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By L. Mabiza

Keywords: Pyrometallurgy, furnace, sulphur, SO2, off-gas, Zimplats Zimplats embarked on an off-gas sampling campaign in December 2009 to characterise the concentration of SO2 in the off-gas from their 13 MW furnace. In excess of forty isokinetic samples (US EPA Method 8) were taken over seven days. The aim of the sampling campaign was to increase the understanding of factors that influence sulphur release from sulphide concentrates in an electric furnace. Specifically, detailed monitoring was conducted over various operating conditions to evaluate: ? The relationship between SO2 and feed rate (i.e. furnace power) ? The relationship between SO2 and ingress (i.e. furnace freeboard pressure) ? The impact of concentrate bed thickness on SO2 (i.e. blacktop) ? The effect of events such as tapping and converter slag return on SO2 ? The desulphurization reactions that take place in the blacktop A model was developed to predict the SO2 content in furnace off-gas for a particular set of operating conditions. In order to evaluate the impact of random, uncorrelated changes in concentrate composition, ingress and power (feed rate) on the SO2 content of the off-gas, a Monte Carlo approach was adopted whereby concentrate composition, power, and ingress were allowed to vary randomly around selected set-points. The model is primarily based on the release of ?labile? sulphur from the partial thermal dissociation of sulphide minerals with an over-stoichiometric sulphur content (e.g., Fe7S8 decomposition to FeS and S). The main findings of this work suggest that labile sulphur does not fully account for the measured SO2 content of the off-gas, and that limited oxidation of sulphides during melting also contributes to the SO2 content. Details of sulphide oxidation reactions in the furnace remain unclear, and it is currently not possible to provide a theoretical framework for the relationship between the extent of oxidation and variables such as temperature, gas composition, particle size, and residence time in the furnace black top. Through the use of the Monte Carlo model it was, however, possible to constrain the extent of sulphide oxidation to about 1%. This work has shown in practice what was expected in concept, that SO2 in off-gas is proportional to furnace power and ingress rate. The model that was developed consistently slightly under-predicts the quantity of SO2 generated. It also highlights that more work is required to better understand the analytical methods used to analyse for SO2 in off-gas.

Jan 1, 2011

By R. Steele

In addition to compliance with government emissions and reporting requirements, mining and mineral processing companies are increasing energy efficiency to reduce costs and become more competitive in the global marketplace. One of the major obstacles to identifying opportunities for increased energy efficiency is the lack of readily available data on energy use, and more importantly the energy use linked to production data, that identify energy reduction opportunities. As well as energy reduction, mining and mineral processing companies often struggle with the prediction of energy use, and are often penalized for under or over forecasting. Once again, it is the lack of timely information that makes this prediction difficult. This paper looks at expanding the use of a Manufacturing Execution Systems by integrating with Energy Solutions. This will provide automatic, timely information, at a granularity that makes it easier to identify energy reduction opportunities, reduce energy costs, and better predict energy use in a mining and mineral processing operation.

Jan 1, 2011

By E. Ringdalen

Keywords: Pyrometallurgy, research, Norway, SINTEF, NTNU The Norwegian Ferro-alloy Industry and the model for research cooperation between SINTEF, NTNU, and the Norwegian ferro-alloy industry is presented as an introduction. The research within pyrometallurgy is illustrated by examples from characterisation of Mn-ores and characterisation of carbon materials. Examples from studies of reaction mechanisms in laboratory- and pilot-scale experiments are presented, in addition to an example of industrial off-gas measurements. Education possibilities at NTNU are also described.

Jan 1, 2011

By Tony Moore, Peter Riccio

"MMG (Minerals and Metals Group) operates the LXML Sepon’s mineral processing facility located 40 kilometers north of the town of Sepon, in the Savannakhet Province, Lao PDR. The Sepon copper plant produces 70,000 tons/year of LME grade A copper cathode using leachautoclave- SX/EW-flotation technology (Baxter et al., 2003). Pyrite recovery in the flotation circuit is critical to the operation, as it is used to generate acid and soluble ferric ion for the leach circuit. Low pyrite recovery has been an on-going challenge in the flotation circuit. Final tailings characterization work done by Ian Wark Research Institute (Bassell et al., 2006) showed that the pyrite losses to the tailings are made up of a combination of coarse liberated particles and finer particles that have been coated by clay fines.In December of 2005, a joint Cytec-MMG technical program was initiated to address the pyrite recovery issue. A series of diagnostic tests were performed in the Cytec Stamford Research Facility using synthetic plant water showing that the collector was precipitating as a metal salt and was unavailable for mineral attachment. The tests also identified several collector chemistries that would likely be robust in the low pH (< 1), high dissolved metal ion environment and will not complex with metal ions in solution. With the support of the Sepon on-site engineers, an extensive, successful laboratory program was completed, which was subsequently followed by on-plant testing that showed a step wise improvement in pyrite recovery.INTRODUCTIONLow pyrite recovery has been an ongoing problem in the flotation circuit at Sepon. Sulfur recovery (indirect measure of pyrite) was improved from 40% to 65%-75% in mid-2005 when on site laboratory work confirmed that AERO® 8045 Promoter was a more effective collector then AERO® 407 Promoter. However, sulfur recoveries above 65% could never be achieved. Sepon requested the Ian Wark Research Institute to complete a surface analysis study using Scanning Electron Microscopy, X-ray Photoelectron Spectroscopy, and Time-of-Flight Secondary Ion Mass Spectroscopy to determine if clay coated pyrite played a role. It was concluded that the pyrite losses to the tailings are made up of a combination of coarse (+ 100µm) liberated particles and finer (-74µm) particles that have been coated by clay fines. The majority of the losses appear to be due to the former. In December of 2005, a series of diagnostic tests were performed in Stamford using synthetic plant water in order to identify what chemistries would likely be robust in the slimy low pH and high dissolved metal ion solution environment. Results showed that several chemistries would not complex with ferric, ferrous or copper in solution and therefore should perform well in the Sepon flotation. The incumbent collector, AERO® 8045 Promoter was complexing with metal ions in solution. This resulted in the collector not being available for adsorption onto pyrite."

Jan 1, 2011

By Q. H. Bui

The elastoplastic self-consistent model is one of the effective models to study the initial microstructure effect on the mechanical behavior of bulk materials. However, the use of this micromechanics-based model which takes into account only the Hall-Petch relationship at grain level for predicting the grain sized effects on the strength of the deformed materials is not accurate yet because of the fact that the dislocation density contributes also to the strengthening of this kind of materials. In this study, a modification made to the Hill-Hutchinson elastoplastic self-consistent model was proposed for investigating the microstructure dependence of the mechanical behavior of cold-drawn 6063 aluminium tubes. Because of the novel modification, an estimation procedure with two steps was required to identify the parameters of this micromechanical model. An acceptable agreement between experimental and theoretical stress-strain curves was achieved.

Jan 1, 2011

By Y. Paul Chugh

NIOSH and the Illinois Clean Coal Institute are funding studies on characterization of coal and quartz dust in Interior Basin mines since 2009. Coal dust characteristics vary significantly and, are vital for the development of the engineering controls. This paper presents wettability characteristics of coal dust with respect to its chemical and physical properties, since wettability is considered to be a primary dust control technique. Particle size distribution, inter-particle interactions during wetting and quartz associations with organic and inorganic matter in coal seams is critical for understanding wetting phenomena. Silica content in the un-wetted fractions was found to be very high during wetting tests. Wetting of quartz may be limited by its association to hydrophobic materials as well as buoyancy forces resulting from particle size characteristics and particle-particle interaction in the wetting agent. Temperature of the wetting solution and effective contact time between dust particles and water droplets are found to be two important variables affecting the wettability. The characterization data obtained from this study can be utilized to develop engineering controls.

Jan 1, 2011

By J. Dong

"Xanthate is a sulfide collector that has been widely used in flotation for almost a century. It is inexpensive, easy to synthesize and apply, and produces good metallurgy in the right applications. However, a major drawback of xanthate is that it decomposes easily and generates CS2 gas in transportation, storage and operation, which can be harmful to human health. Also, excessive xanthate in tailings pond leads to toxicity of the process water and potential damages to aqua-life systems. New regulations in Ontario require that the TWA (time-weighted-average) value of CS2 in the work place is below 1 ppm, which is 1/10 of the previous limit. The stringent regulation may eventually sweep other regions of Canada with the increased awareness of healthy working conditions and environment protection. Therefore, it becomes very important to find xanthate replacements which will be “green”, i.e., environmentally friendly.In this research work, a systematic procedure is used for collector evaluation using the Sudbury nickel sulfide ores from Vale’s Ontario operations, starting with the collector properties (MSDS) evaluation, followed by batch flotation tests, miniplant tests, plant trials and economic evaluation. It is found that the most promising xanthate replacement is dithiocarbamate.INTRODUCTIONSulfide mineral flotation has been practiced since the early 20th century. Its industrial importance is well recognized as mineral concentrates from flotation can be economically smelted and refined to provide primary metals. Collectors play a vital role in froth flotation. There are reagents possessing both a polar group that binds them to the mineral surface and a nonpolar group that is oriented away from the surface to attach air bubbles. The introduction of xanthate as a sulfide collector in 1925 was a remarkable development in froth flotation (Keller, 1925). It is low cost, easy to synthesize, water soluble, simple to control in application. Most importantly, it has strong capability and usually good selectivity for sulfide mineral flotation, which have been keeping its application prominent for almost a century."

Jan 1, 2011

By Eric S. Lindquist

High groundwater levels combined with variable soil and rock profiles present challenges to the design and construction of deep excavation support systems. Increasingly, secant piling techniques are the preferred technical solution for shoring in these cases. Recent developments in drilling equipment, tooling and procedures allow cost-effective construction of deep, overlapped pile systems to tight tolerances in extremely difficult ground conditions. This paper summarizes critical design considerations for secant pile shoring systems, detailing recent advances in installation procedures and verification techniques that allow secant piles to be used for an expanding range of project conditions. Technically- and commercially-viable secant pile shoring designs require that stringent drilling tolerances be achieved in order to successfully provide combined structural support and groundwater cutoff systems, particularly for unreinforced circular secant pile shafts acting in ring compression. Modern drill rigs and tooling can advance fully cased shafts in geotechnical conditions which range from cohesionless soils below the groundwater table to hard rock, within a single drillhole. Down-hole instrumentation provides verification that tolerance requirements are met and allow secant pile shoring to be used at sites previously considered unacceptably risky. In California, secant pile shoring systems are being used for excavation depths of over 100 ft (30 m) on projects with challenging site conditions. Two case studies are presented detailing severe geotechnical conditions and excavation depths which represent the regional state of practice in secant piled excavation support. These projects provide real world examples of the design, construction and construction verification techniques that permit secant pile shoring to be used in more demanding geotechnical conditions and to greater depths than ever before.

Jan 1, 2011

By Mark Maday

As part of the I-94 North-South Corridor reconstruction program, the Wisconsin Department of Transportation (department) is reconstructing the Mitchell Interchange in Milwaukee, Wisconsin. Located on the south side of Milwaukee near Mitchell International Airport, The Mitchell Interchange interconnects I-94, I-43 and I-894. Reconstruction began in 2009 with the letting of the first advance contract for local crossroad bridge reconstruction. A second advance contract for construction of collector-distributer roads on each side of the I-94 mainline was completed in 2010. The main contract involving reconstruction of the core of the Mitchell Interchange was let in the summer of 2010, and is scheduled to be completed by the end of 2012. The core contract includes construction of three cut and cover tunnels along two system interchange ramps. Construction of the three tunnel structures is on the critical construction path. The contract includes an interim contract completion date that requires the tunnels to be open to traffic by the end of 2011. A top down method of construction using drilled shaft secant piles for the sidewalls of the cut and cover tunnel structures was selected as the preferred structure type to address subsurface and construction schedule challenges. The department identified in pre bid coordination that no cost reduction incentives would be reviewed or accepted for changes in tunnel wall type. A major component of the tunnel structures requires the installation of 1,500, 4-foot diameter secant piles. This paper presents mitigation strategies to manage construction risks associated with the installation of the secant piles including; prequalification of the secant pile subcontractors, requirement for use of full depth temporary casing, a site specific quality control plan, specifying drilling equipment, and developing a geotechnical baseline report for this critical component of the Mitchell Interchange reconstruction project.

Jan 1, 2011

By John E. Trombly

System objectives and design criteria for an in-mine ULF radio paging system are discussed Coding formats, frequency and bandwidth selection criteria leading to the system design are discussed. The prototype call alert transmitter and pocket page receiver is functionally described. The report includes circuit descriptions, schematics, parts lists, printed circuit fabrication and assembly drawings. The report concludes with an estimate of the manufacturing cost for each assembly.

Jan 1, 2011

By J. Dahner

Total milling cost is composed of energy, liner and grinding media costs. In primary high ball load milling, the grinding media play the biggest role in total milling cost. This cost can be drastically reduced by improving the impact condition inside the mill. The impact condition inside the mill is influenced by shell liner design (as well as feed end and discharge design) and the type of discharge. The improvement of the impact condition will result in a significant decrease in grinding media consumption. The softened impact condition allows for better alloy optimization, resulting in a further reduction in grinding media consumption. Optimized liner design can also improve energy consumption as less energy is wasted in the projection of the grinding media. Magotteaux utilizes tools to simulate and show the grinding media trajectories for shell and end liners. This paper will present some practical examples where the media and energy consumption can be or has been reduced by optimizing liner design. Keywords Comminution, grinding, liner design, grinding media wear.

Jan 1, 2011

By N. Chow

The recovery of manganese from lower grade resources has been studied for a number of years. Of key importance of prior work, was the discovery that higher valent manganese resource can be readily leached with sulfurous acid. This eliminates the need for high temperature reduction roasting that is conventionally used in processing high grade material. High temperature roasting is energy intensive, emits a large amount of carbon dioxide, and would not be economical for processing lower grade material. While the prior work provides important information to extract manganese from lower grade resources, the production of unwanted by-products, and high water and energy usage has limited its commercial use. This paper describes the results from laboratory work that demonstrate solutions to problems, which to this point preclude commercial development. Preliminary mass and energy balances show that a significant opportunity exists in producing manganese with this hydrometallurgical scheme in a low cost, environmentally friendly manner. Emphasis of the work is on low water use, low overall energy use and economic destruction of unwanted by-products.

Jan 1, 2011

By Jared M. Green

This paper presents the wall stabilization design and implementation for a 541 linear ft masonry and concrete gravity-type retaining wall flanking the west perimeter of a 7.37 acre parcel in Bronx, New York. This paper will discuss the results of static and dynamic stability analyses performed for the pre- and post excavation phases for the proposed 300 ft wide open-cut of up to 14 ft of contaminated soil below the toe of the retaining wall. The wall stabilization consisted of over 74 inclined drilled and grouted anchor dowels, and 55 tiebacks drilled and grouted to the underlying mica schist bedrock. Three over-lapping rows of jet grout columns were chosen as the foundation solution for the existing retaining wall. This paper focuses on the design, construction and performance of the jet grout curtain wall. The jet grout wall served three purposes: 1) underpinning and excavation support for the removal of contaminated site soils, 2) permanent hydraulic barrier, and 3) resistance against a deep seated failure within the thick clay layer present at the site. The originally designed jet grout wall had unexpected negative effects to the existing retaining wall. The jet grouting program was modified while the Observational Method (Peck 1969) was employed to keep wall movements to a minimum. This paper discusses the diagnostic methods used to determine the cause of retaining wall movement; the implementation of a remedial ground improvement program; the modification to the jet grout installation procedure; and the ultimate performance of the jet grout wall.

Jan 1, 2011

By Markus Schönit

Double rotary drilling combines continuous flight auger drilling with a casing for producing a cast-in-place pile. When producing a pile an outer casing and an auger (hollow auger) rotating inside the casing are driven into the ground in counter-rotation. The outer casing serves to support the surrounding soil and the inner auger excavates the drilling cuttings to the surface inside the casing. After reaching the projected drilling depth concrete is pumped through the hollow stem of the auger and outer casing and auger are extracted. After their complete extraction a reinforcement cage can be inserted in the fresh concrete. Compared to Kelly drilling the double rotary drilling method offers numerous advantages, including, for comparable diameter and length, shorter production times and higher accuracy (pile inclination and excess concrete) combined with increased occupational safety and lower noise emissions. Moreover, pile tests have proved that piles produced by double rotary drilling feature higher axial load-bearing capacities than comparable piles produced by Kelly drilling. This article offers an overview of the basic theoretical principles of double rotary drilling lists the required and currently available machinery and, finally, discusses the results and conclusions of a current jobsite.

Jan 1, 2011

By Z. J. Hladysz

A Deep Underground Science and Engineering Laboratory (DUSEL) is being planned at the site of the former Homestake Gold Mine in Lead, South Dakota, under the sponsorship of the National Science Foundation (NSF) in cooperation with the Department of Energy (DOE). This national facility will host a variety of multi-disciplinary science and engineering experiments including physics experiments that require shielding from cosmogenic radiation. Current plans include construction of large rooms (up to 55 m in width) at depths of 1.48 km (4850 ft) and 2.25 km (7400 ft) below the surface. Preparation of the preliminary design required the development of a geotechnical characterization program including: preliminary drilling and coring, core logging, drill hole mapping with a televiewer, drift mapping of the geology and rock structure, in-situ stress measurements, and laboratory testing of the mechanical properties of the rocks and discontinuities. Overall rock quality is very good to excellent. Site investigations were followed by geotechnical assessments for the construction of caverns and laboratory modules. The results are favorable and reaffirm selection of the Homestake site for establishment of a Deep Underground Engineering and Science Laboratory.

Jan 1, 2011

By Lawrence Lien

The reduced need for traditionally trained and educated personnel in the mining industry is systemic to the changing mining industry. Universities and other training institutions are meeting the traditional skill needs required by the industry, but are the skill needs going to be the same in the near future? The answer may be no. Mining is changing because of increased liabilities and costs of environmental and safety is-sues; lower grades of minerals in traditional mining activities and the advent of new bio-chemical processes and robotic equipment. More productive and economic alternatives, and larger, more sophisticated and automatic equipment, are also changing the industry. Engineering is more specific, accurate, precise and expensive. Measurement is more thorough and timely of progress, production, costs and productivity. And, the industry will likely be engaging in more undersea mining, possibly space-based processing, less human interaction and more remote control of events than was previously thought possible.

Jan 1, 2011

By J. Evans

Including: Tailings thickeners, CCD?s, paste thickeners, HI-rate thickeners, lamella thickeners, high compression thickeners, clarifiers etc. Flocculant dosing control for mining thickeners and clarifiers is influenced by a number of process factors. 1. Flow rate into the thickener or clarifier a) As the flow rate increases into the thickener or clarifier ?retention time? decreases which causes a greater affect hydraulically on the settling solids. So as the flow rate increases it will generally mean an increase in flocculant dosing rate. b) As the flow rate decreases into the thickener or clarifier the retention time increases which reduces the hydraulic affect on settling, improving settling rates. This will generally mean that as the flow rate decreases, we will decrease the flocculant dose rate.

Jan 1, 2011

By R. Schwarz, E. Pusch, A. Juch

"The paper describes in general the objectives, goals as well as theoretical background of "METSI"-project proposal submitted to German BMBF (Federal Ministry of Education and Research). The METSI project is a starting point for technology and know-how transfer of German water management and water treatment technologies to South African Mining industry. "METSI" is Setswana, one of the eleven official languages in South Africa, and means "water". It stands also for "Management System for the Implementation of Environmentally Sound Water Supply Technologies in South African Mining Areas with Involvement of all Relevant Stakeholders". The project focuses on development, design and implementation of mathematical models that consolidate and evaluate existing data and generate substantiated projections of "water" amount and quality. METSI covers a wide range of scientific, technical, social as well as economic questions related to "water in mining"."

Jan 1, 2011

By A. F. Marques

The Azores islands are located on a triple junction where the American, African (AFR), and Euroasian (EUR) plates meet. The Mid-Atlantic Ridge (MAR), oriented N-S, represents two branches of the T; an E-W branch defines the EUR/AFR boundary called the Terceira Rift. The nature and structure of this plate boundary, as well as the dynamics of the interaction of tectonics and volcanism remain unconstrained. The Azores plateau is seated on a mantle domain of anomalously low seismic S-wave velocities, and gravity and geoid anomalies, where the apparent thick crust is thought to relate to larger degrees of melting initiated at greater depths [1]. The cause of these anomalies is controversial but many authors consider the presence of an anomalously hot/wet enriched mantle probably supplied by a plume [2]. The geochemistry of the subaerial and most submarine lavas from the plateau reinforces the plume model beneath the Azores [3-4]. The origin, size and present location of the plume is under debate but an area near Terceira is the favoured plume centre [5]. [ ] SEAFLOOR HYDROTHERMAL SYSTEMS IN THE AZORES AREA (36ºN ? 40ºN) More than 150 active and fossil hydrothermal systems are known in the oceanic seafloor [6]. Many more are yet to be found on vast oceanic areas that haven?t been explored [7]. Ever increasing knowledge shows that modern seafloor hydrothermal systems can be hosted in felsic to ultramafic rocks, vary in size and shape and exhibit diverse amounts of sediment cover

Jan 1, 2011

By M. D. Balen

The U. S. Bureau of Mines has undertaken the development of mineral industry cost escalation factors to enable the estimation of mineral development and extraction costs for mineralized sites in Alaska throught the use of the Bureau&apos;s Cost Estimating System v2.0 (CES 2.0). For the purposes of this document, all calculations are based on, and reflect the economic environment in Alaska in July 1992. The greater cost of mining in Alaska as compared to the contiguous-48 States can be estimated for Alaskan mining operations through (1 ) the analysis of capital and operating costs for analogous mine and mill plants in operation in the contiguous-48 States; (2) the hypothetical relocation of mine and mill plants from their actual location(s) to Alaska by making engineering modifications to the mine and mill plant design as required by the Alaskan site characteristics; (3) calculation of the cost of the required engineering modifications and; (4) the escalation of all costs to a level representative of the economic environment in Alaska at some specific point in time.

Jan 1, 2011