Search Documents

By T Perera, B Fan, S Thang, T Hsia

Minerals are valuable resources and critical elements for a broad range of biological and technological applications, including technological developments to improve energy efficiency and the global movement to promote a low-carbon economy. However, in order to extract these critical metals, large amounts of waste and toxic chemicals are generated, as well as the use of high energy and large amounts of water consumption. Froth flotation is one of the most commonly used processes to separate and collect high-value minerals, but it still has some limitations, including low flotation efficiency performances using existing collectors and other reagents. Therefore, there is an urgent need to design and develop new metal-specific collectors to more efficiently separate and recover valuable minerals and to allow bulk water recovery from flocculated tailings. In this research, we propose to use our newly designed and synthesised novel collectors derived from a type of vitamin E (α-tocopherol), a relatively inexpensive and non-toxic natural molecule. As a potential collector-building block, α-tocopherol has a long hydrophobic carbon chain that facilitates the attachment to air bubbles during the froth flotation process. In addition, the phenol group of this molecule can be easily modified to incorporate various functional groups for targeting different types of minerals. Furthermore, α-tocopherol can be converted into a monomer for polymerisation by the reversible addition-fragmentation chain-transfer (RAFT) process, which can provide us with polymer based-collectors with high precision control of molecular weight and architecture. So far, small-scale qualitative experiments on α-tocopherol-based collectors have been performed with good results, which indicates the feasibility of these compounds as novel collectors for improved froth flotation processes.

Aug 24, 2022

By Olson H, Kincaid R

The marine portion of the Pacific Basin and Rim constitutes a significant part of the world's surface in which the mineral resources are virtually undeveloped. Indications of substantial resources have resulted in speculation and uncertainty with regard to their potential in the near term. The main issues are centered on the markets for the resource materials, the technology needs for their recovery, and the possible impacts of their development on the environment. While the governments of Japan, France, the Soviet Union, India, China, and Korea are financing new programs in deep ocean mining, the US is consolidating its early leadership by the continuation of NOAA's authority under the Deep Seabed Hard Mineral Resources Act and the Sea Grant Act, Interior's authority under the outer Continental Shelf Lands Act, and by the development of a new Marine Minerals Technology Center within the Department of Interior's mineral institutes program, managed by the U.S. Bureau of Mines. The Center has a Continental Shelf Division (CSD) located in Mississippi, and an Oceans Basin Division (OBD) located in Hawaii. Research and training in the divisions is directed toward the practical aspects of mineral recovery from the nearshore and deep ocean environments with a strong bias for the OBD toward industrial and international cooperative programs in the Pacific Basin and Rim. In terms of resource development, the marine minerals in the Pacific Basin may be favored in some cases, in competition with land sources, by political and environmental considerations.

Jan 1, 1990

By K Zic, P Pickering, P Fraser

Water is a defining feature of the Pilbara. Its management was and remains vital for the pastoral industry which European settlers established when they first came to the Pilbara, and for the mining industry which now dominates economic activity in the Pilbara. Water availability in the Pilbara is, however, problematic. Severe droughts and major floods can occur at close intervals. In response to this uncertainty, the Department of Water undertook a Prefeasibility Study to determine, at a high level, the water requirements and opportunities in the Pilbara region. This paper reports on the outcomes of this study and the water integration opportunities in the region, identifying the sources of water supply and offers possible options for managing this water sustainably for the present and future demand. A range of supply opportunities is reviewed including: dewatering from mining operations, surface water, and desalination. All opportunities were subject to order of magnitude costing, including capital, whole of life and retail unit pricing with preferred options receiving further interrogation through triple bottom line (TBL) analysis to prioritise solutions. Options were also subject to intangible quantification (IQ) including benefits from the reduction of carbon emissions to ensure that the preferred option is based on factors other than just the least cost. Demand analysis was undertaken to identify current and future requirements and were assessed through review and integration of regional and sub regional master plans and consultation with mining, agriculture, industry and the community. The paper concludes that the viability of a Pilbara integrated water supply scheme depends on the development of a financial mechanism involving both government and industry participation models. The agreed scheme formed the basis of a submission to Infrastructure Australia for funding assistance.

Jan 1, 2009

By D Craw

The Hyde Macraes Shear Zone is a mineralised low-angle shear within the Otago Schist traceable for ~30 km with a NW strike. It is been actively mined along 12km of this strike, producing >6 Moz of gold. The shear zone consists of greenschist facies rocks with a mineralogy only subtly different from that of the host schist. Pervasive fluid flow has occurred along grain boundaries and within microshears which have been enhanced by the deposition of hydrothermal graphite. We model the development of these microshears using a threedimensional numerical code. For an inhomogeneous initial rock with lithostatic fluid pressures and a dynamic permeability deformed under dextral non-coaxial flow, deformation is distributed into weak shear bands. Graphite deposition and associated reaction-softening has a dramatic effect on the development of model shear zones. Graphite is deposited into a shear band, weakening it and further localising the deformation into that shear band, producing an anastomosing and interconnected shear zone structure such as observed in the HMSZ. The degree of graphite precipitation and graphitic-induced weakening are varied in the models. More graphite precipitation with a low degree of reaction-softening results in more diffuse shear bands. In contrast less graphite deposition but with a high degree of reaction-softening more leads to the development of more focused shear bands. Graphite deposition has clearly controlled the formation of the HMSZ structure, and is an important indicator of potentially mineralised structures elsewhere.

Jan 1, 2007

By Sennitt C. M, Hartley J. S

The Twin Hills Gold Deposit is an example of a preserved, high level, epithermal system, with mineralisation introduced contemporaneous with deposition. The deposit is hosted within sediments of the Late Devonian to Early Carboniferous Saint Anns Formation, of Cycle 1 Drummond Basin stratigraphy, situated in central Queensland. Prior to epithermal activity in the Twin Hills region, a lacustrine fan delta depositional environment existed, together with minor tuffaceous activity. An and palaeo climate, with occasional periods of torrential rainfall, together with a basin with faulted margins, allowed alluvial fan prograda- tion. Cyclical repetitions of the fan indicate repeated faulting and seismic activity took place during deposition. Significant gold mineralisation was first intersected at Twin Hills by Metana Minerals NL in 1988, after drill testing a "blind" target outlined by geological mapping and bedrock geochemistry.

Jan 1, 1991

By K C. Corin, C T. O’Connor

In recent years it has been shown that the concept of using partial molar excess Gibbs energy (G̅ex) to explain the behaviour of collectors in the recovery of minerals can be usefully applied to explain flotation performance. Fundamentally this is because hydrophobicity of a mineral particle on which a collector is adsorbed may be strongly related to the fact that the alkyl chain associated with the collector behaves in the same way as any hydrocarbon would in an aqueous medium. This hydrocarbon-water system represents a classical non-ideal mixture, and such mixtures are quantified thermodynamically by determining the activity coefficient of the hydrocarbon moiety of the collector and hence its G̅ex in the mixture. It has been shown that G̅ex is a more rigorous indicator of the contributions of various alkyl groups of a collector than HLB (Corin and O’Connor, 2014) and was also able to explain aspects of froth behaviour (Harris and O’Connor, 2017) and hydrophobicity (O’Connor, 2021). The present paper is aimed at extending the above concepts in two different ways. Firstly, a study is undertaken of a range of results previously reported in which various reagents containing different alkyl groups were analysed in terms of their effect on contact angle and their performance as flotation reagents in terms of recovery. These results sustain the previous observations that there is a robust positive relationship between hydrophobicity as indicated by flotation recovery and contact angle and G̅ex of the alkyl group associated with the collector. Secondly, on the basis of the observation that increases in G̅ex are indicative of increases in the hydrophobicity of the mineral particle-collector aggregate, a study was undertaken to examine the effect of ions typical of electrolytes in water as well as the effect of the presence of alcohols and of pH on G̅ex of the collector alkyl group. In the former two instances the absence of any correlation between G̅ex and recoveries supported the proposition of the respective authors of these studies that the major effect of these electrolytes and added alcohols may be on particle–bubble attachment rather than on the hydrophobicity of the mineral/collector in the aqueous system. On the other hand, the effect of pH on G̅ex correlated reasonably well with changes reported in the literature on the effect of pH on recovery and contact angle.

Aug 24, 2022

By Harraway D. H, Draper N

The association of graphite with a fine grained pyrite in the Mount Isa lead-zinc ore was investigated from mineralogical and metallurgical standpoints. The pyrite has been partially or completely replaced by galena and to a less extent by sphalerite, pyrrhotiteand chalcopyrite with the retention of graphite films or inclusions. During lead flotation the graphite imparts a spontaneous flotability to all associated minerals, resulting in a low grade fraction, which we call the carbonaceous fraction, floating with and diluting the lead concentrate. In times of low metal prices this fraction seriously reduces the economic value of the lead concentrate. A flotation procedure was developed to upgrade the carbonaceous fraction separately, producing an economic concentrate and a tailing.INTRODUCTIONThe lead concentrate produced from Mount Isa ores can vary from 20 to 50 per cent lead, depending on the locality in the mine from which the ore is obtained. Variations of this order are independent of ore grade and lead recovery. The large variation is related to the presence in the ore of a variable fast floating low grade fraction known locally as the carbonaceous fraction because of its association with graphite. During conventional lead flotation with sodium ethyl xanthate the carbonaceous fraction floats rapidly and unselectively with normal Mount Isa galena.The paper discusses mainly the examination and treatment of an average carbonaceous fraction, defined here as the fast floating material in the mill feed of late 1956. The ore was drawn from the Mount Isa Black Star orebodies. The fraction represented about 5 per cent of the total ore...

Jan 1, 1961

This paper investigates dry drilling as a feasible alternative to meet current requirements for improvements in mining productivity in an increasingly competitive world.A field test program was conducted in the surface facilities of a hard rock mine in Sudbury, Canada, to investigate the potential use of dry drilling in underground bulk mining as a conceivably faster and more economical method than wet drilling. The test work consisted of the monitoring of advance rates and bit life while a series of 165 mm diameter holes, wet and dry, were drilled with compressed air at both mine (0.69 MPa) and high (1.72 MPa) pressure levels. The results indicate that penetration rates can be increased by approximately 24 per cent by drilling dry with high air pressure and by approximately 27 per cent by drilling dry with mine air as compared with wet drilling under the same conditions. Dry drilling also has the effect of increasing bit life by up to 69 per cent. An economic analysis for typical hard rock mines indicated that drilling productivity and cost savings can be increased by approximately 23 per cent when dry drilling is utilised.The testing program indicates that dry drilling has the potential to become a feasible technique with regard to performance, productivity and costs.

Jan 1, 1991

By Marsham B, Baker D. C

The expansion of New Broken Hill Consolidated Limited (NBHC) concentrator necessitated the installation of hydrocyclone classifiers where rake classifiers had previously been used. Commissioning of the circuit and optimisation of circuit performance has highlighted problems related to classification of sulphide minerals. Testwork initiated to solve these problems has been used to develop cyclone models which have been incorporated in a ccnputer control strategy for the grinding circuit as a whole. The modifications to the circuit during the commissioning phase and the control philosophy are outlined.

Jan 1, 1983

Parallel lenticular orebodies occurring at the C.S.A. mine of Cobar Mines Pty. Ltd. are mined by mechanized cut and fill stoping over the full strike length. Access is provided for each stope lift from an inclined drive adjacent to the orebody. Mobile drill jumbos mounting hydraulically-operated booms are used for drilling upholes which are subsequently charged with ANFO explosive.Close control of drilling has been found essential for good back conditions and to ensure optimum fragmentation.Broken ore is transported from the face to the main ore pass by rubber-tyred, diesel-powered, load-haul-dump units. Initially, the units trammed ore to the main pass via the incline drive. As the stopes advanced and the lead distances increased, stope passes were developed in the wall rock and raised concurrently with each stoping lift. The passes terminate in drawpoints and production loaders are used to transport ore from the drawpoints to the main ore pass system.Two parallel ore pass systems have been developed to cater for both copper and copper-zinc ores. These systems terminate above a 48 in. by 60 in. jaw crusher. The crushed ore is conveyed to a traversing rock box and thence to one of two crushed ore bins adjacent to the main hoisting shaft. A loading station conveyor is interlocked with the winder to provide automatic ore hoisting.All phases of ore handling have been mechanized as completely as possible. Results to date indicate this policy has been vindicated but highlight the need for tight operating control and close liaison between operating and maintenance personnel.

Jan 1, 1969

This paper shows how small calculators can be used for ball mill simulations. Two calculations are examined, the first to calculate the mill parameters and the second to predict the mill product. In the case of small programmable calculators the programs for two common models are given.

Jan 1, 1976

Natural leaching of minerals has been recorded for some two millenia but surprisingly only in recent years has enough been known of the process for any serious design to be made. Copper has been recovered from natural mine waters since about the 17th century but again little progress was made in de- sign procedures until recently. Natural or dump leaching was started as a recovery process late in the 19th century and in the years up to the classic study of Taylor and Whelan in 1943 a series of impirical optimis- ations made it a valuable process for treating low grade or waste material. The biological nature of Sulphide leaching was proven by Colmer and Hinkle in 1947 and since then a large mass of data has accumulated on the microbiology, biochemistry, and response of ores to this form of attack. In spite of this knowledge and the vast amount of pract- ical experience available there are few recorded attempts to present methods of calculation or design procedures that can be used for setting up a leaching process. A framework is given here on which such procedures can be based and indications given of the inherent advantages and limitations of the process,

Jan 1, 1969

The Plant Control and Data Logging System for the Loy Yang Open Cut (LYOC) is part of a control and communications network designed to provide a high level of surveillance of open cut plant and facilitate the efficient co- ordination of operations and plant maintenance. The computer system selected utilises a central dual mini-computer and multiple microcomputer data transmission network ,linked to the plant controllers using distributed, microcomputer based remote data collectors or outstations. Several aspects of the computer system are outlined.

Jan 1, 1982

By N Tuffs, R Peace, S Xue

Mine gas control is a major issue in most of the gassy underground coal mines, due to its direct impact on safety, production delays and cost of production. Analysis of the gas data, from different collieries in Australia showed that longwall gas emissions have increased substantially over the years. Simply increasing the number of goaf holes in the panel or decreasing goaf hole spacing seems not to be effective, in controlling high goaf gas emissions. A major research project has been undertaken by CSIRO in collaboration with mine sites to address this goaf gas control issue with the aim of developing effective and optimum goaf gas drainage strategies. The project has combined extensive field studies with computational fluid dynamics (CFD) models, to characterise goaf gas flow patterns and develop effective gas control strategies. The research work specifically involved review of gas control issues at field sites, goaf gas monitoring, tracer gas tests, CFD simulations and extensive field trials. Field demonstration studies of the new optimum strategies have been conducted at two collieries in Australia. The project results have shown that the optimum strategies were highly successful, in improving the overall efficiency of goaf gas drainage systems, at both the field sites. Results of the goaf gas flow characterisation studies and field demonstration studies are summarised in this paper.

Jan 1, 2005

By George CW

Western Mining Corporation (W.M.C.)operate a 30 000 tpa nickel refinery at Kwinana, W.A. using the Sherritt Gordon Process. Following ammonia/air leaching of sulphideminerals and subsequent copper removal, nickel metal is produced as powder by hydrogen red-uction of the ammonium sulphate-rich solution. Batchwise reduction in pressure autoclaves is preceded by an oxidation/hydrolysis step to ensure nickel powder quality.The reduction process is energy intensive, requiring high temperatures and pressures. Present energy requirement is 24 GJ per tonne of nickel reduced. Of this, 95% represents steam and hydrogen consumption and 5% electric power. The design and operation of the red-uction circuit is reviewed, outlining the main areas of steam and hydrogen usage.

Jan 1, 1985

An extensive railway construction prog- ram in the People's Republic of China has required the excavation of many tunnels in difficult ground, particularly in mountainous regions. Conclusions drawn from case histories permit guidelines to be formulated as to the optimum location of tunnel alignments in faulted and folded terrains, and also in karst regions. Geological factors adversely affecting durability of tunnel linings can be minimised by adoption of appropriate construc- tion practices.

Jan 1, 1987

By Brant BA, Lewandowski R, Trendle M, Haughton D

There is a vast amount of geotechnical data, which can be obtained during exploration programs at new and existing mine sites. Additional information on the performance of the in-situ rock mass can be obtained from bore cores, which are usually only geologically logged and then stored. A computer based data management system for storage and retrieval of geotechnical data has been developed to access and manipulate such data.

Jan 1, 1983

The price of oil and other minerals may not make the costly business of offshore exploration seem -attractive at present. There is little doubt that the future search for the strategic resources will tend towards deeper waters particularly on the continental slope margins. In addition with the realisation that active tectonic environments (eg the Makassar Straits) cannot be excluded as potential hydrocarbon sources there is an increasing demand by the explorationists for deep water survey capability. Such deep water research has until recently been restricted to a few specialised academic institutions ;however with the anticipated extra, demand from other institutions, companies, and government agencies, Marconi Underwater Systems Limited (MUSL)and the Institute of Oceanographic Sciences in the UK have come together to allow MUSL to provide the deep water mapping system GLORIA on a commercial basis -for the first time. The GLORIA package comprises a deep water(more than 400m) side scan sonar system which, by operating at a frequency around 6.4 kHz can insonify swathes on the seafloor up to 60 km wide. In addition, single channel seismic, 3.5 kHz high resolution profiles, precision echo sounding, magnetic and gravimetric data all combine to provide as complete a regional interpretation as possible. The GLORIA system combines surveying at a reconnaissance level, covering as it does up to 20,000 sq.km per day, with a very high reliability, so that even in- economically unfavourable times, it can-still be considered as an invaluable and cost effective primary exploration tool. Analysis of the GLORIA data enables the identification of areas of particular interest requiring more detailed study by the more costly multi-channel seismics at a later date.

Jan 1, 1987

By Yao S, Wang P, Zhang C

The Zhilingtou Au-Ag deposit is situated in the eastern part of the complexly deformed and metamorphosed South China Caledonian Fold Belt. It consists of seven orebodies that are almost exclusively hosted by biotite plagioclase gneiss of the Precambrian Chencai Group. They form an apparent en echelon pattern in both cross-section and level plan. Three different ore types, based on mineralization textures, have been recognized within the Zhilingtou lode. These are Au-Ag-rich quartz veins, Au and Ag-bearing silicified rocks and Au-Ag-containing altered rocks with quartz stockworks. The mineralization is principally composed of electrum, argentite, pyrite and minor sphalerite, galena as well as traces of hessite and chalcopyrite plus a gangue assemblage of quartz, rhodonite, sericite and chlorite. Fluid inclusions related to Au-Ag mineralization yield a wide range of homogenization temperatures from 110 to 447¦C, with two distinctive peak values at 250-300¦C and 350-400¦C respectively. S30Si values of quartz veins and silicification from the three stages of mineralization range from -0.1 to -0.4%o. The mineralization at Zhilingtou is interpreted as forming by recirculated meteoric water extracting ore-forming elements from metamorphic rocks due to Mesozoic volcano-magmatic activity.

Jan 1, 1995

Carbonation of reinforced concrete is a potential durability issue for vehicular tunnels. This is particularly the case where elevated carbon dioxide concentrations exist and when the design life is 100 years or more. The process of carbonation can result in loss of passive protection to embedded steel reinforcement and initiation of corrosion. Therefore, tunnel design needs to consider the potential for carbonation on internal surfaces and how design life can be achieved in severe environments. This paper examines methods for predicting carbonation and how deterioration can be mitigated through appropriate concrete mix design and construction practices.

Jan 1, 2008