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By Irving Wender

The oxo reaction consists of catalytic conversion of olefins by reacting the olefins with CO and H2 (water gas) to aldehydes that contain one more carbon atom than the starting olefin. The aldehydes are then generally reduced with hydrogen to primary alcohols in a second stage. The two-stage process is called the oxo process. The word "oxo" is derived from the German "oxierung" (ketonization); thus the exact English equivalent of "oxo" is "keto". The oxo process may be applied to nearly all olefins. A wide range of pressures and temperatures may be used in both stages. The pressure range usually employed is 150 to 200 atmosheres. The temperature in the first stage is usually about 140° C. and in the second or hydrogenation stage about 180° C. Although a standard Fischer-Tropsch catalyst may be used for both steps, cheaper catalysts have been utilized to effect hydrogenation of the aldehydes. Most of the information for this, report on the oxo process was gathered from Technical Oil Mission microfilms. T.O.M. Reels 14, 55, and 134 were especially valuable. T.O.M. Report 6 by H. M. Weir was very helpful. Information on the oxo process is scattered throughout documents captured in enemy territory, and the present report does not include all the available data. Some of the information was procured by personal interview. Where, in the body of this report, certain investigators are quoted, the source of the statement is either personal interview or the T.O.M. reports.

Jan 1, 1948

By Ellis S. Hertzog

The relatively large amount of phosphorous occurring in many iron ores limits their usefulness aid sometimes renders them valueless under present conditions of nip-iron manufacture. A practical method for removing the phosphorus would be valuable to the iron and steel industry. Gravity concentration has been of little value as far as the removal of phosphorous is concerned, because the compounds of this element are, as a rule, disseminated very finely. Removal of the phosphorous by leaching is not a new idea and has been the subject of some investigation,3,4/ out for data :lave been published. W.R. Crane published analyse of various ore bodies in the Birmingham ham district. The hard or unleached ores a .re much higher in phosphorous than the Soft, leached ores along the outcrops. This fact indicates that as mild a leaching agent as water removes phosphorus effectively if enough time is allowed for it to react. As the forms in which phosphorous occurs in the iron ores are important in the consideration of any leaching operation, much time was expended in devising a method for determining them. According to Professor McVey, University of Alabama, the phosphorous-bearing minerals in the red iron ores of Alabama have not been positively identified by any microscopic methods.

Jan 1, 1935

By Ellis S. Hertzog

[The relatively large amount of phosphorous occurring in many iron ores limits their usefulness mid sometimes renders them valueless under present conditions of pig-iron manufacture. A practical method for removing the phosphorus would be valuable to the iron and steel industry. Gravity concentration has been of little value as far as the removal it of phosphorous is concerned, because the compounds of this element are, as a rule, disseminated very finely. Removal of the phosphorous by leaching is not a new idea and has been the subject of some investigation,3,4/ but few data have been published. W. R. Crane published analyses of various ore bodies in the Birmingham district. The hard or unleached ores are much higher or in phosphorus than the soft, leached ores along the outcrops. Tips fact indicates that as mild a leaching agent as water removes phosphorus effectively if enough time is allowed for it to react.]

Jan 1, 1935

By Marvin W. Wilson

The Federal Bureau of Mines has conducted laboratory experiments simulating underground gasification of coal to study the feasibility and mechanism of the process and determine the chemical and physical characteristics of a coal-bed during gasification. Laboratory and small-scale field experiments also were made to investigate the properties of coal and other factors affecting the electrolinking-carbonization method of preparing a path through a coalbed before gasification. Laboratory experiments simulating underground gasification of coal: Experiments with a laboratory retort indicated that bituminous-coal deposits could be gasified in place to produce a combustible gas.

Jan 1, 1960

By J. C. Gerdeen

A new analytical model for the shear stiffness at a joint of the fully-grouted resin roofbolt is developed using the Theory of Elasticity and an analogy to a beam on an elastic foundation, Gerdeen [2]. The model developed in this study treats the elastic foundation modulus of the resin as being composed of both an elastic rock and an elastic resin. All previous attempts have neglected the elasticity of the rock and treated only the resin. A three dimensional finite element model of the bolt-resin-rock system is developed also and comparisons are made between the predictions made by it and the analytical solution. It is found that the agreement between the two representations ranges between 1.2% and 10.5%, with the greater differences being observed for systems of very large or very small bolt diameters and resin annulus thicknesses. Since such configurations are not the rule in practice parameter studies are performed using the analytical solution with the finite element solution being used as a check. For a 0.75 in. bolt, a resin annulus thickness of 0.1375 in., a resin with E = 7 x 105 psi and -1) = 0.210, and a rock of modulus E = 6.8 x 106 psi and V = 0.159 the shear stiffness is found to be 1.220 x 106 lb,/in, from the analytical solution and 1.245 x 106 lb,/in, from the finite element model. Applying the finite element model to the problem of the axial stiffness of the fully-grouted resin roofbolt a value of 6.002 x 106 lb./in. is obtained which proves to be at least 50% higher than any of the now existing analytical predictions.

Jan 1, 1976

By W. W. Adams, T. D. Lawrence

"The National Safety Competition of 1938, the fourteenth of its kind conducted by the Bureau of Mines in which bronze trophies known as Sentinels of Safety are awarded to winning companies, has just been completed and the results are presented here.With 345 mines and quarries competing, more than in any previous year except 1931, the contest revealed low accident rates at many of the enrolled plants and, which is even more remarkable, it revealed 113 mines and quarries at which no lost-time accidents occurred during the contest year.The Sentinels of Safety trophies, provided by The Explosives Engineer magazine, were awarded to four underground mines, one open-pit mine, and one quarry. Each employee of the winning plant was awarded a Certificate of Honor by the Bureau of Mines in recognition of the employee's part in helping his company to win the trophy. In addition to the award of trophies, a Certificate of Honorable Mention was awarded to each of the mines and quarries in second, third, fourth, and fifth places in their respective contest groups and also to each mine and quarry that worked 30,000 or more man-hours without a lost-time accident. Ninety-two such certificates were awarded for 1938. Twenty-three other mines and quarries also operated without an accident but worked less than 30,000 man-hours, the minimum required by the contest rules for award of Certificates of Honorable Mention.Previous to 1938, five trophies were awarded annually in the National Safety Competition. For the 1938 contest a sixth trophy was provided by The Explosives Engineer so that open-pit mines and quarries, two classes of operations that previously had been included in one group in the competition, might have separate awards."

Aug 1, 1939

By R. S. Dean

The possibility of cheap electric power for a number of mining areas in this country has suggested to many the idea of electric smelting of nonferrous ores in small units at or near the mines. The electric smelting of nonferrous ores was tested fairly thoroughly 20 years ago by United States Bureau of Mines and by others, and the fact that it did not achieve continuing workable success in any instance is sufficient proof that it offered no advantages at that time.

Jan 1, 1937

By D. W. Bridges

Solvent extraction has become important in recent years as a unit process in extractive metallurgy. The flexibility and simplicity of the technique have attracted widespread attention, and numerous papers describing actual and projected metallurgical applications have been published. However, differences in terminology, procedure, objectives, and standards, as reflected in reports by different operators and investigators, have sometimes made appraisals and comparisons difficult. Consequently, a need appeared for n series of basic reports on the subject. This Bureau of Mines Information Circular is the first of such a series. It deals with the status of solvent extraction in metallurgy, as well as with the rudiments and terminology of the unit operation. In analytical chemistry, extraction of molecular species from aqueous media by immiscible organic solvents has been used for many years to separate and determine chemical elements (61).4 Complex chlorides of iron and other metals are readily soluble in ethers and ketones, as are the nitrates of uranium and thorium. Most metals are extractable as complex salts of some organic reagent, such as dithizone, 8-hydroxyquinoline, or cupferron.

Jan 1, 1962

The revised inspection standards or recommendations herein have been prepared for use in Federal inspection of bituminous-coal and lignite mines. They succeed a compilation of similar standards published as Bureau of Mines Information Circular 7268 in December 1943 and employed as a guide in Federal inspections since that time. Important alterations and additions have been made because of changes in mining, practice and temporary shortages of some safety equipment; moreover, several previous standards have been found not generally applicable and have accordingly been deleted. Mining methods and equipment continue to change, and new hazards and new safeguards are introduced. Consequently, these standards are subject to revision from time to time. Questions from the coal-mining industry regarding these standards and suggestions as to changes and additions thereto will be welcomed and considered carefully when the next revision is made. Many constructive criticisms from the mining industry have been considered in preparing this edition.

Jan 1, 1945

By William J. Campbell

Evaluation by the Bureau of Mines of published expansion values for magnesium oxide shows significant variation in values, which may be attributed to sample variables, experimental errors, or systematic differences between measuring techniques. To eliminate the sample variable in measuring expansion, thermal expansion characteristics of a high-purity polycrystalline magnesium oxide were determined by 21 cooperating laboratories using one or more of the following techniques; X-ray camera, X-ray diffractometer, dilatometer, interferometer, and telemicroscope. All expansion values were corrected by the author to a single reference temperature of 25° C. Linear expansion was expressed as a power series in the form of the following equation. Expansion (percent) = [[ A + B (?t) + C (?t)2] ?t 104] The constants, A, B, and C, were determined by least square techniques for X-ray camera, X-ray diffractometer, and dilatometer data separately, and for combined data of all five techniques. Expansion values are tabulated from 26° C. to 1,400° C. in 2° C. intervals using constants derived from X-ray camera data. Below approximately 500° C., expansion values obtained by dilatometric and interferometric methods are significantly lower than those by X-ray methods; above 500° C., this bias decreases rapidly. Comparison of results within methods showed the least variance for X-ray camera results; dilatometer and X-ray diffractometer results have about the same variance. The average deviations, in percent, between observed and calculated expansion values among methods were approximately 10 percent from 100°C. to 300°C., 5 percent from 300°C. to 500°C., and 2 percent from 500°C. to 1,400°C. Maximum deviations were approximately twice as large in most instances.

Jan 1, 1962

By F. W. Wessel

Manganiferous carbonate slates of the Cuyuna range, which are part of the unoxidized thin-budded iron formation, represent a large potential source of manganese. This report details recent bench-scale research by the Federal Bureau of Mines in applying mineral-dressing techniques to these materials in order to investigate their potential uses. Work outlined in the report was directed toward the production of concentrates usable as iron-blast furnace feed, but an equally important objective might have been to furnish an enriched feed for extractive processes for recovering manganese. Flotation concentrates were prepared that contained 11.1 percent manganese, 27.8 percent iron, and 12.2 percent silica, with recoveries of 73 percent of the manganese and 48 percent of the iron. Calculated analysis for a simulated sinter suggests a product containing 16.0 percent manganese, 40.2 percent iron, and 17.6 percent silica, with 31 percent recovery of the dry weight of the ore. The silica in the flotation concentrates was due to quartz and iron silicates. Substantial quantities of the iron silicates (stilpnomelane and smaller amounts of minnesotaite) were present in the slate, and the need to reject these minerals limited the recovery of iron. The sintered flotation concentrate would be usable as ferruginous manganese ore for iron blast-furnace feed because of its favorable manganese silica ratio. The unsintered flotation concentrates, representing 45 percent of the feed weight and containing manganese enriched in the ratio of 1.6 : 1, also could be used as feed to processes for extracting manganese.

Jan 1, 1961

By Albert L. Toenges

The Deep River coal field is in Chatham, Lee, and Moore Counties, N. C. The coal-bearing part of the basin is about 35 miles long and 5 to 10 miles wide. Sanford, the county seat of Lee County, is the largest town in the area, with a population of 10,000. Four railroads provide transportation to the area, and four United States highways and improved county roads provide easy access to the field. The Carolina mine at Farmville is the only operating mine in the field. The mine was opened in 1921 by two rock slopes driven from the surface to the Cumnock bed. Mining operations continued intermittently until 1945 and then stopped. In the fall of 1947 the mine was reopened by the newly organized Raleigh Mining Corp.

Jan 1, 1952

By G. L. Neumann

The Guymard mine in Orange County, N. Y., is reported to have been discovered in 1862 and mined until 1876, producing 10,000 tons of lead and zinc ore. The property was examined by an engineer of the Bureau of Mines in 1948. Development work was done by the Bureau in April and May 1949 and March 1950. During these two periods four drill holes totaling 2,090 feet were completed. The mineralized sections of the core were sampled and assayed.

Jan 1, 1952

By E. P. Youngman

Tantalum is a rare element ; estimates indicate that there is less tantalum than gold in the earth's crust . After remaining a laboratory curiosity for many years , it was used to a limited extent and for relatively few years (1903- 1911) for incandescent electric-light -bulb filaments . Another wave of interest in tantalum appeared when its electrolytic-valve action was taken advantage of in charging storage batteries , especially for radio work . Tantalum chargers were eventually displaced by other types of chargers , but for a time they were manufac tured in sufficiently large numbers to create a demand for the metal and to bring about its production on a commercial scale in the United States . As tantalum became available in larger quantities and at substantially lower prices , and as high prices for platinum encouraged the employment of tantalum as a substitute , the metal was put to many new uses . Ferrotantalum was made and sold before the World War , and patents have been taken out for a number of special alloys for industrial purposes , but probably the largest use for the metal to-day is in vacuum tubes .

Aug 1, 1930

By D. A. Rice

As part of its mission, the U.S. Bureau of Mines continues to develop technologies that will enable cost-effective compliance with environmental requirements. To this end, investigations to improve the kinetics of chalcopyrite dissolution by simultaneous grinding-leaching in ferric sulfate solution were conducted using the Bureau-designed turbo mill. The development of such a hydrometallurgical process would provide a nonpolluting alternative to conventional smelter technology. The effects of mill rotational speed and volume percent solids on the leaching time and energy required for copper extraction from chalcopyrite were evaluated. The results of this laboratory study have shown that the simultaneous grinding-leaching of chalcopyrite concentrate using the turbomill is technically feasible with essentially 100 pet extraction of copper being possible at 90° C. An optimal energy consumption of 1,153 kW?h/st of copper leached was found in batch testing with the mill operating at 400 rpm with a slurry containing 35 vol pet chalcopyrite. This energy consumption, while higher than other proposed leaching processes (about 600 kW?h/st), is of the same order of magnitude. Further refinement of the energy requirements would require additional testing using a continuous circuit. Leaching times of less than 1 h, for 80 pct copper extraction, are achievable using the turbomill grind-leach process.

Jan 1, 2010

By Eldon K. Stanek

The material presented in this chapter is a review of the work done during the period from June 23, 1972 to June 22, 1973 which was reported in detail in the first annual report for Grant No. 60122088 which was submitted on June 29, 1973. This report has appeared in the National Technical Information Service as bulletin number PB230 972/AS. 1.2 ANALYTICAL PREDICTIONS OF INDUCED VOLTAGES AND CURRENTS The basic building block in this analytical work is the development of an equivalent circuit. The equivalent circuit for the cable depends on all of the distributed parameters of the cable, although the series inductance and resistance are of primary importance. The cable resistances are generally available from handbooks or from cable manufacturers. On the other hand, the cable inductances are not usually available from either handbooks or the manufacturer's published data. Thus, it is useful to present the results of the derivation of the inductance matrix and a few intermediate steps.

Jan 1, 1975

By W. G. Sandell, L. C. Bauerle, K. C. Dean

"INTRODUCTION As a part of the wartime activities of the Bureau of Mines, metallurgical services were extended to other Government agncies engaged in purchasing and stock-piling some of the more critical and strategic materials. At the request of Dr. Alan M. Bateman, special representative of the Metals Reserve Company, metallurgical studies were made on three samples of oxide tin ore from, the States of Zacatecas and Guanajuato, Mexico. The samples were submitted for testing by A. Porraz of the Financiera Miners, S. A., institution Financiera, Edificio Guardiola, Despachos 500-507, Mexico, D. F.The samples as received were marked Nos. 1, 2, and 3 and described as follows:Sample 1. - Origin: Mining camp ""El Naranjo,"" municipality of Sombrerete, State of Zacatecas, Mexico. This sample was partly concentrated by washing and as received was all minus 10-mesh in size.Sample 2. - Origin: Deposits in Sierra. Fria and Juan Cherey, municipality, of Jerez,State of Zacatecas, Mexico. This sample represented run of-mine ore.Sample 3. - Origin: Mine ""La Frontere, "" Ranch of San Pedro del loya, State of Guanajuato, Mexico. This run-of-mine sample was low in tin content but came from a highly mineralized tin field."

Jun 1, 1947

By S. E. Burton

The White Rock area of the Boiling Springs manganese-iron deposits comprises about 3,200 acres of land in Monroe Township, Cumberland County, Pa. (See fig. 1.) This property was brought to the: attention of the Bureau of Mines by Pennsylvania Geological Survey Bulletin 128, entitled "Manganese Ores of Pennsylvania" by R. M. Foose. It was examined by an engineer of the Bureau of Mines in August 1942 and was further investigated by the Bureau by churn drilling and underground development during the period December 1942 to February 1944. Beneficiation tests were made on samples of the ore. This report describes the work done during the investigation and presents the results obtained.

Jan 1, 1949

By E. D. Gordner

Irrespira ble gutses issuing from the rock fofflb tions ere tJ source of expense ond danger in some metGLl mines. There is a great Variation in the compos i-· tion of such gdses and, os shown 'by recent sampling by the Bureau of ines, the gas rr;;,.y consi$t mostly ct carbon dioxide, (Rocle Strata Gtsses in the Mines of the East Tintic Mining District, by G. E. McElroy, Bu.retau of Mines Serial 2Z75) or f methone (Metruine in Ccalifornia C.old Mines, by B. 0. Picl-Q:lrd i:lnd !.. D. ("iordner, Bure, cf Mines Serial 2303), or nitrogen, sin the present instonce. A nl.liilber of unventilated rt:t.ises in some of the mine of l:l Neva&. district conuin «i'ccumulCltions of l;i hih-nitrogen gas the1t will not supi:ort life or combus­tion. The rdises ore in different geologiecil formations and in widely sep1:1rated. loecslities in the mining district. One ot" two ri::lises in the sme fc.rtr.ation may be full of the gos cand einother nec-r'by be t'ree ot· it. Lives have been lost t:lnd a number of men heave been overcome on enteing unvetilated rtsises in which their­respircable tss hcsd c1ccuni..1.l1::1ted between sldfts. Gener1:1lly, however, the gas see:ns to noozett from the .t'onrbtio:1 ond to ecc1: .. ,i.-1,;.1:.1te so slowly tMt its presence is not suspected t the tfr.1e, bu.t discovered. ed:'t&.c' the raise is t)band.oned. OcCE.isionelly 1 t issues from a ne•.,ly cut cre·tice or fissure under considerca ble pressure and in lar!?e enough '3.'16ntities to overcome or drive 011t men working in unventilated places.

Dec 1, 1922

By Donald W. Ross

"INTRODUCTION Sponge iron has been made commercially since 1912 at a Swedish ceramic plant; and the product, known as Swedish disk—type sagger sponge iron, has an excellent reputation as a superior furnace feed wherever high—grade steels are made. The general procedure for making brickyard sponge iron was described frequently in Swedish technical journals prior to 1932 and at that time consisted in filling clay refractory containers, called saggers, with a super-concentrate of Gellivare magnetite plus the necessary amount of solid reducing agent and desulfurizer and then firing in a Hoffmann ring furnace, as used in the ceramic industry.The early Swedish publications describe two types of brickyard sponge iron: (1) An inferior high-sulfur product obtained by mixing the ore and reducing agent, and (2) a high-grade low-sulfur product in the form of coherent disks 7 to 9 inches in diameter and 1 to 1-1/2 inches thick made by the saggers with alternate layers of solid-fuel reducr and of uniaxed ore."

Sep 1, 1945