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By L. Zhang, Y. Zhou, H. Wang, C. Mo

Fluorination of magnetite (Fe₃O₄) by NH₄HF₂ was investigated using simultaneous thermogravimetry and differential thermal analysis (TG-DTA), and observing the morphology and phase changes using scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) and X-ray diffractometry (XRD). The results indicate that fluorination with the involvement of oxygen begins at room temperature, peaks at 178.40C, and is completed at 2000C with the formation of only (NH₄)₃FeF₆. On heating, (NH₄)₃FeF₆ gradually releases NH₄F by the formation of NH₄FeF₄ at 2590C, then (NH₄)0.18FeF₃ at 3270C, and finally FeF₃ with minor FeF₂ at 4000C due to the partial reduction of Fe (III) to Fe (II). At 5500C, FeF₃ is oxidized to FeOF/Fe₂O₃.

Dec 13, 2022

By G. Coetzer

"Prior to operating a non-recovery coke pilot plant oven, it was essential to ascertain coal cake stability during the loading of a 1 m3 (1 m × 1 m × 1 m) coal cake into the cold pilot-plant oven by a pusher mechanism. Previously established laboratory-scale compaction parameters, to obtain coal cakes with sufficient stability, were employed during the loading tests of the coal cakes. Two different coals were evaluated, namely Waterberg semi-soft coking coal (sscc) and Oaky North hard coking coal.It was demonstrated that lower applied compaction forces (14%) can be utilized during 1 m3 compaction, in comparison to laboratory-scale tests, to obtain similar wet cake densities, owing to differences in the effect of frictional forces. Wet cake densities for Waterberg sscc improved slightly (3%) to 1.13 t/m3 when utilizing 79 t/m2 applied force for a 1 m3 coal cake, in comparison to laboratory-scale tests. Similar results were obtained for Oaky North hard coking coal, with a 6% density increase to 1.27 t/m3 at a similar applied force. Porosities decreased by 13% and 32% for Waterberg sscc and Oaky North coal, respectively, when 1 m3 compaction was compared to laboratory-scale tests. An opportunity exists to further decrease the porosities of Waterberg sscc during compaction, whereas acceptable compaction parameters were achieved for Oaky North hard coking coal. Most major vertical cracks and the partial collapse of coal cakes were mitigated, and high-stability coal cakes were obtained that could be successfully loaded into the pilot-plant coke oven by a pusher mechanism.Factors contributing to the instability of the coal cake during loading into the oven, such as vertical cracks, are (i) the cubic geometry (1 m3) of the coal cake, (ii) friction exerted by the oven floor, and (iii) mechanical problems, such as a misalignment between the pusher machine feeder plate and the oven floor. IntroductionOperation of the stamp-charging horizontal 1 t electrically heated coke pilot-plant oven at Exxaro Resources requires coal cake stability during the loading of a 1 m3 compacted coal cake into the oven. In this case, a pusher plate is utilized to push the coal cake into the oven over the oven floor. This is in contrast to a ‘spoon’ or bottom plate feeding mechanism as found in industrial horizontal coke ovens. The pusher plate loading mechanism dictates that the coal cake should possess high stability and inherent strength owing to frictional forces exerted by the oven floor. In order to obtain a coal cake of acceptable stability for the 1 t coke oven, various compaction parameters need to be verified and established."

Apr 1, 2019

By J. A. Sweet, T. BACHMANN, G. E. Sandoval, T. M. Hauyon, F. A. Contreras

In many respects a porphyry copper ore concentrator plant can be considered as a simple system. Chalcopyrite typically liberates well at relatively coarse sizes, and even low grade ores are amenable to upgrading 20 to 30 times to produce concentrate grades in excess of 25 % in very simple Rougher- Regrind-Cleaner+Scavenger flotation circuits. The flotation response of chalcopyrite has been well characterised in many fundamental and applied research studies and the conditions necessary to depress pyrite and other floating gangue species are well understood. But what happens to the particle surfaces when you have a 50 km pipeline between the grinding circuit and the flotation plant? How does the seasonal variation in water quality affect your ability to control pulp chemistry? What impact does the relative concentration of the different sulphide species have on their separability? Why do two plants that receive nominally the same ore produce consistently different results? And most importantly, what do you need to do to improve the performance of both plants? To answer these and other questions, a focussed sampling and analysis programme was carried out at the Las Tórtolas flotation plants in 2018 and 2019. The work included full down-the-bank sampling, hot floats, the use of radioactive tracers for determining residence time distribution profiles, gas dispersion measurements, detailed mineralogy by size across the circuits and multiple regrind surveys. This comprehensive study was augmented by analysis of historical mineralogy, geometallurgy and operating data using modern data science techniques, and has provided the foundation for current and future optimisation initiatives. Some of the findings and their implementation will be presented in this paper. Keywords: Circuit optimization, Residence time, Gas dispersion, Pulp chemistry

Jan 1, 2020

By T. H. Yang, Q. K. Wang, T. Song, J. W. Zhou

The grinding circuit can be one of the most important mineral processing circuits in plants. Along with the application of large-scale milling machines, the design and optimisation of the operation strategy for grinding circuits is more complicated. An in-house grinding process simulation tool was developed to mass balance, model fit and simulate crushing, grinding and classification circuits. An industrial grinding and classification circuit in a copper mine was modelled, and the modelling parameters were verified by a particular group of plant survey data. To justify the prediction ability of the fitted models, the model predictions under different operation conditions were compared with another group of plant survey data. Then the model predicted the effects on the circuit of changing operating conditions. Circuit analysis of the comminution process for water feed to a SAG mill, water feed to sump, the rolling speed of a SAG mill and the percentage of ball filling in a SAG mill was put into practise, based on the simulation results. The simulation results can be used to help plant operators understand the features of the comminution process and may help to build a knowledge library for process control. Keywords: Process modelling, grinding, comminution, circuit analysis

Jan 1, 2020

By A. N. Brown

The Eighteenth International Symposium on the Appli¬cation of Computers and Mathematics in the Mineral Industries was held in London from 26th to 30th March, 1984. The Symposium was organized by the Institution of Mining and Metallurgy under the leadership of Mr M.J. Cahalan, Chairman of the Organizing Committee. The venue chosen was the Royal School of Mines, Imperial College of Science and Technology, in South Kensington. Some 300 delegates from all parts of the world attended, which included a delegation from South Africa that numbered about 20 persons. This extremely successful series of international meet¬ings was begun in 1961 in Tucson, Arizona, and has grown in strength and importance over the years. The arrange¬ment of the symposia is regulated by the International Council for APCOM under the Chairmanship of Professor R.V. Ramani (U.S.A.), the other current members being Professor J. Elbrond (Canada), Dr Thys B. Johnson (U.S.A.), Professor Young C. Kim (U.S.A.), Professor D.G. Krige (R.S.A.), Professor A.J. Lynch (Australia), Professor C.T. Shaw (U.K.), Dr A. Weiss (U.S.A.), and Professor F.L. Wilke (F.R.G.). There is no doubt that the enthusiasm and dedication of this small group of people and the excellent working relationship that exists between them are responsible for the continued success of APCOM meetings.

Jan 1, 1984

The October General Meeting of the Institute was held in Kelvin House, Johannesburg, on Wednesday, 21st October, 1970, at 4.30 p.m. V. C. Robinson (President) was in the chair. There were also present 25 Fellows, including J. K. E. Douglas, Prof D. D. Howat, D. G. Maxwell, Dr R. E. Robinson, P. A. von Wielligh (Council Members). D. Ayres, G. Burrow, E. H. D. Carman, D. L. Carson, M. E. E. Douglas, S. A. Finney, W. R. Flook, A. J. Freemantle, W. A. Gilbert, E. B. Gordon, B. W. Gray, J. M. Jacobs, P. H. Kitto, C. H. Kruger, Dr P. J. D. Lloyd, D. G. Malan, W. Pilkington, W. G. Pyne-Mercier, K. S. Rae, W. T. Ruhmer, D. J. Tutt and D. T. Watt. Seven Members, including E. J. Dominy, S. I. du Preez, L. V. Grobler, D. R. Lings, G. D. Louw, J. S. A. Oelofse and O. B. Prentis. Fifteen Visitors, including J. R. Coppin, Dr A. Faure, P. E. Franzl, G. P. Hart, D. van Heerden, A. W. Hunt, A. R. F. MacDonald, B. G. Meyburgh, P. H. Radcliffe, J. M. Shirley, T. H. Tunley, A. D. Vellema and R. E. Wheeler. Secretary, D. C. Visser. Total present: 49. OBITUARIES The President: "It is my sad duty to announce the death of the following: Sir George Arthur Davenport, Honorary Life Fellow, who joined the Institute in 1930 and passed away on 17th September, 1970. The late Sir George was also, for many years, our corresponding member for Rhodesia. Andrew Malcolm Carmichael, Associate, who joined the Institute in 1944 and passed away on 22nd August, 1970. Cyril John Douglas Veal, Life Fellow, who joined the Institute in 1929 and passed away on 27th August, 1970. As a mark of respect to the memory of the deceased and in sympathy with the bereaved I would ask you all to rise and observe a few moments' silence." CONFIRMATION OF MINUTES The President: "May we confirm the minutes of the Annual General Meeting held on 26th August, 1970, and the minutes of the monthly general meetings which were held on the 20th of May and the 17th of June, 1970, as published in the August Journal." Agreed. MEMBERSHIP The President: "I have much pleasure in announcing that the names of the undermentioned candidates, having been published in accordance with By-Law 5.2.2., Council has elected them to membership of the Institute in the following grades: Members: Nikolaos Lalakakis, Gordon Phillips Rundle. Associates: Henry du Preez, James Robert Forbes, Johannes Stephanus Albertus Oelofse, Casper Vorster van Heerden. Graduates: Michael Harold Crosbie, Graham Robert Wallis Walker, Gary Walker Braithwaite. Students: Mohammad Ali Kazemzadeh, Gerhardus Petrus Benade. APPLICATIONS FOR TRANSFER From Graduate to Member: James Wormald. From Student to Graduate: Peter John Cook, Pieter Willem Greeff. "I welcome the newly elected members to the Institute and congratulate the members who have been transferred to a higher grade." PAPER FOR PRESENTATION The President: "This paper is entitled 'The Design, Erection and Operation of a Purlex Plant at Buffelsfontein Gold Mining Company Limited'. It is presented to the Institute by Mr B. G. Meyburgh, a visitor to our Institute. He is a graduate of the University of the Orange Free State and is the Uranium Plant Superintendent at Buffelsfontein and he, therefore, is in a very strong position to describe this very excellent job which is being done as he has been associated with this plant from the inception." After the presentation of the paper the President said: "Gentlemen, the paper you've heard from Mr Meyburgh is a very concise and interesting account of an important piece of work, and I think the title is so completely descriptive of the subject, which is admirably set out in the paper which you have heard. You probably haven't all had the opportunity of reading it, but you very soon will. I found it interesting to note that the results predicted were surpassed in the operation of the plant to date. The actual results obtained are significantly good, I think. Any process which, in this country, increases production and decreases costs, is to be welcomed, particularly when it is so necessary for South Africa almost to bend over backwards to utilise every avenue available in order to increase the scope of the production for overseas' markets, of her metallurgical and mineral potential. In lighter vein-and there is no reason why we should always be so serious-I am glad to see that, in a scientific journal like this, such words as the American word 'crud' which I have been picked out about so often, because my grandchildren use it, is now given an aura of respectability. Thank you very much, Mr Meyburgh, for an interesting paper. We have a long list of contributors, and I am not going to waste any more time. I am going to call on Mr Tunley of the N.I.M. for the first contribution." T. H. Tunley, P. de Bruyn (read by A. D. Vellema), E. J. Dominy, E. H. D. Carman, A. R. F. MacDonald D. C. Streicher (read by P. H. Radcliff), Dr A. Faure and Dr P. J. D. Lloyd then contributed to the discussion. (This discussion will appear in a later issue of the Journal.) The President: "I wish to thank members and visitors for their attendance, and now declare the meeting closed." The meeting closed at 6.05 p.m.

1. New books Australian Institute of International Affairs. Uranium - energy source of the future? Canberra, thelnstitute (Box E181, P.O., Canberra, A.C.T. 2600, Australia), 1979. 202 pp. A$4,95 (postage 50c). Euroeconomics. The steel industry in Western Europe.. industrial and financial indicators. Paris, Eurofinance (9 Avenue Hoche, 75008 Paris, France), 1979. 167 pp. FF4,500 (Available in English and French.) M. B. Piggott. Load-bearing composite materials. Oxford, Pergamon Press, 1979. $15,00. J. H. E. Olaf. Automation and remote monitoring and control in mines. Essen (West Germany), Verlag Gliickauf GmbH, 1979. 200 pp. DM36. (In English.) J. P. Jenkins and E. T. Brown (eds). KWIC index of rock mechanics literature. Oxford, Pergamon, 1979. 742 pp. £60. R. J. Wakeman (ed.). Progress in filtration and separation 1. Amsterdam, Elsevier, 1979. 346 pp. Dfl.llO,OO. 2. New journal As from 1980, Coal Calendar is being published as a separate monthly periodical. 3. Proceedings L. E. St Pierre and G. R. Brown (eds). Future sources of organic raw materials. Oxford, Pergamon, 1979. 612 pp. £22,50. P. Haasen, V. Gerold, and G. Kostorz (eds). Strength of metals and alloys. Oxford, Pergamon, 1979. 3 vols., 1800 pp. $200. K. J. Miller and R. F. Smith (eds). Mechanical behaviour of materials. Oxford, Pergamon, 1979. 3 vols., 1800 pp. U.S.$200. 4. Tax relief? The Publishers' Association of Great Britain recently issued a circular to a number of professional bodies drawing their attention to a court decision in favour of tax allowances on the purchase of textbooks. In January Electroheat The International Union for Electroheat, which com. prises a score of highly industrialized countries, every four years organizes a congress at which experts discuss the technicalities and economics of the latest applications of electroheat in industry and other sectors. Corrigenda: March issue The following amendments should be made to Table II of the paper 'Commodity analysis:

Jan 1, 1980

Council and Standing Committees, 1977-1978 President: P. A. von Wielligh. Vice-Presidents: Dr M. G. Atmore and D. A. Viljoen. Honorary Treasurer: J. K. E. Douglas. Immediate Past President, Dr M. D. G. Salamon. Members of Council: J. D. Austin, A. N. Brown, A. A. Hazell, Dr P. R. Jochens, Prof. R. P. King, Dr D. G. Krige, Prof. F. Q. P. Leiding, D. G. Malan, J. C. Mostert, H. G. M. Rose, W. T. Ruhmer, A. A. Sealey, R. A. von Maltitz. Chairman, Witbank-Middelburg Branch: T. S. Wilmot. Chairman, Orange Free State-Klerksdorp Branch: A. N. Shand. Past Presidents Serving on Council: R. J. Adamson, H. Britten, J. K. E. Douglas, Prof. D. D. Howat, Dr J. P. Hugo, D. G. Maxwell, Prof. R. P. Plowman, Dr R. E. Robinson, P. W. J. van Rensburg. Standing Committee Chairmen: Membership, D. A. Vil¬joen; Technical Programme - Metallurgy, Dr P. R. Jochens ; Technical Programme - Mining, Dr D. K. Krige ; Vacation School - Metallurgy, Prof. R. P. King ; Vacation School - Mining, Dr M. D. G. Salamon; Awards, Dr M. D. G. Salamon; Excursions, Dr M. G. Atmore; Adjudication, Dr M. D. G. Salamon; Consti¬tution, Rules, and Policy, Dr M. D. G. Salamon; Mines and Works, P. A. von Wielligh ; Education, Dr M. D. G. Salamon; Monograph Series, Dr R. E. Robinson; Phoenix National Committee, Dr R. E. Robinson ; Pyrometallurgical Discussion Group Convenor, Dr J. B. See/Dr D. I. Ossin.

Jan 1, 1979

By X. Xiang, W. Xia, J. Yin

"TiCl4 slurry containing valuable metals is an unavoidable by-product of the titanium ore chlorination process. The recovery of these valuable metals, which include titanium, niobium, tantalum, and aluminum, is an urgent issue to tackle in the titanium industry. The results of this investigation show that the valuable metallic elements can be recovered from the slurry by evaporation in a sealed container and leaching with dilute hydrochloric acid. After evaporation at 200°C for 60 minutes, nearly 99% of the titanium was recovered in the form of TiCl4, which was formed by the reaction of the TiO2 in the slurry with AlCl3. After evaporation, metals like niobium, aluminum, and tantalum remained in the residue. By leaching with 2.1 mol/L HCl at a L/S ratio of 6:1 mL/g at 80°C for 60 minutes, the soluble metals, such as aluminum, iron, and copper were all removed from the residue, and the niobium and tantalum were further enriched in the leach residue. A concentrate containing 53.40 wt% Nb and 5.57 wt% Ta was obtained by washing the leach residue with dilute aqueous ammonia under stirring. A potential waste water purifying agent containing 263.75 g/L AlCl3 was produced by purifying the leaching solution with Al(OH)3 and modified polyacrylamide. IntrodutionTitanium tetrachloride (TiCl4) is an important intermediate in titanium metallurgy that is widely used in the production of titania and titanium sponge (Akhtar, Xiong, and Pratsinis, 1991). In conventional titanium metallurgical processes, high-titanium materials such as synthetic rutile and high-titanium slag are reacted with chlorine to produce TiCl4 in a fluidized-bed furnace. Accompanying elements, such as Al, Nb, and Fe also react with chlorine to form chlorides, which are mixed with gaseous TiCl4 (Anderson, 1917). In the condensation process, gaseous TiCl4 is refrigerated and high-boiling-point chlorides are precipitated in the liquid TiCl4 to form a slurry containing 50~60 wt% TiCl4 (Wang, Xiang, and Wang, 2012).Various methods have been proposed to recover TiCl4 from the slurry, including microwave heating and spray drying (Wang, Xiang, and Wang, 2012, Wang et al., 2010a). To date, the only way to recover the TiCl4 is to return the slurry to the fluidized-bed furnace. However, this causes fluctuations in the temperature in the furnace, resulting in incomplete reaction between titanium-rich materials and chlorine. Therefore, the slurry is often rinsed with water and neutralized by adding lime, which caused serious environmental pollution and wastes a valuable resource (Roy, Bhatt, and Rajagopal, 2003)."

May 1, 2019

By A. Marek

The safe and optimal installation of roof support remains one of the biggest challenges in underground mining today. Traditional hand-held, roofbolt installation in conventional mining has been replaced, in a lot of mining operations, by mechanized equipment. This was a first step to moving the operators out of the unsafe working environment and a start on the trend toward a changed support regime in mechanized mining. However, the challenge of handling of the drill steel itself, as well as inserting resin cartridges and bolts, remains a major hazard and the cause of many lost-time injuries. The paper describes and discusses developments in this area, of mechanized bolting and on-board automation, presenting solutions to known problems, achievements to date, and future developments. The solutions presented will identify with addressing customer needs while touching on possibilities for further technology changes, keeping focus on the safety aspect for operators and the need to bring the operators even further away from the unsafe working environment. The-state-of-the-art technology in mechanized bolting equipment is presented and a brief outlook on the past, current, and future developments is given.

Jan 1, 2012

By I. Mc Dougall

Water-cooled copper tap-hole blocks provide an effective means of extending the life of tap-hole refractories, as the lower temperature of the refractory material inhibits wear and other damage and promotes the formation of a protective frozen slag layer. This is particularly beneficial during prolonged tapping cycles. The copper block forms an integral part of the lining, and provides mechanical support to the refractory, facilitating rapid replacement of tapping channel bricks without disturbing the surrounding lining. Safety considerations are an important design factor, and the positioning of the water channels is optimized to prevent leaks although the copper is not in direct contact with the molten fluids during normal operation. Water-cooled copper blocks designed by Tenova Pyromet have successfully been utilized on metal, matte, and slag tap-holes for a number of processes, including nickel, platinum group metals, and mineral wool.

Jan 1, 2014

By M. Wrobel, J. Hammerschmidt, M. Runkel

Fluid-bed technology is a key pyrometallurgical step for processing a vast number of ores and concentrates. Over the past 50 years, considerable research and development efforts have been made by Metso Outotec to expand the application window of this technology. This paper illustrates different processing routes where fluid-bed technology plays an important role in the production of the copper. The fluid-bed processes utilized are partial, sulfate-producing, and dead roasting. The focus of this paper considers the advantages of the dead-roasting process. This “zero waste” process can provide copper oxides, steam, electrical power, and sulfuric acid for new and existing solvent extraction–electrowinning plants. In a case where an operation is running out of oxidic ores and concentrates, fluid-bed roasting can be applied to close this gap and provide the required copper oxides in a sustainable way.

Jan 1, 2023

By R. J. Durrheim, Y. Yabe, M. S. D. Manzi, DSeis team, N. Z. Nkosi, S. B. Mngadi, Jr. H. Ogasawara

On 5 August 2014, the Orkney M5.5 earthquake, the largest in South African gold mining districts, occurred with an unusual strike-slip mechanism at great depth of 4.78 km below the surface. In a rare case, the ML 5.5 earthquake occurred within the area covered by the legacy 2D and 3D reflection seismic data acquired in the 1990s and 2000s for gold exploration and mine development. In addition, the earthquake ML 5.5 rupture plane was recorded and accurately delineated by the underground in-mine seismic network near the source region. The integration of the legacy 2D reflection seismic data and mine seismicity data allowed us to identify a near-vertical structure, striking northnorthwest-south southeast (NNW-SSE). The ICDP-DSeis team drilled three holes (Hole A, Hole B, and Hole C), and two holes (Hole B and Hole C), intersected the upper edges of the ML 5.5 rupture. These holes recovered metasediments, metabasalts, intrusive rocks including dolerite sills and lamprophyre dykes adjacent to the fault zone, and the fault gouge. Late Prof. Tullis Onstott and geomicrobiologists installed a packer in Hole A and successfully recovered saline water and detected gas (~10 MPa). Slip weakening and rupture propagation are significantly influenced by the existence of fault gouges and the production of wear material between two sliding rock surfaces. Using the fault gouge material recovered from Hole C, we conducted friction experiments under dry and room temperature conditions at high slip velocity of ~100 mm/s and normal stress of 2 MPa. The resulting steady-state frictional strength was ~0.66 over a slip weakening distance of ~9.1 m. The steady-state frictional strength was high, which may be caused by large gouge thickness, and the rate of wear generation. As a result, it is proposed that the Moab Khotsong ML 5.5 seismogenic zone is complex and could be controlled by three main processes: a) the complex structural architecture of the seismogenic zone (e.g., intersection of fault, lamprophyre dykes, and dolerite sills); b) the mechanical process induced by tectonic and/or mining related stresses; and c) the mechanical and chemical processes caused by the water and rock interaction.

Jan 12, 2025

By D. F. Malan, U. Du Preez, P. S. Heyns

South Africa has two main platinum reef deposits, namely the Merensky reef and the UG2 reef. These reefs are currently mined using traditional drilling and blasting methods. Mechanized cutting could potentially enable continuous mining, which would offer significant advantages. This would require thorough understanding of the cutability of the rock. To explore this, a linear cutting machine was developed to conduct laboratory scale cutting tests. This work describes the development and commissioning of the cutting machine using sandstone, as well as subsequent characterization tests on UG2 reef samples. UG2 reef has large variability in strength on a millimeter scale. This introduces uncertainty in the test results due to added variance from one cut to the next for the same UG2 reef sample. Another problem is the variability in rock properties of the UG2 reef, when testing samples from different mines. The cutting tests led to fine fragmentation, which is known to be a significant problem for cleaning operations in underground stopes and warrants further research. A finite element method simulation of the rock cutting was conducted using ANSYS LS-DYNA and the continuous surface cap model to simulate rock cutting in the UG2 reef. It was found that it is possible to use LS-DYNA with the continuous surface cap model to model rock cutting of UG2 reef and get acceptable results, but the user must calibrate the model parameters using the experimental results. Therefore, the model is only fit for one set of cutting parameters and further work is required to generalize results.

Nov 27, 2024

By S. Fuchida, Y. O. Zubair, C. Tokoro

Mining of As-bearing minerals had resulted in the release of arsenic species predominantly As(III), which is known to be more toxic, and undue exposure to it is detrimental to human organ systems. Many materials have been examined for As(III) removal, but it is still challenging to advance sustainable materials for effective removal of As(III). In this paper, a more eco-friendly and superparamagnetic Fe0-Fe3O4 composite was synthesised and evaluated for heterogeneous catalytic oxidation and removal of As(III) with peroxymonosulfate (PMS, KHSO5). The kinetic removal studies showed that removal of As(III) was probably through a chemical process and the Elovich model best represented the experimental data. The removal capacity for As(III) on Fe0-Fe3O4 with PMS (1.76 mmol/g) is superior to that without PMS (0.83 mmol/g). Combined results from XPS and ESR showed that As(III) was fully transformed to As(V) through catalytic oxidation by Fe0-Fe3O4/PMS and afterwards enhanced its removal. The removal mechanism of arsenic was ascribed to the formation of outer-sphere (electrostatic attraction) and inner-sphere complexes. The adsorbent can be separated easily from water due to its excellent magnetisation (64.5 emu/g) and also has good reusability potential as more than 85% of the initial concentration of As(III) was immobilised after five consecutive cycles. Keywords: Arsenite, Fe0-Fe3O4 composite, catalytic oxidation, removal mechanism

Jan 1, 2020

1. Book reviews Perspectives in metallurgical development. London, The Metals Society. 338 pp. £29. Reviewer: John V. Bee Mechanics of oil shale, edited by K.P. Chong and J.W. Smith. London, Elsevier Applied Science Publishers Ltd, 1984. 603 pp. £75. Reviewer: R.W.O. Kersten 2. Recent publications CANADIAN MINERAL POLICY SECTOR. Metallurgical works in Canada. Primary iron and steel 1984. Mineral Bulletin MR 203. Ottawa, Canadian Government Publishing Centre, Supply and Services, 1985. $6.00. Tin and its uses no. 143. Greenford (England), International Tin Research Institute, 1985. Mining 1985, edited by Diana Russell. Harlow England), Longman Group Ltd, 1985. 540 pp. £46. The following books are available from CRC Press, Inc., 2000 Corporate Boulevard N.W., Boca Raton, Florida 33431, U.S.A. Inorganic ion exchange materials, edited by A. Clearfield. 304 pp. $100. Polyurethane foam sorbents in separation science, by T. Braun. $80. Advanced particulate morphology: theory and practice, by J.K. Beddow and T.P. Melloy. 208 pp. $79. CRC handbook of atomic absorption analysis, edited by A. Varma. 2 vols: vol. I $114, vol 11 $102. CRC handbooks of inorganic elecrochemistry, edited byL. Meites, P. Zuman, E.B. Rupp, andA. Narayanan. 3. Mintek reports Report M169 The preparation of three South African coals for as reference materials. Report M190 The preparation and certification of a South African phosphate concentrate for use as a reference material. Report M191 The agglomeration of fine material for bacterial heap leaching. Report M197 A computer programme to monitor the performance of an X-ray-fluorescence spectrometer. Metallurgical award The 1984 Acta Metallurgica Gold Medal has been awarded to Professor John W. Christian of Oxford University. The medal is an international award that was established in 1974 to recognize outstanding ability and leadership in materials research. Proterozoic volcanic suites An international symposium will be held at the British Geological Survey, Keyworth, Nottingham, U.K., from 2nd to 5th April, 1986. Entitled 'Geochemistry and Mineralisation of Proterozoic Volcanic Suites', this special meeting of the Geological Society will discuss the geochemical evidence for the nature of volcanism during the Proterozoic. Powder metallurgy Every second year the International Powder Metallurgy Conference, the world's leading event in powder metallurgy, is organized and held alternately in North America and Eruope.

Jan 1, 1985

By F. Rosenblum, K. E. Water, J. A. Finch, S. Moon, Y. H. Tan

Previous work has shown that sulphide self-heating occurs in three distinct stages referred to as Stage A, Stage B and Stage C. In this paper the focus is on the transition from Stage A to Stage B, which occurs at ca. 100OC. Background literature hints that the transition corresponds to the transformation of the rhombic form of elemental sulphur to the more reactive monoclinic form that occurs at 96OC. A test apparatus is modified for adiabatic heating to track the transition. The results support this transformation of sulphur as being key to the transition, and the transition temperature is thus modified to 96OC. Variations in a sample’s response under adiabatic conditions are observed and possible reasons are discussed. Testing in adiabatic mode provides new insights into the sulphide self-heating process that complement the test designed to identify propensity to self-heat. Keywords: Self-heating; Stage A/Stage B; transition; rhombic/monoclinic elemental sulphur; adiabatic heating

Jan 1, 2020

By N. E. K. Schuttler

Experience with Mars pumping of underground water by N. E. K. SCHUTTLER (Visitor) As the result of a planned increase in production, Vaal Reefs Exploration & Mining Company Limited increased the hoisting capacity of their existing equipment to its fullest extent and installed Mars pumps and a washing plant. The layout of the installation is described, and details are given of the modifications made to overcome its weaknesses. Plans to change the present four-stage system to a seven-stage system are outlined.

Jan 3, 1977

By B. N. Soutar

The design and operation of a double- V compartment vertical-flow settler by B. N. SOUTAR, B.Sc. (Mech. Eng.) Wits. (Visitor) This paper describes the development of a vertical-flow settler for underground pumping installations in the mines of Gold Fields of South Africa Ltd. The recommended settler employs the principle of 'dynamic filtration': the solids that are in suspension in mine water are filtered through a stable horizontal bed of flocculated particles, a technique that was established in about 1958.

Jan 3, 1977

By A. K. Raji, E. F. Orumwense, M. O. Ojumu

This research paper introduces a novel passive method for ocean mining using an electricpowered robotic subsea dredging crawler designed to operate in various subsea conditions, including unstructured and rough terrain. The electric-powered robotic subsea dredging crawler is equipped with two driving tracks and features a complex assembly of tank tread chain link, tank tread idler wheels, tank tread sprockets, bronze bushings, motor hub, motor mount, and a 12-volt direct current motor. To evaluate the performance of the electric-powered robotic subsea dredging crawler, it was compared with existing ocean hydraulic exploration crawlers, such as MK3 ROST, in terms of drive performance on an inclined ramp with five angles of inclination (0°, 15°, 20°, 25°, 30°). The experiment aimed to determine the maximum velocity, torque, and efficiency of the crawler at different angles of inclination. The collected data were analysed and plotted using Python, and the effect of the electric-powered robotic subsea dredging crawler’s weight on its driving performance was also considered. The results of this study demonstrate a quadratic relationship between driving performance and inclination angle, which can be used to optimise the electric-powered robotic subsea dredging crawler’s performance for future ocean mining robot drive applications.

Oct 2, 2025