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By S Fidler

Underground coal gasification (UCG) is a process by which coal is converted in situ to a combustible gas that can be used as a fuel or chemical feedstock. The process has been used in commercial-size projects in the former Soviet Union for more than 40 years, while significant national research programs have been undertaken in the United States and Western Europe. The Chinchilla UCG project is located at a site southeast of Chinchilla in Queensland. The UCG operation commenced in December 1999. A controlled shutdown of the process was initiated in January 2002 and successfully completed in April 2003. The process is currently under conservation and ready for restoration of gas production for commercial use in the near future. Groundwater plays an important role in the gas formation process during UCG. Most of the process water required for chemical reactions is usually derived from the coal seam itself and from surrounding aquifers. If insufficient water is available for chemical reactions the UCG gas will contain reduced concentrations of combustible components, and conversely, excessive water influx into the process area would cool down the reactor and thus limit the energy available for gas production reactions. Because of the importance of groundwater in the gasification reactions, and the potential to contaminate groundwater if the process is not correctly controlled, it is essential to predict and to control the groundwater influx into underground gasifiers during and after underground gasification. Control of groundwater requires a thorough understanding of hydrogeological conditions in the vicinity of the gasifier in order to be able to predict inflow rates, and constant monitoring throughout the process of water production rates and groundwater pressure in the coal seam and adjacent aquifers. Hydrogeological testing and groundwater monitoring in the vicinity of the UCG operation commenced six months in advance of its initiation. Monitoring of groundwater pressures in the vicinity of the gasifier have also been undertaken using vibrating wire piezometers installed in the coal seam at varying distances from the gasifier. This paper presents the results of the hydrogeological testing and groundwater quality monitoring carried out at the site, which show that it is possible to operate a UCG process without uncontrolled impacts on groundwater.

Jan 1, 2003

By Carter A. J, Miller D. M, Holder N. H M, Van Aswegen P C

The Harbour Lights Mine situated at Leonora in Western Australia, mines a refractory sulphidic gold ore. The main sulphide minerals are pyrite and arsenopyrite. Due to the association of gold with the pyrite and arsenopyrite, gold recovery is not amenable to the normal cyanidation process.A pyrite/arsenopyrite flotation concentrate is produced at Harbour Lights. This concentrate has been stockpiled for the past two years.A bio-oxidation process (BIOX«)* to treat refractory gold flotation concentrates has been developed by GENMIN in South Africa. Harbour Lights acquired the technology from CRL BIOX« Pty Limited in Brisbane, to treat the refractory gold concentrates.

Jan 1, 1992

By Rongqing Q, Tiancong Z, Yiyuan L

The influence of pulp density, ferric ion concentration and particle size on the tank bioleaching of two kinds of refractory gold concentrates are discussed. The chemistry and mechanism of the bioleaching process are also presented. The relationship between oxidation of sulphides, liberation of enclosed gold and gold cyanidation are discussed. The consumption of NaCN could be reduced by alkaline treatment of bioleached residues prior to Cyanidation.

Jan 1, 1992

By J J. Cilliers, K Hadler

Air is fundamental to flotation; not only is it required to collect the valuable particles, but it also controls the froth stability and consequently the separation performance for a given feed. Froth stability can be described and quantified in numerous ways, which are subtly different. Air recovery is one such measure of froth stability which accounts for both the stability of the bubbles and the mobility of the froth. The benefit of using air recovery as a measure of froth stability is that it exhibits a peak as air flow rate is increased, and this corresponds to the air rate at which the optimal separation performance is obtained. As such, it provides a single target value for optimising air flowrate for a given set of feed conditions. Use of air recovery, however, has one potential drawback: accurate measurement of the inlet air flow rate to a flotation cell is required. This can be problematic for operations, particularly where calibration of air flow rate is carried out infrequently or where there is no air flow rate measurement, such as for many self-aerated flotation cells. To this end, we present an alternative method for determining the peak in air recovery (PAR) air rate.We introduce a simplified method for determining the PAR air rate using trends in froth velocity and overflowing froth height, both of which are readily measured using existing froth image analysis systems. We will show, using industrial data, the application of this simple technique to find the optimal air flowrate for flotation cells. We will also discuss other alternative techniques for air rate optimisation that have the potential to improve separation performance using existing technology.CITATION:Hadler, K and Cilliers, J J, 2018. How to find the optimum air rate for flotation cells, in Proceedings 14th AusIMM Mill Operators' Conference 2018, pp 377–384 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 29, 2018

By Snowden D. V, Standing C. A, Ryba A, Bywater A

McKinnons open pit gold mine, located within the Cobar Basin in New South Wales, is characterised by complex mineralisation controlled by the intersection of steep faults in the hinge zone of an anticline. Resource estimation using indicator variography and indicator kriging was based on RC drilling on 25 in sections together with grade control RC drilling on 12 in by 12 in and 6 m by 6 in patterns. Rigorous sampling and checking procedures were used to verify the reliability of the drill hole data. Blast hole data was used to assist grade control in defining ore block boundaries.

Jan 1, 1997

By R Hoeppel, D Harimon, A Fisher

This paper examines the importance of examining the relationship between biology and geochemistry when designing a biopile to treat alkaline soils impacted by petroleum hydrocarbons. At a site in Nevada a large, unlined pit was constructed in a loamy sand soil and filled at regular intervals with a mixture of jet fuel, lubricating oils and waste solvents which were set on fire by the local fire department for training purposes. During its period of operation numerous chemicals were also dumped into the pit for disposal purposes, including dichlorobenzene and various chloroethylenes. As a result of these activities a large groundwater contaminant plume was formed. As a part of the site remediation process a decision was made to perform a limited source removal and excavate the top three to four metres of contaminated soil from the burn pit and place it in an engineered biopile. The location of the training pit is in a heavily mineralised basin where the background sulphate level in groundwater exceeds 5000 ppm. Due to naturally occurring biodegradation of the petroleum hydrocarbons a large portion of the sulphate was converted to sulphide which deposited in the soils as marcasite in the anaerobic soils. The initial attempt at soil remediation was to use a forced air treatment scheme that had worked well in small scale laboratory testing. Unfortunately, when attempted in the field on a large scale, marcasite reacted with atmospheric oxygen resulting in internal biopile temperatures exceeding 90¦C resulting in the virtual sterilisation of the soils without remediation occurring. In order to solve this vexing problem Pintail Systems, Inc developed an anaerobic culture that allowed the pile to be operated under anaerobic conditions. Within three months the biopile successfully demonstrated on a large scale significant biodegradation of the refractory petroleum hydrocarbons.

Jan 1, 2004

By A Romanel, M S. Kato, M P. Piermatei, P Artioli

"Brazil is the sixth worldwide producer of aluminum and Votorantim (Metals) has been operating three bauxite open pit mines in a particular way of working. In those the deposits occur on the top of hills, under forest, coffee, eucalyptus plantation or pasture area.The deposits are not large and normally mining takes an average of two months to be completed before starting the rehabilitation process, which demands a good strategy in mining planning to achieve the production goals.The benefit function developed to select feasible areas uses, beyond production costs, fees from the owner by using their area and rehabilitation cost. Both are based on land use and occupation field survey data. In this process each area with different land use receives a specific rehabilitation cost as input into a block model.Once the selection is made the mining schedule begins, taking into consideration the following premise: the orebody needs to be mined in a short period of time because during this time, the surface owners receive from Votorantim a compensation based on the expected profits from their plantation or pasture, plus royalties related to the ore amount existing in their area.Not all operations have waste dumps. Waste is pushed down by bulldozers to the lower part of the ore border. After loading and transporting ore, the waste is handled back to the mined area to fit the topography. With this step concluded, the mined area is directed to the environmental team who, alongside university partners, develop land reclamation to return them to their owners, eg in 2011, 110 ha were rehabilitated of which 29 per cent is native forest.Votorantim closes many mined areas a year and currently the entire mine planning considers this particular way of operation, making profit with minimum interference with the community and the environment.CITATION:Artioli, P, Kato, M S, Romanel, A and Piermatei, M P, 2012. Environmental variables at bauxite mine, in Proceedings Life-of-Mine 2012 , pp 171-178 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jul 10, 2012

For Australian mining projects, sustainable groundwater use is typically defined as a groundwater extraction regime, measured over a specified planning time frame, which allows acceptable levels of stress and protects dependent economic, social and environmental values (DEH, 2004). This principle is compatible with most stakeholdersÆ understanding of our national environmental objectives, yet the application of this policy on a project-specific scale is not always straightforward. Three examples of sustainability issues in the management of groundwater in mining are presented. These examples highlight each of the three dependent values: environmental, economic and social.

Jan 1, 2006

By Mantsevich M, Ivanov V, Volkov V, Ponomarov G

A new ecologically promising technology for the copper-nickel ore benefication using insert gases and pyrrhotite depression is under consideration. The finely dispersed nickel-containing sulphides and the pyrrhotite are easily oxidised during the process of flotation resulting in deterioration of selectivity and valuable component loss in the tailings. One of the ways to improve the benefication is the flotation of easily-oxidising minerals in an inert atmosphere. In the experiments nitrogen was taken as the inert gas supposing that in the industrial scale operations nitrogen generating, as a by-product of the oxigen production. will be used (Rybas et at, 1989). The most wide-spread mineral in the Norilsk rich sulphide copper-nickel ores is pyrrhotite containing iron, sulphur, nickel and platinum group metals. Up to 30 per cent of the pyrrhotite sulphur is recovered into the nickel concentrate causing the high sulphur dioxide emission in the further pyrometallurgical process of nickel production. This is the reason why the problem of the pyrrhotite removal during the ore concentration should be solved, the critical factor of the problem being the lowest possible nickel content in the pyrrhotite. According to the data of the geological and mineralogical mapping the nickel content in the pyrrhotites of rich ores varies from 0.3 to 1.8 per cent, with the mean value equal to 0.6 - 0.8 per cent. This assures the technological and economical effectiveness of the low-grade pyrrhotite removal during the flotation process.

Jan 1, 1993

By D Carroll

Mining of the zinc, lead and silver deposit at the Broken Hill Southern Operations site has been occurring for over 100 years. As a result of this, a significant amount of high-grade ore is now taken from narrow remnant pillars left between old stopes and zones of previously mined ground. Stopes have been filled with either hydraulic fill (also known as ‘sandfill’), cemented hydraulic fill (cemented sandfill), waste rock backfill or a mixture of these fill types.In the last ten years, there has been considerable success mining through narrow pillars where sandfill is exposed in the development face and/or walls using a ‘shell’ support regime, wherein a layer of bolted mesh is sandwiched between two layers of sprayed fibrecrete (25 mm fibrecrete, then mesh and bolt, followed by a final 50 mm layer of fibrecrete). Shell support is also used in very poor, broken, relaxed ground conditions and in areas filled with cemented fill (sandfill with a minimum four per cent cement content).The next stage of innovation has been to develop a technique for mining through old stope voids filled with uncemented sandfill, known locally as ‘contours’ (old cut-and-fill working), an activity where unconsolidated sandfill can run at the face and from the backs. The challenge is to prevent exposed sandfill in the face and the backs from failing before it can be supported.To achieve this, the Southern Operations mine has implemented a technique in which 6 m long spiling bars are used to strengthen and stabilise the sandfill in front of the face. The hollow steel bars are driven in around the heading perimeter in a closely spaced pattern then pumped full of grout. The bars and the grout stabilise the sandfill in front of the face, preventing it from failing into the drive during excavation and prior to further support being installed.A final support system consisting of shotcrete, mesh, bolts and steel girders is installed as excavation progresses. Both the initial and final support systems are essentially passive support systems designed for a low-stress environment (as the stress originates mostly from the mass of unconsolidated sandfill).This process is slow and labour intensive. Fifteen separate cycles of people/machinery are needed to progress one equivalent heading cut (compared to six for a standard fibrecrete- and bolt pattern-supported rock face heading). This slow pace introduces scheduling challenges, but the process opens up parts of the orebody that were previously uneconomical to mine.CITATION:Carroll, D, 2014. Mining through sandfill using spiling bars, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 95–100 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By G Harbort, T Georgiev, M Phillips

Phu Bia Mining Ltd, a subsidiary of Pan Australian Resources Ltd owns and operates the Phu Kham copper concentrator located in the Xaysomboun District, Lao PeopleÆs Democratic Republic. Construction and commissioning of the 12 Mt/a copper concentrator and associated facilities was undertaken by Ausenco Ltd and handed over to Phu Bia Mining Ltd in April, 2008. The first copper concentrate was produced in April 2008 and the ship carrying the first shipment of copper concentrate set sail 27 July 2008. Nameplate mill throughput was reached in August, 2008 when 1 020 000 dmt of ore was treated in the milling and flotation circuit. The Cu-Au mineralisation is contained in skarn and stockwork mineralisation and is interpreted as a distal expression of a conventional porphyry copper-gold system. Copper mineralisation is principally in the form of chalcopyrite with lesser bornite. Gold occurs as small grains, typically associated with copper minerals. In the upper portions of the orebody, oxidation and water table movements have resulted in near surface leaching of the copper and below the leached zone, supergene enrichment resulted in chalcocite mineralisation. The circuit operates with a semi-autogenous grinding (SAG) û ball mill circuit, feeding a bank of OK200 rougher cells. Rougher concentrate is reground in an IsaMill prior to entering a cleaner circuit consisting of three stages of cleaning and one stage of cleaner scavenging. The concentrate typically assaying 24 per cent Cu and 6 - 7 g/t Au is hauled for over 1000 km across the border to the Port of Sriracha in Thailand, and stocked in sheds at the wharf from which it is shipped to various Asian smelters. This paper discusses the successful commissioning and ramp up to design tonnage and metallurgical performance. In addition, a program to optimise both the comminution and flotation circuit is detailed with reference to grinding efficiency, flotation residence time and size by size mineral recovery.

Jan 1, 2009

By Grossi M, Baiden G

This paper describes a new mine backfill method based on a newly invented binder with several years of test results from laboratory and on- site applications. The new binder has several advantages over traditional Portland and slag cement binders. One tonne of the new binder can replace two to three tonne of Portland cement when used to consolidate backfill and can result in the same compressive strength within seven days. When comparing backfill slurries of the same pulp density, the new binder attains more volume of in-place backfill mass than Portland cement because of the high crystallisation of water, resulting in tightly filled stopes. The crystallisation of the water provides for less or no de- watering in the backfill stope and easier transportation of the backfill slurry. Pastefill performance can be achieved by using pulp densities typical of a hydraulic backfill and the new binder, all the while transporting with the same ease of hydraulic fill.

Jan 1, 1998

Studies of the minor element content of sphalerite and pyrite have generally been concerned with individual deposits or localised groups of deposits. However, a small number of more regional investigations have been reported (e.g. Davidson, 1962; Groves and Loftus-Hills, 1968; Loftus-Hills and Solomon, 1967; Price, 1972; Bralia et al., 1979) which have used the minor element abundances to evaluate the petrogenesis and geological affinities of diverse ore types and to fingerprint metallogenic provinces (e.g. Ivanov, 1964). While generally held to be valid, some doubts have nevertheless been cast on the reliability of minor element abundances in petrogenetic deliberations (e.g. Mercer, This paper reports on the distribution of he. Cpl and Mn in sphalerite, and Co, Ni and Mn in pyrite, from sulphide mineral occurrences within the "eugeosynclinal" prism comprising the New England Region of north-eastern New South Wales and south- eastern Queensland (Fig. 1). The occurrences examined are representative of two well-defined styles of mineralisation (Stanton et al., 1974) within which clear patterns of ore-rock distribution give rise to specific metal associations (Herbert. 1977).

Jan 1, 1987

By H Jalalifar, N Aziz

In the ten years since the University of NSW proposed a pillar design methodology for bord and pillar operations, the Australian coal mining industry has changed substantially. What was primarily a bord and pillar design approach is now being applied to chain pillar design in longwall mines where the requirements are substantially different. The dimensions of chain pillars can impact on tailgate conditions (roof, rib and floor), seal performance, and surface subsidence. The status of chain pillar design practice in Australia is reviewed, with a focus on defining pillar strength, chain pillar loading, and assessing the performance of the roof/pillar/system. A new pillar strength equation is proposed for Australian coal that applies for all width/height ratios. An alternative analysis of probability of failure of chain pillars is presented.

Jan 1, 2005

By A Mirzaghorbnali, D Gilbert, R Burton, J Nemcik, N Aziz

Glass-reinforced polymer bolts, commonly known as fibreglass dowels and fibre-reinforced polymer or plastic bolts or plastic dowels are increasingly applied for strata reinforcement in mines as well as in concrete reinforcement in civil engineering. The most popular dowels used in coalmines are the 22?mm diameter fully threaded type. Fibreglass and plastic bolts are cuttable, easy to handle, lightweight and corrosive resistant. A series of tests were undertaken to evaluate various strength properties of fibreglass dowels. These included tensile failure tests by the double-embedment method, a single guillotine shear test and a double shear test, carried out on dowels installed in concrete blocks, and with punch shear tests. Punch shear tests were used to evaluate the dowel shear strength parallel and perpendicular to the fibreglass strands or elements direction of extrusion. The study found that the tensile strength of the 22?mm diameter fibreglass dowels was in the order of 30?t. In the shear testing, the peak shear load was influenced by the encapsulation grout type and the level of fibreglass axial pretension. Also, there was a nearly fivefold difference in the shear strength value of fibreglass dowels tested parallel as against perpendicular to the dowel axis.CITATION:Aziz, N, Gilbert, D, Nemcik, J, Mirzaghorbnali, A and Burton, R, 2014. The strength properties of fibreglass and other polymer-based dowels for strata reinforcement in coalmines, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 263–268 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By A Patwardhan, M M. Alam, K K. Thatavar

A commercial wet scrubber was used in the SIU-Joy dust control laboratory to test several concepts for improving the dust control efficiency of a wet scrubber. The concepts tested included two filter-two-spray systems, hollow and full-cone sprays, horizontal and vertical sprays, different layer filters and addition of surfactant. The optimised scrubber configuration had water-only vertical sprays for pre-wetting coarse dust, and vertical surfactant-laden water sprays for wetting ultrafine particles. This scrubber configuration reduced dust concentrations from 250 mg/m3 to 1.8 mg/m3. In comparison, the conventional scrubber configuration in the feed provides an outlet dust concentration of 3 - 4 mg/m3 in field operation. Upon successful testing and optimisation of parameters in the laboratory, field demonstration of the concepts was conducted at an Illinois coal mine. The optimised scrubber configuration was tested in the field with good results in terms of improved visibility in the face area and reduced respirable and quartz dust concentrations. Additional modifications in the field involved relocation of the scrubber suction inlets from the bottom to the side and changing the water spray configuration on the miner head. These additional changes were based on a conceptualised spatial dust distribution profile in the face area. The results of these laboratory development and field demonstration studies are presented in this paper.

Jan 1, 2005

By J Rostami, T Afshar, M Sharifzadeh

Accurate estimation of rock load and selection of types of ground reinforcement to match post-failure behaviour of rock mass are important issues to assure tunnel stability. This paper focuses on the main factors affecting rock load to evaluate the capabilities of the existing models for prediction of rock load. Rock mass properties, project features and excavation method, as well as ground conditions and stress condition were found to be the key factors affecting the magnitude of rock load. Field data from tunnels of about 37.5?km driven in several geological structures in non-squeezing ground was used in this study. An in depth statistical analysis was performed on data to find correlations between the input parameters and measured/observed rock load. A weighting system was proposed to obtain the proper contribution of each factor for estimation of rock load in tunnelling through various ground conditions. The new classification system offered predicted values for rock load that were in a good agreement with the actual field measurements. The high disturbance factor (D>0.4) was the prime factor which controlled the rock load. Rock mass quality was the second key factor influencing rock load, which could be estimated by GSI, GSIresidual , especially when combined with tunnel depth.CITATION:Afshar, T, Sharifzadeh, M and Rostami, J, 2014. Estimation of rock load for tunnels with different disturbance factors, in Proceedings 15th Australasian Tunnelling Conference 2014 , pp 3–8 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 17, 2014

By B Hou

The Eucla Basin in southern Australia is emerging as an important global source of zircon from heavy mineral sands. Understanding the geological evolution of the basin and movement of heavy minerals down peripheral paleovalleys and along paleocoastlines is essential to effectively refine exploration strategies for heavy minerals in the basin. Integration of geoscientific datasets in a Geographic Information System (GIS) environment has proved to be effective in reconstructing depositional environments along the Cenozoic basin margin and in tracing the buried paleorivers that once drained broad areas of the Archean-Paleoproterozoic Yilgarn and Gawler cratons, the dominantly Mesoproterozoic Musgrave and Albany-Fraser Provinces, and the Neoproterozoic-Early Paleozoic Officer Basin. Sea level highstands during the late Middle Eocene (39 - 36 Ma) are associated with formation of the Ooldea coastal barrier complex and the zircon-rich heavy mineral deposits at Jacinth, Ambrosia and Tripitaka. More extensive transgression during the Late Eocene (36 - 34 Ma) built the complex Barton shorelines that host the Cyclone deposit and the extensive ilmenite-dominated occurrences of the Barton West prospect. Multi-generation reworking of the source sands is indicated by the high proportion of deposits that are zircon-rich relative to titanium minerals. The age distribution of zircon grains in heavy mineral concentrates from the Ooldea and Barton barrier systems points to the Musgrave Province as the predominant ultimate zircon source. Paleorivers discharging along the northern basin margin presumably carried a sediment load that was then redistributed by easterly longshore drift to build the extensive coastal sand deposits along the northern and eastern basin margin. The south-eastern extension of these deposits was reworked during Miocene-Pliocene (15 - 2 Ma) times into a series of regressive strandlines that show angular discordance with the Eocene coastlines. This discordance is consistent with evidence for long-wavelength tilting of the Australian continent from Middle Miocene times, as the continent drifted toward a dynamic topographic low induced by convective mantle processes associated with the South East Asia subduction systems. The Dromedary and Gulliver’s deposits probably formed at this time. Ongoing research is focused on the geological features of the basin that influence heavy mineral transport, concentration and preservation, and the processes leading to deposits with high zircon content.

Oct 5, 2011

The brown coal resources of the Latrobe Valley, which include over thirty thousand million tons of coal suitable for open cutting, provide the main source of fuel for the power generation for the State of Victoria. They also provide the basis for the development of a supply of cheap hard fuel for industrial and domestic use, and for the development of the Lurgi process for manufacture of town gas for most of the State. The production of hard char for metallurgical processes and liquid hydro carbons will each, no doubt, play its part in the industrial growth that will be based on these resources.The State Electricity Commission of Victoria, which has been allocated the task of developing these deposits since the early 1920's, is faced with problems of economic selection of deposits for development, and excavation and transport of huge tonnages of coal and overburden-in this year, 19'59, about 12,000',000 tons of brown coal will be won, and over 7,000,000' cu. yd. of overburden will be removed in the four open cuts operated by the Commission; by 1967, eight years from now, the demand will have doubled.This paper deals with the nature and importance of various factors effecting the planning of the development of these resources. It is in essence an introduction to the papers by C. S. Gloe, H. C. G. Rodgers and J. M. Alexander, also being -presented at the Institute conference in Victoria in August, 1959.INTRODUCTIONIt is the intention in this paper to define the factors that come under consideration in the planning and development of the brown coal fields in the Latrobe Valley, whose exploitation by the State Electricity Commission of Victoria was initiated almost 40 years ago. It is proposed to enumerate, and in sorile cases evaluate, the physical and economic criteria that play their part in determining planning for the future.

Jan 1, 1960

By R Carreau

The results of a detailed acid rock drainage (ARD) prediction program were used to revise the waste rock segregation criteria at the Restigouche open pit mine. Waste rock at the site was predominately derived from altered volcanic rocks that hosted a massive sulfide lead/zinc orebody. The program assessed the five years of drainage chemistry from both the potentially acid generating and the non-acid generating waste rock storage facilities in addition to laboratory-based kinetic test results. Material-specific leaching characteristics including relative metal-release rates and neutralisation potential depletion rates were determined from 12 laboratory-based kinetic tests. Solid-phase analyses indicated that, although pyrite was typically the most abundant sulfide mineral in the waste rock, its abundance varied significantly as documented by total sulfur contents ranging from 4.0 per cent. Kinetic test results were used to establish revised waste rock segregation criteria based on total sulfur content and neutralisation potential. The revised criteria maintain that waste material with a total sulfur content 4.0 per cent as potentially acid generating. When present in sufficient quantities, ankerite provided an effective source of neutralisation potential for the range of observed sulfide oxidation rates. Kinetic testing documented that up to 6 kg CaCO3/t was ineffective at neutralising acidity in samples that contained >4 per cent S. The carbonate molar ratio measured from the humidity cells was adjusted to reflect the stoichiometry of the ankerite and applied as an NP/AP criteria for waste rock containing 0.1 <S per cent <4.0.

Jan 1, 2003