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Utilize innovative processing technology to prepare high-purity, ultrafine advanced ceramic powders with little or no contamination occurring during the milling process. Advanced ceramic materials made from these powders could substitute for high-temperature alloys containing critical materials such as chromium, cobalt, and nickel. Approach Modify and evaluate the Bureau's turbomill, developed earlier to grind a variety of ceramic raw materials (clay, mica, and talc), as a milling or size-reduction technique for hard and abrasive advanced ceramic powders, such as silicon carbide. Background Powders for producing ceramic materials, such as silicon carbide. silicon nitride, alumina, and zirconia, which arc being considered for use in severe applications requiring high-temperature and/or corrosion resistance, are very difficult to reduce to fine sizes for processing into finished parts. Traditional techniques of particle size reduction, such as ball milling and jet milling, are very energy intensive and/or slow. These traditional techniques often produce materials that have a nonuniform particle size distribution and are contaminated by the milling media or container.

Jan 1, 1989

Remotely monitor overburden response to longwall mining using time domain reflectometry (TDR) and a combination of hardware and software, as part of the U.S. Bureau of Mines (USBM) program to characterize subsidence. Background TDR was developed in the 1960's as a method to locate, discontinuities in coaxial transmission cables. In this method, voltage pulses sent along a cable are reflected by cable defects. The pulse reflections are used to determine the type and magnitude of the defects. The TDR concept was extended to material property measurement by embedding cables into particular materials and evaluating the cable's dielectric behavior as material properties were modified. This technique was adapted by the USBM in 1978 for use in monitoring rock movement during underground mining. The same concept is utilized today. A coaxial cable is grouted into a rock mass that is expected to deform. Progressive rock movement causes the cable to deform, as shown in figure 1, and changes to occur in the cable's electrical properties, which then produce changes in TDR reflection signatures. The technology has advanced to the point where it is now possible to distinguish shear deformation from tensile deformation and to quantify rock mass displacements by analyzing the TDR signatures.

Jan 1, 1995

By John L. Reuss

A laboratory study was conducted by the Bureau of Mines to investigate the technical feasibility of decomposing hydrous magnesium chlorides by using a steam pyrohydrolysis technique. This procedure consisted of injecting steam into the atmosphere of a decomposition furnace containing samples of hydrous magnesium chloride and determining the rate of hydrolysis by measuring the rate of chloride evolution. The variables investigated were temperature, amount of water vapor in the decomposition atmosphere, and hydration stage of magnesium chloride. The application of steam was shown to accelerate both the rate and completeness of magnesium chloride decomposition reactions. For example, when magnesium chloride hexahydrate is exposed to a furnace temperature of 600' C in an air atmosphere for 20 minutes, the decomposition is 37 percent. Under identical conditions in a steam atmosphere, the decomposition is in excess of 70 percent. The magnesium oxide produced by the steam pyrohydrolysis of magnesium chloride dihydrate at 800° C contained 98 percent magnesium oxide. Based on magnesium oxide composition, this is equivalent to that of burned magnesite produced at temperatures in excess of 1,300° C. To demonstrate the quality of the product on a practical basis, metal reduction tests have shown it to be equivalent to reagent-grade magnesium oxide as a carbothermic reduction feed material.

Jan 1, 1974

By Charles Findlay, Stephen Krickovic

A methane emission rate study was conducted in 1969 on a longwall section of a Lower Kittanning coalbed mine in central Pennsylvania. The longwall face was mined with a drum shearer between developed headings on the head end and headings on the tail end that were driven with a ripper-type continuous miner as needed. The study was conducted over 22 consecutive shifts (7-1/3 days). The average methane emission rate from the Lower Kittanning coalbed during mining at the face and developing the headings at the tail end of the face was 34 cfm. Caving of the gassy overlying strata as the result of mining at the face increased the methane emission to rates ranging from 702 to 1,049 cfm.

Jan 1, 1971

By Peter F. Strong, Robert L. Lagace, Alfred G. Exslie

The theoretical study of WF radio communication in coal mines, with particular reference to the rate of loss of signal strength along a tunnel, and from one tunnel to another around a comer is the concern of this paper. Of prime interest are the nature of the propagation mechanism and the prediction of the radio frequency that propagates with the smallest loss. The theoretical results are compared with published measurements. This work was part of an investigation of new ways to reach and extend two-way communications to the key individuals who are highly mobile within the sections and haulageways of coal mines.

Nov 14, 1974

By Edward D. Thimons, Jay F. Colinet

NIOSH conducted a strategic planning effort to identify those areas in mining with the greatest research needs. Data analysis and stakeholder input identified the need to reduce worker exposure to respirable crystalline silica dust as a high priority area. MSHA dust sampling data were analyzed to target the mining commodities and occupations with the greatest percentage of samples containing silica above compliance levels. In response, the Pittsburgh Research Laboratory (PRL) has implemented a multi-faceted research program to improve silica dust control for these problematic commodities and occupations. A review of silica compliance trends, PRL silica research programs, and recent control technology developments are provided here.

By Walter J. Frank

Thls report summarizes work done under Bureau of Mines contract H0357100, "Development of a Crimp Connector for Trailing Cable Splices." The purpose of this effort was to establish optimum connector design conditions to meet flex cycle, pullout and electrical resistance criteria on phase power conductors. Field testing of "optimum design" connectors is briefly discussed. One of the primary objectives of contract H0357100 was to enable one to design better performing phase conductor connectors. Illustrating the practical significance of this 1s a discussion on the development of a new splice kit for trailing cables. The connectors in this kit were designed in accordance with the design methods described in the contract final report. Kit components, test data, and a connector installation tool are also discussed. The successful effort on the phase connector has resulted in contract H0377042, entitled "Design and Testing of Joining Sleeves for Trailing Cable Ground and Pilot Wires." The purpose of this contract (currently in effect) is to improve ground-conductor and pilot-wire performance. Significant findings to date are discussed.

Jan 1, 1979

By Ann G. Kim

Methane in coal constitutes a serious hazard during mining. Draining the methane from large blocks of coal in advance of mining is an effective method of improving the safety and efficiency of coal mining. Because of the similarity of the two gases, drained methane can be recovered and added to pipeline supplies of natural gas. To effectively apply advance drainage techniques and recover drained gas, a gross estimate of the methane content of coal is necessary. Using data from previous investigations, the virgin reserves of the Pittsburgh coal in the central and southwestern parts of Washington County, Pa., are estimated at over 1.5 billion tons, with a methane content of 50 to 100 fts/ton. The Pittsburgh bed in this area of approximately 265 mi2 contains over 130 billion ft3 of methane.

Jan 1, 1974

By S. P. Howell, M. W. Von Bernewitz

"Introduction. The first short—flame explosives were made in the United States during the year 1902, then the mount was 11,300 pounds. In 1902 they were designated ""permissible explosives"", and were required to meet specific tests. By 1912 the total consumption thereof had increased to 24,630,000 pounds, equal to 5 per cent of the total quantity of all kinds of explosives produced in this country; while in 1922 the total was 43,429,000 Pounds, or 10 per cent of the production, and 18 per cent of the explosives used for the mining of coal.Each year the Bureau compiles statistics of explosives, one important object of this being to show the extent to which permissible explosives are replacing other classes of explosives in coal—mining operations, and the influence of such replacement in reducing the number of accidents caused by explosives in this class of mines. The consumption of permissible since 1916 has considerably exceeded the quantity of high explosives (dynamites, etc.) used in coal mines. While the increase in use of permissible is good, the replacement of other explosives therewith is not nearly as good as with be, considering the known general efficacy and safety of permissibles."

Mar 1, 1924

By John C. LaScola

The Bureau of Mines repeatedly surveyed a grid of monuments over an active longwall mine panel in southwestern Pennsylvania during a 1-year period. Both conventional ground surveying techniques and photogrammetry were used. The objective of this investigation was to compare elevation measurements of subsidence obtained from aerial and ground survey methods under dynamic ground conditions. The results of a statistical analysis of the survey data show that the mean of the differences between 372 matched pairs of elevation measurements was 0.20 ft (61 mm) with a 95-pct-confidence interval of 0.05 ft (15 mm). The mean of the absolute values of the differences was 0.38 ft (116 mm) with a 95-pct-con-fidence interval of 0.04 ft (12 mm). Ninety-five percent of the absolute values of the differences were less than 1.11 ft (338 mm).

Jan 1, 1988

By S. D. Maksimovic

The Bureau of Mines evaluated the hydraulic stimulation of a gob-degasification borehole to determine if this procedure would aid in degasifying a longwall panel. The stimulated borehole did not degasify the longwall panel as expected either before or after mining of the panel started. It reduced the underground methane emission only 11 pct, considerably less than the reductions effected by two unstimulated boreholes in the same panel. Some probable reasons for the reduced methane flow from the hydraulically stimulated borehole are very low reservoir gas pressure, location of hydraulically stimulated zones within the grouted casing, a casing break caused by lateral shifting, possible vertical movement of rock strata during caving, grouting of a 4-inch pipe blocking three stimulated zones, plasticity of shales, and possible hole damage by swelling of water-sensitive minerals. The borehole was also located between two second-mined areas, which may have allowed partial degasification of the overburden and the coalbed in advance of mining. Finally, a period of 3 months is probably not long enough for the borehole to degasify the overburden before mining.

Jan 1, 1977

Develop a method for recovering phosphate from a wide variety of complex western phosphate materials, including low-grade ores, tailings, and unused fines. Approach A flotation technique is used for this broad type of extraction. The method includes depression of phosphate minerals and anionic flotation of carbonate minerals, followed by cationic flotation of silicate minerals. How It Works A slurry is prepared for flotation by sizing to remove a low-grade, high-impurity slime fraction. Depending on the material, further sizing and/or grinding steps may be used to produce a size concentrate or to remove gangue. The flotation feed is conditioned with H2SiF6 and a fatty acid emulsion. The H2SiF6 is absorbed chemically to the phosphate mineral surface, making it strongly attracted to water and preventing adsorption of the fatty acid. Under these conditions, the fatty acid is a selective collector for carbonate minerals, which are removed as a froth product. Next, the silicates are floated with an amine reagent added directly to the slurry without additional pulp preparation.

Jan 1, 1982

By James M. Spear

The U.S. Bureau of Mines and the U.S. Geological Survey conducted a mineral survey of the Black Butte RARE (I area during the summer of 1981. The study area encompasses 17,800 acres [27.8 sq mi (7,233 ha)] along the course of the Black Butte River, 13 mi (22 km) southeast of Covello, California. No mineral deposits were identified by the U.S. Bureau of Mines during this survey. Assay results of samples taken in this area indicate only trace amounts of manganese, chromium, and nickel. No radioactive or fluorescent minerals were detected. No oil and gas, coal, or geothermal leases have been recorded for the study area.

Jan 1, 1982

By Kenneth J. Miller

The Bureau of Mines conducted an investigation to improve the flotation response of coals that are difficult to wash by froth flotation. A literature survey and experimentation showed that, for the most part, refractory coals can be floated with oily collectors and frothers. Collector reagent consumption can be minimized and the selectivity of the flotation enhanced by assuring adequate, but not prolonged, reagent conditioning. Where flotation selectivity is especially poor, two-stage rougher-cleaner flotation is recommended. It was concluded that a major problem with refractory coals is predicting when they will appear in a flotation circuit so that supplementary flotation collectors can be added. Coal losses due to variation in the floatability of the feed might be reduced if a nonpolar collector such as kerosine or fuel oil is used along with a frother as general coal flotation practice.

Jan 1, 1977

To improve the reliability of the Bureau developed bore-hole gage now widely used to determine the absolute state of stress in rock. Approach Use the knowledge gained by extensive field tests to design a more rugged and reliable Instrument using lighter and stronger materials. How It Works The original gage consisted of a stainless steel cylinder 1-3/8 Inches In diameter and 10-1/2 inches long. The new gage is made from titanium. This lighter material reduces the weight of the gage by 43 percent, which enhances the gage placement and depth of overcoring in vertical up? holes. For added strength, the titanium case and placement end are now threaded to the gage body instead of using screw fasteners. Three pairs of strain gaged transducers are positioned to measure the diametral deformation of a 1-1/2 diameter borehole at 60-degree intervals around the Inner surface of the borehole. Each transducer consists of a beryllium copper cantilever with a strain gage cemented on each side. These transducers are secured Into the gage body by a tapered shank for minimal creep. The transducers opposite each other are wired together to form a 4-arm external bridge circuit. A pair of transducers is referred to as a component. Any deformation of the borehole, which occurs during overcoring, is detected by pistons which translate the motion to the components. Each

Jan 1, 1982

Improve the reliability and accuracy of subsurface images using constrained tomography with enhanced ray-tracing capabilities. Background Geophysical tomography is a technique for imaging the structure of a rock mass using seismic or radio waves, in the same way that medical CAT scans image human tissue using X-rays. Tomography has found numerous practical applications related to mining, including lithologic and structural characterization, fracture detection and fluid monitoring, void detection, and evaluation of stress state and integrity of mine structures. Problems Two fundamental problems have largely prevented geophysical tomography from enjoying the tremendous success achieved by medical tomography. The first is a consequence of practical limitations on the placement of sources and receivers of wave energy: ideal resolution can be attained only when the region being imaged is entirely surrounded by sources and receivers, so that it is crossed by rays traveling in all possible directions. When such coverage is impossible or impractical, the inversion becomes underdetermined: there id not enough information in the measured data to provide a mathematically unique solution. The second major problem in geophysical tomography is the necessity for detailed ray tracing. Commercial software, as well as previous U.S. Bureau of Mines (USBM) software, employs a ray-shooting algorithm that may be unable to model some ray paths when velocity contrasts are larger than about 100%. These ?shadow zones" result in loss of data and degradation of reconstructed images.

Jan 1, 1994

Improve the health and safety of underground mine workers by finding ways of keeping them away from unsupported areas of the mine. Background Roof falls have been the leading cause of fatal accidents in the underground coal mining industry. During 1985-89, 92 coal miners were killed by falls of roof and rib, with more than 4,000 miners injured. According to accident investigation reports from the Mine Safety and Health Administration, 47% of the victims of these fatal roof fall accidents were in the area of unsupported roof al the time they were killed. There is an urgent need to find out why miners go under unsupported roof and to devise strategies for preventing this unsafe behavior. Approach To discover what can be done to prevent miners from going under unsupported roof, confidential interviews were conducted with 297 miners who work in the face crews of 6 different coal mines. The interview topics included company policies and actions regarding going under unsupported roof, how foremen react to people who go under unsupported roof, circumstances likely to cause some people to go under unsupported roof and how to prevent these situations, and observations concerning those who go under unsupported root.

Jan 1, 1991

By C. C. Shale

A semicommercia1, high-temperature electrostatic precipitator and adjunct equipment are described, and operating characteristics at 1,470° F and 80 psig are presented for both positive and negative polarity. Removal efficiency for negative corona waS about 91 to 96 percent while that for positive corona was only about 75 to 77 percent. Results are compared with those from bench-scale investigations, and equipment limitations are discussed. Theoretical aspects of the precipitation process are related to the operating characteristics.

Jan 1, 1969

By R. L. Montgomery

The heats of solution of erbium chloride in water and in hydrochloric acid and of erbium oxide in hydrochloric acid were determined. The results reveal a discrepancy of 10.5 kcal. per gram-atom between the heats of combustion and solution of erbium reported in the literature, the heat of combustion being more negative. The heat of combustion of erbium t4)4 and its heat of solution in hydrochloric acid (1, 18) have been reported in the literature. The heat of solution of erbium chloride was determined in two studies (2, 19). The present work was undertaken to check the reported heats of solution of erbium chloride and to determine the heat of solution of erbium oxide in hydrochloric acid. The latter quantity permits the heats of combustion and solution of erbium to be compared for mutual consistency. It was also desired to determine the degree of similarity between the thermochemistry of yttrium and erbium.

Jan 1, 1961

By Michael D. Fenton

The very modest-sized mineral industry of Afghanistan was burdened for another year with problems of internal strife occassioned by the presence of Soviet armed forces. Despite this, production of the few traditional commodities continued, and the mineral industry moved to develop additional mines and plants for both traditional and new products with considerable technical and construction assistance from the U.S.S.R. Among the limited range of mineral commodities for which production was reported, there were no startling changes between 1984 and 1985. Production of both coal and natural gas advanced only slightly, despite substantially higher 5-year plan goals, and cement output was down marginally. Probably the most significant development in 1985 was the Possibility that mine and/or smelter production of copper was initiated during the year.

Jan 1, 1987