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By M. Cai

"It is well known that Peak Particle Velocity (PPV) plays a critical role in triggering rockburst damage in burst-prone underground mines. To estimate the PPV distribution around excavations, advanced numerical modeling can be used. In wave propagation numerical modeling, velocity field is often assumed to be uniform around an excavation. However, it is observed that wave velocities near mine openings are not constant, but rather non-uniform. Wave velocity in a rock mass depends on many factors such as rock quality and confinement. In particular, confinement has a large influence on wave velocity. The confinement around an excavation is low at the wall boundary and increases gradually and reaches a constant value far away from the excavation boundary. Hence, stress redistribution due to excavation will have a profound influence on wave propagation in underground mines. A better understanding of the influence of excavation effect on wave propagation helps to interpret the field observation of rockburst damage and improve mine safety. For this purpose, a non-uniform velocity model need to be constructed and the influence excavation effect should be taken into account in numerical wave propagation modeling.In the present study, a non-linear velocity model is developed firstly by considering the influence of confinement on wave velocity. This model links wave velocity to confinement explicitly. A coupled numerical method is then developed and used to study the seismic wave pattern around excavations in underground mines. Two codes, FLAC and SPECFEM2D, are coupled in the analysis. The motivation of developing the FLAC/SPECFEM2D coupled approach is to take merit of each code, such as the stress analysis capability in FLAC and the powerful wave propagation analysis capability in SPECFEM2D. The coupling process is realized through three steps: (1) static stress redistribution around an excavation is analyzed in FLAC; (2) data for coupling analysis, such as non-uniform velocity field (based on the new developed velocity model), mesh, absorbing boundaries, etc., are generated by FISH functions in FLAC and passed to SPECFEM2D; and (3) wave propagation modeling is performed in the SPECFEM2D considering a fault-slip seismic source. Because stress redistribution around the excavation is considered, non-uniform velocity field for the SPECFEM2D model can be obtained and this is a notable feature of this study. Very large difference in the S-wave response in these two modeling approaches with uniform and non-uniform velocity fields can be seen from the modeling results.Using the FLAC/SPECFEM2D coupled modeling approach, accurate velocity models can be constructed and this in turn will help to produce accurate PPV distribution around the excavations. Accurate PPV contours can be used to identify high rockburst risk zones for improved dynamic ground support strategy."

Jan 1, 2015

This document presents estimates of future "total cash cost per ounce" and "minesite cost per tonne" that are not recognized measures under United States generally accepted accounting principles ("US GAAP"). This data may not be comparable to data presented by other gold producers. These future estimates are based upon the total cash costs per ounce and minesite costs per tonne that the Company expects to incur to mine gold at the applicable projects and do not include production costs attributableto accretion expense and other asset retirement costs, which will vary over time as each project is developed and mined. It is therefore not practicable to reconcile these forward-looking non-GAAP financial measures to the most comparable GAAP measure. A reconciliation of the Company's total cash cost per ounce and minesite cost per tonne to the most comparable financial measures calculated and presented in accordance with US GAAP for the Company's historical results of operations is set forth in the notesto the financial statements included in the Company's Annual Information Form and Annual Report on Form 20-F, for the year ended December 31, 2009, as well as the Company's other filings with the Canadian Securities Administrators and the SEC.

May 1, 2011

By W. L. Ott, C. L. Lewis

"AbstractA technique is described for preparation of palladium sponge and for spectrochemical analysis of the metal in this form. The precision and accuracy of the method are discussed. Analyses are compared with previous spectrochemical analyses of palladium in the black form. Good agreement was found in the two sets •of results and it is concluded that they are more reliable than wet chemical .analyses of the same material.IntroductionFOR SEVERAL YEARS the problem of platinum metal analysis by spectrochemical methods has been under investigation at the Spedtrographic Laboratory, Department of Geological Sciences, Queen's University. The problem, briefly -stated, is as follows: Samples of platinum, palladium,-rhodium, ruthenium, and iridium are received as fine metal powders, called sponge. Direct spectrographic analysis of this material has not been found satisfactory due to its heterogeneity •as regards contaminant metals, which may be present up to a total of one per •cent or more. Further-more, spectrographic standards are difficult to obtain and difficult to prepare accurately by adding weighed portions of contaminant metals to the sponge. The fact that •contaminant metals in original samples are probably alloyed with the major constituent is a further difficulty since complete fusion of these refractory metals proved impractical in the present case as a means of standard preparation. It •has, therefore, been found most satisfactory to dissolve the metals, prepare standards by addition of solutions of contaminant metals, and to reduce both standards and samples to a homogeneous form. A previous paper, by Hawley, Wark, Lewis and Ott (2) dealt with a method for spectrochemical analysis of platinum and palladium in their black form. Since completion of research on the black technique, the possibility of analyzing palladium accurately in its sponge form has• been investigated."

Jan 1, 1953

By R. V. Kumar, F. Tailoka

In order to use ZnO laden dust as a possible desulphurization reagent, it is important to evaluate thermodynamics of the Zn-O-S system. At temperatures greater than 1450 K, there is an uncertainty in the thermodynamic data for the reaction of zinc with sulfur to form Zinc sulfide. In this work, the standard free energy has been determined using an electrochemical cell: Pt, Mo, MoO2/YSZ/ZnO, ZnS, S02, Pt., between 1198 and 1602 K. AG° varies from -145,880 to -88,100 J (± 2500) , with a phase change to ZnS (g) by sublimation occurring between 1450 and 1460 K. This is supported by thermogravimetric analysis which shows about 80% weight loss in ZnS from 1273 to 1473 K. Feasibility reactions were also performed and confirmed that ZnS (g) is formed when ZnO reacts with FeS (1473 to 1653 K) or with Fe-Csat-S(1473-1673 K). There is therefore potential for the utilization of ZnO laden waste as an additional or alternative reagent for desulfurisation.

Jan 1, 2004

"The United Nations, through the secretariat of the United Nations Economic Commission for Europe (UNECE) and its Ad Hoc Group of Experts on Harmonization of Fossil Energy and Mineral Resources Terminology, developed the Framework Classification.The UN Classification applies to fossil energy and mineral reserves and resources located on or below the Earth's surface. It aims to simplify reporting of energy and mineral reserves and resources in a globalized world and is intended to improve global communications regarding remaining quantities of non-renewable fossil energy and mineral resources. The UN Classification is not recognized as a Foreign Code under NI 43-101.SECTION I1.,The United Nations Framework Classification (UNFC-2009) applies to fossil energy and mineral reserves and resources located on or below the Earth' s surface. It serves the needs for classification at a global level (for energy and mineral supply studies), for governments (resources management and policy formulation), for industry (business process management) and for financial reporting.SECTION II2.,The UNFC is a generic system in which quantities are classified on the basis of the three fundamental criteria of economic and social viability (E), field project status and feasibility (F), and geological knowledge (G), using a numerical coding system. Combinations of these criteria create a three-dimensional system. Categories (e.g. El, E2, E3) and, in some cases, sub-categories (e.g. E1.1) are defined for each of the three criteria as set out and defined in Annexes I and II.3 The first set of categories (the E axis) designates the degree of favourability of social and economic conditions in establishing the commercial viability of the project, including consideration of market prices and relevant legal, regulatory, environmental and contractual conditions. The second set (the F axis) designates the maturity of studies and commitments necessary to implement mining plans or development projects. These extend from early exploration efforts before a deposit or accumulation has been confirmed to exist through to a project that is extracting and selling a commodity, and reflect standard value chain management principles. The third set of categories (the G axis) designates the level of confidence in the geological knowledge and potential recoverability of the quantities.4. The categories and sub-categories are the building blocks of the system, and are combined in the form of ""classes"". The UNFC can be visualised in three dimensions, as shown in Figure 1, or represented in a practical two-dimensional abbreviated version as shown in Figure 2."

Jan 1, 2003

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama, Ryuji Oinuma

"Recently, the arsenic grade in copper ores has been increasing year by year. Arsenic bearing minerals (enargite (Cu3AsS4) and tennantite (Cu12As4S13)) coexist with typical copper minerals such as chalcopyrite (CuFeS2). The removal of arsenic from copper ores that contain relatively high arsenic content is essential due to its adverse impact on the environment and the resulting economic consequences. In this study, arsenic removal and dissolution behaviour of Cu and As from enargite (Cu3AsS4) were investigated using ferric sulphate (Fe2(SO4)3) solutions containing sodium chloride under high pressure oxidation conditions. The effects of numerous parameters including the concentration of Fe2(SO4)3 and NaCl, temperature, total pressure, leaching time and particle size were studied while other variables such as pulp density and stirring speed were fixed at 100 g/L and 750 rpm. The results showed that more than 60% of the copper was dissolved in a 0.1 M ferric sulphate solution under the high pressure oxidative conditions, whereas the leaching rate of arsenic was less than 20%. SEM observation revealed that elemental sulphur was deposited on the surface of enargite forming a passivation layer and the residue was agglomerated. Those phenomena may cause a decrease in the copper leaching rate. It was found that more than 80% of copper was dissolved in the ferric sulphate solution in the presence of 0.34 M sodium chloride under the conditions optimized, whereas the dissolution of arsenic in the mixture did not exceed 2%. XRD analysis of the solid residues from the leaching experiments used ferric sulphate and mixtures of ferric sulphate and sodium chloride showed arsenic to be present as scorodite (FeAsO4).INTRODUCTION In recent years, there has been an increase of the arsenic (As) content of copper ores due to the gradual depletion of high grade copper ores. In some copper deposits, arsenic occurs in the form of minerals such as enargite and tennantite. The removal of arsenic in ores containing copper is critical to the production of pure copper and the management of the environmental challenges caused by the smelting process. Due to the environmental risk caused by arsenic emission and the deteriorated quality of the copper product, smelting of enargite concentrates is not an effective method for the extraction of copper (Padilla et al., 2010; Safarzadeh et al., 2014; Long et al., 2012). Therefore, a number of studies have been carried out to develop arsenic removal technologies from copper ores using various methods such as hydrometallurgy (Curreli et al., 2009; Tongamp et al. 2010), pyrometallurgy (Dalewski., 1999; Padilla. et al, 2012) and bio-oxidation (Ehrlich, 1964; Sasaki et al., 2010). Several hydrometallurgical leaching processes like sulphuric acid, alkaline sodium sulphide and sodium sulphate and ferric sulphate leaching have been developed to treat enargite ores and concentrates. The alkaline sodium sulphide leaching process has been developed for the removal of arsenic from enargite (Anderson, & Twidwell, 2008; Parada et al., 2014). The mechanism of the dissolution of arsenic from enargite in sodium sulphite solution is"

Jan 1, 2016

By Philip Peck

Mine closure issues ?Narrow issues: ?Environmental focus; ?Broad issues: ?Social issues and sustainability; ?Continued importance of mining; ?Historical legacies from closed mines; ?Barriers to development; ?Migration [ir]reversibility Dealing with closure issues ?A matter of choice ?Option 1: Engagein solving closure problems as best possible; ?Option 2: Exit, leaving the playing field to firms not interested in solving problems ?Option 3: Delay, till better time to enter or until early entry [by others] fails and pick property up cheap [?].

May 1, 2006

By John A. Meech, Irene E. Cristoveanu

"The separation of hematite fines (100% - 38 um) from quartz fines (100% -75 um) was investigated using coarse hematite (-212 + 150 um) as a carrier in an oleic acid collector system. Oleic acid additions, per cent coarse additions, combined conditioning time and ferric chloride additions were examined.It was found that carrier flotation is a dominant mechanism for fine hematite recovery at oleic acid levels greater than 200 g/t and coarse additions of 10 per cent. Hetero-aggregation is favoured under conditions of lower levels of oleic acid in the presence of ferric chloride and at conditioning times greater than ten minutes.Ferric chloride acts as a depressant for pre-reagentized coarse hematite at oleic acid levels below 150 g/t. At concentration levels above 500 g/t, ferric chloride interferes significantly with the success of carrier flotation of fine hematite.The sensitivity of carrier flotation to changes in oleic acid addition, ratios of fine and coarse material, conditioning time and the presence of an inorganic electrolyte emphasizes that its application is only suitable when flotation conditions can be stabilized.IntroductionThe production of fine material is unavoidable during the comminution of iron ore . Due to the difficulty of recovering iron from this fine material by various gravity separation methods, flotation can often be a more attractive process producing high-grade material at high recovery. One variation of the flotation process, that can be useful for recovering ultra fine minerals (<10 um) , is known as carrier flotation. This process involves the utilizat ion of coarse particles ( > 150 p.m) which act as flocculation centres to which the fine hematite particles (10 - 40 u.m) become attached and are carried or "" piggy-backed"" into the froth phase."

Jan 1, 1985

By Larson. William

What is Lunar In-Situ Resource Utilization (ISRU)? ISRU involves any hardware or operation that harnesses and utilizes ?in-situ? resources to create products and services for robotic and human exploration In-Situ Lunar Resources ???Natural? Lunar Resources ??Discarded Materials Lunar ISRU Products and Services ??Excavation, Site Preparation, and Outpost Deployment/Emplacement ??Mission Consumable Production ??Outpost Growth and Self-Sufficiency Benefits of ISRU ??Increased science and exploration hardware (instead of consumables) ??Increased safety, crew exploration time, and self-sufficiency ??Technology spin-in/spin-offs help recycling on Earth & space economy

May 1, 2009

By A. D. Burns, K. M. Nikolaisen

Electrolytic reduction followed by the addition of sulfuric acid and the application of heat can be used to selectively crystallize uranous sulfate from solution. This approach, when coupled with downstream thermal decomposition, forms the basis of a process for primary uranium recovery and purification where much of the sulfuric acid value can be recovered and recycled. In this process, a purified uranium (VI) leach solution is first electrolytically reduced to uranium (IV) in a membrane electrolysis cell. Sulfuric acid is then added to the solution which, in conjunction with the input of heat, causes the crystallization of uranous sulfate tetrahydrate. The precipitate is then dried and thermally decomposed to U3O8, which releases a mixture of high-purity SO2, SO3, oxygen, and water vapour. This gas can be recovered as sulfuric acid in an existing acid plant, processed through a new wet sulfuric acid process, or absorbed directly into the upstream electrolyte as a substitute for fresh acid in the crystallization step. This process has been shown to be practical, efficient, and cost-effective on the laboratory scale, and could be practiced on the industrial scale using commercially available equipment. This paper focuses on the thermal decomposition process and options for acid recovery.

Jan 1, 2020

By S. Boisvert

Risk-based Inspection (RBI) addresses the challenges associated with ageing plants by focusing the inspection effort on the process equipments with the highest risk, thereby improving plant safety and reducing inspection costs. The RBI methodology is commonly used in the oil industry through the API 581 standard. Since no such standard exists in the mining and metals industry, BPR-Bechtel has developed one using inspection data from process equipments in CEZinc. Models were developed for various damage mechanisms, such as uniform corrosion and stress corrosion cracking. The equations were organized into a user friendly software that facilitates the implementation process.

Jan 1, 2010

By Tai Sik Lee

Why ISRU into Space Exploration are important NASA and International Mission statements calls for the sustainable human exploration of the Moon, Near-Earth asteroids, and Mars Common Exploration Goals and Objectives are Strongly influenced by ISRU Extend Human Presence: Continually increase the duration and level of self sufficiency at all destinations Develop Exploration Technologies and Capabilities: Develop and validate tools, technologies, and systems that extract, process, and utilize resource to enable exploration missions Perform Science to Support Human Exploration: Characterize available resources at destinations Stimulate Economic Expansion: Encourage commercial services and create new markets, including markets for discovered resources Enhance Earth Safety: Test techniques to mitigate the risk of asteroid collisions with Earth

May 1, 2013

By Mark Sherman

One of the main functions of a process technology and engineering services provider is to select grinding equipment that will meet the client?s throughput rate target. Prudent risk mitigation strategies would suggest that throughput rate estimates be cross-checked using a variety of techniques. Whilst some comminution circuit designers have estimated specific energy requirements via the manipulation of the Bond specific power equation e.g. Barratt?s Grindpower and OMC?s FSAG approach, other designers have opined that the Bond Indices have no role to play in the calculation of SAG mill specific power. As a result, they have developed their own specific energy estimating methodologies, e.g. SMCC?s Drop Weight based power methodology, SPI, SAGDesign, etc. Each method has its supporters and its critics. The challenge facing the engineering provider is how to nominate an SAG mill based circuit throughput rate estimate when faced with significantly disparate specific energies calculated by the different methodologies. This challenge is exacerbated via the continuing evolution of contemporary circuit configurations such as two stage pebble crushing some of which incorporate HPGR technology as the second stage of pebble crushing. The methodology presented in this paper shows that the Bond Indices are an excellent tool for estimating the specific energy requirements for SAG mills in SAB, SABC and SSS circuits. The method accommodates primary crushed feeds, partial and or fully secondary crushed SAG mill feeds, and emulates the impact of pebble crushing on SAG specific energy. As a result, the new Bond Index based method has provided an additional tool for increasing Fluor?s confidence when predicting SAG mill based circuit throughput rates. Based on this outcome, the author proposes that the decades old conundrum of using Bond Indices to calculate SAG specific energies for SAG mill based circuits has been solved.

Jan 1, 2012

By G. Vibert Douglas

"Gold occurs in Nova Scotia in three ways, saddle reefs, fissure veins, and fossil placers. Of these the saddle reefs are the commonest. They have been the source of most of the gold and have also been the subject of most of the literature on the gold occurrences.The Meguma or Gold-bearing series of Nova Scotia is a conformable succession of quartzite's and slates, possibly Precambrian in age, which have been folded into a number of anticlines and synclines that strike (Fig. 1) roughly east and west. This folding has been termed Acadian and is probably a westward continuation of the Caledonian revolution in Britain. It may have started in the Ordovician and continued through the Silurian and into the Lower Devonian. It was followed by the intrusion of the great Devonian granite batholiths. It is thought that the mineralization is connected with the late phases of the cooling of the granite. As the name saddle reef implies, the veins form on the crests and flanks of the anticlines, possibly in the synclinal troughs as well. The beds favoured by the solutions are the slates. The reason for this is apparent when it is realized that in order to fold over 30,000 feet of sediments (the thickness of the Meguma according to E. R. Faribault) through p radians of arc it is necessary to have a differential movement between the top and bottom beds of p times the thickness of the sediments. In the case of the Gold-bearing series, in which strong quartzite beds lie between incompetent slate beds, most of this differential movement was taken up in the slates. The evidence for this is the remarkably fine drag folding and the intense shearing and comminution of some of the beds of slate (Fig. 1). The quartzites exhibit some shearing and faulting, but there is little doubt that the greater permeability lay along the incompetent slate beds. The mineralizing solutions followed these beds and also passed from one slate bed to another through a joint or fault in the intervening bed of quartzite. These joining veins are called angulars in Nova Scotia. Within the veins the gold is in shoots and the real problem is to find out what controls the position and extent of the shoots."

Jan 1, 1954

By Roy O. Ifill, W. Charle Cooper, Alan H. Clark

"Queen’s UniversityIn representative, run-of-mine samples from the Panel and New Quirke mines of the Elliot Lake uranium district, Ontario, brannerite, ametamict uranous titanate, occurs in microscopic grain-aggregates which display wide variations, both in textural habit and in the relative proportions of brannerite, titania polymorphs and/or “uraniferous titania”. As is widely documented, much of the brannerite occurs as trellis-like arrays of laths and needles pseudomorphing rutile oranatase. In some cases, the laths and needles are cemented by coffinite. Brannerite, with an average composition of (U0.629Th0.039Ca0.20)(Ti2.199Fe0.13)O69contains =3 wt% Th and is distinctly Ti-rich relative to the ideal composition, UTi2O6. Much of the Si reporting consistently in electron microprobe analyses (between 1 wt%and 5 wt%) is tentatively attributed to contamination by the quartz-sericite matrix, and a minor proportion is attributed to the presence of coffinite intergrowths. “Uraniferous titania” (average par-tial composition by weight: 10.8% U, 0.3% Th,32.9% Ti) is considered to represent an intermediate stage in the conversion of titania to brannerite.The leaching behaviour of brannerite in its different modes of occurrence was studied qualitatively by the rotating-disc (polished section) method in H2SO4and HCl solutions at 25° to70°C. Redox potential was not measured. The progress of the dissolution of the individual brannerite crystallites and grain-aggregates was monitored by optical and scanning electron microscopes. Regardless of its morphology and texture (laths or needles, reticulate or blocky),brannerite is not readily leachable. Regardless of the process conditions, the rate-controlling step appears to be the initial leach-pit formation. These pits expand radially through the aggregate as leaching proceeds. This dissolution mode is independent of the relative amounts of brannerite and titania, i.e. the type of grain-aggregate. Secondary coffinite intergrowths are readily leachable and enhance the overall leaching kinetics of brannerite by accelerating leach-pit formation. These data provide, for the first time, information on the controls on the leaching of the uraniferous phases which dominate the lower-grade ores in the Elliot Lake district."

Jan 1, 1996

By B. Surender Mohan

Mother Earth being a treasure of minerals, it is prime duty of the mankind to preserve this natural source to ensure steady growth of the nation. Utmost care is to be taken to see that these natural resources are explored and exploited scientifically in a sustained manner to ensure that the resource base improves and last longer. In this backdrop, the topic of ?Lignite - its resource and technology options to exploit deep seated deposits? is an apt subject to be deliberated upon in the present context, where the shallow deposits may slowly get dwindled. I shall deliberate upon the resource base of lignite, production profiles of the last five decades, consumption pattern, demand / supply projections, future available technology options to exploit the deep seated deposits, growth trends of the sector etc. in my paper. With the available resource base and future technology options, I can confidentially make a statement that ?lignite will remain as cocontributor along with coal to India?s energy generation and may well maintain its same status in the 21st century too, as it has been in the later part of the twentieth century?.

Aug 1, 2013

By V. Evans

Mine lateral development advance rates currently average about 5 metres (16.5 ft.) per day. Granduc Tunnel hit 35.1 metres (115 ft.) on their best day, 12 km from the portal, single heading forty-three years ago. This Canadian mining record remains an excellent example of rapid drill and blast excavation with suggestions for improving current practice.

May 1, 2011

By A. S. Eve

The detection of magnetic dykes by using magnetic variometers is the oldest application of. geophysics to mining, and is also one of the more simple and certain methods 0f locating such deposits. As a result of recent improvements in the instruments, it is now possible to find the dyke, deter-mine with magnetic variometers its strike and dip&apos;, with fair accuracy, and to estimate the approximate depth of overburden when there is no outcrop. The application of electrical methods may be used to distinguish mineral from diabase dykes. The authors have had an opportunity of making surveys with the modern Askania types of vertical and horizontal variometers over magnetic dykes in the Sudbury region. The interpretation of the results has been confirmed by diamond drilling in some cases, and by experiments over models. The variometers used were the standard form of Askania instruments (1). The sensitivity of the horizontal type was 17.2 gammas per division, and that of the vertical variometer double this quantity. To make a preliminary survey of the district, parallel lines were laid off two hundred feet apart running north and south, and readings were taken with the vertical variometer every 100 feet along these lines. This can be done very rapidly, and when an indication of a magnetic deposit is found, the readings may be taken every hundred feet, or less if the size of the deposit warrants smaller intervals. If the deposit is a vein or dyke, the readings along the adjacent lines immediately indicate the strike of the body. Thus the presence and strike of a magnetic dyke, whether of mineral value like the pyrrhotite and nickel deposits of the Sudbury district, or simply a worth-less diabase dyke, is simply and rapidly found.

Jan 1, 1932

By M. S. King

"A simple method is proposed for determining the long-term deformation behaviour of evaporites. The theory developed can be tested by measuring the change in diameter as a function of time of a vertical mine shaft opposite evaporite strata. Ultimate shaft closures predicted by the theory agree well with those calculated with the very much more complex theory of Serata (1968), provided that sufficiently high octahedral shear strengths are used in the former.An analysis of measurements made in an isolated opening in a Saskatchewan potash mine shows that the octahedral shear strength of the surrounding potash and halite was approximately 500 psi several years after the opening was mined. This value is less than that deter-mined experimentally for halite by Serata. The same data indicate, furthermore, that the in-situ octahedral shear strength is decreasing slowly with time.The current controversy regarding the actual deformation of evaporites will only be resolved by the cooperation of potash producing companies in releasing data on the long-term deformation of their mine shafts."

Jan 1, 1971

By Andrea R. Gerson, Roger St. C. Smart, Russell Schumann, Joan E. Thomas, Warwick Stewart, Stuart Miller

Sequential Net Acid Generation (NAG) accelerated oxidation testing using peroxide was carried out on single sulfide mineral samples. The calculation of the nett acid production potential (NAPP) assumes that all the sulfide is present as pyrite and that dissolution results in a 2:1 ratio of H+:SO42-. NAPP as kg H2SO4/t is calculated as 30.6 x wt.% S present. To test whether this calculation is valid a NAPP* value was defined in which instead of using the wt.% S present for the calculation the wt.% S dissolved is used. Stoichiometric analysis of the dissolution products of the sulfide minerals as they would occur at pH 7 indicates, that in all cases, the ratio of H+:SO42- of 2:1 is viable. The NAG to pH 7 and NAPP* closely coincided for pyrite, bornite, chalcocite and covellite. For the three Cu-containing minerals, the NAG to pH 4.5 value was 0 as is predicted on the basis of the speciation likely to be present at pH 4.5. Acid generation is due to hydroxylation of the dissolved Cu between pH 4.5 and 7.0. The NAG to pH 7 and NAPP* values for chalcopyrite, arsenopyrite and pyrrhotite were in reasonable agreement but were not for either sphalerite or galena. Zn is not completely hydroxylated at pH 7 as is assumed by the calculation. For galena, surface analysis identified polysulfide formation on of the leach residue polysulfide. The formation of polysulfide is an acid consuming reaction. Therefore under conditions of accelerated oxidation the NAPP value is a reasonable estimate of the possible acid production in all cases except for sphalerite and galena. However, under conditions of less intense oxidation, for instance in columns, waste rock and tailings dumps, the formation of polysulfides is likely to be more widespread thus reducing the correlation between NAPP and the maximum possible acid production.

Jan 1, 2004