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By Reul A. Dejú

The mineral olivine has been the subject of continued research by various authors. Paik (1967) conducted infrared and flotation studies of the adsorption of sodium alkyl benzene sulfonates on olivine. These studies are of interest from two points of view. First, in the metallurgical field it is of interest to understand the mechanism of silicate flotation using sulfonate collectors and second to a hydrologist studying the pollution of surface or subsurface waters it is of interest to study the reactions taking place when water plus sulfonates encounter a porous (silicate) medium. On the basis of Paik's study he was able to postulate a possible mechanism for the attachment of RSO3 (sulfonate radical) to the olivine surface. Parks (1969) has been studying the important influence of the structure of a silicate such as olivine on its dissolution mechanism and its related surface charge. Also Luce, a student of Parks (1964, 1965) has been studying the kinetics of dissolution of olivine using the techniques of direct solution analysis and infrared analysis. Certainly a classic in the study of silicate dissolution is the work of Murata (1940) on the reaction of orthosilicates (olivine in particular) with strong acid solutions. Many authors (Dejú and Bhappu, 1966. 1967. 1968, Dejú, 1969; Rhoades and Krueger. 1968, and Faust and blunter, 1967) have reported studies of the behavior of silicates immersed in water (especially orthosilicates) and have found that there is an exchange of cations from the silicate surface for H+ from the water. Studies by Dejú and Bhappu have also included the system olivine-water-amine.

Jan 1, 1971

By Ulrich Maidl, Gustavo Aguiar, Argemiro Ferreira, Marco A. Peixoto Silva, Marc Comulada

"Metro Line 5 in Sao Paulo is being constructed. This lot extends for 4,940 m with twin EPB shield tunnels under a dense and busy urban area, with an excavation diameter of 6.9 m. The tunnels run predominantly in the tertiary soils of Sao Paulo where extensive experience exists from previous EPB shield tunnel projects. However, new experience is being gained in Sao Paulo in shield tunnelling through Saprolite, the weathered product of the underlying Gneiss crystalline basement, through the resulting residual soils and in rock-soil mixed face conditions. Furthermore, experiences in difficult mixed face soil conditions with overconsolidated clay at the face in combination with loose sands at the crown under the groundwater table will be presented. Additionally, the design, operational and controlling approach followed for the shield drive at particular critical cross-sections where the shields were driven close or under buildings. INTRODUCTION Within the framework of Sao Paulo´s metro network expansion, the excavation of the shield tunnels for Metro Sao Paulo Line 5 is currently taking place. The present paper deals with the description of the most relevant features from the construction of the Line 5 – Lot 3 tunnels. The paper presents how particular challenges were dealt maximising potential of EPB shield tunnelling technology. Challenges were posed not only by the difficult boundary conditions of urban shield tunnelling, such as shield drive under buildings, but also by complex geotechnical situations. PROJECT DESCRIPTION The great urban area of São Paulo is one of the biggest cities in the world, with around 20 Million people living in the city and in the suburb area. The city faces great mobility problems and in the last years the government has been investing great amounts on the megacity´s metro expansion. The Line 5 Extension plays an important role to connect the south area to the central area of the city, with a whole extension of 11 kilometres, including 11 new stations. It is estimated that this line will transport almost 900.000 passengers/day. The first stretch of the expansion, Lot 3, consists of two single tunnels, almost 5 kilometres long each, crossing 4 stations. Figure 1 shows details of the Line 5 Expansion."

Jan 1, 2016

By M. M. Carpenter

Specialty chemicals are widely used in the industrial minerals process industry for many different purposes including beneficiation, filtration, flocculation, dispersion and biological control. Optimal use of such chemicals can confer benefits both in terms of cost efficiency and end product attributes. In this paper we will review recent progress in the fundamental understanding of mineral additive interactions and present data which show how optimization can lead to improved products.

Jan 1, 1999

By K. T. Valsaraj, L. J. Thibodeaux

Solvent sublation, the separation process for the removal of two hydrophobic compounds (penta- and trichlorophenols) from the aqueous phase, is discussed, as is a steady-state mathematical model for fire process. Solvent Sublation "'as conducted in a continuous countercurrent mode. The underlying mechanisms, theory and experimental details on the effects of process variables on removal efficiency are reported.

Jan 1, 1994

By D. D. Misra

Though computer simulation of coal beneficiation has been in use for nearly two decades the models used in the programs for the simulation of the crushing processes concentrate mainly on the size distribution. This paper suggests the use of an empirical equation approximating to the cumulative probability or error function for the simulation of the liberation process in coal crushing. The algorithm outlined here can be incorporated in a computer program already having a size distribution model.

Jan 1, 1989

By A. D. Davis

The Bear Butte Creek watershed, in the northern Black Hills of South Dakota, shows the effects of past mining activities in the form of dissolved metals and arsenic in stream water. Bear Butte Creek, during normal flow periods, loses all of its discharge to sinkholes that recharge the Madison Limestone aquifer. This work focused on the geochemical transport and fate of arsenic and on understanding ground-water flow conditions in the Madison aquifer through development of a three-dimensional ground-water flow model that was coupled to a geographic information system (GIS). Stream sampling and discharge measurements helped determine sinkhole losses and loading rates. Column laboratory tests provided data on arsenic adsorption and the mixing of stream water with aquifer water, which also was simulated with the geochemical models, pHREEQE and NETPATH. The models and GIS can be updated with new information and will be useful in managing the water quality of the Madison aquifer.

Jan 1, 1997

By S. C. Torma

Sources of lead contaminated soils are numerous, i.e., the uses of leaded gasoline, lead-based paints, leaded pesticides, solders, smelting of lead concentrates, refining of lead products, automobile demolition, recycling of lead batteries, and so on. Conservative estimation by the US Environmental Protection Agency, EPA, indicated that several thousand lead contaminated sites are awaiting remediation. The current remediation technologies include immobilization, reclamation and soil washing. In this paper, the above remediation technologies will be reviewed, and where appropriate, the economics of processes discussed and future possibilities indicated.

Jan 1, 1996

By C. T. Thompson

"Rotary percussion" implies two types of energy, rotary and percussion. Into these categories fall rock' drills of varying sizes. The larger ones drill above 6" diameter holes; the medium size, 2 3/4" to 4 1/2" holes; and the smallest, 1 1/4" to 2" holes. Essentially, the larger holes are drilled with doom-the-hole drills using tri-cone bits. Percussion energy evolves from the drill piston and rotation power from the rotary table or overhead drive, using drill collars or pull down mechanism to preload the bit.

Jan 1, 1963

By PAITIP THIRAVETYAN, KANJANA KUDPENG

The aim of this study was to investigate the influence of amino acids (glycine, aspartic acid, glutamic acid, lysine and tryptophan) and organic acids (citric, malic, tartaric, fumaric, oxalic, succinic and ascorbic acid) on gold extraction from silicate ore. Use of amino acids to extract gold was preferred compared with organic acids due to the presence of carboxylic group and amine groups in amino acids. Among the assessed amino acids, aspartic acid and glutamic acid had higher capacities to extract gold due to their structures, which lacked aromatic rings and long side chains. Organic acids could also extract gold. In particular, oxalic and succinic acids had the greatest capacity to extract gold versus the other tested organic acids. Moreover, aspartic acid had a greater capacity to extract gold from ores than the same concentration of succinic acid. We confirmed the aspartic acid and succinic acid functional groups by Fourier transform infrared spectroscopy. The findings revealed that aspartic acid had a greater capacity to extract gold than succinic acid due to the presence of both amine and carboxylic groups (succinic acid contained only a carboxylic group). The optimal gold:aspartic acid molar ratio was 1:6 and low concentrations of aspartic acid extracted 35–42%of gold from silicate ore within 15 days. This can be used as an alternative to traditional methods for extracting gold from ore; it is non-toxic to human health and environmentally friendly.

Aug 10, 2021

By S. K. Nicol

The results of column flotation tests conducted on a bulk sample of ultrafines discarded from the fine coal desliming cyclones at the Riverside coal preparation plant of Theiss Dampier Mitsui Coal Limited are presented. A 9% ash concentrate was obtained from a 51% ash ultrafine feed at 75-80% recovery of combustibles in a single stage of column flotation. From this result it is predicted that installation of column flotation at Riverside would lead to the annual recovery of additional coal worth $US5.1M. The operating conditions for coal and copper column flotation are compared and some differences which may result in a variation in column design are noted.

Jan 1, 1987

The knowledge of aggregate size under various chemical and hydrodynamic conditions is very important for selective agglomeration, flotation and water clarification processes. Traditionally, aggregate size measurements are conducted using an ex-situ technique or in a diluted suspension. In either case, the measurement occurs in an environment that does not resemble the actual conditions under which the aggregates are formed. In this study, an on-line scanning laser microscope has been used to study the coagula size of micronized coal suspensions as a function of pH, solids concentration and agitation intensity. A maximum aggregate size of 310 µ m was obtained under relatively quiescent conditions and at pH values near the iso-electric point (iep) of the coal. The aggregate size results compare well with the coagulation efficiency measurements obtained under the same pH conditions.

Jan 1, 1994

By E. M. Frizzell

An ongoing research program at the Spokane Research Center of the U.S. Bureau of Mines is directed toward investigating drilling parameters (thrust, torque, penetration rate, and drill revolutions) during the drilling of roof bolt holes. A system that measures these drilling parameters calculates the specific energy of drilling, and determines drill bit position has been developed by the Bureau and mounted on a roof bolting/drilling machine, through the use of a microcomputer, critical drilling parameters can be immediately interpreted and analyzed. This makes it possible to inform the operator of hazardous roof conditions. Initial results of this program are presented here.

Jan 1, 1990

By Robert J. Willard

In its search for additional ways to increase understanding of rock behavior, the Twin Cities Mining Research Center has turned to the scanning electron microscope, an instrument rapidly finding application in research concerned with surfaces of materials. Since features indicative of the manner in which rocks fail may be recorded on the surfaces of fragments as disintegration proceeds, this microscope might be used as a tool for seeking and mapping these minute features. In pursuit of such features, we chose to scan a portion of the fracture surface from a quartzite disk compressively loaded to failure between two pins centered along the disk's axis. The resultant fracture appeared as a rough, diametric plane, and the fracture surface near one of the loading points was scanned with the microscope.

Jan 1, 1969

Sphalerite is commonly floated in an alkaline environment and under such conditions the overall activation mechanism is obscured by the hydrolysis of Cu2+ and precipitation of Cu(OH)2. Electrokinetic and kinetic flotation tests show that the activation of sphalerite is a two-stage process; the activation products formed on the surface of sphalerite in near neutral and in alkaline solutions in the first rapid activation stage are "flotation-inactive". These layers, when formed in an alkaline solution, are unstable and are transformed into the "flotation-active" form in the second stage. However, the surface layers formed during activation in alkaline environment by copper in the presence of lead ions are very stable and even after a long conditioning time the flotation rate is not improved. Consequently, while both Cu2+ and Pb2+ activate sphalerite flotation, quite unpredictable effects may result when both are present in the solution.

Jan 1, 1997

By K. A. Natarajan, M. K. Yelloji Rao

Significance of grinding media wear and its effect on chalcopyrite flotation are discussed. Laboratory marked ball wear tests were conducted grinding chalcopyrite ore and quartzite dry, wet, and with collector added during grinding. The effects of oxygen and nitrogen on ball wear were evaluated by the addition of chalcopyrite mineral while grinding quartzite. The effect of dry and wet grinding on chalcopyrite flotation was also studied. Results show abrasive wear is greater in quartzite grinding than in grinding chalcopyrite. Oxygen increases the corrosive wear of high carbon low alloy steel balls in the presence of chalcopyrite ore. Chalcopyrite flotation was retarded due to wet grinding in the presence of oxygen. Though collector reagent increased the media wear, it improved the flotation of chalcopyrite. Probable electrochemical reactions encountered in a grinding mill are outlined.

Jan 1, 1991

By R. E. Williams

University of Idaho scientists research under U.S. Bureau of Mines Cooperative Agreement C0278001 constitutes a complex hydrogeological, hydrochemical and metallurgical mine waste management project at an existing Superfund site. Technologies that may prove useful for the extraction of dissolved metals from acid mine water and solid wastes include lixiviation and biosorption. Acid mine water is the major, long-term problem in the valley. We are attempting to delineate the major sources of ground water recharge which feed the acid mine drainage and their hydraulic properties. Grouting of recharge areas may facilitate minimizing the production of acid mine drainage if recharge pathways can be identified.

Jan 1, 1990

By A. L. de Vegt

Hydrogen sulfide is an expensive chemical used in nickel, zinc and copper mining and metallurgical operations for selective recovery and concentration of metals from leach water streams, acid plant blow down streams, refinery electrolyte bleeds and precious metal plant bleeds. Hydrogen sulfide is either produced on site by catalytic reduction of elemental sulfur or transported to the site as liquefied hydrogen sulfide (H2S) or as a sodium sulfide solution (NaHS). Biologically produced hydrogen sulfide has economically very interesting application possibilities in the mining and metallurgical industry. Converting sulfates from waste streams into usable hydrogen sulfide by biological reduction results in operational cost savings in existing lime treatment systems. H2S can be produced biologically for less than $500/ton S. For the past ten years Paques has been engaged in the development and installation of treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. Paques has designed and installed a groundwater treatment system for the Budelco zinc refinery in the Netherlands to remove sulfate and heavy metals. The hydrogen sulfide produced is used for recovery of metals, mainly zinc, from the ground water stream. The system has been operating since May 1992 treating a flow of 5000 m3/d. At Kennecott's Bingham Canyon Utah copper mine a pilot plant started operation in November 1995 to develop the process for selective recovery of copper from leach water using biologically produced hydrogen sulfide from sulfate containing groundwater. Other pilot plants are operated at DOE's Pittsburgh Research Center and at Cominco Research focusing on selective recovery of metals.

Jan 1, 1998

By H. Fayed

Froth flotation technology is the backbone of the minerals pro-cessing industry where minerals are concentrated by selective separa-tion; either direct or in-direct flotation. In direct flotation useful minerals are conditioned to become hydrophobic (water-repellant) and attach to air bubbles while impurities (non-useful particles) remain in water. The hydrophobic particles are transported by air-bubbles to the top froth (foam) layer in flotation tank which can be removed as a concentrate. There are many factors that controls this selective separation process such as: particle’s degree of hydrophobicity, size, mass loading, air holdup and bubble size distribution. Turbulent fluctuation of the slurry in the tank is another important factor that controls the collisions rate between particles and bubbles and hence attachment rates. The turbu-lent fluctuations are measured by the local distribution of turbulent dissipation rates. Conventional flotation machines are restrained by residence time of the slurry that is about 3-5 minutes that results in a large footprint and limits the capacity of flotation plants. The designers of conventional flotation machines try to reduce the footprint of flota-tion tank by scaling up the flotation machines to increase plant throughput. The scale-up process reduces the specif power consump-tion and the local distribution of shear rates and turbulence dissipation rates. This scale-up results in a larger mean bubble size and lower particle-bubble attachment rates.

Feb 1, 2023

By C. I. Basilio

The adsorption of dialkyl di-and mono-thio-phosphinates on gold, silver and gold-silver alloys has been studied in the present work. These reagents, which are selective collectors for sulfide flotation, have been found to improve precious metals recovery from ores. Voltammetric studies have indicated that dithiophosphinate adsorbs on gold at much higher potentials than on silver, while monothiophosphinate adsorbs only on silver. However, both adsorb on gold-silver alloys with the adsorption potential decreasing with increasing silver content. Using FTIR spectroscopic measurements, the surface species formed during the interactions of these collectors have been identified. The results of the electrochemical and spectroscopic measurements have been compared with the contact angle data obtained at controlled potential conditions.

Jan 1, 1992

By M. Misra

The interaction of xanthate with SO2 in the flotation of sphalerite and chalcopy.ite is discussed. 'The SO depression of sphaledte is due to the decomposition reaction of xanthate by SO2 The decomposition reaction is dependent on the cole ratios of xanthate/SO2, oxygen concentration and pH. Xanthate adsorbs at a faster rate by chalcopyrite than sphalerite. The faster rate of xanthate adsorption by chalcopyrite and the specific action of S02 on the surface of chalcopy.ite facilitate the selective separation of chalcopyrite from sphaledte.

Jan 1, 1989