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A wide variety of process streams are sampled for grade control in the mining industry. However, in many instances the overall precision of the resultant analyses is inadequate for the intended purpose, ie grade control and optimisation of resource utilisation. Consequently, special attention needs to be given to the sampling, sample preparation and analysis procedures in place to ensure that meaningful grade control decisions can be made based on the analyses generated. For example, it is virtually impossible to control a process to within, say, ¦0.2 per cent if the overall precision of the analyses is no better than 0.5 per cent. Hence, precision targets appropriate for the task need to be established and the overall precision achieved in practice monitored and controlled on an ongoing basis.

Jan 1, 2008

Naturally occurring rutile contains approximately 96 per cent titanium dioxide (Ti02), whereas the product from the ilmenite reduction - aeration upgrading process, "sub- rutile", contains only about 92 per cent Ti02. Therefore, there is an-incentive to lift the quality of sub-rutile by removing transition metal impurities, in order to supply a more valuable and marketable product, particularly for the chloride-route pigment producers. Previous studies have shown that the sub- rutile residual iron content (of approximately 4 per cent) and residual manganese content (of approximately 1.5 per cent) are chemically bound within the titanium-oxygen mineral lattice, and are most difficult to remove by simple leaching methods. In attempts to improve their eventual removal, a simple process modification has been successfully investigated in laboratory scale trials. Transition metal sulphides have been formed in the reduced ilmenite by using a "sulphur-doping" technique during reduction (metallization) conducted at controlled temperatures. These compounds give rise to greatly enhanced dissolution of the unwanted transition metal constituents during the sub- sequent aeration and acid washing steps. Thus, the manganese content of the final sulphur- doped, reduced-aerated, acid washed product can be reduced by about 90 per cent to 0.2 per cent, and the iron content by about 70 per cent to less than 1.5 per cent, in comparison with those levels remaining after unmodified pro- cessing. Additions of sulphur as low as 2 per cent of the weight of the ilmenite have proven satisfactory. Preliminary studies reveal that the modified process is economically feasible. These results suggest that the sulphur content of the Collie coal char used in an unmodified reduction step must exert some influence on the eventual removal of iron and manganese during aeration and acid washing.

Jan 1, 1973

Exploration for uranium in Australia has so far discovered reserves equal to 17.5% of the Western World's. The Australian uranium industry, when fully developed, will be one of the largest producers and possibly the largest exporter in the world. The world's nuclear industry is young, rapidly developing in size and technology and is subject to more social, political and regulatory controls than any other industry. This paper considers the probable development of Australia's uranium industry against a background of normal commercial parameters together with other factors which are peculiar to the nuclear industry. As the theme of this conference is "Australia's role in the World Mineral Indus- try" this paper concentrates on the commercial and practical aspects associated with the development of Australia's uranium resources in a world context.

Jan 1, 1979

I stand here as a financial advisor who has been particularly close to the whole concept of reporting, independence and all the issues that are brought together in Release 149. However, I was asked to introduce this session by dealing with matters of Prospectuses, Part B's, 3J3's, 12G's and other requirements to report. Now I find it very interesting that one of the keynote issues is whether or not one should have a panel from which one chooses the so-called expert, and this is to deal with the question of independence.

Jan 1, 1989

By J G Reid

In the period since 1989 the Yabulu Nickel Refinery of Queensland Nickel has undergone a transformation both in terms of the nickel laterite ore feed and the refined nickel product. These two changes were mutually supporting, as will be shown in the following paper. It had been realised since the early-1980s that the Greenvale orebody would be exhausted by 1992. Consequently planning had been in progress throughout the 1980s for the importation of overseas ore as a replacement for the Greenvale ore. The existence of extensive lateritic ore deposits in New Caledonia and Indonesia made these locations the natural focus of attention. With the three Japanese ferronickel smelters sourcing their nickel garnierite ore feed from these locations it was relatively easy for the miners to supply the overlying limonite ore to Yabulu. This limonite ore was previously discarded as waste. The Yabulu refinery now receives about 85 per cent of its ore from these two overseas sources. The transition from Greenvale ore to imported ore occurred gradually between 1989 and 1993. It was during the ore importation planning stage of the mid 1980s that Queensland Nickel commenced the technical investigation which led to the ammoniacal solvent extraction (ASX) plant installation and the product change from nickel oxide to nickel metal.

Jan 1, 1994

Mount Isa Mines Ltd. annually extracts 5.6 million tonnes of copper ore from the 1100 Orebody. All production is by longhole open stoping, with an increasing emphasis on pillar recovery. Drilling and blasting prac- tices have been modified to allow more efficient pillar extraction, with the evolution of a "core and shell" approach. Blast design occurs at the stope design stage, while individual blast preparation is based on detailed ring plans. A programme of blasting research involving surface and under- ground vibration monitoring and fragmentation assessment has been car- ried out in conjunction with production personnel. Drilling and blasting practice in the orebody must continue to evolve with continued research, to suit changing conditions and take advantage of new technology.

Jan 1, 1988

Mount Isa mine is the largest underground mine in Australia and is located 2,000 kilometres north-west of Brisbane. This mine has been in continuous operation since 1931 and in 1986/87 the silver/lead/zinc stream achieved the peak annual mining rate of 4.7 million tonnes. At present about fifteen different steeply dipping stratiform orebodies are being mined to maintain an annual production rate of around 3.0 million tonnes. Out of these, only two orebodies (2 & 5) are amenable to sub level open stoping (SLOS) type bulk mining methods. This year only 150,000 tonnes are scheduled from pillars and remnant areas but in future, more sources will be required to meet the budget production targets.

Jan 1, 1990

By Hood M

Rock cutting excavation technologies and particularly continuous excavation technologies, can offer benefits in the areas of reduced costs, higher revenue and increased safety in a variety of mining situations. Non-explosive rock excavation technologies for example, can deliver significant benefits in the areas of dilution and improved ground support (no overbreak). This paper is an attempt to focus on the development and future of alternative rock breaking technologies and to provide some insights as to why and how we should proceed in this direction. The market size for underground hard rock excavation technologies is examined. A short review of the evolution of various rock excavation technologies in terms of cost and production rate is given and a summary of the state-of-the-art technology is presented. Mechanical excavation technologies (TBM) have very high production rates compared to D&B and the gap is widening, however, they have not been successfully applied to mining applications. Operating costs for mechanical and D&B systems have been dropping over time, however, D&B costs are the lowest. Given the current state of knowledge it appears that with regard to hard rock underground metalliferous mining that R&D efforts should be focussed in the following areas - disc cutter tool development (materials and design; operation; presentation to the rock surface), hybrid cutting systems (consisting of water jets and disc cutters) and development of pressurised hole breakage technologies. It is also possible that two techniques known as the pulsed laser and pulsed water jets may have some potential. The generally agreed specifications for a widely applicable underground hard rock excavating machine are - disc cutter based, a minimum production rate of 100 t/h, be flexible, manoeuvrable and deployable, weight of less than 100 tonnes and be economically competitive with D&B in rocks over 150 MPa UCS. Such a machine would seriously challenge the position of conventional D&B in a wide range applications and provide some of the benefits of mechanisation and automation that the mining industry is pushing so hard for. However, technology developments in the D&B area are not static and hence the target is moving and is increasingly difficult to overtake.

Jan 1, 1995

By Amer S, Novais A. Q, Limpo Gil J

A proprietary hydrometallurgical ammonium chloride process for the recovery of not only zinc, but also copper, lead and silver from sulphidic zinc-rich concentrates has been developed at bench scale by CENIM and INETI (ex-LNET) as part of a research project supported by the Commission of the European Community (DGXII). This paper deals with the innovative chemical aspects applied to this chloride process and also with the more relevant data relating to mass balance, heat balance and process economics. Under mild temperature and oxygen pressure leaching conditions it is possible to extract practically all the zinc together with the other metals of interest and to precipitate simultaneously the solubilised iron fraction as goethite. The pH is kept close to neutrality in spite of the ammonia released in the leaching of the non-ferrous sulphides. A buffer effect is observed mostly due to the formation of zinc ammines which are very soluble in this medium. The zinc is further extracted by D2EHPA, the acidity being neutralised by the ammonia. Most of the ammonium chloride is naturally regenerated in this step. The zinc is recovered as zinc cathodes in a conventional sulphate electrowinning circuit. All the main raw material consumptions excluding the concentrate, such as oxygen, lime and ammonium chloride are linked to the sulphate formation in the leaching step which must be kept as low as possible by decreasing the reaction time under neutral conditions. The process analysis is complemented by the economic evaluation of a reference case. Difficulties encountered in finding a more convenient method of assessing the economics of the process in the absence of a reference price for a complex sulphide concentrate are examined and discussed. The reason why this analysis was performed with a much more optimistic metal prices scenario is also highlighted. The process economics are primarily dependent on the zinc market quotations and of course on the concentrate cost. Around 70 per cent of the total revenue is due to zinc sales. Assuming an internal rate of return of 17 per cent, the price of the concentrate can be as high as 255 $US/t for a plant capacity of 320 000 t/y (90 000 t/y of zinc).

Jan 1, 1993

By Nilmani M, Fountain CR

Injection of gases into slag-melt mixtures produces various zones as a result of bubble formation and disintegration within the melt. The extent of these zones depends on the type of reactor used. When compared with ferrous processes, non ferrous processes are character- ised by large bubbles formed adjacent to the tuyeres, low flowrates and shallow tuyere sub- mergence. These features can result in a greater proportion of reaction occurring above the bath, more refractory wear and tuyere blockage with more splashing. The large bubble zone adjacent to the tuyeres has been investigated using the tech- niques of physical modelling, mathematical modelling and plant trials. Large bubble form- ation in physical models was recorded using a high speed camera and a rapid response pressure transducer coupled to an oscilloscope and data recorder. It was found that the bubble volume (Vb) could be correlated at low flowrates using the single bubble model Vb = 1.378 Q6/5 g-3/5 Deviations from this correlation occurred with increasing gas jet momentum. Plant trials were carried out on a copper converter at Mount Isa Mines during five different charges. Pressure measurements were made through the tuyeres during the slag blow and commencement of the copper blow. The power spectrum density showed that the dominant pulse amplitude occurred at a frequency of approximately 3 pulses/sec. Plant data from this and other converters were correlated using the same relationship as for physical modelling. De- viations occurred due to the state of the re- fractory, bath composition or bath circulation effects.

Jan 1, 1984

By Miller M. J, Bauer J. C

The continuous copper drossing process operated at Port Pine since 1962 has had limited copper removal capacity as determined by a maximum tolerable Cu/S ratio in feed and the level of sulphur in blast furnace bullion. Recent process development has been to overcome these limitations to meet increased copper throughput requirements. A sulphur addition system was developed and installed in August 1987. The system has capacity to increase sulphur input by over 150%, meeting the increased copper capacity requirement and also allowing independence from the upstream process for sulphur supply. Developments in process understanding have been applied within the limitations of the existing furnace design with a 10% increase in the maximum tolerable Cu/S ratio.

Jan 1, 1989

By K Nakashima, K Aya, T Sumita, N Saito

Electro slag remelting (ESR) is one of the methods used to produce high-cleanliness steel. In the ESR method, the product steel electrode is immersed in flux, and the electrode is melted by the Joule heat of the flux generated by high current. CaF2-based melts are mainly used as fluxes, but the electrical conductivity of CaF2-based melts varies widely among researchers and measurement methods. Therefore, this experiment aims to measure the electrical conductivity of CaF2-based melts based on the van der Pauw-Ohta method, which does not require the cell constant that is a fundamental error factor in electrical conductivity measurement at high temperatures. The measurement temperature was set at 1450–1600°C, and dehydrated Ar flowed through the furnace at 200 mL/min. Electrodes were fabricated by Pt-30mass per cent Rh alloy, and the electrodes were connected to an impedance analyser using a four-terminal probe. The electrodes were immersed in the melt, and the impedance and phase angle were measured by AC frequency sweep (50 Hz to 200 kHz). The electrical conductivity was then calculated by utilising the impedance’s real part values when the impedance’s imaginary component was zero. The electrical conductivity showed a positive temperature dependence. The electrical conductivity of 60(CaO⋅Al2O3)-40CaF2 melt increased with increasing temperature but was found to be roughly one-third of those of the previous studies. In the conductivity measurement of 60(CaO⋅Al2O3)-40CaF2 melt, the AC frequency with a phase angle of 0° was found to be different depending on the temperature and immersion depth. By sweeping the frequency, the impedance at the phase angle of 0° can be obtained, which enables us to measure the electrical conductivity more accurately.

Jun 19, 2024

Coal exploration and mine planning now use all the modem techniques to indicate geological hazards to a new or developing coal mine. Drilling, seismic and other sophisticated geophysical methods aim to increase the reliability of prediction of features which will inhibit mine development. But do they?. During the past 40 years, geological investigations for coal mines in New South Wales have ranged from the general observations of Eric Rudd, in the Southern Coalfield in the late 1940s to the very detailed examinations of roof strata by John Shepherd and others in the 1980s. Then, the large scale regional relationships between sedimentary and structural features often were ignored as the minute examination of seam roof strata became fashionable.

Jan 1, 1991

By Best R. J, Poulos H. G

The method for design of primary roof support for the large todoidal cavern constructed to house the Sydney Opera House parking station is presented. The cavern was constructed with 5 m of rock cover beneath Sydney's Royal Botanic Gardens. Design of rock reinfonnent using a combination of fully grouted rock dowels and Macalloy bars was based on control of horizontal shear movement along bedding features in the roof. A combination of linear arch type analyses and non-linear jointed finite element analyses were used in the design study together with an analysis of the shear resistance offered by fully grouted bolts under shear deformation.

Jan 1, 1993

By LeJuge G. E, McKenzie C. K

Innovative mining and blasting techniques were demanded at the Richmont Mines, Francoeur Mine in Quebec, Canada, by a narrow, shallowly dipping high grade gold ore body. The ore body being mined occurs as a thin tabular deposit varying in thickness between 1.5 and 3.7 metres, and dipping at 36¦. The mine proposed experimenting with open stoping techniques using small diameter drill-holes. The hangingwall required progressive, full face rockbolting after each production blast, utilising a specially manufactured machine which provided access to the hangingwall for both scaling and bolting. Blasted material is mucked from the stope by scraper and hoisted directly to surface without benefit of primary crushing.

Jan 1, 1992

The paper describes the development leading to the bucket wheel excavator systems now used in the Latrobe Valley and refers in particular to the new S.E.C.V. dredgers Nos. 14 and 15 which will be employed in the Loy Yang open cut. The design concept and operating possibilities of these dredgers are described in detail with reference to the machine characteristics designed for the operating conditions in the Latrobe Valley. The design is compared with units of similar capacity in open cuts of other countries.

Jan 1, 1982

By King CJ

The C.S.A. concentrator of Cobar Mines Proprietary Limited was expanded in 1974 to treat 80 000 tonnes of copper-lead-zinc ore per four week period. Jaw crusher product is fed to two par- allel primary autogenous mills followed by a secondary ball mill. Each mill operates in closed circuit with cyclones. Improved control of grinding rate and product sizing has been obtained from this circuit compared with the system of two parallel single stage autogenous mills. The main operational variables are des- Cribed.

Jan 1, 1978

Working thick coal seams in Poland is a very serious problem. Nearly 40 per cent of all coal is extracted from seams more than 3 m. thick. In absolute figures this represents about 70 million tons of coal per year. Working seams with thicknesses up to 3.5 m. does not present, at present, major difficul- ties. Working thicker seams calls for a steady improvement in order to increase the degree of utilization of the deposit and to enlarge the concentration of output. The problem is sometimes more difficult because, in many cases, the seams are worked under protected surface structures which compels the mines to use hydraulic stowing with all its advantages and disadvantages. Rock burst hazard, the control of which is the basic problem hindering the mining, is a further problem. The mining systems used in Poland are adapted to these natural and technical conditions.

Jan 1, 1976

By H R. Watling, W van Bronswijk

Of the various copper sulfides in the EarthÆs crust, chalcopyrite is by far the most common. This mineral is also the most difficult to leach, with hydrometallurgical extraction processes characterised by prohibitively slow kinetics. While a number of processes, including leaching at atmospheric pressure and temperature, pressure leaching at higher temperature, and bioleaching of concentrates in stirred tanks and whole ores in heaps have been demonstrated to some extent, there is currently no full-scale unit process for the hydrometallurgical extraction of copper from chalcopyrite ores. Titan Resources NL operated a test bacterial heap leach at Radio Hill, Western Australia in 2001, to extract nickel and copper from a mixed sulfide ore that contained significant amounts of chalcopyrite, pentlandite and pyrrhotite. A proprietary mixed bacterial culture was used to inoculate the heap, and the nickel and copper were precipitated from the resultant solution as mixed hydroxides. Although 65 per cent of the copper from the Radio Hill heap was eventually recovered, the rate of extraction followed an unexpected trend, as the initial rates of copper recovery were much slower than column tests had suggested. It was postulated that this was due to dissolved copper precipitating as covellite or chalcocite in the most poorly aerated zones within the heap, ie furthest from the aeration pipes at the base. It was further hypothesised that the lack of oxidants (oxygen, ferric iron) and the likely inactivity of bacteria in these areas limited the re-dissolution of such secondary copper precipitates. In this study the above hypothesis was tested in column experiments using the same mixed sulfide ore and a synthetic leach solution. One set of columns was aerated and another set was operated without aeration. Results showed that precipitation of copper occurred regardless of whether the column was aerated or not. The results suggested that pH of the leach solution played a significant part in the precipitation of the copper. Further column tests revealed this to be the case. These results are described here in detail.

Jan 1, 2004

By S Prakash, P S. R Reddy, S K. Biswal, V N

The beneficiation potentials of two Indian iron ore slime samples by flotation technique using both cationic and anionic collectors are investigated. The direct and reverse flotation of slimes using oleic acid and dodecylamine as the collector have been studied using both conventional cell and flotation column to upgrade the iron content. The characterisation studies of iron ore slimes indicated that the samples are extremely fine in nature and contain substantial amounts of martite, magnetite, goethite, limonite, kaolinite and quartz beside hematite as the dominant iron mineral phase. The samples on average contain around 52 - 58 per cent Fe, four to seven per cent SiO2 and five to six per cent Al2O3. Taking into account the physico-chemical properties of the slimes, it is attributed that both the samples need to be deslimed by hydrocyclone before flotation. The results of both cell and column studies on sample I showed that a feed containing 57.5 per cent Fe could be upgraded to 65.5 per cent Fe at 50 per cent overall recovery with simultaneous decrease in SiO2 and Al2O3 content to 2.3 per cent and 1.8 per cent respectively by using oleic acid as the collector. In the case of sample II, it has been established that reverse flotation of silica is the better technique to improve both the grade and recovery of iron. Batch flotation studies in cell indicated that a product with 63.1 per cent Fe could be obtained at 40.0 per cent yield with 63.6 per cent iron recovery by the combination of reagents such as gum acacia, sodium hexa meta phosphate and dodecylamine. The performance of column flotation techniques is far superior to that of the cell with respect to both grade and recovery. The concentrates are found to be quite suitable for commercial exploitation as pellet feed.

Jan 1, 2005