Search Documents

By Li Xibing

The In order to mine safely with reasonable cost, it is necessary to research the fracture characters of backfill and its matches with rock mass. Four kinds backfill with cement-tailing ratio of 0.250, 0.125, 0.100 and 0.083 respectively were tested, and basing on stress-strain curves tested, the deformation characters and fracture laws as well as the damage constitutive equations investigated with damage mechanics whose calculating results are coincided with experiment results well were proposed. The results of damage analysis show that there have different damage characters in different backfill, e. g. the lower the ratio of cement to tailings the lower the damage values when stresses reach to peak value; the lower the content of cement the more rapid in damage and the more abrupt in breakage process. In addition, using catastrophe theory, an energy model was proposed for backfill and rock mass acted each other in mechanics, and the unstable condition of the system was obtained. Research results show that the higher is the stiffness of rock mass the more stable the system, and the lower is the ratio of cement to tailings, the more unstable the system will be. Further more, according to the catastrophe model proposed, the reasonable matches between backfill and rock mass were researched, and a calculation formula that designs reasonable strength of backfill during mining was put forward. It has been proved by practice that the model and theory researched in this paper can guide filling design in mining. Keywords: Cemented tailings backfill, constitutive equation, catastrophe theory, match of backfill and rock mass

May 1, 2007

By Unknown

Diesel locomotives for underground haulage have been used in coal mines in Continental Europe for twenty-five years or more. In Great Britain, it was not until 1935 that permission was granted to use them in gassy coal mines, but since that time they have been employed in increasing numbers both in gassy and non-gassy coal mines and in metal mines. Their use underground in coal mines in the United States is still prohibited and the same was the case in Canada until 1946, when permission was granted to operate a Diesel underground in the Adanac mine of West Canadian Collieries, Limited, at Bellevue, Alberta. The locomotive used here is a 50 h.p. Hunslet Mark II. More recently, a 100 h.p. Diesel was placed in operation for underground haulage at No. 18 Colliery of the Dominion Steel and Coal Corporation, in the Sydney coalfield, N. S. Thus, on this continent, Canada has been a pioneer in the use of these locomotives underground in coal mines and there is no doubt that more and more of them will be employed as time goes on. We feel, therefore, that the following notes concerning their design and performance, which we have received from the High Commissioner for the United Kingdom, will be of interest to our members.

Jan 1, 1949

By A. Gourlie

"This paper describes the performance properties of a new 95 ksi minimum yield strength, oil well casing grade designed specifically to resist hydrogen sulphide stress corrosion cracking, SSCc. The new grade, Soo-95SS, demonstrates NACE Tensile threshold values greater than 90% specified minimum yield strength, SMYS, and NACE Bent Beam values in excess of 12.7 x 1()4 psi. The new Soo-9588 grade also exhibits superior collapse and notch toughness values. IntroductionIn recent years, a trend toward casing grade specialization has resulted in the introduction of numerous proprietary grades designed specifically for particular production environments, In response, Algoma Steel has developed, as part of a "" grade for service"" philosophy, two new 95 ksi minimum yield grades. The two grades are Soo-95, High Collapse (HC), and Sour Service (SS). This paper describes the development of Soo-95 Sour Service.Four main objectives were established:1. Definition of the steelmaking and continuous cast processing practices2. Determination of the acceptable maximum and minimum levels for all chemical elements3. Definition of special processing requirements4. Definition of the physical characteristics and ranges of the product properties.This paper provides a description of the experimental approach, followed by a presentation and discussion of the trial results . Finally, a number of conclusions are given."

Jan 1, 1988

By Vishal Shukla, Prateek Singh, D. P. Chakraborty

"Continuous thickening by an operation called sedimentation is the separation of suspended solid particles from a liquid stream by gravity settling. The primary purpose of thickening is to increase the solids concentration of the feed stream. High rate thickeners are designed specifically to maximise the flocculation efficiency. A detailed investigation has been carried out to understand the influence of ore type and operating parameters such as bed level, bed mass, rake arm torque and flocculent concentration on thickening operation. Tata steel’s Noamundi plant data shows that variation in ore type, and operating parameters are major contributors to fluctuation in thickener performance. A lot of research has been done earlier on thickening operation but effect of ore type and operating variables by using plant data was never touched before.In this context, the performance of thickener was evaluated by daily data to study the influence of ore type and operating variables on thickener operation. Investigation shows that friable ore % in feed mix is proportional to slime density because friable ore is porous & brittle in nature. As a result, friable ore generates more fines/ultrafine during communition process in wash plant. Increase in flocculant concentration and bed mass is showing a positive change on high rate thickener performance Investigation shows that optimum bed mass and flocculant concentration is required to achieve desired pulp density in thickener underflow at different feed pulp density (g/cc).INTRODUCTIONOver the years, Iron Ore Beneficiation at Tata Steel, Noamundi has seen varied changes. Depletion of high grade iron and with increasing iron ore throughputs coupled with lowering of the hard ore a subsequent increase in slime generation, slime management and clear water requirement for wet Plant has thrown up myriad challenges. To overcome these challenges, many improvements initiatives were taken by Tata Steel in last decade. One of the major changes is the recent High Rate Thickener commissioning at Tata Steel Noamundi to cater the high iron ore throughput requirement. Slime reporting to Thickener has increased from 1.4 MTPA 2.5 MTPA over the last few decades. The above changes further aggravate the poor settling and dewatering characteristics of the slurry which is being feed to HRT. Considering the above mentioned constraints and stringent environmental implication proper water management has become a major challenge to reckon with. The thickener is used to increase the concentration of the suspension by sedimentation, accompanied by the formation of a clear liquid. In most cases the concentration of the suspension is high and hindered settling takes place."

Jan 1, 2016

By S. Shairp

At the Hudbay zinc pressure leach plant, filtration and washing of the second stage leach slurry takes place on a vacuum belt filter prior to disposal to tailings. Due to periods of poor filterability, laboratory studies were undertaken to investigate the effect of temperature of the filter feed slurry, and to compare filterability to the resulting cake particle size distribution.

Jan 1, 2014

By Shin-Kun Ryi

The world nowadays faces many challenges associated with excessive utilization of fossil, fuels, such as poor air quality and greenhouse gas emissions. Hydrogen appears to be an attractive alternative to the conventional, fossil, fuels with better energy efficiency and less environmental, impact. Pd and Pd-based alloy are the most often used membranes for hydrogen separation due to their superiority over other membranes. However, the stability of the commonly-used thin Pd-based composite membranes at high temperatures still, remains a big challenge. In this presentation, we will, report our progress on thin Pd-Ru alloy composite membrane by electroless plating high temperature applications.

Jan 1, 2010

By M. S. Millman

Close monitoring of performance at each process stage, from raw material through to finished product, is vital for operational consistency and the production of high quality steel. However, many of the integrated iron and steelmaking process route stages operate under such severe conditions of temperature, dust, water, thermal radiation, vibration, pressure, vacuum, extreme dynamic events, high material flows, corrosion, erosion, electrical-noise, electromagnetic-noise, or audio-noise that, in general, it is a very difficult challenge to obtain useful information for control. Thus, state-of-the-art non-contact and remote sensors are applied to help monitor and control specific process operations. Often, these sensor systems have been developed especially for the steel industry and they are based on four principal technologies: Laser, Microwave, Electro-Magnetics and Thermal Imaging with supporting technologies such as: X-ray Fluorescence, Audiometry, Digital Image Processing, Radio Telemetry, GPS and many others. These advanced sensor technologies are reviewed with respect to their application at various stages along the integrated process route.

Jan 1, 2004

By J. Cayouette, . Blatter, P. Cousin

The Laronde mill was commissioned in 1988 and has been treating the Laronde Perim ore since 2000. The Laronde plant, situated in the Abitibi region of Quebec, has experienced mill expansions to accommodate 7500 mtpd and to recover gold and silver as well as important amounts of base metals (Cu, Zn, Pb). Ten sequential metallurgical and environmental processes are responsible for metals recovery and process viability. Over 200,000 ounces of gold, 4,5 million ounces of silver, 7000 tonnes of copper, and 78,000 tonnes of zinc are produced annually. In 2008, the Goldex plant began trucking high wade (35-45 Wt Au) pyrite sulphide concentrate (TCGO) for gold extraction at a newly constructed treatment plant, increasing gold output at Laronde by 40,000 ounces. In 2009, the high gold wade Lapa ore processing facilities were annexed to the Laronde plant increasing output by 120,000 ounces of gold. TCGO and Lapa productions are forecasted until 2018 and 2015 respectively, with known reserves of each mine. Today, up to 140 permanent employees run and optimise the Laronde plant operation. As a result, Laronde has intricacies intrinsic to a large and varied operation. The paper will outline the metallurgical highlights, challenges, and future outlook related to the treatment of each ore type (Laronde, TCGO, and Lapa)

Jan 1, 2011

By M. J. Dry, G. B. Harris

"This paper presents basic chemistry and operating conditions for the hydrolysis of ferric chloride into solid hematite and gaseous hydrogen chloride, and shows how this unit operation can be applied in chloride hydrometallurgy to regenerate strong hydrochloric acid and reject iron without also rejecting valuable metals such as nickel, copper and cobalt. Two examples are used to illustrate the hydrolysis technology and compare it to existing technology. The first is the regeneration of spent steel pickling acid, comparing hydrolysis to conventional pyrohydrolysis. The second example is the processing of a hypothetical low grade nickel laterite, comparing the novel chloride hydrolysis route to conventional sulphate HPAL technology.INTRODUCTION Whilst, in many respects, the control and removal of dissolved iron from chloride leach solutions can resemble the manner in which it is done in sulphate systems, chloride chemistry additionally offers the ability to achieve the same objectives in different ways (Harris, 2014). Conventionally, iron is oxidised to its ferric state (if necessary) and then precipitated with a base, usually magnesia where the feed is a laterite and lime where it is a sulphide, since calcium will precipitate sulphate formed during leaching. One method for controlling iron is to form FeOOH, either ß-FeOOH (akaganéite), a-FeOOH (goethite), or a mixture thereof (Fillipou and Choi, 2002). However, if akaganéite is formed, the precipitate will contain a significant chloride component (as high as 7% Cl), leading to chloride losses and difficulty in satisfactorily disposing of the residue. Washing chloride from akaganéite is almost impossible due to the propensity of the solids to undergo peptization. The conventional approach requires the addition of a base, but it is based to some extent on controlled supersaturation precipitation (Demopoulos, 2009), which produces a more uniform and crystalline material and is far more attractive than, for example, the turboaeration process proposed by Great Central Mines in their chloride copper process (Raudsepp & Beattie, 1986)."

Jan 1, 2016

By Q. G. Reynolds, R. T. Jones

"Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. A mathematical description is presented for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are shown to have a significant effect on the residence time distribution.INTRODUCTIONThere are some processes in which the time spent by the feed material in a smelting furnace plays a significant role in determining the extent of the reactions between metal and slag and influences the degree of settling of metal droplets from a molten slag.Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. Here we will focus on producing a mathematical description for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are studied.Previous work (Jones, la Grange and Assis, 1997) has studied the effect of retention time on the degree of cobalt recovery achieved in a slag reduction process. In that work, a method was proposed for the calculation of the mean residence time of the contents of a pilot-plant furnace. That approach is to be extended here for the purposes of providing a more general design or scale-up tool.The maximum allowable depth of molten material in a given furnace is affected by such factors as the desired batch size (or the size of the ladles) and the pressure of the molten material that the tap-hole and surrounding system can withstand. Within these constraints, there might be some scope for choice of taphole position. The effects of this choice need to be understood mathematically."

Jan 1, 2012

By G. Kipouros, M. Dadvand, A. Dadvand

"A novel methodology was developed to obtain a 3D porous layer with a high aspect ratio of porosity on a titanium electrode. The porous structure allowed more active material such as hydrous ruthenium oxide to be accommodated during the fabrication of the supercapacitor, resulting in an exceptionally high capacitance per surface area. The electrode demonstrated a remarkably high capacitance of 4,800 mF/cm2. The porous layer was composed of functionalized nanoparticles of TiO2 organized in a perfect 3D hexagonal close-packed array that resulted in a highly porous 3D structure. The layer was used as a template to electrolessly deposit a thin layer of silver prior to the electrodeposition of active material. KEYWORDS Capacitance, Porous, Ruthenium, Silver, Supercapacitor, Titanium RÉSUMÉ Une méthodologie innovante a été mise au point afin d’obtenir une couche poreuse tridimensionnelle (3D) affichant un rapport d’aspect élevé en termes de porosité sur une électrode en titane. La structure poreuse permet d’utiliser une matière plus active telle que l’oxyde de ruthénium hydraté durant la fabrication du supercondensateur, ce qui se traduit par une capacité exceptionnellement élevée par surface active. L’électrode affichait une capacité remarquablement élevée de 4 800 mF/cm2. La couche poreuse était composée de nanoparticules fonctionnalisées de dioxyde de titane (TiO2) organisées dans un arrangement regroupé parfaitement hexagonal en 3D, qui a engendré une structure en 3D hautement poreuse. Cette couche a servi de modèle pour le dépôt autocatalytique d’une fine couche d’argent avant l’électrodéposition de la matière active. MOTS CLÉS argent, capacité, poreux, ruthénium, supercondensateur, titaneINTRODUCTION There is a growing demand for integrating compact energy storage elements into electronic circuits due to the miniaturization of electronic circuits, sensors, and actuators, and the increasing importance of portable and wear-able devices incorporating more advanced electronic technologies that operate in controlled or uncontrolled environments to gather, process, store, and communicate information (Deng, Ji, Chen, & Banks, 2011; Beidaghi & Wang, 2012; Chen, Ramachandran, Mani, & Saraswathi, 2014). The manufacturing of compact energy storage elements needs to be compatible with the electronic circuit microfabrication processes. Recently, interest in integrating miniaturized supercapacitors into electronic circuits has increased due to their high charge–discharge rate and long operating life; however, ultra-high power miniaturized supercapacitors suffer from low energy density, hence requiring significant enhancement in their energy density for various applications (Deng et al., 2011; Beidaghi & Wang, 2012; Chen et al., 2014)."

Jan 1, 2019

By G. V. Sirianni, G. E. Viens, R. A. Campbell, G. N. Banks, R. L. Sachdeva

"A combined shaft-electric furnace for the smelting of ores and the melting of metallized iron pellets is being developed. The materials are preheated, and in some cases pre-reduced, in the shaft before being transferred to the electric furnace, where melting or smelting is completed. It has been demonstrated that this combination of equipment will enable much of the relatively expensive electrical energy to be replaced by cheaper energy in the form of oil or natural gas, and preliminary experiments indicate that the total energy requirements for a melting or smelting operation are significantly reduced. Projections based on results obtained from the preliminary experiments indicate that further improvements will be possible when certain modifications to the equipment are completed."

Jan 1, 1968

By N. Bartie

Realising the circular economy (CE) is faced with some significant challenges. Process metallurgy and its infrastructure play key roles at the heart of making the CE work. Therefore, the enabling role of process metallurgy within the CE will be central to the discussion in this paper, touching among others on product and system design as well as the key metallurgical and other process fundamentals that need to be investigated and understood to make the CE a reality. The central role of materials and its processing will be discussed in an integrated circular cities perspective. A key focus will be a discussion on designing a resilient “Smart Materials Grid” using and innovating metallurgical process engineering tools, which will manage the flows through Sustainable Circular Cities. The discussion will be using copper as leitmotiv of the discussion i.e. from copper ore, to metal, to complex products, recycling, product design and simulation and its impact. INTRODUCTION The transformation of our economies from linear to circular models in which waste materials become resources is the focus of the Circular Economy (CE) paradigm. Its important intentions: to take control of the damage we have been doing to the planet to ensure its livability and the welfare of future generations. This can only be achieved through careful utilisation of human, natural and economic resources. The concept is derived from several others (Beaulieu et al., 2015), of which Cradle-to-Cradle, Extended Producer Responsibility (EPR), Industrial Ecology, and Life Cycle Thinking are just a few. Other relevant concepts include resource efficiency (RE), design-for-recycling (DfR), and various others discussed by Blomsma and Brennan (2017) and Homrich et al. (2018), as well as various R-hierarchies e.g. Reduce, Reuse, Recycle (3R). However, does society comprehend these concepts, the actors and actions that influence them and how they interact? Do we know the limits of CE? Does society understand the key role of Copper and other metals to rendering the CE operable? True life cycle and systems thinking, focussed on simulation-based, process and metallurgical design are required to answer these questions. Lieder and Rashid (2016) identify nine widely-varying fields that study the concept ranging from sustainability sciences and engineering to economics, business, law, and social sciences. Overlap between questions addressed highlights the need for interdisciplinary collaboration (Nanz et al., 2017) in the assessment of the current status, and further steps needed to transform to CE. This doesn’t apply just in academia, but also in industry where concrete implementation of CE needs to occur at multiple levels, thus necessitating cooperation between government, civil society and other stakeholders (Beaulieu et al., 2015).

Jan 1, 2019

By D. J. Lloyd

"Bending is involved in the forming of many sheet parts and it is important to understand the phenomena involved. In this paper the basic equations describing bending on a global scale are compared with strain measurements of bent sheet. The development of strain on a local, microstructural scale is also investigated, as is the general aspects of plasticity and the failure process. It is shown that the global equations can be used to estimate the strains involved and the local strains can be attributed to various aspects of the plasticity. The bendability can be related to the fracture strain of the sheet and the ability of a sheet alloy to accommodate the necessary bending to form the part can be assessed.INTRODUCTION The ability of a sheet alloy to undergo bending without failure is an important capability in the forming of many parts and it is useful to be able to assess the bendability of an alloy during its development. The basic mechanics of bending were developed in the 1950s (Lubhan & Sachs, 1950; Hoffman & Sachs, 1953). When a sheet is bent the upper bend surface is in tension, the lower surface in compression and at some point within the sheet there is a plane of zero strain which is referred to as the neutral axis. For sheet exhibiting limited plasticity the neutral axis is static and occurs at the mid-point of the sheet thickness but for sheet exhibiting extensive plasticity the neutral axis progresses deeper in to the sheet as bending progresses. This results in two expressions for the maximum strain at the upper bend surface depending on the motion of the neutral axis. For Al alloys such as AA6111, AA6016 and the like extensive plasticity occurs and the neutral axis is expected to move during bending. However, very few studies have examined how the neutral axis motion and the strains develop, compared with the mechanics analysis. Geist and Parker (1984) used hardness measurements to investigate neutral axis motion but these experiments did not have the resolution necessary to compare the results with experiment but did indicate neutral axis motion. To understand the nature of plasticity and failure during bending it is important to know the extent of neutral axis motion, the scale of strain gradients developed through the sheet and the maximum strains occurring at the bend surface, finally comparing experimental results with the theoretical predictions. The influence of microstructure on the evolution of strain and failure can then be considered in the context of these parameters. Recently, bending in some automotive Al alloys has been reported mainly from the microstructural perspective (Lloyd, 2000, Lloyd et al., 2002, Mattei et al., 2013) and FEM studies have also investigated the development of plasticity under bending, demonstrating the tendency for strain localization (Becker, 1992, Shi et al., 2014)."

Jan 1, 2018

By F. N. Smith

The carbon steel casings of Heat Recovery Steam Generators (HRSGs) in a co¬generation plant were found to have developed cracks that originated on the inside surfaces. The HRSGs receive hot exhaust gases from the primary Gas Turbines (GTs), which are fuelled with pipeline natural gas. The GTs was initially operating without any suppression of nitrogen oxides (NOx). After being in service for about two years, some of the cracks were found to have penetrated right through the 1/4 in. thick casings. The casings are fitted with insulation on the inside (hot gas side). Examination of steel samples cut from the casing walls revealed (i) fine cracks propagating through the steel from the inside surfaces, and (ii) the presence of relatively large amounts of nitrate ion on the inside surfaces. It was concluded that the nitrate ions originated from nitric acid that was condensing on the relatively cool walls of the casings behind the insulation. Nitric acid was formed in the GT exhaust gases by the combination of water vapour (formed from combustion of the hydrocarbon fuel and from moisture in the combustion air) and nitrogen oxides (formed from nitrogen and oxygen in the combustion air).

Jan 1, 2005

By E. D. Kindle

"The Duthie mine is on the southwest slope of Hudson Bay mountain 7 1/2 miles west of Smithers, British Columbia. A good motor road about 15 miles long connects the mine with the Canadian National railway at Smithers. The principal workings are on the Henderson group of claims between elevations of 3,200 and 4,000 feet above sea-level. Silver, lead, and zinc were produced from this mine between 1924 and 1930.Three adit drifts known as the Compressor, McPherson, and Thompson levels were driven along the Henderson vein-lode in 1922, and the following year the operating company, known as Duthie Mines, Limited, shipped some high-grade silver-lead-zinc ore. Further shipments of high-grade, handsorted ore were made in 1926, and in 1927 a modern flotation-type mill was built, having a capacity of 50 tons of ore a day. Mining operations were suspended in March 1930."

Jan 1, 1954

By A. Fahr, T. Byczkowski, M. Genest, C. Mandache

"Layered aluminum structures assembled with rivets are often found in aircraft fuselage. These structures are exposed to various mechanical loads and a range of environmental conditions that contribute to their ""aging"". The rivet holes are the source of stress concentrations and the location of crack nucleation and growth. Detection and sizing of second and third layer cracks under fasteners represent a major challenge for non-destructive evaluation (NDE) technicians. Electromagnetic methods are currently the most feasible NDE techniques that are capable of successfully inspecting such structures. However, different probe lift-offs, due to protruding rivets and paint coatings, or interlayer separations, due to sealant or air gaps, pose difficulties in detecting and sizing cracks. In addition, the use of conventional eddy current technique is limited due to the inverse relationship between the probe spatial resolution and its field penetrability. In this paper, we present an alternative approach that overcomes the previously mentioned shortcomings by using pulsed eddy current excitation and magnetoresistive sensor pick-up. Various signal manipulations are employed for defect detection and quantification."

Jan 1, 2006

By James F. A. Hatley

Northern Saskatchewan comprises an area of about 350 000 km2 and boasts some of the world's largest known high-grade uranium deposits. The successful mining of these deposits, however, can not be accomplished without overcoming technical challenges. Not only is the high grade of the uranium ore challenging, but mining methods need to be developed to deal with groundwater at very high pressures, and ground conditions that vary substantially from excellent to wholly unconsolidated clays and sand. This paper discusses the various mechanisms of inflows at the three of the Cameco Corporation Mines in Northern Saskatchewan. The risk of inflows is quantified in terms of unique challenges from hydrogeologic conditions, rockmass integrity, and uncertainty in geologic conditions. Mitigation strategies in case of an inflow are also briefly described. The paper concludes by addressing the impact of institutional rules (corporate standards) on minimizing, monitoring, and controlling the probability and/or impact of unexpected inflows.

Aug 1, 2010

By Kazuteru Tozawa, Robert G. Robins

"The stability of calcium arsenate is discussed in relation to the possible misuse of lime in the treatment of gold processing waste waters. Stability diagrams have been derived and experimental results cited to show that calcium arsenate has a higher solubility in neutral to alkaline solution than has previously been recognized and this solubility is further enhanced by the presence of carbon dioxide, bicarbonate or carbonate.IntroductionThe removal of arsenic from gold mine waste waters has been of interest for more than thirty years, but with the recent emphasis on clean water standards there has been renewed activity in relation to that problem. The processing of gold-bearing sulphides which contain arsenopyrite and other complex arsenic sulphides is well established. Initial roasting to oxidize the sulphides leaves the arsenic in the form of both arsenic and arsenic, in which forms it is soluble in the subsequent leaching stage. Further oxidation of the leach liquors is required before the well-established procedure of precipitating calcium arsenate with lime, which is carried out despite an immense lack of knowledge of the calcium-arsenic-water system.The solubility product and free energy of formation for Ca3(AsO4)2, which are to be found in recent and reliable sources of data, originate from the work of Chukhlansev, whose experimental determination of the concentration of calcium from the solubility of calcium arsenate in solutions of various pH yields the results plotted in Figure 1. This is the work which has resulted in a wide acceptance of the ""insolubility"" of calcium arsenate and the use of lime to stabilize arsenic in that form.Laguitton attempted to further elucidate the chemistry of the lime addition method for treating arsenical waste waters from gold processing operations. The low solubility product for Ca3(AsO4)2 was the basis for his examination of likely chemical equilibria in the system. Laguitton and other workers have not considered atmospheric carbon dioxide as an important component in this system."

Jan 1, 1982

By G H. Reavely, The University of Western Ontario Department of Geology

The lower Middle Devonian Sylvania Sandstone occurs in the sub-surface in the western part of Mal-den township, Essex county, Ontario. The formation is composed of well rounded, frosted quartz grains with a silica content varying from 42 to 93 per cent and the grains are cemented by carbonate, constituting up to 57 per cent of the rock. This sand-stone is not a homogeneous bed but is divided by strata rich in carbon-ate cement. The thickness of the Sylvania in Malden township varies up to a known maximum thickness of 88 feet. The lower contact with the chert-bearing Bois Blanc formation is sharp but the upper contact with the Amherstburg formation (Detroit River group) exists as a transition by a gradual downward increase in quartz grains. The Sylvania would seem to outcrop in the lake bottom near the mouth of the Detroit River dipping to the north along a broad anticline the axis of which follows the Detroit River. Just south of Amherstburg, a local east-west trending

Jan 1, 1961