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By V. Z. Sun

One of the major concerns of ground control in a coal mine is safety against failure of one of three components (i.e. roof, pillar, or floor) of the mine entry. In order to better design and evaluate stability of the mine entry with a certain confidence, a reliability approach is introduced rather than using the conventional safety factor (SF) method only. Advantages of using the reliability approach is that it not only takes variability of both rock/coal properties and stress distribution into consideration, but also assesses the stability of each component and mine entry as a whole system. Therefore, it is anticipated that, by using this approach, the current ground control technology in coal mine will convey a better sense of confidence. The results of a case example show a significant influence on the current design concept and stability evaluation of mine entry.

Jan 1, 1997

By William R. Nash

Case histories of water problems in underground mine shafts and tunnels are outlined to illustrate varying degrees of sophistication in grouting techniques currently applied in such construction. The interception of water underground can be one of prior knowledge, i. e., the site investigation provides necessary data to plan a grouting program prior to construction start, or excavations may encounter "changed conditions" or unplanned water. The latter includes catastrophic inflows and emergency situations where the structural integrity of a building or concrete shaft lining are jeopardized. The presentation of this paper outlines some applications of grouting work in underground mine construction throughout the United States in a variety of geological provinces and for a variety of minerals.

Jan 1, 1984

By Albert F. Duzy

Recently there have been some problems associated with hot coal in shipments from the USA to overseas markets. This paper will serve several functions. First, a brief review is presented, together with a selective bibliography. Second, a thorough discussion of coal oxidation is covered. Third, potential effects of storage are presented and, lastly, methods are suggested for the safe storage and bulk transfer of coal. The scope includes coal storage for power plants.

Jan 1, 1983

By R. Gray, B. Hebblewhite

Experience from Australia had identified what is referred to as nonconventional surface subsidence behavior. This occurs under irregular surface topography, resulting in valley closure, valley floor uplift or “upsidence,” and far-field horizontal movements, occurring even beyond conventional “angle of draw” limits. This paper discusses such behavior recently observed in Pennsylvania and focuses on the 2005 case of Duke Lake Dam in Ryerson Station State Park. In July 2005, there was a significant increase in water leakage through a number of growing cracks in the dam, leading to the dam being breached to avoid an uncontrolled failure. An underground longwall mine was located approximately 900 ft to the north, mining at depths of 330 to 720 ft. Investigations, including a subsequent ground movement monitoring program, found a range of evidence in the vicinity suggesting that valley closure and farfield horizontal movements may have occurred, resulting from the adjacent mining. Besides discussing the phenomenon of nonconventional subsidence behavior and the Ryerson State Park case study, this paper includes an assessment of the mining, geology and subsidence impacts and suggested ground behavioral mechanisms.

Jan 1, 2015

By A. Khan

The effect of sulfur dioxide on collectorless and collector induced flotation of chalcopyrite was studied by cyclic voltammetry on a rotating disc electrode. Contact angle measurements were made to determine the effect of sulfur dioxide concentration and electrochemical treatment. The benefits of sulfur dioxide in enhancing the selectivity of separating chalcopyrite from complex sulfide ores are discussed.

Jan 1, 1996

By E. L. Piper

Natural graphite has been known for many centuries, having first been reported as a distinct mineral form by Gessner in 1565. At that time, graphite was used extensively as pencil "lead" because of the ease with which it marks paper. It is a black, unctuous material found as flakes, lumps, or needles in scattered locations throughout the world. The less crystalline, or "amorphous", natural graphites are thought to have been formed from coal under conditions of high temperature and pressure. The more crystalline varieties, such as those mined in Ceylon, probably were precipitated from molten solutions or were pyrolyzed from gaseous carbon compounds. Recognition of the good thermal and electrical conductivity of graphite, together with its highly refractory nature, led to an increasing number of appli¬cations for this material. Clay and pitch bonded natural graphite has been used in crucibles, refractories, foundry facings, and other high-temperature appli¬cations. These forms constitute the most important current uses for natural graphite in the United States. Other products containing natural graphite include batteries, lubricants, pencils, brake linings, etc.

Jan 1, 1973

By C. Hanson

Two modes of potential loss of oxime extractants in liquid extraction processes for the extraction of copper have been studied. In loss "by chemical degradation, two mechanisms of acid hydrolysis are possible, some reagents degrade primarily in the organic bulk phase, Others at the interface between the organic phase-- phase protects the oxime but salts added to the aqueous acid phase can promote the rate of degradation. The reagents reported on are the LIX series (Henkel Cpn), SME529 (Shell Chem.Co.) and P5100 (Acorga) Loss by organic entrainment in the aqueous phase leaving mixer-settlers has also been studied, parameters investigated including impeller/tank geometry and the phase inlet arrangements. The consequences of extractant loss by the above mechanisms...are commented upon. They include the direct economic cost, the possible environmental problems and the implications for downstream operations such, as electrowinning.

Jan 1, 1980

By David X. Zhang

This paper describes the results of using shear flocculation and flotation known as aggregative flotation technique for the enrichment of coal-derived char produced from mild gasification process. Aggregative flotation is a separation process which involves the use of suitable aggregating liquid under the action of high shear forces to render hydrophobic surface of coal-derived char particles to aggregate in an aqueous slurry. The fine carbonaceous particles are aggregated into larger floes while the impurities remain hydrophilic. In subsequent flotation process, the char aggregates are then separated from mineral matters by aeration in the flotation cell. The floatability of char aggregates and removal of mineral matters from chars are studied in a lab scale flotation column cell. The effect of various operating parameters on the aggregative flotation responses is presented. Emulsification of aggregating liquid using high intensity agitation and ultrasonic energy provides excellent aggregating liquid dispersion and increases selectivity for char aggregation. In subsequent flotation process, it results in significantly increasing the flotation rate of char aggregates. The microscopic examinations of bubble attachment to coal-derived char particles under various aggregating liquid dispersion levels were conducted by induction time measurement. The distributions of hydrophobicity of char particles and char aggregates prepared under various aggregating liquid dispersion techniques were measured by film flotation. The char particles prepared under high intensity emulsification attach at significantly faster rates to air bubble and with lower mean critical wetting surface tension than that of char with direct aggregating liquid addition. An interrelationship of increasing in flotation rate/combustible recovery with decreasing in induction time, mean critical wetting surface tension and dispersion of hydrophobicity on the char particles and char aggregates were obtained.

Jan 1, 1992

By H. EI-shall

The conventional beneficiation scheme for Florida phosphates involves reverse flotation with an intermediatory acid scrubbing step. A single reagent flotation process, using fatty acids or amine as the collector, would eliminate the scrubbing step along with the other flotation step. This can not only simplify the process flowsheet, but also result in reduced reagent costs. The potential of single reagent flotation of Florida phosphates using fatty acids as the collector was examined in this study.

Jan 1, 1993

By Robert Moore Lewis

Extensive exploration is being undertaken throughout the world in search for heavy minerals, particularly rutile and other titanium minerals. The federal government is sponsoring research involving rutile ores and recovery of stockpile-grade concentrates from domestic sources. Producers are being forced to turn to deposits with a heavy mineral content as low as 0.50% (essentially rutile and zircon). The North Carolina State University Minerals Research Laboratory investigated the possibilities of recovering heavy minerals from the amine tailings of the Texasgulf Inc.'s phosphate plant at Aurora, North Carolina. One laboratory beneficiation procedure using gravity, electrostatic and magnetic processes, resulted in the recovery of 78.7% of the heavy minerals in the amine tailings. Based on this percentage recovery and the present rate of phosphate mining, approximately 13,000 tons per year of heavy minerals (principally ilmenite and zircon) with a potential value of approximately $1,045,000 (1977) could be recovered. The economic potential for recovery of these heavy minerals appears to be favorable. A flotation procedure for up-grading the heavy minerals content in the amine tailings has been developed at the Laboratory, which could allow for concentration of heavy minerals and storing them in tailings area other than main tailings for future processing.

Jan 1, 1978

By R. K. Will

An inactive mining operation in northern California is known to be a source of acid mine drainage and heavy metals which have impacted adjacent creeks. Elevated concentrations of copper and zinc are a concern to aquatic populations, particularly steelhead trout and salmon downstream in the Sacramento River. Previous regional geological surveys of mineralization by the U.S. Geological Survey located and mapped outcrops of massive sulfides and gossan. Recent investigations indicate that a substantial amount of the metals in the local creeks are due to natural causes. The investigations include locating and mapping surface and subsurface minerals, soil and water sampling, and chemical analysis. Groundwater, seeps, and surface water were also sampled and analyzed. A water balance was conducted on a sub-basin level following delineation of surface water drainage and groundwater divides. A chemical mass balance incorporated metal concentrations and water volumes and was then used with other data to determine the contribution of metals from natural versus mining-related causes.

Jan 1, 1998

The Cadia Mine is located 25kms South West of Orange in the central west of New South Wales (NSW), Australia (Figure 1). Orange is a major regional centre with a population of 35,000 people. Cadia has a history of mining and exploration dating back to 1851 and shortly after the first Australian gold rush at Ophir, north of Orange. Newcrest Mining commenced an exploration program at Cadia Hill in 1992. This identified a substantial zone of copper and gold mineralization. Subsequent resource definition drilling defined an orebody with a mineable reserve of 200 million tonnes of ore with an average gold grade of 0.74g/t and 0.17\ copper. A full feasibility study commenced in 1994, approvals to proceed with development were granted in September 1996 and the processing plant was commissioned in July 1998. The project came in on budget at A$440 million and on time, 24 months from design to construction. The estimated operating cost at the time of commissioning was A$8.85/t of mill feed.

Jan 1, 1999

By G. F. Ayakwah

Point load strength (Is50) and slake durability (ID2) indices provide a measure of the strength and durability of rock fragments and are related to the alteration intensity and frictional resistance of the materials. Samples were collected from the rock piles, alteration scars and debris flows at the Questa mine with the purpose of examining relationships between Is50 and ID2, mineralogy, chemistry, weathering, hydrothermal alteration, and other geotechnical parameters. The Is50 from the various rock piles ranges from 0.6-8.2 MPa and the ID2 ranges from 80.9-99.5%. The Is50 and ID2 results indicate that the samples from the debris flows are stronger (average Is50= 4.0 MPa and ID2= 98.4%) than the rock-pile samples and that the alteration scar samples are weaker (average Is50 = 2.8 MPa and ID2 = 89.2%) than the rock-pile samples, but still most of these rocks are strong in terms of their Is50 and ID2. The Is50 decreases as the degree of alteration increases in some rock pile and alteration scar samples, but not in all. However, the majority of the rock fragments within the rock piles still indicate high strength, even after 25-40 years of weathering.

Jan 1, 2009

By J. D. Miller

Fluid flow phenomena and therefore the flotation efficiency of air-sparged hydrocyclone (ASH) flotation are strongly dependent on the operating and design variables such as air flow rate, slurry flow rate, underflow and overflow opening areas, percent solids in the feed, reagent levels, particle size, ASH length, etc. Time-averaged multiphase flow characteristics, as deter-mined by x-ray CT and described in a previous publication, are used to understand and explain the steady-state ASH flotation of quartz. A detailed parametric study of quartz flotation by a nominal 2-inch diameter air-sparged hydrocyclone (ASH-2C) revealed the influence of these variables on the flotation response which is discussed in terms of the multiphase flow characteristics. Thus, a phenomenological description of quartz flotation has been established to assist in the further development and utilization of the ASH technology.

Jan 1, 1995

By David Lynn Passmore

The reliability of mine operators reports to the Health and Safety Analysis Center of the U.S. Deparetment of Labor of days lost from work by injured miners is .267.

Jan 1, 1985

By S. K. Kawatra, S. K. Valluri, S. J. Root

Common carbon dioxide capturing reagents, such as amines and sodium hydroxide, are expensive, toxic, and energy intensive to regenerate. We have added frothers to a sodium carbonate solution in order to increase the surface area available for CO2 transport within the packed bed of a counter current scrubbing column. Addition of frothers has improved the performance of sodium carbonate scrubbing solutions to be on par with sodium hydroxide scrubbing solutions. This novel enhancement of a relatively inexpensive CO2 capture-regeneration cycle shows potential to allow plants to turn a profit by sequestering a waste product. These results are discussed in detail in the following manuscript. INTRODUCTION The combustion of fossil fuels converts chemical energy to thermal energy. CO2 is produced as a byproduct of the reaction. 80% of the world’s electricity is produced by using this thermal energy to power a generator, accounting for 40% of global carbon dioxide emissions. In an effort to stabilize the rising atmospheric CO2 levels, researchers are investigating the application of carbon capture and storage (CCS) systems in power plants. [1] Efforts to capture CO2 at some power plants have been successful, but the cost of installing and operating the required equipment is high. As such, very few power plants have CCS systems. If CO2 can be captured and processed into a product that can be sold at a profit, installing CCS systems in power plants will be a very attractive business decision. In order for the sale of captured CO2 to become a profitable venture, the cost of capturing the CO2 from a flue gas must be reduced. BACKGROUND The most common method for separating CO2 from a flue gas is by passing it through a counter-current packed bed scrubbing column. The flue gas enters the bottom of a column while a solution of a chemical with properties advantageous to the absorption of CO2 is pumped to the top. The fluids interact in a packed bed, where the CO2 is transported from the gas to the liquid. CO2 is an acid gas, so it is common for the scrubbing solution to be alkaline in nature in order to neutralize the carbonic acid that is formed when it is dissolves into water. The exhaust exits the top of the column free of carbon dioxide, which exits the column in the scrubbing solution, reacting or complexing with the absorbent. Figure 1 is a schematic drawing of a CO2 scrubbing column. It shows the molar flowrates and compositions of the gas and liquid at the bottom [1], the top [2], and an arbitrary height in the column [Z]. [2,15] L is the molar flowrate of liquid at any point in in the column. G is the molar flowrate of gas at any point in the column. Since the CO2 is transported from the gas to the liquid, L and G are variable with respect to height. To simplify calculations, the CO2 free molar flowrates Ls and Gs are often used. X is the fraction moles of aqueous CO2 per mole of CO2 free liquid. Y is the fraction moles of gaseous CO2 per mole of CO2 free gas. Figure 2 is a composition diagram of the scrubbing column depicted in figure 1.

Jan 1, 2019

This one day field trip is sponsored by the Denver Region Exploration Geologists? Society, May 14th 2009. The trip highlights major geologic features and some notable uranium occurrences along the north-south mountain-basin boundary southwest of Denver and continuing north to Fort Collins, Colorado. Uranium deposits visited include sandstone?hosted roll front type and polymetallic veins hosted in metamorphic rocks. A replacement ?episyenite? type occurrence is considered via description and hand samples but is not visited owing to logistical constraints. Recovery methods addressed include underground mining and in-situ leach recovery. Samples of Precambrian basement rocks, deposit host rocks, uranium ore samples, and ore polished sections viewed by reflected light microscopy will be available. A road map showing the locations of the stops serves as the front cover of this field guide. The Robinson episyenite-hosted occurrence (not visited) is labeled as Stop 6. A stratigraphic column is provided which shows the position of the host rocks at each stop (Figure 1-1).

Jan 1, 2009

By Theodore H. Budd, Austin M. Cooney

The North Shore 9 Collector System comprised an integral part of the Milwaukee Metropolitan Sewer District's Water Pollution Abatement Program. The project required the construction of 1,490 m of tunnel, ranging from 1.5 m to 4.6 m in diameter along three separate alignments beneath arterial streets traversing Milwaukee's central business and cultural districts. This paper details the various aspects of the tunnel drives which were accomplished using two Lovat EPB type TBMs in conjunction with pipe-jacking procedures. Shaft configurations developed for the project, including ancillary subsidence mitigation components and portal pressurization facilities are discussed. Anomalies in observed soil behavior at variance with the parameters delineated in the project's geotechnical report are addressed.

Jan 1, 1991

By T. Guler

Turkey has important celestite reserves in Sivas. These reserves have gypsum and/or calcite as gangue minerals. Celestite-calcite ore cannot be concentrated by gravity methods due to the low efficiency of gravity methods in fine sizes. Research was tried to concentrate celestite to a market grade by flotation. Parameters such as pH, particle size, dosage and types of collector and depressant were examined. Cyanamid A-845 and Na-oleate combination as collector, sodium silicate as depressant, and Aerofroth-65 as frother were found as the optimum flotation reagents. By applying 3-stage cleaning, a concentrate assaying 95,34 % SrS04 was obtained with 84,93 % recovery.

Jan 1, 1999

By Nikhil Dhawan, Shrey Agrawal

India’s most extensive renewable energy expansion program targets 280 GW of solar energy by 2030. Due to the massive generation of photovoltaic waste (expected 34,600 T by 2030), stringent recycling effort to recover metal resources from endof- life PVs is required for resource recovery, circular economy, and subsequent reduction in the environmental impact. The present study investigates the recycling potential of end-of-life silicon solar modules. The feed characterization reveals that most of the values in PV modules are concentrated in the frame (pure Al), Si wafer (72–84% Si, 9–12% Al, and 0.13–0.71% Ag), and electrical connections (Cu wire coated with Sn). The Si and Ag values in the feed were beneficiated using water fluidization, and concentrate with 90% Si and 2% Ag was attained in the underflow concentrate. Ag values were recovered in the form of AgCl by leaching in nitric acid and precipitation. After the purification step, the residue containing 99% Si can be further utilized to fabricate Si wafer and Al-Si alloy. The preliminary cost estimations suggest that the proposed process is economically viable for the recycling of solar panels with the maximum value generated from the AgCl precipitate followed by Al panels and Si wafers.

Nov 14, 2022