and transition from oxygen bottom-blown to top and bottom-blown converter operation.

Jan 1, 2015

By L. St-Georges

In aerospace and transportation industries, severe problems are related to fatigue failure. Aluminium is frequently used in these industries to optimize the solidity and minimise the weight of the structures. Nevertheless, the fatigue life of aluminium alloys is limited and specific efforts have to be made to reduce the vibratory stresses in the mechanical parts. When riveted, the life of the sheet metal structures can be increased compared to welded structures, due to the energy dissipated by the friction between the rivets and the sheet metal and the sheets themselves. In the past decade, a new tool was developed to assemble aluminium structures; the friction stir welding. With this new technique, fatigue life of the aluminium welded joints can be increased by a factor from two to ten. However, less energy can be damped by the friction between the components and increased vibratory stresses may occur. In this investigation, the potential of the friction stir welding to create damped aluminium sheet metal structures is evaluated.

Jan 1, 2006

By O. Bernal

The Sociedad Minera Cerro Verde S.A.A, a subsidiary of Phelps Dodge Mining Company, operates a copper mining facility located in southern Peru. This "mine-forleach" operation currently produces 90,000 mtpy of copper cathode from secondary sulfide ore utilizing crushing, leaching, solvent extraction and electrowinning processes. The leach solution handling and application rates have undergone constant development over the years. This paper discusses the improvements in leach application designed to: 1) satisfy the needs of the "lixiviant request rate", which requires the use of application rates as low as 3.5 L/h/m2 and as high as 15 Llhlm2 with variable rest periods according to the leach kinetics, and 2) alleviate the poor solution distribution on the surface of the leach heaps inherent to drip emitters. Low application rates result in poor surface solution distribution and the formation of upside down cones of dry, non-leached material in the top meter of stacked ore, with heavy jarosite and iron salt precipitation; moreover, ferric iron is lost as insoluble precipitates. On the other hand, high unit flows associated with poor agglomerate quality can lead to uneven solution flow patterns within the heap leading to solution short-circuits, fines migration, and ponding with adverse effects on acid consumption and recovery.

Jan 1, 2007

By O. Hall

STOPING at Noranda" is a sequel to "Mining at Noranda". "Mining at Noranda", presented in 1937 (1), sketches Noranda's history, metallurgical problems, exploration, mining methods, mining details, pillar extraction, and costs. "Stoping at Noranda" deals in greater detail with our stoping, the use of sub-level drifts instead of benches, and the drilling out of the stopes with jointed rock drill steel and diamond drills. Sun-LEVEL DRIFT STOPING: Sub-level drift stoping is almost universal throughout the mine and is the standard sroping method in both sulphide ore and rhyolite flux ore. The features that have led to the adoption of this standard are: (1) Continuous symmetrical drilling in sub-level drifts with no delay for blasting. (2) Large-tonnage blasts Saturday night after the drillers have left. (3) Comparative freedom from gas and smoke during the working days. ( 4) The daily safety achieved by having all stope drilling done in drifts. (5) The safety and security achieved by drilling out stopes, floors, and pillars before there is any weighting or cracking.

Jan 1, 1939

By A. E. Aho

"The material presented in this paper will be subject to modification as new data become available, but it is presented in the hope that it will inspire more intensive mineral exploration and geologic studies of what appears to be one of Canada's richest mineral provinces. A metallogenic province 400 by 150 miles in extent, lying mostly northeast of Tintina trench, encompasses most of the base metal deposits of Yukon, as well as deposits of other metals. Its main features are northwesterly trending arcuate fold belts, with several orogenic axes, which include most of the metamorphosed rocks, granitic intrusives and mineralization; and which are modified by regional uplifts, northwest-striking fault trenches, and lesser transverse folding and faulting.The main base metal occurrences and their regional controls are summarized briefly. Most of the replacement-type deposits are localized in late Proterozoic to early Paleozoic rocks, particularly Lower Cambrian -probably because these are the most physically and chemically favourable hosts encountered in an appropriate temperature and pressure environment; perhaps because of early age of deposition. Most of the deposits also occur near heat sources or intrusives with associated structural uplift, which has, moreover, served to expose the older rocks. They also tend to occur near known or suspected regional fault trenches, such as Tintina, Macmillan and Hess, although this relationship may be fortuitous. In detail, they may be localized in fold axes, flat-lying beds or other appropriate structural traps. Vein-type deposits are fracture-controlled and localized by dilational localfties, the competence of wall rocks and ""damming"" effects.In the Anvil district, large stratiform iron-zinc-lead replacement deposits lie parallel to gently plunging flex-ures in phyllite in a zone parallel to the Tintina trench, along the southwest flank of the arch-like Anvil batholith. About 80 million tons of massive sulphide ore probably existed before erosion of the Faro orebody, the Vangorda deposit could have been of similar magnitude before erosion and much more tonnage probably remains to be discovered in the district. The Anvil deposits may differ from others found to date in Yukon, but resemble the Sullivan orebody of southeastern British Columbia in their large size, localization in essentially non-limy peptic to arena-ceous host rocks of Proterozoic or early Paleozoic age and proximity to the Rocky Mountain -Tintina trench sys-tem. These features suggest an origin from primordial subcrustal sources.More major ore deposits, not only of lead, zinc and copper but probably of other metals as well, will no doubt be found in similar environments in Yukon or Alaska. Thus, the base metal province of Yukon offers challenging opportunities for prospecting, development, field studies and basic research."

Jan 1, 1969

By J. Cayouette, . Blatter, P. Cousin

The Laronde mill was commissioned in 1988 and has been treating the Laronde Perim ore since 2000. The Laronde plant, situated in the Abitibi region of Quebec, has experienced mill expansions to accommodate 7500 mtpd and to recover gold and silver as well as important amounts of base metals (Cu, Zn, Pb). Ten sequential metallurgical and environmental processes are responsible for metals recovery and process viability. Over 200,000 ounces of gold, 4,5 million ounces of silver, 7000 tonnes of copper, and 78,000 tonnes of zinc are produced annually. In 2008, the Goldex plant began trucking high wade (35-45 Wt Au) pyrite sulphide concentrate (TCGO) for gold extraction at a newly constructed treatment plant, increasing gold output at Laronde by 40,000 ounces. In 2009, the high gold wade Lapa ore processing facilities were annexed to the Laronde plant increasing output by 120,000 ounces of gold. TCGO and Lapa productions are forecasted until 2018 and 2015 respectively, with known reserves of each mine. Today, up to 140 permanent employees run and optimise the Laronde plant operation. As a result, Laronde has intricacies intrinsic to a large and varied operation. The paper will outline the metallurgical highlights, challenges, and future outlook related to the treatment of each ore type (Laronde, TCGO, and Lapa)

Jan 1, 2011

By J. M. Wetherill

"This paper presents the results of an investigation into the level of radon, as against the natural background, at the Vicary Creek coal mine in Alberta. The concentrations of radon and daughter products detected in the mine were considered to be insignificantly higher than the concentrations of naturally occurring radon and thus do not constitute a health hazard to the miners.INTRODUCTIONTHE HIGH INCIDENCE OF LUNG CANCER among miners exposed to radon was established some thirty years ago. The presence of this gas in mines is primarily associated with pitchblende extraction operations, al-though coal contains detectab`e quantities of U30s. A previous study bas shown that coal from southwestern Alberta (Exshaw and Banff) contains lower than average concentrations of this element (1).As part of a general investigation into the occupational health environment of coal miners in Alberta, field measurements were made to establish the level of radon and to investigate the natural background radiation in the Vicary Creek coal mine, located some 16 miles north of Coleman, Alberta, on the easternmost slopes of the Rocky Mountains."

Jan 1, 1968

By S. Amid, D. Fisk

"Wireless technologies are permeating the mining and metals industry and enabling a myriad of benefits. With standards such as IEEE 802.11 for wireless devices and ISA100.11a for wireless field instruments protecting their investments, customers look to benefit from the cost and flexibility offered by wireless devices. Using wireless field instruments, plants are eliminating the costs associated with wired system by 50 to 70% and using these savings to install more field instruments, which, when used smartly, enables them to optimize their processes efficiency and equipment reliability. Wireless also empowers a mobile workforce by allowing them to have access to key process and maintenance data directly from the field. This paper describes how wireless can help operations and maintenance personnel to be more effective. Three case studies, illustrating how the mining and metals industry is taking advantage of the technology today, are presented:1.,Optimisation of the water recovery process using wireless2.,Field operations improvement with wireless handhelds3.,Improving fleet maintenance through wireless mobile equipment management"

Jan 1, 2011

By J. Dubinski

Poland is the ninth largest coal producer in the world and Coal Company is the largest Polish producer of this deposit yielding 51% of national production. Coal Company mines are located in the Upper Silesian Coal Basin. These are underground mines which operate in difficult geological conditions at great depths of up to 1200 m. One of the most common natural hazards in Polish mines are rockburst and seismic hazard impacting on surface infrastructure and habitants. In the assessment of the rockburst and seismic hazard methods of mining seismology play a leading role. This paper presents progress that was achieved in the last few years in the implementation of new seismic monitoring systems and seismic interpretation methods for the prevention of hazard deriving from seismicity induced by mining. This progress in assessment of rockburst hazard and impact of seismic activity on the surface infrastructure was achieved through close cooperation between the Coal Company and Central Mining Institute ? the country?s leading scientific institute in the field of mining seismology. New theoretical solutions are in the process of testing in mines of Coal Company where seismic monitoring systems are installed and controlled by well-qualified personnel. Some directions of further joint actions to increase the effectiveness of rockburst and seismic hazard assessment are presented as well.

Aug 1, 2013

By Georges Houlachi, Raynald Labrecque, Jean-Noël Cloutier

"Electrodialysis (ED) is an electro-membrane technology based on electrochemical process using electrical energy for the production of chemicals. The process can be used for concentrating, extracting, separating products, modifying molecules, purifying solutions, pH adjustment and regenerating salts into their base and acid. This paper reviews the principle of ED, present some of the different options and discuss applications that are relevant to the hydrometallurgy and mining industries for the treatment of effluents focusing on recovery of chemicals (acid and metals) and recycling of water minimizing the environmental footprint.INTRODUCTIONElectrodialysis (ED) is usually defined as an electrochemical separation process in which electrically charged membranes and an electrical potential difference are used to separate ionic species from an aqueous solution and other uncharged components [1]. ED technology consists of an electro-membrane technology based on an electrochemical process using electrical energy for the production of chemicals. It is a method combining electrolysis and dialysis was proposed for the first time in 1890 by Maigrot and Sabates [2]. In the late 1930s Teorell, Meyer and Sievers discussed membrane phenomena, revealed membrane potential, electric conductivity, transport number [3]. Meyers and Strauss introduced a multi-compartment ED apparatus consisting of two electrodes and a stack of ion-exchange membranes between them [1]. They succeeded to double the concentration of a KCL solution [3- Tarleton]. In general, ED consumes less energy than electrolysis to perform salt splitting. In that regard, one can expect an energy reduction of about 30% [4–5]. ED offers a great versatility in the domain of separation processes. Indeed, it can be used for concentrating, extracting, separating products, purifying by desalination, pH adjustment and regenerating a salt to acid and base components. This paper reviews the principle of ED, presents various options available and discusses potential applications relevant to the mining and metallurgy industries with economics of some successful industrial applications."

Jan 1, 2016

By E. Krause, V. G. Papangelakis, S. Garg, R. Mahadevan, E. Edwards

"Bioleaching uses iron and sulfur-oxidizing bacteria to extract base metals from sulfide minerals. As bioleaching involves breaking the iron-sulfur bonds by ferric attack, the biologically mediated rate of iron oxidation is recognized to play a key role in influencing the overall kinetics. In this study, we investigate the catalytic ability of an indigenous AMD culture for oxidizing Fe(II) in solution. This culture was subsequently adapted on pyrrhotite tailings (0.6% Ni) by gradually increasing the solids loading. Results from this study show that such an adaptation reduces the initial lag phase in the biotic oxidation of Fe(II), thereby allowing for a higher Ni extraction when compared to experiments with an un-adapted culture at a similar solids loading. The use of adapted cultures also helps to reduce the residence time for bioleaching of Ni from pyrrhotite tailings. INTRODUCTIONAs the world demand for pure base metals grows; the mining industry is increasingly faced with the burden of processing lower grade ores and mining waste streams in order to recover the occluded metal VALUES ((Watling, 2006). The extractive metallurgy of nickel from sulfide minerals focuses on using a combination of mineral processing, pyrometallurgical (smelting) and hydrometallurgical techniques to extract Ni from its ore bodies.Pyrrhotite (Fe1-xS) is commonly found in association with pentlandite and chalcopyrite in sulfidic Ni ores, such as those found in Sudbury, Ontario, and in Russia, e.g. Norilsk. The vast majority of this pyrrhotite needs to be removed using mineral processing techniques, in order to minimize the Fe and S contents of the concentrates that proceed on to smelting. If all pyrrhotite were left in the concentrate, much more slag and SO2 would be produced, and the smelter throughput would be limited. Beneficiation of Ni sulfide ores leads to the rejection of unwanted constituents as mining wastes, which may still contain extractable amounts of Ni (Edgar Peek et al., 2010)."

Jan 1, 2012

By J. -M. Lalancette, D. Lemieux, C. Chouinard

"A gold bearing concentrate containing 107 g/T of gold, 9.3% copper and 706 ppm of mercury was processed at the demonstration scale for the extraction of gold and copper using a cyanide free process. The concentrate was generated through flotation to upgrade the gold and copper grade, but also showed contamination with mercury. This concentrate was submitted to the DST process demonstration plant. The concentrate was first oxidized using a fluidized bed to produce a calcine. The mercury was volatilized during the oxidation stage with an efficiency higher than 98%. The mercury was condensed and removed from the sulfuric acid using a thiosulphate process. Copper was extracted from the calcine as copper sulphate using diluted sulfuric acid. The solid remaining after acid leaching was submitted to the DST chlorination process for gold extraction. Under optimized conditions, a gold extraction of 97.3% was achieved in the chlorination reactor. Gold was recovered from the pregnant brine by precipitation on silica using a DST proprietary process.INTRODUCTION Dundee Sustainable Technologies Inc. (DST) offers proprietary metallurgical processes for the treatment of material from the mining industry. DST processes enable the extraction of precious metals and for the removal and stabilization of contaminants, such as arsenic, from ores and concentrates. DST provides environmentally-friendly, viable and efficient processes, capable of handling complex and refractory ores which cannot be processed with conventional approaches due to metallurgical issues or environmental considerations. Several mining jurisdictions around the world have banned or restricted the use of cyanide. DST has developed a closed loop chlorination process as an alternative to the conventional cyanidation process for the extraction of precious metals from minerals. The tailings from the process are inert from toxic substances such as cyanide and organic compounds, are sulphide depleted which means they do not generate acid, and thus, meet and/or exceed environmental norms. The process has demonstrated excellent gold recoveries within a fraction of the time needed for cyanidation to obtain similar results. Moreover, the closed loop process does not generate any liquid effluent and does not consume much water: it only requires a water make-up to compensate for moisture leaving with the tailings and by-products, and seawater may be used. The improved environmental footprint of the DST process has been certified by the Environment Technology Validation program (ETV) which provides an independent evaluation of the performance claims of innovative technologies."

Jan 1, 2017

By Matej Petružálek, Václav Vavrycuk, Tomáš Svitek, Tomáš Lokajícek

The most common type of waves used for probing anisotropy of rocks in laboratory is the direct P wave. Information potential of the measured P-wave velocity, however, is limited. In rocks displaying weak triclinic anisotropy, the P-wave velocity depends just on 15 linear combinations of 21 elastic parameters, called the weak-anisotropy parameters. In strong triclinic anisotropy, the P-wave velocity depends on the whole set of 21 elastic parameters, but inversion for 6 of them is ill-conditioned and these parameters are retrieved with a low accuracy. Therefore, in order to retrieve the complete elastic tensor accurately, velocities of S waves must also be measured and inverted. For this purpose, we developed a lab facility which allows the P- and S-wave ultrasonic sounding of spherical rock samples in 132 directions distributes regularly over the sphere. The velocities are measured using a pair of P-wave sensors with the transmitter and receiver polarized along the radial direction and using two pairs of S-wave sensors with the transmitter and receiver polarized tangentially to the spherical sample in mutually perpendicular directions. We present an inversion method for elastic parameters describing general triclinic anisotropy. We demonstrate on synthetic tests that the inversion becomes more robust and stable if the S-wave velocities are included. This applies even to the case when the velocity of the S waves is measured in a limited number of directions and with a significantly lower accuracy than that of the P wave. Finally, we analyze velocities measured on a rock sample from the Outokumpu deep drill hole, Finland, including the error analysis for several levels of confining pressure.

Jan 1, 2015

By Eduardo A. Pérez, Alejandro R. Alonso, Rosa María Luna-Sánchez, Gretchen T. Lapidus

Rare earth elements have been widely used in various sectors, from the aerospace and steel industries, to electronic applications, particularly in displays and batteries for portable devices. The high demand for newer and better equipment, such as cell phones, tablets and lap tops, has increased the consumption of the rare earth elements and at the same time the need for its recovery from electronic wastes. For that reason, the recycling of batteries is important, principally the Ni-HM batteries, due to their elevated content of rare earths elements, in addition to the high concentrations of cobalt and nickel. The current processes are based on dissolution in strong acid solutions (sulfuric acid concentrations from 2 to 4 mol/L), and temperatures from 30 to 90°C. In the present work, electrodes from spent Ni-HM batteries were leached using 1 mol/L H2SO4, in the presence of ozone as the oxidant, where recoveries of 96% for La, Ce and Nd were obtained at room temperature. The separation of Ni and Co from the leach solutions was performed using an electrochemical reactor, after which rare earth elements were precipitated, obtaining a mixture of its hydroxides with impurities below 1%, according to EDS analysis.

Jan 1, 2014

By N. N. Rulyov

"Starting from fundamental principles of colloid-hydrodynamic theory of disperse systems we have shown that application of strongly non-uniform hydrodynamic fields allows to achieve not only faster rates of flocculation of suspension, but also supports significant improvements in the quality of clarified water and separation characteristics of solid phase. Specifically, it has been experimentally proven that the new treatment method based on these principles (then termed as ""ultra-flocculation"") allows:•,Increase the output of thickeners and pressure filters by 1,5-1,7 times;•,Decrease solids fall through into the filtrate in the process of vacuum filtration by 2¬3,5 times;•,Improve the rate of purification of water phase in the upright thickener by 1,5-1,9 times;•,Decrease flocculant consumption by 1,5-3 times;•,Increase the effective operational life time of cloth filters by 3-4 times;•,Ensure sustainable operation of separation equipment, i.e. decrease the sensitivity of process to variation in suspension concentration, as well as to variations of suspension composition and dispersion characteristics;•,Apply flocculant solutions of concentration 2-3 times higher, thus increasing the capacity of equipment used for solutions preparation."

Jan 1, 2004

By DON E. MacDONALD

Marl in Alberta is confined to highly specific geological, hydrogeologica/ and climatic settings. Tufa is fa irly abundant in those areas of western Alberta where bedrock is of the Paskapoo Formation. Marl and tufa originate when the following conditions are met: presence of a carbonate source in drift or nearsurface bedrock; leaching of the carbonate by percolating groundwater; transportation of calcium and bicarbonate ions in a permeable aquifer; discharge at the surface as springs, seeps or lakes; re-precipitation of calcium carbonate. Alberta has seven categories of marl and tufa deposits, based upon over-all depositional environment and calcium carbonate

Jan 1, 1984

By Peter C. Jones, Wanda M. Carter, David H. Watkinson

"Abstract - Pyrrhotite, chalcopyrite, and pentlandite are the dominant sulfide minerals in the 740 zone of the Kelly Lake orebody (Inco Ltd.), Copper Cliff Offset, Sudbury. Petrographic and quantitative electron microprobe analyses of minerals, from sulfide assemblages and host quartz diorite, of the 740 deposit have revealed three processes that have affected sulfide mineralization and associated sulfarsenide and platinum-group-mineral (PGM) distribution: magmatic, hydrothermal, and tectonic. Accessory, zoned cobaltite, and gersdorffite occur in sulfides as a result of these three processes, and PGM occur dominantly in hydrothermally remobilized and deformed ores. Where PGM are present in sulfarsenides they provided nuclei for sulfarsenide growth. Solitary PGM are orders of magnitude larger than those PGM found within sulfarsenide minerals. Five varieties of PGM occur, michenerite and sperrylite being the most common, with lesser froodite, hollingworthite, and ruarsite.The effect of a deformation is a localized fabric in the ore, revealed by pyrrhotite and chalcopyrite bands; pentlandite porphyroblasts also partially define the foliation. The deformed ore is also characterized by alteration of the adjacent quartz diorite, which produced an alteration assemblage including almandine garnet, Fe-rich biotite, and chlorite."

Jan 1, 2001

By A. Haldar

The major problem encountered in the casting of hypereutectic Al-Si alloys is the stoppage of flow below the rigidity level of solid fraction. In this study, the flow stoppage mechanism was studied using three Al-Si alloys with 14%, 18% and 22% silicon. The horizontal foam patterns used were 12.50 mm (0.50 inch) wide with two section thicknesses 12.50 mm (0.50 inch) and 6.25 mm (0.25 inch) with a common sprue. The primary silicon distribution along the length of the casting was studied to determine the mechanism of flow stoppage. It was found that the surface of the flow tip of Al-14%Si alloy was smooth with a few undulations. As the silicon level increased, undulations at the flow tip increased. The number and size of undulations were maximum for the Al-22%Si alloy. Microstructural analysis using optical image analyzer revealed that the flow tip consisted mainly of eutectic silicon in the aluminum matrix and a few primary silicon crystals (PSC). The PSC were in the interlocked condition few centimeters behind the flow tip. It was also found that the gap between the flow tip and the PSC concentrated area increased with an increase in silicon level. Phase characterization was done with SEM-EDX to identify the precipitating phases.

Jan 1, 2007