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By S. S. Al-Thyabat, A. M. Ghrair

"Printed circuit board (PCB) is the main part of any electric or electronic device, providing mechanical support and electric connection for the board eclectic components such as capacitors, resistors, diodes etc. PCB consists of non-conductive substrate overlaid with one or more layers of copper sheets. They also contain appreciable amounts of base metals (copper, nickel, tine, and aluminum) and precious metals (gold, silver, and rare earth elements (REE)) which end up in the landfill at the PCB end-of-life.PCB recycling E-waste in general is a profitable business; many valuable raw materials, precious and base metals, can be extracted with high purity. Approximately, one metric tonne of PCBs may contain 80-1500 g of gold and 160–210 kg of copper. The precious metals recovered from PCBs occur at concentrations higher than commercially mined minerals. Also PCB recycling is very important to our environment since many heavy metals (e.g. lead) may be leached from the landfills to the underground reservoirs. In Jordan, however, the work conducted on E-waste and PCB recycling in particular is limited; currently most of the E-waste is either exported or dumped in the landfill.In this work, a combination of physical (magnetic separation), physicochemical (flotation), and chemical methods (leaching) were used to compare metals concentrations in leach liquors produced from a concentrates resulted from a combination of these methods. It was found the leach liquor of the magnetic fraction of the PCB coarse size gave the highest concentration of Fe, Al, and Ni while concentration of Cu was higher in leach liquor of nonmagnetic sink fraction. On the other hand, metals concentration almost similar for both sink and float of the fine size fractions, indicating even distribution of metals concentrations in the fine size fractions."

Jan 1, 2016

By Y. Hayashi, A. Fuwa

To analyze zinc vaporization kinetics of zinc smelting slag in the ISP furnace, reduction reaction rate of zinc oxide from ZnO-FeOx-CaO-SiO2 slag system with CO-CO2-Ar gas mixtures has been measured by a therm o-gravim etric apparatus at various ZnO content, Pco, and temperature. The reduction rate was measured under a chemical reaction control in the initial three minutes where surface zinc content can be assumed constant. Through the reaction rate dependency analysis on ZnO contents, Pco and temperature, discussion has been made on its reaction mechanistic information in terms of rate coefficient, adsorption/desorption mechanism and activation energy.

Jan 1, 2008

By L. Yaun

In underground coal mining operations, gas content in a coal seam is used to assess the risk of coal and gas outbursts. To estimate the gas content, a number of systems have been developed, however issues remain about the rapidness and accuracy of these systems. To address these issues, a new and improved system has been developed that includes a sampling-while-drilling unit for coal sampling, a coal canister, an underground-based portable measurement unit, a surface-based measurement apparatus, and gas content calculation software. The system has been successfully applied in underground coal mines at Huainan, China. This new, rapid and accurate system, its main components and field trials are described in this paper.

Aug 1, 2013

By A. Perucho, J. P. Harrison, A. Bedi, L. Alejano, L. Lamas, A. Sofianos, A. M. Ferrero, R. Migliazza, R. Olsson, J-F. Mathier

"In 2010, the Eurocode for Geotechnical Design, EN-1997-1:2004 (CEN, 2004), informally known as Eurocode 7 or EC7, became the Reference Design Code (RDC) for geotechnical design – including rock engineering design – within the European Union (EU). EC7 is one standard within the comprehensive Structural Eurocode suite, which as a whole has been also adopted by a number of other countries beyond the EU. EC7 is thus becoming a key design standard for geotechnical engineering worldwide.As part of the Structural Eurocode suite, EC7 requires designs to adhere to the principles of Limit State Design. However, it is not clear that current rock engineering design practice can satisfy this requirement. In addition, evidence is accumulating that EC7 is currently difficult to apply to, and may even be inappropriate for, rock engineering design. These issues may be due to the fact that the development of EC7 to date took place without any formal input from the international rock mechanics and rock engineering community.In early 2011 under the auspices of CEN (Comité Européen de Normalisation / European Committee for Standardisation), EC7 entered a formal period of maintenance which was aimed at improving the applicability and ease-of-use of the Code. This maintenance cycle will conclude in 2020 with the publication of a revised version of EC7.This paper describes a number of critical aspects for rock engineering in the context of EC7, inparticular the following:– the history of the Structural Eurocodes and the concepts they embody;– the nature of Limit State Design and the challenges and opportunities it poses for rock engineering design;– the formal means by which the Structural Eurocode maintenance cycle proceeds;– the plans currently being developed for improving EC7 with regard to rock engineering design and construction;– the unique and vital opportunity for the entire international rock mechanics and rock engineering community to comment on the Code and make suggestions for its improvement."

Jan 1, 2015

By Donka H. Andreeva

Gold catalysts based on different supports, titania, zirconia, ceria and mesoporous titania and zirconia, nonpromoted and promoted by vanadia in the reaction of complete benzene oxidation have been studied. XRD, HRTEM, TPR, Raman and ESR spectroscopy were applied for the characterization of the catalysts. The influence of gold on the reduction behavior, state and structure of vanadia on the surface was studied, as well as the role of supports nature on the properties and catalytic activity. A strong synergistic effect between gold and vanadia was observed for the all studied catalysts with an exception of the catalysts supported on mesoporous zirconia. In the last case the catalysts containing gold and gold-vanadia exhibit high and equal catalytic activity. The catalysts on ceria show highest and stable catalytic activity in the studied reaction among the all studied catalysts.

Oct 1, 2003

By A. O. Orumwense

Mill circumferential speed, the number of passes of pulp through the grinding chamber, media type, size and filling ratio were investigated in an attempt to determine how to effectively grind copper concentrates in a stirred mill. The stirred mill product fineness was enhanced to some extent by decreasing media size, high media filling, and an increased number of passes of the pulp through the grinding chamber. Shape also plays a major role in grinding media effectiveness, with spherically shaped media producing a finer size. The fineness of the product increases with increasing power consumption but the method of energy transfer is very important in energy utilization. The effect of the mill parameters on copper flotation was evaluated. Copper recovery was influenced by grinding media size, mill speed and the number of pulp passes through the grinding chamber.

Jan 1, 2006

By E. O. Magnusson

THE orebodies of the Preston East Dome mine show a considerable variation in size,? shape, dip, and ground condition. They vary from small and large irregular masses being mined by shrinkage, cut-and-fill, and square set-and-fill mining methods to narrow veins being mined by open stoping. Standardization of mining operations has necessarily been difficult. This considerable variation in mining condition prompted the development of a bonus system which would give more equitable bonus payments through-out the mine than those obtained by the usually accepted methods of calculating mine bonus. PRINCIPLES ON WHICH THE SYSTEM IS BASED Under an incentive bonus system, performance (efficiency) and a price per unit of work done are inter-related. It is in the application of this? principle to working conditions .in the Preston East Dome mine that the system to be described differs from the standard methods of calculating mine bonus. It was found that the method of paying a fixed price per unit of work done, under the 'contract' system, gave satisfactory results in development, less satisfactory results in timbering, and results which were not satisfactory in stoping. Under the fixed price system, bonus payments, in timbering and stoping particularly, were very erratic and did not necessarily represent fair payment for the work done. A fixed price in development is satisfactory because the work done, and the conditions under which the work is done, are uniform. The drilling and blasting cycle is completed in one shift, the size of heading is con-trolled, and a minimum number of holes are required in order to obtain a satisfactory break. The performance possible under these conditions has been found to be confined to a fairly narrow range. By performance in development is meant the efficiency of the working crew as expressed in terms of the two variables of feet of advance per round and pounds of ex-plosives consumed per foot of advance. A change in rock formation, how-ever, may alter to a marked degree the performance possible, quite independent of the skill and energy of the working crew. The changes in working conditions that affect development performance from the standpoint of bonus calculation are usually easily apparent and are satisfactorily met by establishing several fixed prices.

Jan 1, 1944

In this study, we develop a detailed model of the likely future carbon footprint of primary copper supply. We develop a peak copper production model, based on a detailed copper resource data set, and combine this with a comprehensive life cycle assessment model of copper mining and milling to predict greenhouse gas emission rates and intensities of Australian and global copper production up to 2100. By establishing a quantitative prediction of both copper production and corresponding greenhouse gas emissions of Australian and global copper industry, we then analysed the emissions intensity of various energy input scenarios, such as business-as-usual, solar thermal electricity and solar thermal electricity with biodiesel. The Australian Government has an aspirational goal for long-term greenhouse gas emissions of an 80% reduction from the 2000 level by 2050. For the copper sector, this means moving from about 12.6 Mt CO2e in 2000 to a goal of some 2.52 Mt CO2e in 2050 (assuming equal emissions reductions across the economy). Based on the energy sources modelled, only the solar thermal plus biodiesel scenario was capable of achieving this goal at about 0.15 Mt CO2e, since the solar thermal alone scenario still includes normal petro-diesel as a major source of emissions. Overall, it is clear that there are abundant resources which can meet expected long-term copper demands, the critical issue is more the carbon (and environmental) footprint of different copper supplies and use rather than how much is available for mining. It is clear that the switch to renewable energy can have a profound impact on the carbon intensity of copper supply, even allowing for increased energy intensity as ore grades decline, and a complete conversion to renewable energy will position the copper sector to meet existing annual greenhouse gas emissions targets and goals.

Aug 1, 2013

By B. A. Monkman

"IntroductionONE OF :THE most effective methods by which the construction industry is combatting mounting building costs is by making increased use of lightweight materials, thus reducing the dead load to be carried •by structures. This applies to non-metallic materials as well as to metallic ones, and particular attention has been given to developing lightweight aggregates for use in concrete.The use of lightweight aggregates is not new and, in fact, dates back to the Roman Empire, when pumice was used in the walls and domes of the Roman buildings. More recently, and up to a decade or so ago, the demand for these aggregates was met from deposits of volcanic cinders, pumice, scoria, etc., and from the by-products of blast furnaces and coal burning boilers. However, these sources of supply are no longer sufficient to meet the demand, for transportation costs pretty well restrict the use of the natural lightweight aggregates to the western cordillera regions where the deposits of these materials occur, and the use of expanded slag aggregates to the areas neighbouring the plants where slags are produced. As for cinders, the supply has been greatly reduced by the conversion of industry to fuel oil, natural gas, and powdered coal, and the large stockpiles which existed previously have been pretty well exhausted.Industry's approach to the problem of a decreasing supply, in the face of an increasing demand, has been characteristically direct. The solution has been to construct plants whose sole .purpose is to produce economically an acceptable light-weight aggregate from materials close at hand."

Jan 1, 1955

By T. Johnson, D. Kelley, J. Graham

"Hydrometallurgical processes can be exceptionally corrosive. Conditions associated with metal extraction and refining require materials of construction that can withstand process acids and acid chlorides at temperatures up to 90°C (194°F). Process vessels, piping, scrubbers and ducting can be rapidly compromised in these aggressive environments if not designed with care. Design engineers are challenged to find materials that can stand up to hydrometallurgical processes especially for copper, zinc, nickel, cobalt and uranium. This paper will evaluate material solutions to determine which provides attractive economics for initial procurement as well as high durability for reasonable life cycle costs.INTRODUCTIONMining activity in a number of metal ores has been running quite high over the last few years. In particular, those metals that employ acid functional extraction processes such as copper, nickel cobalt and uranium have been particularly active.The world’s largest nickel mine – the massive $4.76 billion Ambatovy nickel mine on the African island nation of Madagascar is nearing completion. When it reaches its full production capacity in 2013, the mine will produce 60,000 MT/yr of nickel and 5600 MT/yr of cobalt. Coming on the heels of the Ambatovy project is the Long Harbour Processing Plant in Newfoundland, Canada which will process the ore from Vale’s Voisey Bay mine in Labrador. Voisey’s Bay is expected to generate more than 50,000 MT/yr of nickel ore when it starts up in 2013. Next up will be the Boleo project in Mexico on the Baja peninsula. When commissioned in 2013, the $858 Million Boleo project is expected to produce 60,000 MT/yr copper, 3100 MT/yr cobalt, 36,000 MT/yr zinc and 100,000 – 250,000 MT/yr manganese carbonate.High nickel alloys and rubber lined steel have been used for decades to design corrosion resistant equipment for mineral processing environments. These materials demonstrate reasonable resistance to corrosion for most environments. Unfortunately, higher nickel alloys are quite expensive. Rubber lined steel is a bit more affordable but requires continuing service over time which ultimately drives up its cost as well. FRP (Fiberglass Reinforced Plastic) has also been used extensively in mineral processing for tanks, piping and ducting employed in aggressive environments. Today, more and more design engineers and material specifiers are calling for FRP composites for both new and replacement equipment used in the refining and processing of a variety of metal ores."

Jan 1, 2012

By T. G. Joseph, E. Lampard

ABSTRACT: Surface mining operations must manage variability from within their operations as well as variability imposed upon them by external forces. A framework to manage both internal and external variability through the continuous review and adjustment of a mine plan during active mining lifetime operation is introduced, to minimize lost production and maintain operational safety. The observational approach of “observe, evaluate, interpret, predict, and adapt” is employed as the backbone of this approach. Although written with a surface mining operation in mind, the framework outlined in this paper would be equally applicable to any mining or processing operation.

Jan 1, 2011

By V. Bondarenko

The importance and necessity of gas hydrates deposits development followed by natural gas extraction is considered in the present paper. Analysis is given to world sources focused on methane hydrates formation conditions. Information covering the most perspective gas hydrate deposit of the Black Sea is presented in the article. Two most common methods of gas hydrates development ? thermo stimulation and inhibitor injection are analyzed presenting their comparative characteristics. Basic scientific trends and developments of underground mining department in the field of gas methane extraction from gas hydrates are scrutinized. Schemes and methods of natural gas hydrates development are shown together with formulas, parameters and factors influencing the extraction process. Also the analysis is given to the possibility of gas hydrates formation from methane-air mixtures of degassing wells from coal mines of Ukraine. Improved experimental unit for gas hydrates formation under laboratorial conditions is presented with its basic characteristics. General conclusions and basic tasks requiring further research are given in the end.

Aug 1, 2013

By J. Kempken, R. Hagmann, C. -P. Reip, W. Hennig

The CSP technology symbolizes a highly productive process for the cost-effective production of steel grades with a range of sophisticated properties comprising both the inner quality of hot strip, its surface formation as well as the relating technological characteristics. Thanks to extensive development work undertaken during the last 15 years, the range of steel grades that can be produced was continuously expanded and the process technology optimized. The present paper describes the ongoing development work concerning the production of higher-strength, microalloyed pipe steels. The resulting hot strip, due to the associated thickness and the potential pipe diameters, is particularly suited for being processed to HFI-welded pipes. Based both on ferrite-pearlite as well as very fine-grained, ferrite-bainite hot-strip microstructures, strength levels of up to grade API X80 can be realized. It can be demonstrated that hot strip produced in a CSP plant has very good toughness values at temperatures down to -60°C and can even make application with required sour-gas resistance possible.

Jan 1, 2005

By M. E. Moraes Castanho de Almeida, A. Ribeiro Cotri

Recovery of cobalt to produce high grade cobalt sulfate from cobalt concentrate by leaching and solvent extraction was investigated. The PLS typically contains Co 10g/l, Mg 2g/l, Fe < 10ppm, Mn < 200ppm, insolubles <100ppm and is extracted with 20wt% Cyanex??272. The typical strip solution contains Co 60g/l, Mg 0.03g/l, and was sent to the current process for the production of cobalt sulfate heptahydrate. The cobalt yield of the plant with two extraction steps was 92%, with three steps was 97% and with four steps 99%. The extraction stage used the concept of "scrubbing" in a countercurrent system. In the first stage of extraction pH was 4.8, and in the last stage of extraction pH 5.5 to promote the exchange of magnesium in the organic with cobalt contained in the PLS. Following the extraction, when using two scrubbing stages, Co/Mg selectivity between of 2,000-3,000 was obtained, and with three scrubbing stages, selectivity was greater than 6,000. The desired selectivity was reached when using a scrubbing configuration with O/A ratio of 10:1. The typical cobalt sulfate heptahydrate had the following composition: Co 20wt%, Mg < 0.01wt%, Fe < 5ppm, Mn < 0.01wt%, Cu < 0.01wt%, Zn < 0.01wt%.

Jan 1, 2014

By A. R. Hekmat

Hypereutectic Al-Si alloys are used in applications that require high resistance to wear and corrosion, hardness and low coefficient of thermal expansion, To maximize the properties of these alloys, semi-solid processing can be utilized to modify the solidification structure of the primary silicon crystals as well as to reduce microsegregation and porosity, The transformation and spheroidization of primary Si crystals by shearing in the semi-solid state are not fully understood as they precipitate in the presence of other alloy phases, The objective of the present work is the determination the rheological characteristics of A390 (Al-17%Si-4,5%Cu-0.5%Mg) alloy using a Couette type (Haake RV12) viscometer and examining the microstructural evolution during continuous cooling and isothermal shear rate experiments, The effect of shear rate, solid fraction (temperature) and morphological evolution of the silicon crystals are investigated.

Jan 1, 2005

By C. F. Gleeson

"Geochemical stream-sediment reconnaissance can be a useful exploration tool from the point of view of rapidly and cheaply evaluating the mineral potential of an area. This is particularly true of rugged and mountainous areas such as are found in Gaspé. For the past two years, SOQUEM has been carrying out such surveys over favorable geological regions in the Appalachians of northern New Brunswick and Gaspe. To date, about 4,000 square miles of terrain has been systematically covered by reconnaissance geochemistry. Jeeps have been used as a means of transportation in the easily accessible areas and a helicopter equipped with a winch has been used to lower crews into the more difficult-to-reach regions. Such surveys have been successful in finding metallic mineralization which otherwise might not have been detected.Electronic computation of analytical information has been used to construct regional metal maps, rolling mean maps and residual metal maps. These maps have helped in evaluating anomalies, in relating the regional geo-chemistry to the regional geology and in comparing the distribution patterns of metals. To date, some 30,000 stream-sediment samples have been collected from the Gaspe region and analyzed for Cu, Pb, Zn and Mn. These analyses are being subjected to computer analysis."

Jan 1, 1969

By J. E. Dutrizac

The dissolution of low-iron sphalerite, (Zn,Fe)S containing 0.08% Fe, in ferric sulphate-sulphuric acid media was investigated using closely sized fractions of crushed sphalerite crystals and sintered disks made from the crushed crystals. Linear kinetics are observed, and the predominant reaction products are ZnSO4, FeSO4 and elemental sulphur. The leaching rate increases systematically with increasing temperature, and the calculated apparent activation energy is 56 kJ/mol for the sized sphalerite and 54 kJ/mol for the sintered disks. The relatively high apparent activation energy suggests that the rate is chemically controlled, a conclusion supported by the insensitivity of the rate to the disk rotation speed. The rate increases as the 0.22 power of the Fe(SO4)1.5 concentration, and as the 0.22 power of the H2SO4 concentration. However, in the absence of ferric ions, the rate increases more significantly with increasing H2SO4 concentrations, and relatively rapid rates are observed in solutions containing >0.5 M H2SO4. In 0.1 M Fe(SO4)1.5-0.3 M H2SO4 media, the measured rate decreases with increasing sulphate concentrations, added as Li2SO4. The rate of dissolution of low-iron sphalerite is promoted by dissolved copper concentrations as high as 800 mg/L. In contrast, dissolved silver, even in the 0-2 mg/L concentration range, significantly retards the dissolution of the low-iron sphalerite.

Jan 1, 2008

By Marc Piard

In a cool mine, tapping high-pressure lines through reducing valves lowers the temperature beyond remedy. It is the writer&apos;s suggestion that, for low-pressure work, law-pressure air ,should be generated in a compressor installed underground adjacent to the work, and that the jacket-water of the compressor should be utilised for re-heating purposes. Such a system of compressed air distribution, designed especially for service in cool mines, is described in the following notes. The suggested system includes a three-wire pole line from the sub-station to the opening nearest to the working face, with a cable connection extending to the latter from the openings; an electrical centrifugal unit; a reservoir excavated in the ground; and a distribution line, re-heated by jacket-water. As regards the reservoir, it may be pointed out that in many mines there are blind or abandoned tunnels that could be used for the purpose. The centrifugal type of compressed air machine is a comparatively new departure, and it was formerly considered that such a machine, operating at less than 1,000 kilowatts per unit, would be commercially impracticable. At the present time, however, these machines are being built in Europe for as little as 400 kilowatts per unit, and as much as 110 lb. per sq. inch pressure. One advantage which these centrifugal machines have over other types is that they may be driven by plain induction motors, without the help of special starters-a consideration of the first importance where the electrical regulations are severe.

Jan 1, 1926

By T. A. Utigard

To improve recoveries of Ni, Cu and Co in the Inco flash furnace, a new operating concept was investigated. By adding sufficient coke to form a supernatant coke layer, a reducing barrier would form allowing for improved reduction of descending oxidized sulfide mineral particles formed in the flame. The objective of this investigation was to study the kinetic mechanism and efficiency of the coke layer to produce a sulfur deficient matte. The mechanism and rate of carbon reduction of each of the phases formed in the flash flame, i.e. sulfides and oxysulfides were investigated by means of X-ray visualization tests. Graphite-slag reduction was also conducted for comparison purposes. In the case of slag, poor wettability and the formation of a gas film on the surface of the carbon reductant are often blamed for limiting the reaction surface area that ultimately results in poor reaction kinetics. The X-ray visualization tests confirmed that matte and oxysulfide wet coke better than slag and that the rates of reduction of matte and oxysulfide are faster than that of slag.

Jan 1, 2005

By M. Sahoo, P. Burke, Y. Fasoyinu, J. P. Thomson

The effects of grain refinement, mold temperature and chemical composition on the hot tearing resistance of aluminum alloys 535.0 and 206.0 has been studied by pouring constrained rod castings in metal molds. In addition, two prototype components that could be used in automotive applications were also poured from both alloys by gravity tilt-pour and low pressure permanent mold casting processes. This paper summarizes the results and issues encountered during the casting trials. It was shown that grain refinement and mold temperature ::::: 400°C reduced, and sometimes eliminated hot tear cracks in both alloys. The two prototype engineering components could be cast successfully from both alloys in metal molds. The metallurgical issues related to molten metal treatment and processing temperatures were well controlled. However, issues related to the control of hot tearing, casting and mold design must be addressed in future studies to guarantee the production of defect free castings.

Jan 1, 2006